Raannos, John Emmanuel A. CHE ATF ~Cheunicak ChE 320) Reaction Engineering Problem ct #3 The gac-phase reaction of chlorine with chilomfocm is describes by He equation: Chis) + CHCIsl) —* HClesy + CClycgy “The rate law dettrmines from Experiment has a non-integer order rote = & [0lx\"? (cHcis) Ai proposed mechanism for iis reaction follows: dha hy (£0 CE) fo ferer] —————_— “Go kK Yes, it iS Gn aceptable mechan'sn, Answer& The Compound NOLL is thvught te decompse fo Ny and Ch, by te Following mechan: kK NoyCl < wa tor O porte! wo,el © NOC +l tor scl, Derive the rake law fir foo production of Cle wing fre skaly-state appeximahon cme reuchon aed vp © Gentify the inrmediate 6: ol en enn d ZNO, —*2NOzt Cy ® dal, k, [Wosct] - K,LNOKI- k. [wo,ciJl}=0 (i) al No,ct} _ dt —k Choc!) + KaLhoe ICT - be fyo,ci) [ci] =o 6 Ape): formation of oes MON FT soci fer ee 0 ® “peumeys = FiLWOvcl) ~ key — beLnonct}+ Kauai Splyo\LOU®@ 1 Eque O® © —e fuorcrdt Ki Luo, Vict) - & [ont fet) = kLwoct)~ K Loo Wek Cwoci fed 4k LNo,Ct] ~ 2; Luorllci] - 2 QKTNoCt) = oe Cao. £1) [alt= 4 Wnrironct) fel ‘ sTaneil( 4 hy -werst ' Xt Att Tuer? {po | Ter) - Ke Cworcitfci) a3. Thare are sovuatl 265 whore “he reaction is complicatd fn example i dbig| LHe 6 Hac) + BG) —* 2HBe cg) he Clec\+ ry “the Slowing mechanism bas been props Yo account fir $his rade law Initiation: Bro + M—* Bre +Bre + M Mic sith ry 2 Hy- Propagation Bre ty —* HBr + He He + Be. —? HBr + Bre Retardation: He + HBr —* Ha + Bre Termirotion: Bret Bre tM —+ Bar Mt The Hoird boy Uallion remowsfhe excess enurgy- Using Ss ee determing Hoe take of Hr formation: —ngurs ALHB, ov, CE)" Laer] a 7 (Be1+ (Us aN) Sed? re te Be bee tag (Ar Sept Bre, By He + fe Bel, 202 2b, (BrJtMil Bauslnys + Ln gL) Sep He ty Be He ee “eT tM Skpy: He HO Ss toe Bb Ce, MDA 2 ks [Bo PD Uirl= (6)* Ges ke D8-T CH} = LyCHS Lie = by Lt] (48+) J+ Feloe1L4.1 Sep F Bee tiem Ee tt at In dermediobes : Br 2 the Ks LBe.) + K4CH6r) a6 Vf 1) pp 7 pe lisa, kel) Ut fe GR)" La)" balLte) ky a ( .)°(, Phen Ug] + hy He] ksLBrn T+ ky C6) “bled + by Cad = ak (Ke) ify qe | tb mae a | Arvwier: 3B) oe fo, + Se tHO vomplcke Skip Solution on scratol janper (I - kg) (1 + Hilts4 he Harkin of fre reaction ebween Ha, oe Bry were detterningl one by Prbercltin arunf 100 pare agp. “tht overalh reaction has fhe equation» Ha +¥iry —* HBr aH <5 (4, 306) th. flowing machanigm hos been proposed: fg =r i eR) <1, nee be pops itchaion 5 lost fet Hy & Hoe +d wilt epee deltrrnined ratt-tow . \ It be “* tlhe Hr we AHA» ake (e)*tu (lao, Ha Hee 28 Yh 46 Ow REFERENCE (10.3): t= (£)*L5,)* web Lb 3UbI bs Baly tylH8e} CH) Selb) + ECHO Wy CCH = ke (oT) + Kee LO THA Bed ~ vey l8-W HT Hee) KBr} + ky Loe) = KelbICKT (1 4 Uda] byltisa Ws lBed Hey Coed ie dks _Aky Cg) ele (Fw) eH EY" ("Cased C8) + ky (HBr) slid - (Bye Ce," + Be ar fas) oe 4 oh 15 much fess tron |, (ey tes k) [ry be assumed approaching O-5 fh Unlemaan( Tas Fraday Sten Fr, SA (D2)) propued the fallouty mechanism fir o Unitnaeculay ges reaction - The species A* is cn entire! meloalle frat Is Ce in (ow concentrations “ Hed pnt at “yap Ootain an expression Fite rote B in fens of (4, ki ktrky- IE AY very large ch Kat ky LA) >> &, show fe a reaton wlll be foe Tot elerd IE (ALB very simath Such Yoat k [a] <<, > Show thd fe reaction will be Ind oder of p, AGA Ms atta ptig & “ a @k lk 5 kn 0 ab kek LA Inder dat: eee os [op tecan| de 7 SeehtAl APL oe utd -ks(aSta)- BU et YON kcal tet) — @ KLAD <<) Kaleo [r= BE” geo SeeGT feta) He ° be Foe anny | AB AP). acct) = 2, [a8) oe * ove {| ——_ ee ae AN hae (eeewes 9 Jone xn amas uoneunoidae ss Bsn ‘AMlav ssn soho USO A pn AL ShHB tes se woe J+ WH +H -vONePRY ae BH CUB + s0H © 5+ woneRedong usc ayyestiy vir re roe ¢H4 i woneDER esodon! va sey sje MUCHO} a Shae € Mg Stafdues uy pares uonaeas oy) oun ose sons ave oia4L “E eae ots a Bun py Jo uonanpoud m4 05 me ays ay ANID sD+0N > D+ Dion sueyoou Burmopoy 24 Mg Pue“OW 01 250duo>9p ©) HOY STON PunOdOD MAL “Z| uonpea sin] wsueypou agendarse ue sn 5, aaa ery esau an iesien gumepeu pode sae amy > (Pt) (Dn Mp Nw usiveyrau pasodaud y opi s9Bowuwoue sty Wauar26x3 wey POUMLEP mel ae) 34 {nurse apt ota sm put prem} man + PH € MOHD +8 pesodor ug sey usEIDaU 3U/H0} D4, tonenba ay 9 paqusop s aHojoroy> yam suv 0 UoRzeasaseyd-se@ a4, “T sence na +H ‘wojgoud upeo sons pue 244m push vonenbo sey ‘J enna pauusoip ia elo BE SHEA 9 pune HaSL3pOR (siisinvi3 NOUDVEHI € ON 35 WOME usages! af) S9NRUT BL“ Ye02-07oz"ueqeeups ‘ONIAEENIONS NOLDW34 TWOWABHD “CEP 3HDfir, —* bre thy line Qn thy Mrt be hh be Het fi * Hlth ate. IH CFs SLs el I ler ft HBr —e Hat Br. hale jot re me TI “bs bce Ab (fr, | “2obs Cert* Od left 2)" De)” a kl rs Sed = 6 30, 1 + ky Ch IL HBS kel SUK] ali) pile D-DHS) py LDH OS> Fran © bi = balteSLt) + by ka Leela) a “tata bla) + vy 8) = at (Bead) - ey [HB bTpll { | + et) > btw Lia ( (a aisle) = (He) "Len * F )(+3) Lies) Le ba CA lt kg Lier) < db (42) Yo Y* rs) (3 Ce.) + Gy i) Cha) = 2h(he)"( (5) Di} ke / fel + +e Ere)a= bl Jnd Bide imme ES i Car} = (4) (.,)" bas 2Ce)*a*(u) ae MO nb tePinl te) le bUtrl + yee) elBcl+ tL Heed =bC4)* GT" SUE bl ( gt ae - ales, br CE)" a+ hfs) NORTE Ea = 2 )*(H,3" [ = th Che) *O)* [ TT Hind Tm + Ter