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April 19 Chemistry AP Daily Live MCQ without a calculator

Multiple Choice
Identify the choice that best completes the statement or answers the question.

____ 1. When 6.0 L of He(g) and 10. L of N 2 (g), both at 0C and 1.0 atm, are pumped into an evacuated 4.0 L rigid container,
the final pressure in the container at 0C is

A) 2.0 atm B) 4.0 atm C) 6.4 atm D) 8.8 atm

____ 2. What is the maximum number of moles of Al 2O 3 that can be produced by the reaction of 0.40 mol of Al with 0.40 mol
of O 2 ?

A) 0.10 mol B) 0.20 mol C) 0.27 mol D) 0.40 mol

____ 3. What is the number of moles of excess reactant reamaing when 0.40 mol of Al with 0.40 mol of O 2 ?

A) 0.10 mol B) 0.20 mol C) 0.27 mol D) 0.40 mol

____ 4. What is the percentage yield of O 2 if 12.3 g of KClO 3 (molar mass 123 g) is decomposed to produce 3.2 g of O 2 (molar
mass 32 g) according to the equation below?
2KClO 3  2KCl (s)  3O 2
(s) (g)
A) 33% B) 50% C) 67% D) 100%

____ 5. The value of K sp for PbCl 2 is 1.6  105 . What is the lowest concentration of Cl  that would be needed to begin
(aq)
precipitation of PbCl 2 (s) in 0.010 M Pb(NO 3) 2 ?
A) 4.0  104 M C) 2.6  103 M
B) 1.6  103 M D) 4.0  102 M

____ 6.
4NH 3  3O 2  2N 2  6H 2 O (g)
(g) (g) (g)

If the standard molar heats of formation of ammonia, NH 3 and gaseous water, H 2 O (g) ,are - 46 kJ/mol and - 242
(g)
kJ/mol, respectively, what is the value of H o for the reaction represented above?
298

A) -1270 kJ / mol rxn C) -290 kJ / mol rxn

B) -580 kJ / mol rxn D) - 190 kJ / mol rxn

____ 7. A sample of a compound contains 3.21 g of sulfur and 11.4 g of fluorine. Which of the following represents the empirical
formula of the compound?

A) SF 3 B) SF 4 C) SF 5 D) SF 6

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____ 8.
1 1
H (g)  I 2  HI (g) H  = 26 kJ / mol rxn
2 2 2 (s)
1 1
H (g)  I 2  HI (g) H  = -5.0 kJ / mol rxn
2 2 2 (g)

Based on the information above, what is the enthalpy change for the sublimation of iodine, represented below?
I2  I2
(s) (g)
A) 15 kJ / mol rxn D) 42 kJ / mol rxn
B) 21 kJ / mol rxn E) 62 kJ / mol rxn
C) 31 kJ / mol rxn

____ 9. What is the molarity of I  in a solution that contains 34 g of SrI 2 (molar mass 341 g) in 1.0 L of the solution?
(aq)

A) 0.20 M B) 0.10 M C) 0.068 M D) 0.034 M

____ 10.
2S (s)  2O 2  2SO 2 K 1  2  10 105
(g) (g)
2SO 2  O2  2SO 3 K 2  7  10 24
(g) (g) (g)
Given the value of the equilibrium constants K 1 and K 2 for the reactions represented above, what is the value of the
equilibrium constant, K 3 , for the following reaction?
2S (s)  3O 2  2SO 3 K 3 ? ? ?
(g) (g)
A) 1  10 130 B) 3  1080 C) 1  1065 D) 2  1040

____ 11. The pressure, in atm, exerted by 1.85 mol of an ideal gas placed in a 3.00 L container at 35.0°C is given by which of the
following expressions?

(1.85)(35) (1.85)(8.314)(308)
A) atm C) atm
(3.00)(0.0821) 3.00
(1.85)(0.0821)(308) (1.85)(3)
B) atm D) atm
3.00 (35)(0.0821)

____ 12. The table below shows the results from a rate study of the reaction X + Y ® Z. Starting with known concentrations of X
and Y in experiment 1, the rate of formation of Z was R.
Experiment [X]o [Y]o Initial Rate of
Formation of Z (mol
L-1 sec-1)
1 0.40 0.10 R
2 0.20 0.20 ?

If the reaction was first order with respect to X and second order with respect to Y, the initial rate of formation of Z in
experiment 2 would be

R R
A) B) C) 2R D) R
4 2

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____ 13. If 0.40 mol of H2 and 0.15 mol of O2 were to react as completely as possible to produce H2O, what mass of reactant
would remain?

A) 0.20 g of H2 B) 0.40 g of H2 C) 3.2 g of O2 D) 4.8 g of O2

____ 14. How many carbon atoms are contained in 2.8 g of C2H4?

A) 1.2 x 1023 C) 6.0 x 1023

B) 3.0 x 1023 D) 1.2 x 1024

____ 15. How many mL of 10.0 M HCl are needed to prepare 500. mL of 2.00 M HCl?

A) 10.00 mL B) 20.00 mL C) 100.00 mL D) 200.00 mL

____ 16. Equal masses of He and Ne are placed in a sealed container. What is the partial pressure of He if the total pressure in the
container is 6 atm?

