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DOWCAL™ Fluids
Inhibited Glycol-based Heat Transfer Fluids
Guide to Products, System Design, Installation and Operation
DOWCAL™ Fluids
Table of Contents
3
DOWCAL™ Fluids
Breweries use DOWCAL™ N Fluid to control fermentation and wort tanks temperature.
DOWCAL™ heat transfer fluids are clear, ethylene or propylene water, DOWCAL™ fluids offer reduced viscosity, increased heat
glycol-based liquids formulated with our signature corrosion capacity and thermal conductivity, and take advantage of the
inhibitors for optimum system performance. They are optimal excellent heat transfer properties of water over a broad range
solutions if the freezing point of water is not low enough to of temperatures.
allow its use in certain applications. Typically diluted with
4
DOWCAL™ Fluids
Advantages of
DOWCAL™ Heat
Transfer Fluids
Are all heat transfer fluids the same?
Absolutely not. Heat transfer fluids
must address a wide range of often
vastly different process-specific needs.
Selection of the wrong product for a
given application may cause damage
when the system is filled. Corrosion or
gasket decomposition can lead to leaks,
lack of performance and damage to
property at the worst case. Major Ground source heat pumps use DOWCAL™ 100 and DOWCAL™ 200 fluids to help provide efficient heating and cooling in private and
industrial buildings while reducing energy use.
equipment overhauls may be required
to repair system damage. Considering
the potential high price of system
repairs – and the potential cost of • Long-lasting Performance—DOWCAL™ Expert Technical Support
property and other damage in the event fluids are also long-lasting and can be As a Dow heat transfer fluids customer,
of a system failure and leakage due operated for many years in properly you have direct access to our industry-
to ruptured components, it pays to maintained systems. Their special leading heat transfer expertise,
carefully select a heat transfer fluid. corrosion inhibitor package supports including our in-depth and highly
higher temperature operation diversified application experience.
Dow offers a full range of DOWCAL™ compared to alternative technologies. Dow heat transfer specialists will help
heat transfer fluids – including both you select the exact fluid you require,
ethylene glycol- and propylene glycol- • Sustainable—DOWCAL™ fluids are then work with you to properly install
based fluids – to meet your specific nitrite, borax, and CMR (carcinogenic, and optimize fluid operation for best
system requirements. When you choose mutagenic, and reprotoxic) free. results. Contact us as indicated on the
a DOWCAL™ fluid, you can be confident back of this brochure to learn more
it will provide long-lasting protection • Formulated for Maximum about our services and to begin
and performance without jeopardizing Convenience— DOWCAL 100 and working with our experts on your
the integrity of the equipment in DOWCAL 200 can be diluted with successful heat transfer project.
which it is used. local tap water supplies when
demineralized water is not available. Additional Resources
• Corrosion Protection—DOWCAL™ (See additional details on page 14). FLUIDFILE™ software from Dow is
fluids are formulated with carefully available to assist in the design of
chosen corrosion inhibitors to provide • Use in Regulated Industries – heating and cooling processes and in
protection to the metallic parts of DOWCAL™ N is suitable for use in food the selection of the best DOWCAL™ fluid
process equipment, therefore improving plants (see additional details regarding for specific applications. FLUIDFILE™
process efficiency and reducing food contact on page 15 of this brochure). provides physical properties and fluid
maintenance costs. DOWCAL™ 100 and dynamics for any temperature range
DOWCAL™ 200 in particular are very and any DOWCAL™/water mixing ratio.
efficient at protecting aluminum (see Combined with the information in
additional details on page 11 and 12). this guide, FLUIDFILE™ can help you
achieve optimum heat transfer system
• Compatibility—DOWCAL™ fluids set performance. Visit www.DOWCAL.com
the industry standard for compatibility. to download the FLUIDFILE™ Software.
The fluid formulations will not affect
most plastics and metals, minimizing
the potential for gasket decomposition
in process equipment.
