TASK 4 REVISION

NAME : GROUP : __________

Section One: Multiple-choice (20 minutes) (15 Marks)

This section has fifteen questions. Answer all questions.

1. In the diagram, curve X was obtained by observing the decomposition of 100 cm3 of 1.0
mol L–1 hydrogen peroxide, catalysed by manganese(IV) oxide.

Which alteration to the original experimental conditions would produce curve Y?

(a) increasing concentration to 1.1 mol L-1 hydrogen peroxide.
(b) adding water
(c) lowering the temperature
(d) using less manganese(IV) oxide

2. A reaction has an equilibrium constant (K) of magnitude 2.56 x 10-7.

From this we can say that:

(a) There has been minimal conversion of reactants into products
(b) Equilibrium will be established very quickly
(c) Equilibrium will be established very slowly
(d) The reverse reaction will have a faster rate than the forward reaction.

3. Which of the following solutions would have the greatest concentration of chloride ions?
(a) 0.20 mol L-1 AlCl3
(b) 0.50 mol L-1 HCl
(c) 0.70 mol L-1 NaCl
(d) 0.40 mol L-1 MgCl2

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4. Which of the following best describes a necessary condition for the system below to be
at equilibrium?
2NO(g) + O2(g) 2NO2(g)
(a) All chemical reactions have stopped.
(b) The concentrations of NO(g) and NO2(g) are equal.
(c) The concentrations of all species are equal.
(d) Forward and reverse reactions are continuing at equal rates.

5. A reaction has the following potential energy diagram.

Choose the false statement regarding this reaction.

(a Enthalpy change for this reaction is positive.
)
(b This reaction would cause a temperature rise.
)
(c) The reverse reaction is exothermic.
(d Activation energy for the forward reaction is higher than for the reverse
) reaction.

6. Which of the following statements is FALSE for a 1 mol L-1 solution of (NH4)2Fe(SO4)2?
(a) It contains an equal concentration of cations and anions.
(b) The NH4+ (aq) ion has a concentration of 2 mol L-1.
(c) NH4+ (aq) and SO42- (aq) have the same concentration.
(d) The total concentration of ions is 5 mol L-1.

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7. What mass of anhydrous sodium carbonate must be used to make up 250 mL of a

0.153 mol L-1 sodium carbonate solution?
(a) 0.0383g
(b) 4.05g
(c) 2.24g
(d) 3.17g

8. How many carbon monoxide molecules are there in 84.0g of carbon monoxide?
(a) 3.00 x 10-23 molecules
(b) 2.53 x 10-22 molecules
(c) 1.81 x 1024 molecules
(d) 18.1 x 1024 molecules

9. What mass of oxygen is contained in 132g of carbon dioxide?

(a) 6.00g
(b) 16.0g
(c) 48.0g
(d) 96.0g

10. 17.75g of chlorine gas reacts with hydrogen to form hydrogen chloride gas. Calculate the
number of moles of hydrogen chloride formed.
(a) 0.250 mol
(b) 0.500 mol
(c) 0.100 mol
(d) 2.000 mol

11. Which one of the following statements best describes a covalent bond?

a) The atoms have a noble gas configuration.

b) The atoms have formed an infinite network.

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c) One of the atoms involved in the bond is a metal and the other is a non-metal.
d) There is simultaneous attraction of both nuclei to a shared electron pair.

12. Which one of the following is a polar molecule?

a) CCl4
b) CH3Cl
c) CO2
d) CH4

13. Why is NH3 classified as a polar molecule?

a) N-H bonds are non-polar.

b) NH3 molecules have asymmetrical charge distributions.
c) Nitrogen and hydrogen are both nonmetals.
d) It is a gas at room temperature and pressure.

14. Which is an example of a non-polar molecule that contains polar covalent bonds

a) N2
b) H2O
c) CO2
d) None of these

15. Which of the following best describes a dipole moment?

a) When electrons are unevenly distributed within a molecule
b) When several atoms in a compound are electronegative
c) A non-polar molecule
d) Having more than 4 dipoles

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End of Section One

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Section Two: Short Answer (30 minutes) (25 marks)

This section has three questions. Answer all questions. Write your answers in the spaces
provided.
Final answers to calculations should be expressed to three significant figures.

Question 16 (8 marks)

Consider the following reaction:

CO2(g) + NO(g) ⇌ CO(g) + NO2(g) ΔH = + 226 kJ mol-1, Ea = 360 kJ

(a) On the axes below draw an energy profile diagram for this reaction. Label the activation
energy, reverse activation energy and enthalpy change for the forward reaction. Include
a scale on the vertical axis.
(5 marks)

Enthalpy (kJ)

Reaction pathway

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(b) (i) How much energy is consumed when 2.5 mol of CO2(g) is reacted with 2.5
mol of NO(g)? (1 mark)

______________________________________________________________

(ii) What is the activation energy when 2.5 mol of CO2(g) is reacted with 2.5 mol of
NO(g)? (1 mark)

______________________________________________________________

(c) Write the equilibrium constant expression, K, for the above system. (1
mark)

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Question 17 (5
marks)
The complex ion, [Cu(NH3)4]2+, is royal blue in colour, while at low concentrations the copper (II)
ion is light blue and ammonia is colourless. Use Le Châtelier’s principle to predict what effects
the following changes will have to the equilibrium system described by the reaction below:

Cu2+(aq) + 4NH3(aq) ⇌ [Cu(NH3)4]2+(aq)

State your answer as ‘no change’, ‘solution becomes a deeper blue’ or ‘solution becomes a
paler blue’.
(a) The concentration of Cu2+ ions is increased by the addition of small amount of a copper
(II) chloride solution. (1mark)
______________________________________________________________________

(b) A few drops of 1.0 mol L -1 sodium carbonate solution is added to the system.
(1mark)
______________________________________________________________________

(c) A few drops of 2.0 mol L-1 HCl solution is added to the system. (1mark)
______________________________________________________________________

(d) In the graph below, draw the curve for concentration of Cu 2+ ions based on the changes
made in (a).

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Question 17 (12
marks)

The reaction between lead (II) nitrate and potassium iodide can be represented by the following
equation:
Pb(NO3)2 (aq) + 2 KI (aq) → PbI2 (s) + 2 KNO3 (aq)

2.00 g of lead (II) nitrate is added to 3.00 g of potassium iodide.

(a) Identify the limiting reagent. (6 marks)

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(b) Calculate the mass of lead (II) iodide formed. (3 marks)

(c) Calculate the mass of excess reactant remaining after the reaction. (3 marks)

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End of Section Two

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