J Resonence Educating for better tomorrow TARGET : JEE (ADVANCED) 2015 DAILY PRACTICE PROBLEMS — Course : VIJETA& VIJAY (ADP & ADR) Date : 05-05-2015 NO. 09 TEST INFORMATION DATE : 06.05.2015 PART TEST (PT) - 04 Syllabus : Physical : Atomic Structure, Nuclear chemistry, Chemical Kinetics, Inorganic : Qualitative Analysis, Metallurgy, d & f-block Elements. DPP No. # 09 (JEE-ADVANCED) Total Marks : 169 Max. Time : 137 min. Single choice Objective (~1 negative marking) Q.1 to Q.15 (3 marks 2% min.) [45, 37%] Multiple choice objective (1 negative marking) Q.16 to @.20 (4 marks, 3 min.) [20, 15] Assertion and Reason ('-1" negative marking) Q.21 to 0.23 (3 marks 2% min.) [09, 7%] Comprehension (~1 negative marking) Q.24 to Q.32 (3 marks 2% min.) [27, 22%] Single Digit Subjective Questions (no negative marking) Q.33toQ.38 (marks 2% min.) —_—[24, 15] Double Digit Subjective Questions (no negative marking) 2.90.41 (4 marks 2% min.) ——_[12, 7.5] Match the column (4 vs 4) (no negative marking) Q.42 (8 marks, 8 min.) (08, 08] Match the column (4 vs 5) (no negative marking) Q.43 to Q.45 (8 marks, 8 min.) [24,24] 1. Bia,Ne2t ot, major product UV Fat ON Major product is, Br Br Br a oO ® So © )} on on Br ‘No, on’ 2. Inthe reactions given below (KCN (ii) LiAIH, (CH;-CH,CI Product A cli cH,cl DAICN ALAM. products The compoundA and B are (A) Chain isomers (8) Position isomers (©) Functional isomers (©) Metamers R [Corporate Office | OG Tower, A466 62, PIA, Noat Oly Mall, Jhalawar Road, Kola (al ESONSNCE hietsterramareeonencescmT Educating for better tomorrow carrraeTaGO ZOD ZIGT TOD 255 SESS] CH USSISERIEOOTPT COTOHOBriH® on{O)y-ee-{O)-o ———* The major product is: p r “Ot O~ a OyLO- bb 8 be Br Br OH OH OH OH w(Oprorrororon @ (Oyen on go 8 CH-©-CH, © (Op yromo © © Ce oO CH, O 2 Hera, Product ‘oO Product is oC, ©) LJ ©) © . C OH Ho) CH, (Cult. x (Major product) i CH,-CH-CH,-CH, + LBishw, ¥ (Major product) X and Y are respectively oH, oH cH, GH. (a) CHe-G-CH.-CH,, CH,-G-CH,-CH, (@ CH-CH-CH-CH, | CH-CH-CH-CH, a Br a Br oH, oH oh, oH, (©) CH-CH-GH-CH, CH-G-CH.-CH, (0) CH. -CH.-CH, , CH=CH -CH-CH, cl Br a Br arpa Oi CS Tost A BER, Wat Gy Wa tay Roe Ra RESONSNCE rene rmaresmmeonT Educating for better tomorrow carrraeTaGO ZOD ZIGT TOD 255 SESS] CH USSISERIEOOTPT COTO10. 1. 12. Which of these reaction gives meso compound as product ? CH CHS na Phos oeCH Wr ype=cG eae, ye“ Spy —Baersonmet_, Hye eP hoa Hao ecH MCPBA ©) pyr = Ny Path ©) py7O = C\ph,“Wetaconerbersic acs Identify the major product(P) of the following sequence of reaction. api, HBr mp, _@Acstone_, _H,50, CHy (Only one isomer} Ether (ii) NHZCI 8 P “ co © Se © a © Cc The pair of compounds in which both the compounds give positive test with Tollen’s reagent and Fehling solution is (A) Glucose and Sucrose (®) Propanal and Benzaldehyde (C) Propanal and 2-Phenylethanal (O) Benzaldehyde and 1-Hydroxypropanone Which of the following is monomeric unit of the polymer Nylon-5 ? ~NH~ (CH, -NH=(CH),— P= NHECH),- 6 = é é ° NH “ ® oe ° © H ()NH,4CH),-NH, + HOOC-{CH.),—COOH Select the correct statements about the following fl 0. CH,OH H -OH HO- H Hot bj H-OHO ac 0/604 H—-OH 4 Aeylation H CH,OH CH.OH (i) sucrose forms an octaacetate (i) sucrose is nonreducing suger. (i) sucrose is a polysaccharide #O0.Gi) 8) (0, (i, Gi) © 0.6 (©) only () A polypeptide contains five type of «-amino acids. It gives following dipeptides only on hydrolysis. (Asp, Glu, His, Phe, Val) —Y®¥S8_, (yal-asp + Glu-His + Phe-Val + Asp-Glu) The correct sequence of amino acids in the polypeptide is (A) Asp-Glu-His-Phe-Val (B) Phe-Val-Asp-Glu-His (©) VakAsp-Giu-His-Phe (©) Glutis-Phe-Val-Asp-Glu-VakAsp arpa Oc CS Tot EH BER ar CW Tay Ro Rae HF THOS Resonance} cating for better tomorrow carereeTSGS ZOD ZIG TOD 255 SSSR] CU USSICER ISOC TPT CUETO13. 14. 