5
DOWCAL™ Fluids
Optimum operating
temperature range
DOWCAL™ 200
Fluid can be operated
with minimum oxygen
contact
Note: If operated above 100°C, the fluid needs to be pressurized to avoid evaporation in the system
6
DOWCAL™ Fluids
Note: freezing point varies as a function of the concentration of DOWCAL™ fluid in the solution. Specific
heat, density, thermal conductivity and viscosity also vary depending on the concentration of DOWCAL™
fluid as well as the temperature at which the DOWCAL™ solution is used. See the freezing and boiling
point tables on pages 16,17 and 18 or refer to FLUIDFILE™ software from Dow to review properties
data at specific fluid concentrations and system temperatures. Download the FLUIDFILE™ software at
www.DOWCAL.com.
7
DOWCAL™ Fluids
In solar panels, a solution of DOWCAL™ 200 fluid absorbs solar heat, and transports the energy so it can be used to heat water or air.
8
DOWCAL™ Fluids
Fermentation Cooling
Breweries and wineries use DOWCAL™ N fluid to cool
fermentation and wort tanks. The fluid’s anti-corrosive
properties safeguard the integrity of the piping systems.
Conveyor Roller Deicing DOWCAL™ N fluid is widely used to cool, ferment, and bottle beverages.
The conveyors in food freezing tunnels are often affected
by frost formation on rollers and other moving parts.
DOWCAL™ N fluid offers an ideal remedy; sprayed directly
onto the rollers, it absorbs free moisture, lowers the freeze
point of water, prevents frost build-up and protects the
rollers against corrosion.
9
DOWCAL™ Fluids
A solution of DOWCAL™ 200 fluid can help protect warehouse floors from damage caused by frost heaving.
10
DOWCAL™ Fluids
-10
-30
Corrosion of Cast Aluminum Under Heat-Rejecting Conditions According to ASTM D 4340 at a concentration of 25% by volume
Measured at BfB Oil Research S.A., Gembloux, Belgium, 05/2012 and 03/2013
11
DOWCAL™ Fluids
OAT Fluid
DOWCAL™ 100
1 2 3 4 5 6
ASTM D1384 Corrosion Test Results at 20% Concentration
by Volume Propylene Glycol (Weight Difference [mg])
OAT Fluid
DOWCAL™ 200
12
DOWCAL™ Fluids
Materials Ethylene glycol based fluid, Propylene glycol based fluid, e.g.
e.g. DOWCAL™ 100 DOWCAL™ 200 & DOWCAL™ N
Plastics
ABS 66°C 32°C
Acrylics 32°C
Chlorinated Polymer 110°C
CPVC 93°C a 93°Cb
Epoxy 143°C 99°C(U)c
Fluorocarbons FEP 199°C 199°C
Fluorocarbons TFE 249°C 249°C
Noryl®
66°C
Polyamides - Nylon 99°C
Bisphenol A-Fumurate 110°C 88°C
Hydrogenated Bisphenol 104°C 93°C
A-Bisphenol A
Isophthalic 43°C(U)c 88°C
Chlorinated Polyesters 127°C 104°C
Polystyrenes 77°C
Polyethylene 71°C 66°C
Polypropylene 116°C 66°C
PVC – Type 1 49°C 49°Cd
PVC – Type 2 49°C 49°Cd
Polyvinylidene Chloride 88°C
Vinylidene Fluoride 143°C 138°C
Vinyl Ester 104°C 104°C
(a) But only if the solution contains 50% or less of ethylene
Polymethylmethacrylate 70°Ce glycol, according to BF Goodrich
(PMMA)
(b) But not in a solution containing more than 25% of
Rubbers propylene glycol, according to BF Goodrich
Butyl GR-1 93°C (c) When U follows a recommended temperature range, the
fluid was found to cause a problem with the plastic above
Fluoro Elastomers Viton A ®
182°C 38°C the range, and is therefore unsuitable at higher temperatures
Fluoro Elastomers KEL-F 99°C (d) The Geon Company, a major manufacturer of PVC resins
and compounds, cautions against using PVC above 49°C
3700
Hard Rubber 93°C (e) Tested by Ecofys Netherlands BV, 2008
Neoprene GR-M (CR) 77°C 32°C ™Trademark of The Dow Chemical Company
Nitrile Buna M (NBR) 88°C 32°C Table Sources: “Corrosion Resistance Tables,” Second
Edition, Philip A. Schweiter, P.E., 1986 BF Goodrich and
NORDEL ™
154°C The Geon Company
Polyurethane 38°C
13
DOWCAL™ Fluids
Some of the most elite ice arenas depend on DOWCAL™ 100 and DOWCAL™ 200 fluids to help
keep the ice cool and consistent.
