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FIITJEE JEE(Main)-2014
ANSWERS, HINTS & SOLUTIONS
PART TEST–IV
(Main)
ALL INDIA TEST SERIES

Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. B C C
2. B B C
3. A A D
4. A A A
5. B A A
6. B D C
7. B C A
8. D D B
9. C D A
10. C A D
11. C D B
12. C A A
13. C B D
14. A D B
15. D C D
16. B A A
17. A A C
18. A B A
19. B B C
20. D C B
21. B C B
22. C B B
23. B D C
24. B C D
25. D B C
26. A B D
27. A C C
28. C D D
29. A B C
30. B D D

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AIITS-PT-IV-PCM(S)-JEE(Main)/14
2

Physics PART – I

SECTION – A

1 1 2 st nd
1. use   . Image after 1 reflection will act as object for 2 reflection.
v u R
2. In inductor current lags voltage by /2

D
y
4d
dy
 4I0 cos2 dy
D
D
y 
4d
3. n(4I0 )  d
4d

D
dy

4d

hc GM2
4. E 
 L
hc LM2
 dimensions of   M2
G L

5. <P> = VRMSIRMScos

11. Use Lenz’s Rule

12. Speed of image = speed of object in all the mirrors

 A  m 
sin  
13. Use  =  2 
A
sin  
2
d 2
15. =  and P =
dt R

dy
16. For CBF P = 0 = tA(A  1)  tB(B  1) +
D

18. VA  iR + 15 + (5  103)  103 = VB

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Chemistry PART – II

SECTION – A

dbcc packing efficiency of bcc 67.92

2.    0.918
dccp packing efficiency of ccp 74.02

2
3. Except Ti(+IV) in TiCl4 all other metal ions Fe3 in FeCl3 , Cu2  in CuCl2 and Mn in
MnCl2 contains unpaired electrons and are coloured.
2+
4. Fe = 0.07 mole in 0.1 mol of Fe0.9O
2+ 4+
So to balance charge, some of the place has been left vacant as Fe is replaced by Sr .
0.07 × 2 = x × 4
0.07  2
x  0.035
4
Vacant place = 0.07 – 0.035 = 0.035 NA

5. In diamond, all the carbon atoms are tetrahedrally bonded to one another so octahedral voids
cannot be occupied. Also, the lattice points and the holes are occupied by carbon atoms. As a
result the packing efficiency is less than 74%.

7. 4FeCl3  3K 4 [Fe(CN)6 ]  Fe4 [Fe(CN)6 ]3  12KCl

Prussian blue

8. SnCl2  HgCl2 
 SnCl4  Hg2Cl2 
 white

Hg2Cl2  SnCl2 
 Hg  SnCl4
grey 

YA P /P  .P0
9.  A T  A A0
YB PB / PT B .PB
Y  P0 
 B  A0 
YA

A B  PB 
PA0
Because 1
PB0
YA 
Hence  A
YB B

10. PBr5 (s) [PBr4 ] (s)  Br  (s); [i  2]

 
2PCl5 (s) [PCl6 ]  [PCl4 ] ; [i  1]
2
ratio  2
1

CRT
11. =
M

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4

RT
 4.65  10 3
M
293
8.314   4.65  103
M
5
M = 5.2410
2s
12. 3.610-7 =
55.55
(Let solubility is ‘s’)
Solubility = 105

80Po
13. PS  , W B = ?, MB = 40, W A = 114 g, MA = 114 g
100
P = 0.2 P0
WB / 40
Hence, 0.2 
 WB / 40  1
Hence W B = 10 gm

0.059
15. Eo  log10 K
n
0.059
 log10 108
2
= 0.236
EoCell  ERe
o o
duced species  EOxidised species
o
0.236  EFe 3
/ Fe 2 
 0.54
o
EFe 3
/Fe2 
 0.776V

16. Pt | H2 | H || H | H2 | Pt
1 atm x 104 1 atm
 2H  2e ; at anode
H2 g 
x
 
 H2 g; at cathode
2H  2e 
104 M
0.0591 (104 )2
Ecell  log
2 x2
–6 +
x = 10 M = [H ]

19. Copper deposited = 0.01 mole; Cu2+ already present = 0.05 mole.
Total solute remaining = 0.04 + 0.05 = 0.09 mole in 250 ml (250 gm) H2O.
0.09
Tf  K f .m  1.86   0.67
0.25
Tf = 0.67


21. (NH4)2Cr2O7  N2 + Cr2O3 + 4H2O

NH4NO2  N2 + 2H2O

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22. Zinc blende is ZnS and not ZnCl2.

23. Aluminium will react with carbon to form aluminium carbide.

26. Bi3  KI 
 BiI3 
brownish black 

KI
BiI3   BiI4 
orange
solution
yellow

27. Nitroprosside ion is [Fe(CN)5NO]2. If the central atom is present here in Fe2+ form, its effective
atomic number will be 26 – 2 + 6  2 = 36.
It does not have unpaired electron, so this anionic complex is diamagnetic. If the nitroprusside ion
3+
is having Fe and NO, the electronic distribution will be such that it will have one unpaired
electron and the complex will be paramagnetic. Thus magnetic moment measurement
established that in nitroprusside ion, the Fe and NO exist Fe|| and NO+ rather the Fe||| and NO.

hydrolysis
29. ICl3   HIO2  HCl
hydrolysis
IF5   HIO3  HF
hydrolysis
IF7   HIO 4 .2H2 O  HF
hydrolysis
ICl   HOI  HCl

30. P4O10 is anhydride of H3PO4.

All P atom are sp3 hybridized.
There are 6 (P  O  P) linkage in one molecule.

