APPROVAL SHEET

Complete report of Physical Chemistry I Experiment entitled

“Determination The Equilibrium Constants of Triodide Ion” that arranged by:
name : Nur Akifah Pardan
id : 1813442002
class : ICP of Chemistry Education
group : IV (Four)
Has been checked by assistant and assistant coordinator so this report is accepted

Makassar, April 2021

Assistant Coordinator, Assistant,

Putri Sarimurti Yuliana

ID. 1613142009 ID. 1713142006

Known By
Responsibility Lecturer

Diana Eka Pratiwi, S.Si.,M.Si

ID. 198006 14200801 2 016
A. TITLE OF EXPERIMENT
Determination The Equilibrium Constants of Triodide Ion

B. OBJECTIVE OF EXPERIMENT
To determine equilibrium constants of triodide ion formation reaction.

C. LITERATUR REVIEW
Chemical reactions tend to move towards a dynamic equilibrium in which
both reactants and products are present but have no further tendency to undergo
net change. In some cases, the concentration of products in the equilibrium
mixture is so much greater than that of the unchanged reactants that for all
practical purposes the reaction is ‘complete’. However, in many important cases
the equilibrium mixture has significant concentrations of both reactants and
products. In this chapter we see how to use thermodynamics to predict the
equilibrium composition under any reaction conditions. Because many reactions
of ions involve the transfer of electrons, they can be studied (and utilized) by
allowing them to take place in an electrochemical cell. Measurements like those
provide data that are very useful for discussing of ionic equilibria in solution
(Atkins and Julio, 2006: 200).
Responsiveness of a glass electrode to the hydrogen ion activity is a result
of complex processes at the interface between the glass membrane and the
solutions on either side of it. The membrane itself is permeable to Na+ and Li+
ions but not to H+ ions. Therefore, the potential difference across the glass
membrane must arise by a mechanism different from that responsible for
biological transmembrane potentials. A clue to the mechanism comes from a
detailed inspection of the glass membrane, for each face is coated with a thin layer
of hydrated silicar. The hydrogen ions in the test solution modify this layer to an
extent that depends on their activity in the solution, and the charge modification of
the outside layer is transmitted to the inner layer by the Na+ and Li+ ions in the
glass. The hydrogen ion activity gives rise to a indirect mechanism (Atkins and
Julio, 2010: 239).
 The principal business of this chapter is to establish the thermodynamic
relations obeyed by two or more phases that are at equilibrium with each other. A
phase is a portion of a system (or an entire system) inside which intensive
properties do not change abruptly as a function of position. The principal kinds of
phases are solids, liquids, and gases, although plasmas (ionized gases), liquid
crystals, and glasses are sometimes considered to be separate types of phases.
Solid and liquid phases are called condensed phases and a gas phase is often
called a vapor phase. Several elements such as carbon exhibit solid-phase
allotropy. For the example, diamond and graphite are both solid carbon, but have
different crystal structures and different physical properties.With compounds, this
phenomenon is called polymorphism instead of allotropy. Most pure substances
have only one liquid phase, but helium exhibits allotropy in the liquid phase
(Mortimer, 2008: 200).
A reaction for which ΔrG < 0 is called exergonic (from the Greek words
for work producing). The name signifies that, because the process is spontaneous,
it can be used to drive another process, such as another reaction, or used to do
non-expansion work. A simple mechanical analogy is a pair of weights joined by
a string the lighter of the pair of weights will be pulled up as the heavier weight
falls down. Although the lighter weight has a natural tendency to move
downward, its coupling to the heavier weight results in it being raised. In
biological cells, the oxidation of carbohydrates act as the heavy weight that drives
other reactions forward and results in the formation of proteins from amino acids,
muscle contraction, and brain activity. A reaction for which ΔrG > 0 is called
endergonic (signifying work consuming). The reaction can be made to occur only
by doing work on it, such as electrolysing water to reverse its spontaneous
formation reaction. Reactions at equilibrium are spontaneous in neither direction:
they are neither exergonic nor endergonic (Atkins and Julio, 2006: 202).
Consider a one-phase system that has a uniform temperature and pressure
but a nonuniform composition. Imagine dividing the system into small regions
(subsystems), each one of which is small enough so that the concentration of each
substance is nearly uniform inside it. Any substance will move spontaneously
from a subsystem of higher value of its chemical potential to an adjacent
subsystem with a lower value of its chemical potential. The fundamental fact of
phase equilibrium for nonuniform systems can be stated: In a system with uniform
temperature and pressure, any substance tends to move from a region of higher
chemical potential to a region of lower chemical potential (Mortimer, 2008: 202)
The starch indicator is an indicator that is very commonly used during this
iodometric titration. The determination of the end point of the titration can occur
because a complex is formed starch I2 which is dark blue. This is because in a
starch solution, there are glucose units that form a helical chain because of the
bonds configuration on each glucose unit. This form causes starch to get form
complexes with iodine molecules that the can enter the spiral. So that it causes the
complex dark blue color (Yolla and Fitri, 2020: 4).
Fluid Phase Equilibria publishes high-quality papers dealing with
experimental, theoretical, and applied research related to equilibrium and transport
properties of fluids, solids, and interfaces. Subjects of interest include
physical/phase and chemical equilibria; equilibrium and nonequilibrium
thermophysical properties; fundamental thermodynamic relations; and stability.
The systems central to the journal include pure substances and mixtures of organic
