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Chapter 8 1) The value of K eq for the equilibrium

H 2 (g)  I 2 (g) ‡ˆ ˆ †ˆ 2 HI (g)

is 794 at 25 °C. What is the value of K eq for the equilibrium
Equilibrium below?
1/ 2H 2 (g)  1/ 2I 2 (g) ‡ ˆ ˆ HI (g)
ˆ ˆ†

A) 397
B) 0.035
C) 28
D) 1588
E) 0.0013
General Chemistry-Problem 2

6) Acetic acid is a weak acid that dissociates into the 7) At elevated temperatures, molecular hydrogen and
acetate ion and a proton in aqueous solution: molecular bromine react to partially form hydrogen
HC 2 H 3 O 2 (aq) ‡ˆ ˆ †ˆ C 2 H 3 O 2 (aq)  H + (aq) bromide:
H 2 (g)  Br 2 (g) ‡ˆ ˆ †ˆ 2HBr (g)
At equilibrium at 25 °C a 0.100 M solution of acetic acid A mixture of 0.682 mol of H 2 and 0.440 mol of Br2 is
has the following concentrations: [HC 2 H 3 O 2 ]  0.0990M combined in a reaction vessel with a volume of 2.00 L. At
[C 2 H 3 O 2 ]  1.33  103 M and H   1.33 103 M The equilibrium at 700 K, there are 0.566 mol of H 2 present. At
equilibrium constant, K eq , for the ionization of acetic acid at equilibrium, there are __________ mol of Br2 present in the
is __________. reaction vessel.
A) 5.71  104 A) 0.000
B) 0.100 B) 0.440
C) 1.75  107 C) 0.566
D) 1.79  105 D) 0.232
E) 5.71  10
6
E) 0.324
General Chemistry-Problem 3 General Chemistry-Problem 4

8) Dinitrogentetraoxide partially decomposes according to 11) A sealed 1.0 L flask is charged with 0.500 mol of I2 and
the following equilibrium: 0.500 mol of Br2 . An equilibrium reaction ensues:
N 2 O 4 (g) ‡ˆ ˆ †ˆ 2NO 2 (g) I 2 (g)  Br 2 (g) ‡ˆ ˆ †ˆ 2IBr (g)
When the container contents achieve equilibrium, the flask
A 1.00-L flask is charged with 0.04 of N 2 O 4 . At equilibrium contains 0.84 mol of IBr. The value of Keq is _________.
at 373 K, 0.0055 mol of N 2 O 4 remains. K eq for this
reaction is __________. A) 11
A) 2.2  104 B) 4.0
B) 13 C) 110
C) 0.22 D) 6.1
D) 0.022 E) 2.8
E) 0.87

General Chemistry-Problem 5 General Chemistry-Problem 6

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1) At equilibrium, __________.
A) all chemical reactions have ceased
B) the rates of the forward and reverse reactions are equal
C) the rate constants of the forward and reverse reactions
are equal
D) the value of the equilibrium constant is 1
E) the limiting reagent has been consumed
5) Which one of the following will change the value of an
equilibrium constant?
A) changing temperature
B) adding other substances that do not react with any of
the species involved in the equilibrium
C) varying the initial concentrations of reactants
D) varying the initial concentrations of products
E) changing the volume of the reaction vessel

General Chemistry-Problem 7 General Chemistry-Problem 8

7) The equilibrium-constant expression depends on the 8) Given the following reaction at equilibrium, if K c  6.44 x 105
__________ of the reaction. at 230.0 °C, Kp= __________.
2NO (g)  O 2 (g) ‡ˆ ˆ †ˆ 2NO 2 (g)
A) stoichiometry A) 3.67 x 10
2

B) mechanism B) 1.56 x 10
4

C) stoichiometry and mechanism C) 6.44 x 10

5

D) the quantities of reactants and products initially present D) 2.66 x 106

E) temperature E) 2.67 x 107

General Chemistry-Problem 9 General Chemistry-Problem 10

45).

General Chemistry-Problem 11 General Chemistry-Problem 12

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45). 45).

General Chemistry-Problem 13 General Chemistry-Problem 14

45).

General Chemistry-Problem 15 General Chemistry-Problem 16