14
DOWCAL™ Fluids
15
DOWCAL™ Fluids
16
DOWCAL™ Fluids
Typical Freezing, Boiling Points and other properties of DOWCAL™ 200 Fluid†*
DOWCAL™ 200 DOWCAL™ 200 Freezing Refractive Index Boiling Point Density Dyn. Viscosity Kin. Viscosity
Vol.% Wt. % Point °C @ 20°C °C @ 1 bara g/cm³ @ 20°C mPa.s @ 20°C mm²/s @ 20°C
†
Typical properties, not to be
5.0 5.3 -1.6 1.3391 100 1.006 1.36 1.95 construed as specifications.
10.0 10.5 -3.3 1.3452 100 1.011 1.62 1.66
15.0 15.8 -5.3 1.3513 101 1.015 1.93 1.81 *Temperature-dependent
physical properties
20.0 20.9 -7.5 1.3573 101 1.020 2.30 2.11 are provided in the
21.0 22.0 -8.0 1.3585 101 1.021 2.39 2.18 FLUIDFILE™ Software.
22.0 23.0 -8.5 1.3597 101 1.022 2.48 2.26 Generally, for an extended
23.0 24.0 -9.1 1.3609 102 1.022 2.57 2.34 margin of protection you
should select a temperature
24.0 25.1 -9.6 1.3621 102 1.023 2.66 2.42 in this table that is at least
25.0 26.1 -10.2 1.3633 102 1.024 2.76 2.51 3°C lower than the expected
lowest ambient temperature.
26.0 27.1 -10.8 1.3645 102 1.025 2.87 2.61 Contact Dow for information
27.0 28.2 -11.4 1.3657 102 1.026 2.97 2.71 and further assistance with
specific cases.
28.0 29.2 -12.1 1.3669 102 1.027 3.09 2.81
29.0 30.2 -12.7 1.3681 102 1.028 3.20 2.92
30.0 31.2 -13.4 1.3693 102 1.029 3.33 3.04
31.0 32.3 -14.1 1.3704 102 1.030 3.45 3.16
32.0 33.3 -14.8 1.3716 102 1.031 3.58 3.29
33.0 34.3 -15.6 1.3728 102 1.032 3.72 3.42
34.0 35.3 -16.4 1.3739 102 1.033 3.87 3.56
35.0 36.3 -17.2 1.3751 102 1.034 4.02 3.70
36.0 37.4 -18.0 1.3762 103 1.035 4.17 3.85
37.0 38.4 -18.9 1.3774 103 1.036 4.34 4.01
38.0 39.4 -19.8 1.3785 103 1.037 4.51 4.17
39.0 40.4 -20.7 1.3797 103 1.038 4.68 4.35
40.0 41.4 -21.7 1.3808 103 1.039 4.87 4.53
41.0 42.4 -22.7 1.3820 103 1.039 5.06 4.71
42.0 43.4 -23.7 1.3831 103 1.040 5.26 4.91
43.0 44.4 -24.8 1.3842 103 1.041 5.47 5.12
44.0 45.4 -25.8 1.3853 103 1.042 5.69 5.33
45.0 46.4 -27.0 1.3864 103 1.043 5.92 5.55
46.0 47.5 -28.1 1.3875 104 1.044 6.16 5.79
47.0 48.5 -29.3 1.3886 104 1.045 6.40 6.03