and inorganic materials, including polymers, biochemicals, and surfactants with
sufficient characterization of composition and purity for the results to be
reproduced. In all cases, enough detail must be given to permit independent
verification, and authors are also expected to provide physical or chemical
interpretations of the results (Economou et all, 2019: 5)
The number of components is also equal to the number of substances from
which the system could be prepared, given the conditions imposed on the system.
A mixture of gaseous hydrogen, oxygen, and water vapor can remain unreacted
for a very long time at room temperature if no catalyst is present.We can treat this
metastable mixture as if no reaction were possible and say that there are three
components. If a platinum catalyst is introduced into the system, a chemical
equilibrium is rapidly established, reducing the number of components to two (not
counting the catalyst). In the presence of the catalyst the amount of water vapor is
determined by the amounts of hydrogen and oxygen and the nature of the
chemical equilibrium. If the additional constraint is added that the hydrogen and
oxygen are in the stoichiometric ratio of 2 moles to 1, then the system has only
one component. In this case the system could be produced from water vapor in the
presence of the catalyst (Mortimer, 2008: 203).
The existence of equilibrium between the liquid and solid phase is well
described by sorption isotherms. Equilibrium studies that give the capacity of the
sorbent and the equilibrium relationships between sorbent and sorbate are
described by sorption isotherms which are usually the ratio between the quantity
sorbed and the remaining in solution at fixed temperature at equilibrium. Sorption
isotherms are important in describing how solutes interrelate with the sorbents and
so is critical in optimizing the use of sorbents. Equilibrium data collected were
fitted into the well-known Langmuir, Freundlich, and Dubinin-Raduskevich
sorption isotherm models, with the assumption of crude oil being a mono-
component system and thereby eliminating the possibility of multicomponent
competition. These isotherm models are depicted. The isotherms yield constants
whose values express the affinity of sorbate for the surface of sorbent (Thomso et
all, 2015: 2).
In the cell, each ATP molecule can be used to drive an endergonic reaction
for which ΔrG⊕ does not exceed +31 kJ mol−1. (In an actual cell the
composition may be far from standard, and the ATP reaction might be much more
potent.) For example, the biosynthesis of sucrose from glucose and fructose can
be driven by plant enzymes because the reaction is endergonic to the extent
ΔrG⊕ = +23 kJ mol−1. The biosynthesis of proteins is strongly endergonic, not
only on account of the enthalpy change but also on account of the large decrease
in entropy that occurs when many amino acids are assembled into a precisely
determined sequence. For instance, the formation of a peptide link is endergonic,
with ΔrG⊕ = +17 kJ mol−1, but the biosynthesis occurs (Atkins and Julio, 2010:
212)
Computations of the application of the homogeneous model to vapor-
liquid flow for predicting the transient performance of a heat exchanger is
presented. The simulation of the model is capable of predicting distributions of
the refrigerant temperature in both position and time domain without solving large
number of nonlinear algebraic equations. The dynamic behavior of the heat
exchanger is investigated with a step increases and step decreases in the inlet
refrigerant flow rate after obtaining steady state which results in variation of time
steps and two phase length that is clearly obtained by using the present simulation.
This knowledge of the dynamic characteristics of a heat exchanger is important to
the design and air-conditioning and refrigeration system (Malthora, 2016: 8)
The conclusion that K is independent of pressure does not necessarily
mean that the equilibrium composition is independent of the pressure, and its
effect depends on how the pressure is applied. The pressure within a reaction
vessel can be increased by injecting an inert gas into it. However, so long as the
gases are perfect, this addition of gas leaves all the partial pressures of the reacting
gases unchanged: the partial pressures of a perfect gas is the pressure it would
exert if it were alone in the container, so the presence of another gas has no effect.
It follows that pressurization by the addition of an inert gas has no effect on the
equilibrium composition of the system (provided the gases are perfect).
Alternatively, the pressure of the system may be increased by confining the gases
to a smaller volume (that is, by compression). Now the individual partial pressures
are changed but their ratio (as it appears in the equilibrium constant) remains the
same. Consider instance, A 5 2 B, for which the equilibrium constant (Atkins and
Julio, 2006: 210)
Equilibrium constant value (K) is directly proportional to the conversion
(X). On Reversible exothermic reaction, when temperature is increased (T2> T1),
then the value of K will decrease (K2 <K1) so that X2 <X1. On reaction
exothermic reversible, the higher the temperature the equilibrium conversion will
be the smaller (Principle Le Chatelier). The speed of this epoxidation reaction
expressed by the conversion of iodine (IV) numbers. In this research, a process
was carried out oleic acid epoxidation to see the effect temperature against the
reaction based conversion thermodynamics and equilibrium review chemistry
(Malthora, 2016: 11).
 Reaction to the formation of performic acid in situ (equation 1) is a
reaction reversible and exothermic (reaction to the right exothermic while the
reaction to the left is endothermic). Shift in the equilibrium reactionchemistry is
influenced, among other things, by the temperature of the reaction. Chemical
equilibrium occurs when velocity the reaction to the right is the same as the
reaction rate to the left. When in an exothermic change in reaction temperature,
then the chemical reaction equilibrium will direction of the endothermic reaction
(towards the left), so that the product formed is reduced (Maisaroh and Purwanto,
2019: 9).

