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AB-3125 Third Year B. Sc. (Sem. V) Examination March/April - 2015 Inorganic Chemistry : Paper - VI Time: Hours} (Total Marks : 50 Bate (a) Seat No. Ti aka @ Gala Gad Guede wate wad Fill strictly the detalls of @~ signs on your answer book Name ofthe Examination [third Year B. Sc. (Sem. V) Name ofthe Subject [Inorganic Chemistry : Paper - VI Students Signature e-SubjoctCodono.| 3 |} 4 |] 2 |] 5 | e-Section No. (1,2...) Nil (2) gat WA yarae war avid (3) eel ouget ais uae yet ae cela 8. a Att walle Zari raue aan é (a) eiSQor ung sdBeet ada wllsre ueell S4 sell-24 a2 wb? “solani 4 Bis siddert wu, olen 22 edd VAgell we BY. aw we ? (a ada (3) [AIR], [S%]’. [PE] [six uRadueladien aed sai olsd. (e) CP, H,IH A OHH A zr BARA ABaL Suri Ded, (4) Ao, eg #7 toy rare vend. (e) AA urmugsris Wiad vig As Far sila satel a} dl 2 a He 2 (9) aude ga Bear ws oa B ? (¢) avidd are vizsiaa aieed ua sf aigd aa aaiad Ada 7 AB-3125] 1 [Contd... = (wi) (a) ( AB-3125] allen Ey, "5 ng +n +n?) ad. qu aaat sdren trai wad woud. q Mader Bavrievii Wt wi citar veud. N atat oa sidsissri sider Rix cid wind. Y Vavbarri at ARa vse ca wind. ¥ Gouda Baa Aad yf? a i=N Bn= J Kj atv Quand. i maal uRadadladt 224 a? uRadadladiA ae saci y ued eeudd [Cof,]* awit aGi2e aust Ad ar dose qevolll aal #2. aaat aster BU Wiad WA gs BoM Arla swesadly u AAA ra warned. Cue? weet Hohl met az oA Wiad. ¥ Ni(CO), Bisa Wet WA sia aa. Y aaat fig sella Aza i ? aig sited aflsea veud. y aad dears Ria wad. q aaat BARS HEL AA BARS 2wwL UR gseile ard 4 Re sie Faded ue geile anil. ¥ 2 (Contd... ENGLISH VERSION Instruetions : (1) As per the Instruction No. 1 of Page No. 1. @) Write short and to the point answers (8) Figures to the right indicate full marks of the question. 1 Answer the following in brief : 8 (2) Which quantum numbers are obtained from hydrogen atom's Schordinger's wave equation ? 2) ‘In diborane two bridge hydrogen atoms are different from four other hydrogen atoms.’ Why ? @) Arrange [AIF,]~ [Sh], [PRI ana [sing] ions in increasing order of lability. (4) ArrangeCl-,H~,J~ and QH~ in increasing order of trans effect. (5) Give the meaning of As, eg and tyy. ©) Can metals having odd atomic number form monocentric carbonyls ? Why ? (How many types of bond are in tetraborane ? (8) To avoid corrosion of iron, which metal can be coated on the iron ? 2 (A) Derive the equation £, o (nf +nf +12) OR (A) Give postulates of quantum mechanics. 5 (B) Explain structure and bonding in dodecaborane anion. 5 OR (B) Explain hydrogen bridge bond in boron hydrides. 5 (©) Explain various types of bonds in pentaborane. 4 AB-3125] 3 [Contd... 3 (A) What is thermodynamic stability ? Derive the equation OR (A) What is lability ? Give the factors affecting lability. (B) Draw energy level diagram for [CoF,]’~ ion and discuss its magnetic property OR (8) Explain Jahn-Tellor effect and explain structure of a® strong field octahedral complex (©) Explain Jahn-Tellor effect with reference to Cy*® 4 4 (A) Discuss structure and bonding in Ni(CO), 5 OR (A) What is metal carbonyl ? Give classification of metal 5 carbonyls. (B) Discuss the principles of electrochemical theory of 5 corrosion. OR ®) Write short note on "Anodic protection" and "Cathodic 5 protection" (©) Write short note on various types of inhibitors. 4 AB-3125] 4 [ 600 }

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