15. The following compound on hydrolysis will give HOH cH, n}—o4 ON oH WL Ku HO HO CHOH HOH HOH (A)Apair of anomers ® Apair of enantiomers (©)Apair of epimers (O)Apair of functional isomers (Observe the following road map and identify the carbohydrate 'X’ (Tagatose) (It shows mutarotation) (Negative) < BENS (c41,0) Toten eagent_, (Mixture of we ) 5? Nepimeric acids, (Tagatose) (has pyranose structure) HOH _ naa HOH OH 4 non a non w wtol @® "*7T*] ©, 1, | © ° Hon HoH § anion ° H on? non H——o# o . H on H HOH iM 4 cHoH 4 ti) HO L161, (2) P1 and P2are respectively 19 <> 00H 8 <> 0H) o> 080, TL. : oP ol SS er Resonance} ducating for better tomorrow [Corporate Otfice + OG Tower, AAG & 62, PIA, Neat Giy Wall, Jhalawar Road, Kota (Raj) W2400516. 47. 18. 19. 20. R-G-OR' —LMeMgEr_, acetone as the sole organic product. W 2.H0° which is/are correctly matched with R and R’ (A)R=-H ®R (R=-EH-CH, OR cH, Which of the following would be the significant product/s of the given reaction? °, H-C=C-cH-cH=cH, —H (aces) | oH (A) CH = CH-C-CH=CH (®)CH,= CH-CH=CH-CHO i ° (©) H-C=0-C~CH; ~CHy (©) CH) ~CH=CH-C = CH IL | ° oH Select the chain propagation steps in the free radical chlorination of methane ? (A) cl, —> 201 (8) CH,+ Cl,—> CHCl + a1 (©) GH, + G1 —>cH-cl (0) RO+ CH ROH + CH, Following graph between AG and reaction progress represented by which of the following reaction ? a] DA reaction (A) S\1 reaction ®)E, reaction (©) Aromatic electrophilic substiution (©) Electrophilic addition reaction CH, (0 Bote THF (i202 108 True statement about above reaction (A) Reagent involve stereospecific SYN addition of H and OH species (B) Product obtained is trans isomer (©) BH, acts as electrophile (D) two stereoisomers are obtained as product arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrow21. 22, 23. STATEMENT-1 : 2-Bromobutane on heating with alcoholic KOH gives 3 isomeric alkenes which on treatment with Br /CCI, give 5 products, STATEMENT-2:: Stereochemical nature of elimination by alcoholic KOH and addition of Br, is ANTI and SYN respectively. (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (B) Staterent-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2 is False. (0) Statement-1 is False, Statement-2 is True. STATEMENT : The rate of catalytic hydrogenation of ethyne at raney nickel finely divided Nis faster than that of ethene. STATEMENT-2 : Calalytic hydrogenation of ethyne to ethane is less exothermic than that of ethene to ethane. (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1 (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2 is False. (©) Statement-t is False, Statement-2is True STATEMENT -1 : Hydrolysis of sucrose brings a change in sign of rotation towards plane polarised light. STATEMENT -2 : Fructose has specific rotation -92.4 and glucose has +52.5° (A) Statement-1 is True, Statement-2 is True; Statement-2s a correct explanation for Statement-1 (B) Staterent-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-t is True, Statement-2 is False (0) Statement-1 is False, Statement-2 is True Comprehension #1 24. 2. ‘CH.OH CH.OH CH.OH H OH H AH 4 A oinwiatn , 4 HOH ae IH ; oO ‘OH HOH HOH a Starch (polymer) (III) What is true about compound (1) (A) Ithas an acetal structure (B)Ithas tertiary hydroxy group (©) thas a hemiacetal structure (0) Its degree of unsaturation is two ‘Compound (Il ismhas (A)A polysaccharide (8) Oligosaccharide (C) Monosaccharide (D) Hydrogen deficiency indexis three [Corporate Office + OG Tower, AG & 62, PIA, Neat Gly Wall, Jhalawar Road, Kola (a) jie yaw resonance oT TE TED SOU BEET TOOD SB SST CO URIOAR TOOT PTCORIOR Resonance} Educating for better tomorrow28. Assuming that polymerisation of (1) takes place in the manner similar to its dimerisation, then the structure of polymer (III) can be correctly represented as chow 4 QH 4 LA 4 ® Ly o © on On © Comprehension #2 CH fomo1, p MONIC, q Nails yp Onl2n yg Red, 7 Baim (Major product) £20, y 27. When's reacted with PhMgBrthe product formed is (A) PhCH CH, ~ GH— Ph (® Ph—CH—CH,~ CHO bu OH bu © oO (©) Ph—-CH—Ph OH 28, Thetotal number of monochloro products of compound 'V' and the fractional stilton of product mixture respectively are A4,4 (86,5 (C)6,4 4,2 28, Compounds which liberate H, gas with Na metal are (APS (@P (C)P,R,S Os,v arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} cating for better tomorrow carereeTSGS ZOD ZIG TOD 255 SSSR] CU USSICER ISOC TPT CUETOComprehension #3 cooMe jp ease cross wo | ett? 2nicoH cooMe 30. Reagent 'P'is (A) NaiNH, (i) (HANI 31. The structure of the product Q is “a Ne z ° al Me, oH (OM, 20 HD ao he 5 MOMO2 _, ainses of: B108 (NHN ho® Jon (8H, , Pd-BaSO, (quinoline) (0) NaBH, Me. Me @r oH Me. Me ©) Me on We 32, Thestrutueof Ris Me te Me gM oY ¥ 8 Lo4 we Me Me Me, Me © ie I om I Mee Me We 33, Thesum of structural and diastereomers ofa hydroxy compound C,H,O, formed by the substituion reaction of 3-chlorobut-1-ene wth AgNO, solution. 34. How many alkenes (be sure to consider the stereochemistry of the alkene) can be hydrogenated to form methyl cyclohexane. Resonance} Educating for better tomorrow [Corporate Office + OG Tower, AG & 62, PIA, Neat Gly Wall, Jhalawar Road, Kola (a)36. 36. 37. 38. 39. ‘An optically active compound (M) on ozonlysis gives following structure in absence of zine. COOH Hooc OH if (M) does not responds to NaHCO, test, what product is obtained when (M) isheated in presence of cone. H,SO, as catalyst. Fill the number against product in key oH ” OL @ w ° 6x ® OL Ho on on oH oH © © Ou o Yor ® Cx Ho cH, ‘CH, OH Lithium di(3-pentyt) cuperate on reaction with an alkyl bromide produces (X) C,H,,. The mixture of all monochloro isomers formed from (X) are subjected to fractional distillation. Find the number of fractions obtained Observe the following reaction and find out that how many number of reactant stereoisomers can be reduced to optically inactive meso products. Ho grow GHoH bHoH GHOH NaBH, 5 GHOH CHOH bHoH HOH bon GH.0H HOH Among the 6, how many cyclic isomers of molecular formula C,H, Br can form 1-methyleyclohexane-1-ol on reaction with H,O/acetone/Ag’. SES XR ‘An undergraduate student heated 2-Cyclopentylethy! ethanoate at 300°C to obtain an unsaturated hydrocarbon K" which was then treated with mercuric acetate followed by water then sodium Borohydride to give *L” which is dehydrated by concentrated H,SO, at 180° C to give *M" as major product, Find molecular mass of ‘compound*M" arpa Oi CS Tot SH BER War Ci Wa Tay Ro Rae ay Resonance} ducating for better tomorrow40. Ozonolysis of next higher homolog of simplest alkene in presence of zinc yields (A) and (B). (A) gives positive iodoform test while (B) does not, (A) when treated with excess of (8) in NaOH solution gives (C) and (0) as final product after acidification. If"C" gives positive NaHCO, test then calculate molecular mass of (0). Report your answer as molecular mass divided by 4. 41. Observe the following sequence of reactions and report your answer as molecular weight/10 : Bez ihn HI ead » ae xo, amo 40H? p Br 42. Column=1 Column — 11 (A) CH,-C=C-CH, > CH-CH=CH-CH, (p) Rate of HBr addition (©)CH.-CH=CH, > CH,-C=CH ( AH of hydrogenation cH, (dD) el > oO (S) AH of combustion cH, 43. Match the reactions given in column | with ther properties lstedin column I Column =1 Column = i Ph “ . 4 ()Antielimination COOH—}— COOH Ph (8) Ph-c=C-Ph —— > (q) stereoselective eisone Ph ner © y+ or 2n, CHO, (9 Optical diastereomers Ph (0) Ph-e-GD-G-0H (9)CO,willevolve 8&8 () Racemic mixture eoipeate OWICe © GS Tovar KAGE EPR Wot ly Wal, Talat Road, Kola Ry SEE Resonance} cating for better tomorrow carereeTSGS ZOD ZIG TOD 255 SSSR] CU USSICER ISOC TPT CUETO44, Column (A) CH,-C=CH I @cH-¢ H ()HCOOH ()CH,-CH=CH, 45. Column CH, el CH,-Cl ®) hy (NaOH! 6 aH © Br CH=CH, © oon aon Column (p) Undergoes oxidation (@) Undergoes reduction (9 Gives ppt. with AgNOJNH,OH (6) Can be reduced with help of H,/Pt (catalytic hydrogenation) ( more acidic than water Column (p) Substitution reaction (@) Free radical reaction (®) Nucleophile is the attacking species. (8) Electrophile is the attacking species, (® Addition reaction, Resonance} ducating for better tomorrow [Corporate Otfice + OG Tower, AAG & 62, PIA, Neat Giy Wall, Jhalawar Road, Kota (Raj) W24005