D. APPARATUS AND CHEMICALS

1. Apparatus
a. Funnel (1 piece)
b. Burette 50 mL (1 piece)
c. Stative and clamp (1 piece)
d. Graduated cylinder 250 mL (1 piece)
e. Graduated cylinder 50 mL (1 piece)
f. Graduated cylinder 10 mL (1 piece)
g. Erlenmeyer flask with lid 250 mL (3 pieces)
h. Erlenmeyer flask 250 mL (3 pieces)
i. Separating funnel 500 mL (1 piece)
j. Rough cloth (1 piece)
k. Soft cloth (1 piece)
l. Stopwatch (1 piece)
2. Chemicals
a. Potassium iodide solution 0.1 M (KI)
b. Saturated solution of I2 in CHCl3 (I2 in CHCl3)
c. Sodium thiosulfate solution 0.02 M (Na2S2O3)
d. Aquadest (H2O)
e. Tissue
f. Label
E. WORK PROCEDURES
a. 10 mL of I2 in CHCl3 was put into graduated cylinder after that put into
separating funnel
b. 100 mL of KI was put into graduated cylinder after that added into
separating funnel
c. Shake until 30 minutes
d. The solution was separated between top layer and bottom layer
e. 2.5 mL of each layer was inserted into the erlenmeyer flask
f. Na2S2O3 was put into the beaker glass after that put into the burette
g. Titrated the bottom layer and top layer with Na 2S2O3. The volume of
Na2S2O3 was recorded