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Mathematics PART – III

SECTION – A

1. There should not be a gap of 5 or more than 5 between any two numbers from the set {3, 5, 6, 9}.
This gap can occur only when these numbers can occupy first four and last four position.
Hence number of favourable ways = 9!  2(4!  5!)
Total number of cases are 9!
2  4! 5! 62
Hence probability = 1  
9! 63

2. Required area is
  
0
 1

2  ex ln x  1  1  (x  1)2 dx 
 


1

1 1

3.  
Let d = x b  c  y  c  a   z a  b  
 
ad bd cd
Where x = , y= , z=
a b c  a b c  a b c 

      
  a b c  d  a  d b  c  b  d c  d  c  d a  b  | d | = 1.  
4. AB = A + B
 B = AB  A
= A (B  I)
 det (B)  det A  det (B  I) = 0
 det (B) = 0.

5. Given equation can be written as

2x2y (x2dy + 2xy dx) + y2 dy  x2 dx = 0
or 2x2yd (x2y) + y2 dy  x2 dx = 0
Integrating, we get
3 (x2y)2 + y3  x3 = c

6. Area of the triangle inscribed in the ellipse is maximum if difference of the eccentric angles of the
2
point A, B, C is .
3
3 3 1
So maximum area of the inscribed triangle is   8 3  3 sq units.
4 6

2 2
 1 2 3 3 6
7. PM = 1  2    0  1  2  2   2
   

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8. Take ei/3 common from R2 and multiply in C2.

9. A y
y=2
(0, 1/2)

x=2

x =- 2

y =- 2

10. If x  (0, 1)
Then 1 x + y < 0
and if x  (1, 2) 2
0x+y<1
1 
Required area = 4   1 2sin  = 2 sq 1
 2 4 
1 2 3
units.
-1 0

-1

x+y=1
x+y=0
x + y = -1

11. Writing y = vx in the given equations, we get

dv  1
x   
dx v
1
and logc + logx =
v
2 dv
–v =x
dx
 1
     v2
v
x y2
   = – 2 .
y x

 2 3 2 
12. D.C of the line PQ are  , ,  and those of the normal to the given plane are
 17 17 17 
 2 1 2 
 , , .
3 3 3 
1
If  is the angle between these two lines, then cos =
17
4
 the angle  between PQ and the plane is given by cos = .
17

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Length PQ = 17 .
4
Hence the length of the projection of PQ on the plane = 17  4.
17
13. Let Ram arrives x minutes and Shyam y
minutes after 11 noon. So they will be
able to meet if |x – y|  20. Thus y R
c
Favourable cases = Area OPQBRSO
Total ways = Area OABC
B
2000 5 (0, 20)S
 .
3600 9
x
o P A
(20, 0)

2
14. Let x – 13 = t, then
3
t – 67t + 126 = 0
 t = – 9, 2, 7  x =  2,  20 ,  15

           
15.  
a  b  2a  c  0  a  b  2c  0  a and b  2c are collinear
         
 b  2c  a | b  2c |  2 | a |2 | b |2 4 | c |2 4b  c  2 | a |2
1
 16 + 4  4 (4) (1) . = 2 (1)
4
  = 4.

 ab b2   ab b2  a2b2  a2b2 ab3  ab3  0 0 

16. A2 =     
 a2 ab   a2 ab   a3b  a3b a2b2  a2b2  0 0 
 Minimum value of n = 2

x
17. – d    xy 1  log x  dx
y
x x
  d    x 2 1  log x  dx gives solution.

y y

dy dy1
18. y1 is solution of  Py  Q is  Py1  Q …(1)
dx dx
again y2 = y1z is solution of (1)
d
then  y, z   P  y, z  = Q …(2)
dx
(2) – (1)  z
Q
  y1 dx
 z = 1 + ae .
52
C1 5 C 2 2! 50
20. P= 2

 52
C2  663

2 2
  sin x  x   2  dx    2 sq. units.
21. Required area A =  
2

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22. Area = ab =  sin cosec = .

2
23. r  a  | r  b |2  | r  c |2 = sin2  + sin2  + sin2  = 2

24. n(S) = 81, E = sum of number is 11

n (E) = 9  P(E) = 9/81 = 1/9.

 5 0
25. Pre-multiply the given equation by   , we get
 a 5 
 1 
0  1
 5 0   25  5 0
 a 5    
  x 1   a 5 
 25 
 1 
0 
 5 0   5 0   25 1 0
      
 a 5   a 5   x 1  0 1
 25 
 1 0
  2a   1 0
  
 25x 1 0 1
 5 
2a
 25x – = 0.
5

26.  A is a unit matrix

so A2 = A.

27. 2x3y dy + (1 – y2)(x2y2 + y2 – 1)dx = 0

2y dy y2 1 1
 
2 2 dx 2 x
(1  y ) 1 y x3
y2 2y dy du
Put u  
2 2 2
1 y (1  y ) dx dx
du u 1
   3
dx x x
1
u.x = 2
xdx  c  x2y2 = (cx – 1)(1 – y2).
x

28. a  b  ˆi  ˆj  kˆ
ˆi  ˆj  kˆ
 c  .
3

30. Equation of circle will be (x + r)2 + y2 = r2.

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