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6. Which statement about the reactions of halogenoalkanes with aqueous sodium hydroxide is correct?
A. Primary halogenoalkanes react mainly by an SN1 mechanism.
B. Chloroalkanes react faster than iodoalkanes.
C. Tertiary halogenoalkanes react faster than primary halogenoalkanes.
D. The rate of an SN1 reaction depends on the concentration of aqueous sodium hydroxide.
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10. Which product is formed by the reaction between CH2CH2 and HBr?
A. CH3CH2Br
B. CH2CHBr
C. BrCHCHBr
D. CH3CHBr2
11. Which reaction(s) involve(s) the formation of a positive ion?
–
I. CH3CH2CH2Br + OH
–
II. (CH3)3CBr + OH
A. I only
B. II only
C. Both I and II
D. Neither I nor II
12. Which compound has the lowest boiling point?
A. CH3CH2CH(CH3)CH3
B. (CH3)4C
C. CH3CH2CH2CH2CH3
D. CH3CH2OCH2CH3
13. Which species will show optical activity?
A. 1-chloropentane
B. 3-chloropentane
C. 1-chloro-2-methylpentane
D. 2-chloro-2-methylpentane
14. What type of reaction does the equation below represent?
CH2=CH2 + Br2 → BrCH2CH2Br
A. substitution
B. condensation
C. reduction
D. addition
The compounds are treated separately with acidified potassium dichromate(VI) solution. Which will produce a
colour change from orange to green?
A. I and II only
B. I and III only
C. II and III only
D. I, II and III
18. What is the organic product of the reaction between ethanol and ethanoic acid?
A. CH3CHO
B. CH3COOCH3
C. CH3CH2COOCH3
D. CH3COOCH2CH3
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19. Which statement is correct about the reaction between methane and chlorine?
–
A. It involves heterolytic fission and Cl ions.
B. It involves heterolytic fission and Cl radicals.
–
C. It involves homolytic fission and Cl ions.
D. It involves homolytic fission and Cl radicals.
23. Which type of compound can be made in one step from a secondary alcohol?
A. an aldehyde
B. an alkane
C. a carboxylic acid
D. a ketone
25. Which substance is not readily oxidized by acidified potassium dichromate(VI) solution?
A. propan-1-ol
B. propan-2-ol
C. propanal
D. propanone
26. Propane, C3H8, undergoes incomplete combustion in a limited amount of air. Which products are most likely to be
formed during this reaction?
A. Carbon monoxide and water
B. Carbon monoxide and hydrogen
C. Carbon dioxide and hydrogen
D. Carbon dioxide and water
28. Which of the following products could be formed from the oxidation of ethanol?
I. ethanal
II. ethanoic acid
III. ethane
A. I and II only C. II and III only
B. I and III only D. I, II and III
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29. What is the reaction type when (CH3)3CBr reacts with aqueous sodium hydroxide to form (CH 3)3COH and NaBr?
A. Addition
B. Elimination
C. SN1
D. SN2
32. How many chiral carbon atoms are present in a molecule of glucose?
A. 1
B. 2
C. 3
D. 4
33. An organic compound X reacts with excess acidified potassium dichromate(VI) to form compound Y, which reacts
with sodium carbonate to produce CO2(g).
What is a possible formula for compound X?
A. CH3CH2COOH
B. CH3CH2CH2OH
C. CH3CH(OH)CH3
D. (CH3)3COH
34. Which products can be potentially obtained from crude oil and are economically important?
I. Plastics
II. Margarine
III. Motor fuel
A. I and II only
B. I and III only
C. II and III only
D. I, II and III
35. What is the product of the following reaction?
CH3CH2CH2CN + H2
Ni
A. CH3CH2CH2NH2
B. CH3CH2CH2CH3
C. CH3CH2CH2CH2CH3
D. CH3CH2CH2CH2NH2
36. What is the correct IUPAC name for the following compound?
CH 3 CHCH 2 CH 2 CN
CH 3
A. 4-methylbutanenitrile
B. 4-methylpentanenitrile
C. 2-methylbutanenitrile
D. 2-methylpentanenitrile
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ANSWERS
1. D
2. C
3. D
4. D
5. B
6. C
7. B
8. D
9. C
10. A
11. B
12. B
13. C
14. D
15. A
16. C
17. B
18. D
19. D
20. B
21. A
22. C
23. D
24. A
25. D
26. A
27. D
28. A
29. C
30. A
31. A
32. D
33. B
34. D
35. D
36. B