A) 2 atm B) 3 atm C) 4 atm D) 5 atm

____ 17. A 360. mg sample of aspirin, C9H8O4, (molar mass 180. g), is dissolved in enough water to produce 200. mL of solution.
What is the molarity of aspirin in a 50. mL sample of this solution?

A) 0.0800 M B) 0.0400 M C) 0.0200 M D) 0.0100 M

____ 18. The pH of a solution prepared by the addition of 10. mL of 0.002 M KOH(aq) to 10. mL of distilled water is closest to

A) 12 B) 11 C) 10 D) 4

____ 19. An electric current of 1.00 ampere is passed through an aqueous solution of Ni(NO 3)2. How long will it take to plate out
exactly 1.00 mol of nickel metal, assuming 100 percent current efficiency?
(1 faraday = 96,500 coulombs = 6.02 x 1023 electrons)

A) 48,200 s B) 96,500 s C) 193,000 s D) 386,000 s

____ 20. An acetate buffer solution is prepared by combining 50. mL of 0.20 M acetic acid, HC2 H 3 O 2(aq), and 50. mL of 0.20 M
sodium acetate, NaC2 H 3 O 2 (aq). A 5.0 mL sample of 0.10 M NaOH(aq) is added to the buffer solution. Which of the
following is a correct pairing of the acetate species present in greater concentration and of the pH of the solution after the
NaOH(aq) is added? (The pKa of acetic acid is 4.7.)

A) HC2 H 3 O 2(aq); pH < 4.7 C) C2 H 3 O  (aq); pH < 4.7

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B) HC2 H 3 O 2(aq); pH > 4.7 D) C2 H 3 O  (aq); pH > 4.7
2

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2 H 2O 2(aq)  2 H 2 O(l) + O 2 (g) H=  196 kJ mol rxn

The decomposition of H 2O 2(aq) is represented by the equation above. A student monitored the decomposition of a 1.0 L
sample of H 2O 2 (aq) at a constant temperature of 300. K and recorded the concentration of H 2O 2 as a function of time.
The results are given in the table below.

Time (s) [H 2O 2 ]

0 2.7
200. 2.1
400. 1.7
600. 1.4

____ 21. The O 2(g) produced from the decomposition of the 1.0 L sample of H 2 O 2(aq) is collected in a previously evacuated
10.0 L flask at 300. K. What is the approximate pressure in the flask after 400. s? (For estimation purposes, assume that
1.0 mole of gas in 1.0 L exerts a pressure of 24 atm at 300. K.)

A) 1.2 atm B) 2.4 atm C) 12 atm D) 24 atm

____ 22. In as saturated solution of Zn(OH) 2 at 25oC, the value of [OH  ] is 2.0  106 M. What is the value of the
solubility-product constant, Ksp, for Zn(OH) 2 at 25o C ?

A) 4.0  10 12 B) 1.6  10 17 C) 8.0  10 18 D) 4.0  10 18

____ 23. COCl2 (g) decomposed according to the equation below. When pure COCl2 (g) is injected into a rigid, previously
evaculated flask at 690 K, the pressure in the flask is initially 1.0 atm. After the reaction reaches equilibrium at 690 K,
the total pressure in the flask is 1.2 atm. What is the value of K P for the reaction at 690 K?
COCl2 (g)  CO(g) + Cl2(g)

A) 0.050 B) 0.80 C) 0.040 D) 1.0

____ 24. The K sp for PbCl2 at a particular temperature is 3.2  105 . What is the solubility of in g/L? The molar mass is 278
g/mol.
A) 0.0022 B) 0.0089 C) 5.6 D) 8.8

____ 25. The K sp values for a series of phosphate saltes are provided in the table above. Which compound is the least soluble in
water?

Salt K sp
Ag3PO4 1  10 16
AlPO4 1  10 20
Ca3(PO4)2 1  10 33
Mg3(PO4)2 1  10 24

A) Ag3PO4 B) AlPO4 C) Ca3(PO4)2 D) Mg3(PO4)2

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____ 26. At 25o C the solubility product constant, K sp , for MnS and the acid dissociation constants K 1 and K 2 for H2S are shown
in the table.

H 2 S (aq)  H  (aq) + HS  (aq) K 1  1  10 7

HS  (aq)  H  (aq) + S 2  (aq) K 2  1  1013

MnS(s)  Mn 2+ (aq) + S 2  (aq) K sp  5  1015

Mn 2  (aq) + H 2 S(g)  MnS(s) + 2H + (aq) ???

What is the equilibrium constant for the reaction represented by the equation below at 25o C ?

A) 5  10 35 B) 2  106 C) 5  10 5 D) 2  10 8