48.0 49.5 -30.5 1.3897 104 1.046 6.66 6.29
49.0 50.5 -31.8 1.3908 104 1.047 6.93 6.55
50.0 51.5 -33.1 1.3919 104 1.048 7.22 6.83
51.0 52.5 -34.5 1.3930 105 1.048 7.51 7.12
52.0 53.5 -35.9 1.3941 105 1.049 7.82 7.42
53.0 54.4 -37.3 1.3951 105 1.050 8.14 7.74
54.0 55.4 -38.7 1.3962 105 1.051 8.48 8.07
55.0 56.4 -40.3 1.3973 105 1.052 8.83 8.41
56.0 57.4 -41.8 1.3983 106 1.053 9.20 8.77
57.0 58.4 -43.4 1.3993 106 1.053 9.58 9.14
58.0 59.4 -45.0 1.4004 106 1.054 9.98 9.54
59.0 60.4 -46.7 1.4014 106 1.055 10.4 9.94
60.0 61.4 -48.5 1.4024 107 1.056 10.8 10.4
65.0 66.3 -51 1.4074 108 1.059 13.3 12.8
70.0 71.2 -51 1.4122 109 1.062 16.5 15.8
75.0 76.1 -51 1.4168 111 1.064 20.4 19.5
80.0 80.9 -51 1.4212 113 1.066 25.4 24.1
85.0 85.7 -51 1.4253 116 1.066 31.6 29.8
90.0 90.5 -51 1.4291 121 1.065 39.5 36.9
95.0 95.3 -51 1.4327 129 1.062 49.5 45.7
100.0 100.0 -51 1.4360 142 1.057 62.3 56.5
17
DOWCAL™ Fluids
DOWCAL™ N DOWCAL™ N Propylene Freezing Refractive Boiling Density Dyn. Viscosity Kin. Viscosity
Vol.% Wt. % Glycol Point °C Index Point g/cm³ @ 20°C mPa.s @ 20°C mm²/s @ 20°C
Wt. % @ 22°C °C @ 1 bara †
Typical properties, not to be
5.0 5.2 5.0 -1.6 1.3383 100 1.004 1.2 1.2 construed as specifications.
10.0 10.5 10.0 -3.3 1.3438 100 1.009 1.4 1.4
*Temperature-dependent
15.1 15.7 15.0 -5.1 1.3495 100 1.014 1.6 1.6 physical properties
20.3 20.9 20.0 -7.1 1.3555 101 1.020 2.0 2.0 are provided in the
FLUIDFILE™ Software.
21.3 22.0 21.0 -7.6 1.3567 101 1.021 2.0 2.0
22.4 23.0 22.0 -8.0 1.3579 101 1.022 2.1 2.1 Generally, for an extended
margin of protection you
23.4 24.1 23.0 -8.6 1.3591 101 1.023 2.2 2.2 should select a temperature
24.5 25.1 24.0 -9.1 1.3603 101 1.023 2.3 2.2 in this table that is at least
3°C lower than the expected
25.5 26.2 25.0 -9.6 1.3615 101 1.024 2.4 2.3 lowest ambient temperature.
26.5 27.2 26.0 -10.2 1.3627 101 1.025 2.5 2.4 Contact Dow for information
and further assistance with
27.6 28.3 27.0 -10.8 1.3639 101 1.026 2.6 2.5 specific cases.