F. OBSERVATION RESULT
No Activity Result
1 10 mL of I2 in CHCl3 was put into separating Purple solution
funnel
2 100 mL of KI was put into separating funnel Colorless solution
3 Shake until 30 minutes Formed two layers
4 After being formed two layers Top layer : Brown solution
Bottom layer : Purple
solution
5 2,5 mL of top layer was inserted into the Brown solution
erlenmeyer flask
(I2 in H2O solution)
6 2,5 mL of bottom layer was inserted into the Purple solution
erlenmeyer flask
(I2 in CHCl3 solution)
7 Top layer was titrated with Na2S2O3. V1 = 1,4 mL
V2 = 1,1 mL
V3 = 1,2 mL
8 Bottom layer was titrated with Na2S2O3. V1 = 2,5 mL
V2 = 3,7 mL
G. DATA ANALYSIS
Known:
M Na2S2O3. = 0,02
V I2 in H2O solution = 2,5 mL = 0,0025 mL
V I2 in CHCl3 solution = 2,5 mL = 0,0025 mL
V Na2S2O3. of titration I2 in H2O solution
Titration I = 1,4 mL
Titration II = 1,1 mL
Titration III = 1,2 mL
V Na2S2O3. of titration I2 in CHCl3 solution
Titration I = 2,5 mL
Titration II = 3,7 mL
Asked = K : ….?
Solution :
The reaction : 2 Na2S2O3. + I2 2NaI + Na2S4O6.
1. Bottom layer (I2 in CHCl3 solution)
2,5 mL+3,7 mL
Average volume of Na2S2O3. =
2
= 3,1 mL = 0,0031 L
Mol of Na2S2O3. = M Na2C2O3 x M Na2S2O3.

= 0,02 mol/L x 0,0031 L

= 6,2 x 10-5 mol

asked coefficient
Mol I2 in CHCl3 solution = x known mol
known coefficient
1
= x 6,2 x 10-5 mol
2
= 3,1 x 10-5 mol
So concentration of I2 in CHCl3 solution is:
mol I 2 ∈CHCl 3
[I2] CHCl3 =
V I 2 ∈CHCl3
 3,1 x 10−5 mol
=
0,0025 L
= 1240 x 10-5 M
2. Top layer (I2 in H2O solution)
1,4 mL+1,1 mL+ 1,2mL
Average volume of Na2S2O3. =
3
= 1,23 mL = 0,00123 L
Mol of Na2S2O3. = M Na2C2O3 x M Na2S2O3.

= 0,02 mol/L x 0,001233 L

= 2,46 x 10-5 mol

Mol I2 in H2O solution
So concentration of I2 in H2O solution is:
[I2] H2O
asked coefficient
= x known mol
known coefficient
1
= x 2,46 x 10-5 mol
2
= 1,23 x 10-5 mol
mol I 2 ∈CHCl 3
=
V I 2 ∈CHCl3

1,23 x 10−5 mol

=
0,0025 L
= 492 x 10-5 M
3. Coefficient Distribution (CD)
[ I 2 ] CHCl3
Coefficient Distribution (CD) =
[ I2 ] H 2 O
1240 x 10−5 M
=
492 x 10−5 M
= 2,52 x 10-5
4. Calculate [I3-] H2O
[I3-] H2O = b - [I3-] H2O
 n
b=
V
1 mL Na2S2O3 0,02 M = 124 x 10-5 mol I2
0,1 mL Na2S2O3 0,02 M = 0,1 mL x 1240 x 10-5 mol I2
= 12,4 x 10-5 mol I2
0,1 mL x 12,4 10−5 mol I 2
b =
2,5 x 10−2 L
12,4 x 10−6 mol I 2
b =
2,5 x 10−2 L
b = 4,96 x 10-4 M
[I3-] H2O = b - [I2] H2O
= 4,96 x 10-4 M – 4,92 x 10-5
= 4,96 x 10-4 M – 0,492 x 10-4 M
= 4,468 x 10-4 M
5. Calculate [I-] H2O
[I-] H2O = [I-] H2O initially - [I3-] H2O
= 0,1 M – 4,468 x 10-4 M
= 1000 x 10-4 M – 4,468 x 10-4 M
= 995,532 x 10-4 M
= 0,0995 M
6. Calculate Equilibrium Constant (K)
K = ¿¿
4,468 x 10− 4 M
=
49,2 x 10−4 M x 0,0995 M
4,468 x 10−4
=
0,4445 x 10−4 M
= 10,051 M-1

H. DISCUSSION
Ekstraksi yaitu kegiatan penarikan kandungan kimia yang dapat larut
sehingga mampu terpisah dari bahan yang tidak dapat larut dengan pelarut yang
cair (Kuspendy et all, 2017:5). Secara umum, ekstraksi ialah proses penarikan
suatu zat terlarut dari larutannya di dalam air oleh suatu pelarut lain yang tidak
dapat bercampur dengan air. Iodium, I2, sedikit larut di dalam air namun larut di
dalam air yang mengandung ion I-, misalnya dalam larutan KI. I2 dan I- dalam
larutan air akan membentuk ion triodida, I3- dan reaksinya merupakan reaksi
kesetimbangan. Adapun reaksinya:
I2(g) + I(aq) I3-
(Penuntun Praktikum Kimfis 1, 2021: 21)
Misal dalam suatu reaksi kesetimbangan: 
pA  +  qB          rC + sD

Maka di dapatkan tetapan kesetimbangan Tetapan Kesetimbangan Konsentrasi:

[C ]r [D] s
Kc = p q
[ A ] [ B]

(Atkins and Julio, 2006: 118)

Seperti yang diketahui bersama bahwa ada beberapa faktor yang
mempengaruhi kesetimbangan kimia yaitu perubahan konsentrasi, perubahan
tekanan, perubahan volume dan perubahan suhu (Fikri, 2014: 3). Dalam
percobaan penentuan tetapan kesetimbangan ion triodida, kesetimbangan ini
berlangsung dalam larutan air, untuk itu perlu menghitung konsentrasi-konsentrasi
yang bersangkutan dalam air. Dari percobaan penentuan tetapan distribusi di atas
dapat dihitung nilai Kd, kemudian dengan rumus:
[ I2 ] H 2 O
Kd =
[ I 2 ] CCl 4
Dapat dihitung konsentrasi [I2]H2O dengan melalui persamaan [I2]H2O = Kd
[I2]CCl4 dan selanjutnya rumus tersebut dapat dihitung dengan rumus [I3-]H2O dan
[I-]H2O (Penuntun Praktikum Kimfis, 2021: 21)
Percobaan ini bertujuan untuk menentukan tetapan kesetimbangan reaksi
pembentukan ion triodida. Kesetimbangan kimia terjadi apabila laju reaksi maju
dan laju reaksi balik sama besar dengan konsentrasi reaktan dan produk tidak lagi
berubah seiring berjalannya waktu. Percobaan ini menggunakan titrasi iodometri.
Dimana titrasi iodometri merupakan titrasi dengan menngunakan bahan
pengoksidasi yang mengoksidasi Kalium iodide (KI) dalam suasana asam,
sehingga Iod yang dibebaskan kemudian ditentukan dengan menggunakan larutan
baku Natrium tiosulfat (Nadia et all, 2014:2)
Prinsip dasar percobaan ini yaitu distribusi zat terlarut I2 dalam dua pelarut
yang tidak saling bercampur yaitu air dan kloroform (Hukum Distribusi Nernst).
Sedangkan prinsip kerja percobaan ini yaitu pengukuran, pencampuran,
pengocokan, pemisahan dan titrasi. Nilai KD dalam percobaan ini perlu diketahui
untuk mengetahui banyaknya I2 yang terdistribusi ke dalam pelarut organik dan
air. I2 dalam CHCl3 akan terekstraksi ke dalam larutan KI kemudian akan
ditentukan tetapan kesetimbangan pembentukan I3- (ion triodida). Selanjutnya
untuk dapat menentukan konsentrasi yang nantinya akan dipakai dalam penentuan
terekstraksi dalam KI. Iodin yang terbentuk akan ditentukan dengan menggunakan
larutan baku natrium tiosulfat (Nadia et all, 2014: 7).
Percobaan ini dilakukan dengan cara mencampurkan I2 dalam CHCl3
dengan larutan kalium iodida (KI) dalam corong pisah. Dimana penambahan KI
berfungsi sebagai penyedia ion iodide I- yang kemudian akan bereaksi.

Gambar A: Gambar B: Gambar C: Pencampuran

Penambahan 10 mL Penambahan 100 10 mL I2 dalam CHCl3
I2 dalam CHCl3 mL KI dengan 100 mL KI

Campuran I2 dalam CHCl3 dengan KI dalam corong pisah kemudian dikocok yang
berfungsi untuk mempercepat proses distribusi I2 dalam kloroform dan air. Prinsip
dasar corong pisah yaitu memisahkan campuran berdasarkan perbedaan sifat
kepolaran dan massa jenis zat dalam campuran dan prinsip kerjanya yaitu dengan
menambahkan pelarut pengekstraksi yang tidak bercampur dengan pelarut semula,
kemudian dilakukan pengocokan sehingga terjadi kesetimbangan konsentrasi zat
yang akan diekstraksi pada kedua lapisan, setelah itu tercapai maka lapisan
didiamkan kemudian dipisahkan (Febrianti et al, 2019: 13). Saat pengocokan
dilakukan sekali-kali mulut corong dibuka dengan tujuan untuk mengurangi
tekanan dalam corong pisah yang apabila tidak dilakukan dapat menyebabkan
kerusakan pada corong pisah selama proses pengocokan berlangsung.

Gambar D: Proses pengocokan pada

larutan campuran I2 dalam CHCl3 dengan
KI dalam corong
Setelah itu, larutan didiamkan pisah
sehingga terbentuk dua lapisan. Lapisan
bawah adalah kloroform dan pada lapisan atas adalah air. Terbentuknya dua
lapisan tersebut disebabkan karena adanya perbedaan kepolaran antara air dan
kloroform. Dimana air bersifat polar, sedangkan kloroform bersifat nonpolar.
Lapisan atas adalah air dan lapisan bawah adalah kloroform dikarenakan air
memiliki massa jenis lebih kecil dibandingkan dengan kloroform. Massa jenis air
sebesar 1 g/mL, sedangkan massa jenis kloroform yaitu 1,48 g/mL (Fikri, 2014:
11).

Gambar E: Proses pemisahan dua lapisan

antara air dan kloroform

Adapun reaksi yang terjadi yaitu:

KI(aq) K+(aq) + I-(aq)

 I-(aq) + I2(aq) I3-(aq)

Percobaan ini menggunakan titrasi iodometri. Dimana titrasi iodometri

merupakan titrasi tidak langsung, yaitu I2 yang digunakan terlebih dahulu
direaksikan dengan larutan KI. Lapisan-lapisan yang terbentuk dalam percobaan
ini masing-masing dikeluarkan pada wadah yang berbeda masing-masing lapisan
tersebut dititrasi dengan Na2S2O3 hingga berwarna bening lapisan atas berwarna
bening, lapisan atas berwarna coklat dan lapisan bawah berwarna ungu.
Lapisan atas dalam (I2 dalam H2O) dan lapisan bawah (I2 dalam CHCl3)
yang dititrasi dengan larutan Na2S2O3 tidak menggunakan indikator amilum, hal
ini dikarenakan I2 banyak terdistribusi kedalam kloroform dibandingkan air, dan
juga dengan sifat I2 sebagai autoindikator bagi dirinya sendiri, maka tidak
dilakukan proses penamabahn indikator amilum. Adapun reaksi yang terjadi yaitu:

Gambar F: Lapisan atas Gambar G: Lapisan atas

Proses titrasi diperoleh volume rata-rata natrium tiosulfat yaitu untuk
lapian atas (I2 dalam H2O) sebesar 1,23 mL dan untuk lapisan bawah (I2 dalam
CHCl3) sebesar, 3,1 mL. Hal ini menunjukkan bahwa distribusi I2 lebih banyak ke
lapisan kloroform dibandingkan lapisan air. Berdasarkan hasil tersebut, dapat
diketahui bahwa I2 terdistribusi lebih banyak ke dalam lapisan bawah (I2 dalam
CHCl3) dibandingkan pada lapisan (I2 dalam H2O). Hal ini sesuai dengan nilai
koefisien distribusi (Kd) yang diperoleh berdasarkan hasil analisis data, dimana
nilai Kd yang diperoleh pada percobaan ini adalah 2,52 x 10 -5 yang artinya nilai
Kd < 1. Hal ini tidak sesuai dengan teori yang menyatakan bahwa jika harga Kd
besar (> 1), solute secara kualitatif akan cendrung terdistribusi lebih besar atau
banyak ke dalam pelarut organik begitu pula dengan hal yang sebaliknya
(Castellan, 1998:312). Hal ini disebabkan karena pada larutan pelarut kloroform
yang mudah menguap yang tidak langsung dimasukkan kedalam corong pisah
sehingga kloroform sedikit menguap. Dari hasil analisis data yang diperoleh
tetapan kesetimbangan reaksi pembentukan ion triodida (K) sebesar 10,051 M-1
yang menunjukan bahwa produk triodida yang diperoleh jumlahnya sangat
sedikit. Hal ini tidak sesuai dengan teori yang menyatakan bahwa tetapan
kesetimbangan pembentukan ion triodida sebesar 710 M (Day and Underwood,
1999: 296). Perbedaan tersebut dikarenakan adanya perbedaan suhu kamar yang
digunakan dan distribusi iod yang tidak merata. Adapun Persamaan reaksinya
yaitu:
- Lapisan atas [I2]H2O
Oksidasi : 2 S2O32- (aq) S4O62-(aq) + 2e-
Reduksi : I-3 (aq) + 2e- 3 I- (aq)
Redoks : 2 S2O32-(aq) + I2 (aq) S4O62-(aq) + 3 I- (aq)
Adapun reaksi lengkapnya adalah:
2Na2S2O3 (aq) + I2 (aq) Na2S4O6 (aq) + 3 NaI(aq)
- Lapisan bawah[I2]CHCl3
Oksidasi : 2 S2O32- (aq) S4O62-(aq) + 2e-
Reduksi : I2 (aq) + 2e- 2 I- (aq)
Redoks : 2 S2O32-(aq) + I2 (aq) S4O62-(aq) + 2 I- (aq)
Adapun reaksi lengkapnya adalah:
2Na2S2O3 (aq) + I2 (aq) Na2S4O6 (aq) + 2 NaI(aq)
(natrium tiosulfat) (Iod)
(natrium iodide) (Natrium tetrasianat)
(tidak berwarna) (jingga) (tidak berwana)

Gambar H: Gambar I:
Lapisan bawah lapisan atas
I. CONCLUSSION
Based on the experiment that had been carried out can be conclude that
equilibrium constant of triodide ion formation reaction is 10,051 M-1

J. SUGGESTION
It is hoped that the next appreantice will be more careful in the shaking
process and titration in order to obtain the correct result.

BIBLIOGRAPHY

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