28.6 29.3 28.0 -11.4 1.3651 102 1.027 2.7 2.6
29.7 30.4 29.0 -12.0 1.3663 102 1.028 2.9 2.8
30.7 31.4 30.0 -12.7 1.3675 102 1.029 3.0 2.9
31.8 32.5 31.0 -13.4 1.3687 102 1.030 3.1 3.0
32.8 33.5 32.0 -14.1 1.3698 102 1.031 3.3 3.2
33.9 34.6 33.0 -14.8 1.3710 102 1.032 3.4 3.3
35.0 35.6 34.0 -15.6 1.3621 102 1.032 3.5 3.4
36.0 36.6 35.0 -16.4 1.3733 103 1.033 3.7 3.6
37.1 37.7 36.0 -17.3 1.3744 103 1.034 3.9 3.8
38.2 38.7 37.0 -18.2 1.3756 103 1.035 4.0 3.9
39.2 39.8 38.0 -19.1 1.3767 103 1.036 4.2 4.1
40.3 40.8 39.0 -20.1 1.3779 103 1.036 4.4 4.2
41.4 41.9 40.0 -21.1 1.3790 104 1.037 4.5 4.3
42.4 42.9 41.0 -22.1 1.3802 104 1.038 4.7 4.5
43.5 44.0 42.0 -23.2 1.3813 104 1.039 4.8 4.6
44.5 45.0 43.0 -24.3 1.3825 104 1.039 5.0 4.8
45.7 46.1 44.0 -25.5 1.3836 104 1.040 5.2 5.0
46.7 47.1 45.0 -26.7 1.3847 104 1.041 5.4 5.2
47.8 48.2 46.0 -27.9 1.3858 104 1.041 5.6 5.4
48.9 49.2 47.0 -29.3 1.3870 104 1.042 5.8 5.6
50.0 50.3 48.0 -30.6 1.3881 105 1.043 6.1 5.8
51.1 51.3 49.0 -32.1 1.3892 105 1.043 6.3 6.0
52.2 52.4 50.0 -33.5 1.3903 106 1.044 6.6 6.3
53.2 53.4 51.0 -35.0 1.3914 106 1.045 6.9 6.6
54.3 54.5 52.0 -36.6 1.3924 106 1.045 7.2 6.9
55.4 55.5 53.0 -38.2 1.3935 106 1.046 7.6 7.3
56.5 56.5 54.0 -39.8 1.3945 106 1.046 7.9 7.6
57.5 57.6 55.0 -41.6 1.3956 106 1.047 8.2 7.8
58.5 58.6 56.0 -43.3 1.3966 106 1.047 8.6 8.2
59.6 59.7 57.0 -45.2 1.3977 107 1.048 8.9 8.5
60.6 60.7 58.0 -47.1 1.3987 107 1.048 9.3 8.9
61.7 61.8 59.0 -49.0 1.3998 107 1.049 9.7 9.2
62.7 62.8 60.0 -51.1 1.4008 107 1.049 10.0 9.5
68.0 68.1 65.0 -51.1 1.4058 108 1.052 11.7 11.1
73.2 73.3 70.0 -51.1 1.4104 110 1.054 14.2 13.5
78.4 78.5 75.0 -51.1 1.4150 114 1.055 17.1 16.2
83.6 83.8 80.0 -51.1 1.4193 118 1.054 21.2 20.1
88.9 89.0 85.0 -51.1 1.4235 125 1.053 26.0 24.7
94.1 94.2 90.0 -51.1 1.4275 132 1.052 33.4 31.7
100.0 100.0 95.5 -51.1 1.4315 165 1.051 45.7 43.5
18
DOWCAL™ Fluids
Inhibited Glycol-based Heat Transfer Fluids
®™Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow Printed in U.S.A.
NOTICE: No freedom from infringement of any patent owned by Dow or others is to be inferred. Because use conditions and applicable laws may differ from one location to another and may change with
time, Customer is responsible for determining whether products and the information in this document are appropriate for Customer’s use and for ensuring that Customer’s workplace and disposal practices are in
compliance with applicable laws and other government enactments. The product shown in this literature may not be available for sale and/or available in all geographies where Dow is represented. The claims made
may not have been approved for use in all countries. Dow assumes no obligation or liability for the information in this document. References to “Dow” or the “Company” mean the Dow legal entity selling the products
to Customer unless otherwise expressly noted. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED.