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CONTROL OF SUBSTANCES

HAZARDOUS TO HEALTH
Publication No. 3334 Issue 05 - June 2003

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Control of Substances Hazardous to Health Publication 3334

Issue 05 - June ‘03

CONTENTS
Section Title Page

1 Introduction ........................................................................................................................ 1-1

2 Antifreeze (Fleetguard – ES compleat/EG premix) ........................................................ 2-1

3 Antifreeze (Valvoline coolant premix).............................................................................. 3-1

4 Antifreeze (Valvoline – MPG Coolant 50/50) .................................................................. 4-1

5 Antifreeze (Valvoline – MPG Coolant 67/33) .................................................................. 5-1

6 Coolant Treatment – Water Filter.................................................................................... 6-1

7 Coolant Treatment - Liquid Additive............................................................................... 7-1

8 Gas Oil................................................................................................................................. 8-1

9 Grease – Mobilgrease XTC ............................................................................................... 9-1

10 Grease –Val-Lith EP 2 ..................................................................................................... 10-1

11 Lubrication Oil – Premium Blue E 15W40.................................................................... 11-1

12 Lubrication Oil – Premium Blue GEO 15W40 ............................................................. 12-1

13 Lubrication Oil – Premium Blue GEO-LA 40............................................................... 13-1

14 Natural Gas ....................................................................................................................... 14-1

15 Sulphuric Acid Battery Quality 1140 – 1400 SG (15-50%) .......................................... 15-1

16 Potassium Hydroxide - Solid ........................................................................................... 16-1

17 Potassium Hydroxide - Solution...................................................................................... 17-1

Contents
Page i

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Publication 3334 Control of Substances Hazardous to Health
Issue 05 - June ‘03

Page ii
Contents

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Control of Substances Hazardous to Health Publication 3334

Issue 05 - June ‘03

SECTION 1 – INTRODUCTION
1 Introduction
The generating set(s) covered by this manual contains several substances that require
special consideration when handling to avoid becoming hazardous to health and safety.
Personnel operating and maintaining the machinery must read the following notices and
follow all of the instructions given.
Operators of generating plant and machinery must obtain the relevant suppliers’ Material
Safety Data Sheets, and information/instructions therein should take precedent over the
information provided within this document. In the absence of the suppliers' information,
the following information may be used on a temporary basis only. In addition to
preventing hazards to personal health, these instructions are designed to minimise
environmental damage and pollution.
The information contained herein is based on the data available to us. It is the
responsibility of the user to comply with any relevant laws and regulations that may exist.

Section 1 – Introduction Page 1-1

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Publication 3334 Control of Substances Hazardous to Health
Issue 05 - June ‘03

Page 1-2
Section 1 – Introduction

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Control of Substances Hazardous to Health Publication 3334

Issue 05 - June ‘03

2 Antifreeze (Fleetguard – ES compleat/EG premix)


2.1 Other Names
Ethylene Glycol based coolant, summer coolant, coolant additive.

2.2 Appearance
A purple coloured, viscous liquid, with a mild chemical odour, is soluble in water and
harmful. The substance has a boiling point of 107oC, and a flash point of 121oC.

2.3 Recommended Use


Engine coolant additive.

2.4 Where Found


Engine cooling systems, heat exchangers.

2.5 Constituents
Ethylene glycol, Diethylene glycol.

2.6 Potentially Hazardous Constituents


Ethylene glycol.

2.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

2.8 Hazardous Reactions


Ethylene glycol is combustible when exposed to heat or flame and can react vigorously
with oxidants. Moderate explosion hazard in form of vapour when exposed to heat or
flame. Hazardous products resulting from combustion or decomposition include carbon
monoxide, carbon dioxide and acrid smoke. Self-contained breathing apparatus must be
worn in the event of fume build up.
Avoid strong oxidising agents – incompatible with sulphuric acid, nitric acid, caustics and
aliphatic amines.
Refrain from eating, drinking or smoking when using the product.

2.9 Effects of Over-exposure


May cause neurological signs and symptoms, and kidney damage.
Very toxic in particulate form upon inhalation. Harmful if swallowed, lethal dose for
humans reported to be 100ml.
Skin and eye irritant.

2.10 Storage / Transport


Store and transport only in correctly marked containers. Keep cool, out of sunlight, away
from naked flames and strong acids, do not freeze. Store well away from food-stuffs and
drinking water. Take special care to avoid discharge into drains, sewers and water-
courses.

Section 2 – Antifreeze (Fleetguard – ES compleat/EG Premix) Page 2-1

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2.11 Protective Measures


Ensure good ventilation and avoid heat sources. Wash thoroughly after handling.

2.12 Personal Protection Equipment


Eye protection, gloves, overalls, impervious apron. Avoid contamination inside the gloves.
If overalls become contaminated, discontinue use and clean thoroughly.
Avoid breathing mist.

2.13 Hygiene
Adopt a high standard of personal hygiene. In case of skin contact wash immediately with
soap and water.

2.14 Environmental Protection


Contain leak/spill with sand, earth or non-combustible, absorbent material to prevent
entry of substance into drainage/sewerage system, water-courses and land. Eliminate all
ignition sources, use plastic shovel to transfer to suitable container and dispose of
unwanted or absorbed substance through an authorised contractor to a licensed site.

2.15 Emergency Action


2.15.1 Fire
Extinguishing media: CO2, alcohol resistant foam, dry powder, or water spray.
Fire fighters to use self contained breathing apparatus. Keep fire exposed containers
cool. Prevent run-off from entering waterways, drains and drinking water supplies.

2.15.2 Ingestion
Toxic by ingestion. If swallowed induce vomiting only under the advice of a Doctor or
poison control centre.
Delayed treatment may result in fatality.

2.15.3 Inhalation (of vapour)


Remove from further exposure. In case of irritation to lungs or throat, seek medical
advice.

2.15.4 Aspiration (inhalation of liquid)


Obtain immediate medical assistance.

2.15.5 Eyes
Flush copiously with water or preferably eye-wash solution for at least five minutes. Seek
medical advice.

2.15.6 Skin
Wash thoroughly with soap and water, and seek medical attention if irritation develops.
Change clothing if necessary and wash before re-use.

2.15.7 Spillage
Soak-up using an absorbent material and dispose of this as directed under Environmental
Protection

Page 2-2
Section 2 – Antifreeze (Fleetguard – ES compleat/EG Premix)

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3 Antifreeze (Valvoline coolant premix)


3.1 Other Names
Antifreeze

3.2 Appearance
A green, viscous liquid, which is practically odourless, and soluble in water The
substance has a boiling point between 171-203oC, with a flash point of 118oC, and a
vapour pressure of 0.4mm Hg at 20oC.

3.3 Recommended Use


Engine coolant additive.

3.4 Where Found


Engine cooling systems, heat exchangers.

3.5 Constituents
Ethylene glycol, Diethylene glycol.

3.6 Potentially Hazardous Constituents


Ethylene glycol.

3.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

3.8 Hazardous Reactions


This product is considered stable but must be kept away from oxidising agents.
In the event of a fire, or excessive heat, there is a risk of the containing drum bursting.

3.9 Effects of Over-exposure


Harmful, or fatal, if swallowed. At elevated temperatures vapour, or particulate, may
irritate respiratory tract and continued exposure is reported to induce unconsciousness.
May cause skin sensitisation.

3.10 Storage / Transport


Store and transport only in correctly marked containers. Keep cool, out of sunlight and
away from naked flames. Store well away from food-stuffs and drinking water. Take
special care to avoid discharge into drains, sewers and water-courses.

3.11 Protective Measures


Ensure good ventilation and avoid heat sources.
Refrain from eating, drinking or smoking when using the product.

Section 3 – Antifreeze (Valvoline coolant premix) Page 3-1

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3.12 Personal Protection Equipment


Eye protection, rubber or PVC gloves, overalls, impervious apron. Avoid contamination
inside the gloves. If overalls become contaminated, discontinue use and clean
thoroughly.
Ensure good ventilation. If there is a risk of vapour, or particulate, use a suitable organic
vapour mask.

3.13 Hygiene
Adopt a high standard of personal hygiene. In case of skin contact, wash with soap and
clean water.

3.14 Environmental Protection


Contain leak/spill with sand or earth, and prevent entry of substance into
drainage/sewerage system, water-courses and land. Dispose of unwanted or absorbed
substance through an authorised contractor to a licensed site.

3.15 Emergency Action


3.15.1 Fire
Extinguishing media: Large fires - alcohol resistant foam, or water fog.
Small fires - CO2, alcohol resistant foam, dry chemical, sand, earth
or water fog.
Fire-fighters to use self contained breathing apparatus. Keep fire exposed containers
cool. Prevent run-off from entering waterways, drains and drinking water supplies.

3.15.2 Ingestion
Harmful or fatal if swallowed. Rinse mouth with water. If conscious, give water to drink
and obtain medical advice.

3.15.3 Inhalation (of vapour)


Remove from further exposure. In case of irritation to lungs or throat, seek medical
advice.

3.15.4 Aspiration (inhalation of liquid)


Obtain immediate medical assistance.

3.15.5 Eyes
Flush copiously with water or preferably eye-wash solution for at least fifteen minutes. If
irritation persists seek medical advice.

3.15.6 Skin
Wash thoroughly with soap and water, and seek medical attention if irritation develops.
Change clothing if necessary and wash before re-use.

3.15.7 Spillage
Soak-up using an absorbent material and dispose of this as directed under Environmental
Protection.

Page 3-2
Section 3 – Antifreeze (Valvoline coolant premix)

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4 Antifreeze (Valvoline – MPG Coolant 50/50)


4.1 Other Names
Propylene Glycol based coolant

4.2 Appearance
A colourless liquid with a mild odour, and soluble in water. The substance has a flash
point of 112°C min.

4.3 Recommended Use


Engine coolant, suitable for open and closed cooling systems.

4.4 Where found


Engine cooling systems.

4.5 Constituents
2-propane diol, Ethylhexanoic acid (Sodium salt), Aliphatic acid.

4.6 Potentially Hazardous Constituents


2-propane diol, Ethylhexanoic acid.

4.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

4.8 Hazardous Reactions


This product is considered stable but must be kept away from strong oxidizing agents,
acids. and sources of ignition.
Oxides of carbon. aldehydes and ketones are products of decomposition.

4.9 Effects of Over-exposure


Prolonged contact, as with clothing wetted with material, may cause more severe irritation
and discomfort, seen as local redness and swelling.
If more than several mouthfuls are swallowed, abdominal discomfort, nausea and
diarrhea may occur.

4.10 Storage / Transport


Store and transport only in correctly marked, tightly closed, containers. Keep cool, out of
sunlight and away from naked flames. Keep away from incompatibles such as oxidizing
agents, acids, and water.

4.11 Protective Measures


Ensure good ventilation and avoid heat sources.
Refrain from eating, drinking or smoking when using this product.

Section 4 – Antifreeze (Valvoline - MPG coolant 50/50)Page 4-1

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4.12 Personal Protection Equipment


Wear appropriate respirator when ventilation is inadequate. Use a lab coat, impervious
gloves and eye protection. Avoid contamination inside the gloves and if clothes become
contaminated, discontinue use and clean thoroughly.

4.13 Hygiene
Adopt a high standard of personal hygiene. In the case of skin contact, wash with soap
and water. Cold water may be used.

4.14 Environmental Protection


Absorb with an inert material and put the spilled material in an appropriate waste
disposal. Dispose of unwanted or absorbed substance through an authorized contractor
to a licensed site. Finish cleaning by spreading water on the contaminated surface and
allow to evacuate through the sanitary system.

4.15 Emergency Action


4.15.1 Fire
Extinguishing media: Use water fog, dry powder, foam or carbon dioxide. Water or foam
may cause frothing. If a leak or spill has not ignited, use water fog
to disperse the vapours. Do not use a water jet.
Fire-fighters to use self contained breathing apparatus. Keep fire-exposed containers
cool. Prevent large quantities from entering waterways, drains and drinking water
supplies.

4.15.2 Ingestion
If patient is conscious and can swallow, give two glasses of water (500ml). Induce
vomiting as directed by medical personnel.

4.15.3 Inhalation (of vapour)


If irritation, headache, nausea or drowsiness occurs, remove to fresh air. Get medical
attention if breathing becomes difficult, or symptoms persist.

4.15.4 Aspiration (inhalation of liquid)


Obtain immediate medical assistance.

4.15.5 Eyes
Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation
persists.

4.15.6 Skin
Wash thoroughly with soap and water for several minutes. Get medical attention if skin
irritation develops or persists.

4.15.7 Spillage
Contain spill if possible, and dispose of as directed under Environmental Protection.

Page 4-2
Section 4 – Antifreeze (Valvoline - MPG coolant 50/50)

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Control of Substances Hazardous to Health Publication 3334

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5 Antifreeze (Valvoline – MPG Coolant 67/33)


5.1 Other Names
Propylene Glycol based coolant

5.2 Appearance
A colourless liquid with a slight characteristic odour, easily soluble in cold water. It has a
boiling point greater than 120°C (248°F) and a flash point Closed Cup greater than 115°C
(239°F).

5.3 Recommended Use


Engine coolant, suitable for open and closed cooling systems.

5.4 Where found


Engine cooling systems.

5.5 Constituents
2-propane diol, Ethylhexanoic acid (Sodium salt), Aliphatic acid.

5.6 Potentially Hazardous Constituents


2-propane diol, Ethylhexanoic acid.

5.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

5.8 Hazardous Reactions


This product is considered stable but must be kept away from strong oxidizing agents,
acids. and sources of ignition.
Carbon Oxides (CO, CO2) and water, and some metallic oxides are products of
decomposition.

5.9 Effects of Over-exposure


Prolonged contact, as with clothing wetted with material, may cause more severe irritation
and discomfort, seen as local redness and swelling.
If more than several mouthfuls are swallowed, abdominal discomfort, nausea and
diarrhea may occur.
Contains material which may cause birth defects based on animal data.

5.10 Storage / Transport


Store and transport only in correctly marked, tightly closed, containers. Keep cool, out of
sunlight and away from sources of ignition. Keep away from incompatibles such as
oxidizing agents, acids, and water.

5.11 Protective Measures


Ensure good ventilation and avoid heat sources.
Refrain from eating, drinking or smoking when using this product.

Section 5 – Antifreeze (Valvoline - MPG coolant 67/33)Page 5-1

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5.12 Personal Protection Equipment


Wear appropriate respirator when ventilation is inadequate. Use a lab coat, impervious
gloves and eye protection. Avoid contamination inside the gloves and if clothes become
contaminated, discontinue use and clean thoroughly.

5.13 Hygiene
Adopt a high standard of personal hygiene. In the case of skin contact, wash with soap
and water. Cold water may be used.

5.14 Environmental Protection


Absorb with an inert material and put the spilled material in an appropriate waste
disposal. Dispose of unwanted or absorbed substance through an authorized contractor
to a licensed site. Finish cleaning by spreading water on the contaminated surface and
allow to evacuate through the sanitary system.

5.15 Emergency Action


5.15.1 Fire
Extinguishing media: Small Fire - Use dry chemical powder, or CO2.
Large Fire – Use water spray, fog or foam. Do not use a water jet.
Fire-fighters to use self contained breathing apparatus and full turnout gear. Keep fire-
exposed containers cool. Prevent large quantities from entering waterways, drains and
drinking water supplies.

5.15.2 Ingestion
Do not induce vomiting unless directed to do so by medical personnel. Loosen tight
clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.

5.15.3 Inhalation (of vapour)


If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Obtain medical attention.

5.15.4 Aspiration (inhalation of liquid)


Obtain immediate medical assistance.

5.15.5 Eyes
Flush eyes with plenty of water for minimum of fifteen minutes. Cold water may be used.
Obtain medical attention.

5.15.6 Skin
Wash thoroughly with soap and water for several minutes. Get medical attention if skin
irritation develops. Cold water may be used.

5.15.7 Spillage
Contain spill if possible, and dispose of as directed under Environmental Protection.

Page 5-2
Section 5 – Antifreeze (Valvoline - MPG coolant 67/33)

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6 Coolant Treatment – Water Filter


6.1 Other Names
Coolant additive, engine coolant treatment, Fleetguard DCA-4/powder/paste/pellet.

6.2 Appearance
Product is a white solid (powder or pellet) or blue paste inside a filter container, having a
mild chemical odour, and soluble in water.

6.3 Recommended Use


Engine coolant additive.

6.4 Where Found


Engine cooling systems, heat exchangers, radiators.

6.5 Constituents
Dipotassium phosphate, potassium nitrate, sodium molybdate, sodium nitrite,
mercaptobenzo thiazole, sodium silicate.

6.6 Potentially Hazardous Constituents


Alkaline salts, nitrates, nitrites, etc.

6.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

6.8 Hazardous Reactions


Incompatible with strong acids and oxidising materials. In contact with strong acids may
form nitrous oxide gas.
Contact of sodium nitrate with combustible materials and organic matter may cause fire.
Sodium nitrite intensifies fires of other materials. When heated to decomposition, Nox and
K2O emitted.

6.9 Effects of Over-exposure


Dust may irritate nasal passages. Prolonged or repeated contact with the skin will cause
irritation. Will irritate eyes on contact. Not to be taken internally.

6.10 Storage / Transport


Store and transport only in correctly marked containers. Keep cool, out of sunlight and
away from naked flames. Keep product dry and container closed when not in use. Store
well away from food-stuffs and drinking water. Take special care to avoid discharge into
drains, sewers and water-courses.

6.11 Protective Measures


Ensure good ventilation and avoid heat sources. For industrial use only.

Section 6 – Coolant Treatment – Water Filter Page 6-1

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6.12 Personal Protection Equipment


Eye protection, dust mask, PVC gloves, overalls and plastic aprons. Avoid contamination
inside the gloves. If overalls become contaminated, discontinue use and clean
thoroughly. Use a respirator to avoid inhalation of dust.

6.13 Hygiene
Adopt a high standard of personal hygiene. In case of skin contact wash immediately with
soap and water.

6.14 Environmental Protection


Sweep up and return to container for use if not contaminated. Prevent entry of substance
into drainage / sewerage system, water-courses and land. Dispose of unwanted
substance through a licensed chemical disposal service.

6.15 Emergency Action


6.15.1 Fire
Extinguishing media: CO2, dry powder, water.
Fire-fighters to use self contained breathing apparatus. Keep fire exposed containers
cool. Prevent run-off from entering waterways, drains and drinking water supplies.

6.15.2 Ingestion
Toxic by ingestion. Seek medical advice immediately.

6.15.3 Inhalation (of vapour)


Remove from further exposure. In case of irritation to lungs or throat, seek medical
advice.

6.15.4 Eyes
Flush copiously with water for at least fifteen minutes Seek medical advice immediately.

6.15.5 Skin
Wash immediately with soap and water. Seek medical advice If irritation develops or
persists. Change clothing if necessary and wash before re-use.

6.15.6 Spillage
Sweep up and return to container if not contaminated. Discard contaminated product as
directed under Environmental Protection.

Page 6-2
Section 6 – Coolant Treatment – Water Filter

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7 Coolant Treatment - Liquid Additive


7.1 Other Names
Coolant additive, liquid cooling conditioner, Fleetguard DCA-4 Liquid.

7.2 Appearance
Pale blue liquid with a mild chemical odour. This substance has a boiling point of 100oC;
vapour pressure of 760mm Hg at 100oC, and is soluble in water

7.3 Recommended Use


Engine coolant additive.

7.4 Where Found


Engine cooling systems, heat exchangers, radiators

7.5 Constituents
Potassium phosphate, potassium nitrate, sodium molybdate, sodium nitrite, adipic acid.

7.6 Potentially Hazardous Constituents


Alkaline salts, nitrates, nitrites, etc.

7.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

7.8 Hazardous Reactions


Sodium nitrite/potassium nitrate are strong oxidisers. Avoid organic matter (including
wood), cyanides, strong acids, salts and urea. This product may ignite with heat or
friction. When heated to decomposition, Nox, K2O, sodium monoxide, carbon monoxide
and carbon dioxide are emitted.

7.9 Effects of Over-exposure


Contact will cause irritation to both skin and eyes. Inhalation may cause nasal passage
and upper respiratory tract irritation. Ingestion can cause severe vomiting, shock and
death. Ingestion of sodium nitrite can result in motor activity changes, coma, and
decreased blood pressure.

7.10 Storage / Transport


Store and transport only in correctly marked containers. Keep cool (but do not freeze), out
of sunlight and away from naked flames and strong acids. Keep product container closed
when not in use. Store well away from food-stuffs and drinking water. Take special care
to avoid discharge into drains, sewers and water-courses

7.11 Protective Measures


Ensure good ventilation and avoid heat sources. Avoid breathing mist. Observance of
good housekeeping rules will ensure general safety.

Section 7 – Coolant Treatment – Liquid Additive Page 7-1

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7.12 Personal Protection Equipment


Eye protection goggles, PVC gloves, overalls, Impervious apron. Avoid contamination
inside the gloves. If overalls become contaminated, discontinue use and clean
thoroughly. No special respiratory precautions are necessary in normal use.

7.13 Hygiene
Adopt a high standard of personal hygiene. In case of skin contact irrigate with copious
quantities of clean water.

7.14 Environmental Protection


Prevent entry of liquid into drainage/sewerage system, water-courses and land. Use
industrial absorbent and place in suitable container. Dispose of unwanted liquid through
an authorised contractor to a licensed chemical disposal service.

7.15 Emergency Action


7.15.1 Fire
Extinguishing media: Water, carbon dioxide, dry powder.
Fire fighters should wear self-contained breathing apparatus. Keep fire exposed
containers cool. Prevent run-off from entering waterways, drains and drinking water
supplies.

7.15.2 Ingestion
Toxic by ingestion. Ingestion can cause severe vomiting, shock and death. Ingestion of
sodium nitrite can result in motor activity changes, coma, and decreased blood pressure.
Seek medical advice immediately.

7.15.3 Inhalation (of vapour)


Remove to fresh air. If symptoms persist seek medical advice.

7.15.4 Eyes
Flush copiously with water for at least fifteen minutes. Seek medical advice immediately.

7.15.5 Skin
Wash immediately with soap and water. If irritation develops or persists seek medical
advice. Change clothing if necessary and wash before re-use.

7.15.6 Spillage
Contain leak / spill and prevent entry of liquid into drainage/sewerage system, water-
courses and land. Use industrial absorbent and dispose of to an authorised contractor to
a licensed chemical disposal service.

Page 7-2
Section 7 – Coolant Treatment – Liquid Additive

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Issue 05 - June ‘03

8 Gas Oil
8.1 Other Names
Red Diesel; Fuel Oil; 35 second Oil.

8.2 Appearance
Pale red or clear liquid with a characteristic mild odour. The substance has an initial
boiling point of 180oC, a flash point greater than 56oC, and a vapour pressure less than
0.7mm Hg at 20oC and has negligible solubility in water.

8.3 Recommended Use


Used as a fuel for off-road diesel powered vehicles and stationary engines. The
substance should not be used for any other purpose without contacting the manufacturer
or supplier.

8.4 Where Found


Fuel tanks; fuel pipes; fuel injection systems.

8.5 Constituents
Catalytically cracked oil; petroleum distillates, quinizarin, and gas oil marker dye red.

8.6 Potentially Hazardous Constituents


Catalytically cracked oil; Petroleum distillates.

8.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

8.8 Hazardous Reactions


Liquid is flammable. Avoid smoking, heat sources, such as welding and naked flames,
sparks and static electricity build-up. The vapour is explosive.
Thermal decomposition products are hazardous, containing COx, NOx and SOx
compounds.
Avoid strong oxidising agents, e.g. chlorates which may be use in agriculture.

8.9 Effects of Over-exposure


Gas oil is slightly irritating to the skin and has a de-fatting action. Toxicity following single
exposure to high level of gas oil is of low order.
High vapour concentrations can cause respiratory irritation, dizziness, nausea, and loss
of consciousness. Excessive and prolonged exposure to the mist can cause chronic
inflammatory reaction of the lungs and a form of pulmonary fibrosis. Prolonged repeated
skin contact may de-fat the skin resulting in possible skin irritation and dermatitis. In some
cases warty, cancerous growths have occurred.

Section 8 – Gas Oil Page 8-1

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8.10 Storage / Transport


Store and transport only in correctly marked containers. Keep cool, out of sunlight and
away from naked flames. Electrical continuity is required between the transport and
storage vessels during product transfer.

8.11 Protective Measures


Ensure good ventilation and avoid heat sources. Avoid breathing mist. Observance of
good housekeeping rules will ensure general safety. Do not smoke.

8.12 Personal Protection Equipment


Gloves and overalls, eye protection goggles if there is risk of splashing. Use oil
impervious gloves and avoid contamination inside the gloves. If overalls become
contaminated, discontinue use and clean thoroughly. Use eye protection in the event of a
suspected high pressure leak. When working on, or testing, injection equipment, special
care is required to avoid perforation of skin by high pressure fuel. No special respiratory
precautions are necessary in normal use.

8.13 Hygiene
Adopt a high standard of personal hygiene. In the case of skin contact, wash well with
soap and water. Contaminated clothing should be soaked with water, removed, and
laundered before re-use. DO NOT use as a solvent for removing dirt / grease etc, from
skin.

8.14 Environmental Protection


Contain leak/spill with sand, earth or other suitable material, and prevent entry of
substance into drainage/sewerage system, water-courses and land. Dispose of unwanted
or absorbed substance through an authorised contractor to a licensed site.
Inform local and fire authorities if product reaches waterways, drains etc.

8.15 Emergency Action


8.15.1 Fire
Extinguishing media: Large fire – Foam/water fog. Never use water jet.
Small fire - foam/dry powder, AAAF, CO2, sand, earth.
Avoid making sparks. Fire fighters to use self-contained breathing apparatus. Keep fire
exposed containers cool, using water fog/spray. Prevent run-off from entering waterway,
drains and drinking water supplies.

8.15.2 Ingestion
Do not induce vomiting. Wash the mouth out with water, and send to hospital
immediately.

8.15.3 Inhalation (of vapour)


Remove from further exposure. Obtain medical assistance immediately.

Page 8-2
Section 8 – Gas Oil

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Issue 05 - June ‘03

8.15.4 Aspiration (inhalation of liquid)


If, following ingestion of gas oil, vomiting occurs, there is danger of aspiration into the
lungs. This would cause intense local irritation and chemical pneumonitis that can be
fatal. Obtain immediate medical assistance.

8.15.5 Eyes
Irrigate copiously with water or preferably eye-wash solution for at least five minutes. If
irritation persists seek medical advice.

8.15.6 Skin
Wash thoroughly with soap and water. Change clothing if necessary.
If high pressure injection has occurred prompt surgical attention is required.

8.15.7 Spillage
Absorb using sand, earth or other suitable material. Dispose of unwanted or absorbed
flammable material as directed under Environmental Protection.
Inform local and fire authorities if product reaches waterways, drains etc.

Section 8 – Gas Oil Page 8-3

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Page 8-4
Section 8 – Gas Oil

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Control of Substances Hazardous to Health Publication 3334

Issue 05 - June ‘03

9 Grease – Mobilgrease XTC


9.1 Grade
NLGI No. 1 Lithium soap-base product

9.2 Appearance
Highly viscous, dark brown in colour, with a mild odour. The substance has a boiling point
greater than 316oC and has negligible solubility in water. The substance has a flash point
greater than 204oC and a vapour pressure of less than 0.1mm Hg at 20oC.

9.3 Recommended Use


High speed flexible gear and grid couplings. Use of hand-operated grease guns at low
ambient temperatures, without auxiliary heat, is discouraged.

9.4 Where Found


In Industrial situations for high speed and high temperature coupling applications.

9.5 Constituents
Bitumen or vacuum residue, Zinc alkyl and long-chain alkyl dithiophosphates.

9.6 Potentially Hazardous Constituents


Based on available information this product is not expected to produce adverse effects on
health when used for the intended application and the recommendations provided in the
MSDS are followed.

9.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

9.8 Hazardous Reactions


Under normal conditions of use, this product is not considered hazardous according to
regulatory guidelines.

9.9 Effects of Over-exposure


Excessive exposure may result in eye, skin or respiratory irritation.

9.10 Storage/Transport
Store and transport only in correctly marked containers. Keep containers closed when not
in use. Store away from heat, sparks, flame or strong oxidants and combustible materials.

9.11 Protective Measures


Ensure good ventilation and avoid heat sources. For industrial use only. Prevent small
spills and leakages to avoid slip hazard.

Section 9 – Grease – Mobilgrease XTC Page 9-1

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9.12 Personal Protection Equipment


High pressure injection under the skin may occur due to the rupture of pressurised lines.
No special respiratory precautions are necessary in normal use and with adequate
ventilation. If prolonged or repeated skin contact is likely, oil impervious gloves MUST be
worn, and eye protection should be used.

9.13 Hygiene
Adopt a high standard of personal hygiene. In the case of skin contact wash with soap
and water.

9.14 Environmental Protection


Contain leak/spill and prevent entry of substance into drainage / sewerage system, water-
courses and land. Dispose of unwanted or absorbed substance through an authorised
contractor to a licensed site.

9.15 Emergency Action


9.15.1 Fire
Extinguishing media: CO2, foam, dry powder, and water fog.
In enclosed areas fire-fighters MUST use self-contained breathing apparatus. Keep fire
exposed containers cool. Prevent run-off from entering waterway, drains and drinking
water supplies.

9.15.2 Ingestion
Do not induce vomiting. Seek medical advice if discomfort occurs.

9.15.3 Inhalation (of vapour)


Remove from further exposure. If respiratory irritation, dizziness, nausea, or
unconsciousness occurs, seek medical advice.

9.15.4 Aspiration (inhalation of liquid)


Obtain immediate medical assistance.

9.15.5 Eyes
Irrigate copiously with water or preferably eye-wash solution for at least five minutes. If
irritation persists seek medical advice.

9.15.6 Skin
Wash thoroughly with soap and water. Remove and clean oil soaked clothing daily and
wash affected area.

9.15.7 Spillage
Contain spilled liquid with sand or other suitable absorbent. Dispose of used material as
directed under Environmental Protection.

Page 9-2
Section 9 – Grease – Mobilgrease XTC

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Control of Substances Hazardous to Health Publication 3334

Issue 05 - June ‘03

10 Grease –Val-Lith EP 2
10.1 Grade
Lithium based grease

10.2 Appearance
A liquid (paste) product, light brown in colour, with a slight characteristic sulphurous
odour. The substance has a boiling point of 371oC and is insoluble in water. The
substance has a flash point - closed cup greater than 221oC.

10.3 Recommended Use


Lubrication of automotive and industrial equipment over a wide temperature range.

10.4 Where Found


In bearings and shaft joints to reduce ingress of moisture and/or lubrication.

10.5 Constituents
Lithium based grease

10.6 Potentially Hazardous Constituents


The preparation is not classified as dangerous according to Directive 1999/45/EC and its
amendments. This product is not classified according to the EU regulations.

10.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

10.8 Hazardous Reactions


The product is stable. However do not expose containers to heat or sources of ignition.
Reactive with oxidising agents. Results of decomposition are carbon oxides (CO, CO2)
and water. Some metallic oxides.

10.9 Effects of Over-exposure


Repeated or prolonged exposure is not known to aggravate medical conditions.

10.10 Storage/Transport
Store and transport only in correctly marked containers. Keep containers tightly sealed
when not in use. Store in a well ventilated area, away from heat, and combustible
materials.

10.11 Protective Measures


Ensure good ventilation and avoid heat sources. For industrial use only. Prevent small
spills and leakages to avoid slip hazard.

Section 10 – Grease – Val-Lith EP2 Page 10-1

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10.12 Personal Protective Equipment


No special respiratory precautions are necessary in normal use and with adequate
ventilation. Wear a lab coat and wash hands after handling.

10.13 Hygiene
Adopt a high standard of personal hygiene. In the case of skin contact wash with soap
and water.

10.14 Environmental Protection


Wear boots and gloves and use a tool to scoop up solid or absorbed material. Dispose of
unwanted or absorbed substance through an authorised contractor to a licensed site.

10.15 Emergency Action


10.15.1 Fire
Extinguishing media: Small fires - CO2, dry chemical powder.
Larger fires - water spray, fog or foam. For safety reasons do not
use a full water jet.
Fire-fighters should wear self-contained breathing apparatus, and full turnout gear. Keep
fire exposed containers cool.

10.15.2 Ingestion
Do not induce vomiting. Seek medical advice if discomfort occurs.

10.15.3 Inhalation (of vapour)


Remove from further exposure. Seek medical advice.

10.15.4 Aspiration (inhalation of liquid)


Obtain immediate medical assistance.

10.15.5 Eyes
Irrigate copiously with water or preferably eye-wash solution for at least fifteen minutes. If
irritation persists seek medical advice.

10.15.6 Skin
Wash thoroughly with soap and water. Remove oil soaked clothing daily and wash before
reuse. Clean shoes thoroughly before reuse. Obtain medical attention.

10.15.7 Spillage
Use a tool to scoop up solid or absorbed material and dispose of used material as
directed under Environmental Protection.

Page 10-2
Section 10 – Grease – Val-Lith EP2

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Control of Substances Hazardous to Health Publication 3334

Issue 05 - June ‘03

11 Lubrication Oil – Premium Blue E 15W40


11.1 Other Names
Oil, Lube Oil, Sump oil.

11.2 Appearance
New oil is a dark, viscous liquid with a slight, characteristic odour. It has a boiling point
greater than 150oC, a flash point Open Cup of 220oC (Cleveland), and is insoluble in cold
water.

11.3 Recommended Use


Lubrication oil for use on wide range of engines operating under severe conditions.

11.4 Where found


Engine lubrication oil system, sump pan and filters, make-up tanks and piping systems.

11.5 Constituents
Baseoil; distillates (petroleum), solvent-dewaxed heavy paraffinic

11.6 Potentially Hazardous Constituents


The preparation is not classified as dangerous according to Directive 1999/45/EC and its
amendments. This product is not classified according to the EU regulations.

11.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers

11.8 Hazardous Reactions


This product is stable although slightly re-active with oxidising agents. Results of
decomposition are carbon oxides (CO, CO2) and water.

11.9 Effects of Over-exposure


Repeated or prolonged exposure is not known to aggravate medical conditions. Harmful if
swallowed or aspirated (breathed in). Used oil may contain harmful combustion by-
products and unburned fuel that will cause skin reactions as detailed for fuel. Particular
care must be taken if oil from a severely overheated engine is handled - use impervious
gloves, lab coat and safety glasses. Do not breathe vapour/spray.

11.10 Storage / Transport


Store and transport only in correctly marked containers. Keep containers tightly sealed
when not in use. Keep in a cool, well ventilated area, out of sunlight and away from naked
flames. Store well away from food-stuffs and drinking water.

11.11 Protective Measures


Ensure good ventilation and avoid heat sources.

Section 11 – Lubrication Oil – Premium Blue E 15W40Page 11-1

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11.12 Personal Protection Equipment


Safety glasses, impervious gloves and lab coat. Avoid contamination inside the gloves. If
overalls become contaminated, discontinue use and clean thoroughly.
No special respiratory precautions are necessary in normal use. Do not breathe
vapour/spray when handling hot materials.

11.13 Hygiene
Adopt a high standard of personal hygiene. In case of skin contact wash thoroughly with
soap and water.

11.14 Environmental Protection


Wear splash goggles, full suit, boots and gloves. Absorb leak/spill with an inert material
and dispose of unwanted or absorbed substance through an authorised contractor to a
licensed site. Finish cleaning by spreading water on the contaminated surface and allow
to evacuate through the sanitary system.

11.15 Emergency Action


11.15.1 Fire
Extinguishing media: Large fire – Use water spray, fog or foam. Do not use water jet.
Small fire – Use dry chemical powder or CO2.
Fire-fighters to use self contained breathing apparatus and full turnout gear. Keep fire
exposed containers cool.

11.15.2 Ingestion
Do not induce vomiting. Obtain medical advice immediately.

11.15.3 Inhalation (of vapour)


Remove from further exposure. Obtain medical attention.

11.15.4 Aspiration (inhalation of liquid)


Obtain immediate medical assistance.

11.15.5 Eyes
Flush copiously with water or preferably eye-wash solution for at least fifteen minutes.
Obtain medical advice.

11.15.6 Skin
Wash thoroughly with soap and water. Obtain medical advice if irritation develops.
Change clothing if necessary and wash before re-use.

11.15.7 Spillage
Absorb with an inert material and dispose of this as directed under Environmental
Protection.

Page 11-2
Section 11 – Lubrication Oil – Premium Blue E 15W40

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Control of Substances Hazardous to Health Publication 3334

Issue 05 - June ‘03

12 Lubrication Oil – Premium Blue GEO 15W40


12.1 Other Names
Oil, Lube Oil, Sump oil.

12.2 Appearance
New oil is a clear amber, viscous liquid with a characteristic odour. It has a flash point of
204oC and is insoluble in water.

12.3 Recommended Use


Lubrication oil for use in the QSK19 series, gas engines.

12.4 Where found


Engine lubrication oil system, sump pan and filters, make-up tanks and piping systems

12.5 Constituents
No information supplied.

12.6 Potentially Hazardous Constituents


To the present knowledge of the supplier, this product does not contain any hazardous
ingredients.

12.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers

12.8 Hazardous Reactions


No dangerous reactions known. Avoid oxidising agents.

12.9 Effects of Over-exposure


Repeated contact can de-fat skin and cause dermatitis. Harmful if swallowed or aspirated
(breathed in).
Used oil may contain harmful combustion by-products and unburned fuel that will cause
skin reactions as detailed for fuel. Particular care must be taken if oil from a severely
overheated engine is handled - use gloves, leather apron and face mask.

12.10 Storage / Transport


Store and transport only in correctly marked containers. Keep in a cool, well ventilated
area, out of sunlight and away from naked flames. Store well away from food-stuffs and
drinking water. Take special care to avoid discharge into drains, sewers and water-
courses.

12.11 Protective Measures


Ensure good ventilation and avoid heat sources.

Section 12 – Lubrication Oil – Premium Blue GEO 15W40 Page 12-1

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12.12 Personal Protection Equipment


Safety glasses (recommended during re-filling), gloves and overalls. Avoid contamination
inside the gloves. If overalls become contaminated, discontinue use and clean
thoroughly.
No special respiratory precautions are necessary in normal use.

12.13 Hygiene
Adopt a high standard of personal hygiene. In case of skin contact rinse thoroughly with
warm water.

12.14 Environmental Protection


Contain leak/spill with the use of liquid-binding material – sand, diatomite, acid binders,
universal binders, sawdust - and prevent entry of substance into drainage/sewerage
system, water-courses and land. Dispose of unwanted or absorbed substance through an
authorised contractor to a licensed site.

12.15 Emergency Action


12.15.1 Fire
Extinguishing media: Large fires – alcohol resistant foam, water spray/fog. Do not use full
water jet.
Small fires - CO2, extinguishing powder, water spray/fog.
Fire-fighters to use self contained breathing apparatus. Keep fire exposed containers
cool. Prevent run-off from entering waterways, drains and drinking water supplies.

12.15.2 Ingestion
Do not induce vomiting. Rinse out mouth and then drink plenty of water. In case of
persistent symptoms obtain medical advice immediately.

12.15.3 Inhalation (of vapour)


Remove from further exposure. In case of persistent symptoms obtain medical advice
immediately.

12.15.4 Aspiration (inhalation of liquid)


Obtain immediate medical assistance – danger of chemical pneumonia.

12.15.5 Eyes
Flush copiously with water or preferably eye-wash solution. If irritation persists seek
medical advice.

12.15.6 Skin
Rinse with warm water. Change clothing if necessary and wash before re-use.

12.15.7 Spillage
Absorb with an inert material and dispose of this as directed under Environmental
Protection.

Page 12-2
Section 12 – Lubrication Oil – Premium Blue GEO 15W40

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Control of Substances Hazardous to Health Publication 3334

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13 Lubrication Oil – Premium Blue GEO-LA 40


13.1 Other Names
Oil, Lube Oil, Sump oil.

13.2 Appearance
New oil is a dark, viscous liquid with a slight, characteristic odour. It has a boiling point
greater than 200oC, a flash point Open Cup of 206oC (Cleveland), and is insoluble in cold
water.

13.3 Recommended Use


Lubrication oil for use in gas engines with the exception of the QSK19 series.

13.4 Where found


Engine lubrication oil system, sump pan and filters, make-up tanks and piping systems.

13.5 Constituents
Baseoil; distillates (petroleum), solvent-dewaxed heavy paraffinic.
Contains Phenol, alkylated, alkyl aryl sulphonate (calcium salt).

13.6 Potentially Hazardous Constituents


The preparation is not classified as dangerous according to Directive 1999/45/EC and its
amendments. This product is not classified according to the EU regulations.

13.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers

13.8 Hazardous Reactions


The product is stable although slightly reactive to oxidising agents. Decomposition
products are COx, and water.

13.9 Effects of Over-exposure


Repeated or prolonged exposure is not known to aggravate medical conditions. Harmful if
swallowed or aspirated (breathed in). May cause an allergic reaction. Used oil may
contain harmful combustion by-products and unburned fuel that will cause skin reactions
as detailed for fuel. Particular care must be taken if oil from a severely overheated engine
is handled - use gloves, leather apron boots and face mask.

13.10 Storage / Transport


Store and transport only in correctly marked containers. Keep in a cool, well ventilated
area, out of sunlight and away from naked flames. Keep containers tightly sealed when
not in use. Store well away from food-stuffs and drinking water. Take special care to
avoid discharge into drains, sewers and water-courses.

Section 13 – Lubrication Oil – Premium Blue GEO-LA40 Page 13-1

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13.11 Protective Measures


Ensure good ventilation and avoid heat sources.

13.12 Personal Protection Equipment


Safety glasses, impervious gloves and lab coat. Avoid contamination inside the gloves. If
overalls become contaminated, discontinue use and clean thoroughly.
No special respiratory precautions are necessary in normal use. Do not breath
vapour/spray when handling hot material.

13.13 Hygiene
Adopt a high standard of personal hygiene. In case of skin contact wash thoroughly with
soap and water.

13.14 Environmental Protection


Wear full suit, boots, gloves and splash goggles. Contain leak/spill using an inert material,
and dispose of unwanted or absorbed substance through an authorised contractor to a
licensed site Finish cleaning by spreading water on the contaminated surface and allow to
evacuate through the sanitary system.

13.15 Emergency Action


13.15.1 Fire
Extinguishing media: Large fire – Use water spray, fog or foam. Do not use water jet.
Small fire – Use dry chemical powder, or CO2.
Fire-fighters to use self contained breathing apparatus and full turnout gear. Keep fire
exposed containers cool.

13.15.2 Ingestion
Do not induce vomiting. Obtain medical advice if symptoms appear.

13.15.3 Inhalation (of vapour)


Remove from further exposure. In case of persistent symptoms obtain medical advice
immediately.

13.15.4 Aspiration (inhalation of liquid)


Obtain immediate medical assistance.

13.15.5 Eyes
Flush copiously with water or preferably eye-wash solution for at least fifteen minutes.
Obtain medical attention.

13.15.6 Skin
Wash thoroughly with soap and water. Change clothing if necessary and wash before re-
use. Obtain medical attention if irritation develops.

13.15.7 Spillage
Soak up using an absorbent material and dispose of this liquid as directed under
Environmental Protection.

Page 13-2
Section 13 – Lubrication Oil – Premium Blue GEO-LA40

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Control of Substances Hazardous to Health Publication 3334

Issue 05 - June ‘03

14 Natural Gas
14.1 Other Names
Methane.

14.2 Appearance
Not visible. Should have strong smell if gas has been treated with a smell additive for
leakage detection. Soluble in water, alcohol, ether, most organic solvents.

14.3 Recommended Use


Fuel to run Natural Gas fuel gensets.

14.4 Where Found


Gas pipeline, gas train, genset carburettor system, mixed with part of air inlet system.
Natural Gas inlet pipes identified by being painted yellow.

14.5 Constituents
Carbon dioxide 0 – 2.2%, Ethane 2 – 8%, Methane 86 – 94%, Propane 0.5 – 3%,
Nitrogen 0 – 6%.

14.6 Potentially Hazardous Constituents


Methane, Propane, Ethane.

14.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

14.8 Hazardous reactions


Extremely flammable/explosive at low levels in air atmosphere (4% to 15% gas in air).
Gas at high gas mains transportation pressure.

14.9 Effects of Over-exposure


Headaches, dizziness, drowsiness, nausea and vomiting. Gas under pressure can
penetrate skin, damage or blind eyesight.

14.10 Storage / Transport


Gas pipeline, not applicable.

14.11 Protective Measures


Ensure good ventilation. All pipelines, gas train and fittings are gas tight and free from
leaks. If leakage occurs isolate the gas supply. DO NOT operate any equipment,
electrical or otherwise that may cause a spark or become a source of ignition. Fully
ventilate the area and evacuate the building. Only suitable qualified personnel who are
fully trained should handle natural gas emergencies.

Section 14 – Natural Gas Page 14-1

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14.12 Personal Protection Equipment


Under normal working conditions protection is not required. In the event of gas leakage,
eye protection, gloves and breathing equipment may be required. Use non-sparking tools.

14.13 Environmental Protection


No effect known.

14.14 Emergency Action


14.14.1 Fire
Extinguishing media: CO2, dry powder, Halon, sand, water spray fog, mist or water based
foam. In the event of fire, attempt to shut off the gas supply and inform the local fire
authority and gas supplier. Extremely flammable, may re-ignite after fire is extinguished.
Carbon Dioxide (CO2) and Carbon Monoxide (CO) gas is released when burning.

14.14.2 Ingestion
Not expected to be a health risk via this route.

14.14.3 Inhalation of vapour


Remove from further exposure. Can cause headaches, dizziness, nausea and vomiting.
High vapour concentrations can lead to general narcotic effect and unconsciousness.
High volumes of gas or vapour displace oxygen content available for breathing and can
cause asphyxiation and death.

14.14.4 Aspiration (inhalation of liquid)


N/A.

14.14.5 Eyes
Not expected to be a health risk via this route.

14.14.6 Skin
Not expected to be a health risk via this route.

14.14.7 Spillage
In the event of gas leakage, isolate gas supply, ventilate the area and inform local
supplier. DO NOT operate electrical switches, mobile phones, torches etc., or any other
equipment that may cause a spark to ignite gas – these should be removed or rendered
inoperable.
In circumstances of excessive leakage, evacuate the building and call the Emergency
Services and local gas supplier.

Page 14-2
Section 14 – Natural Gas

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Issue 05 - June ‘03

15 Sulphuric Acid Battery Quality


1140 – 1400 SG (15-50%)
15.1 Other Names
Battery acid, battery electrolyte, electrolyte.

15.2 Appearance
A colourless to dark brown liquid, with a characteristic acrid, acidic odour. Readily soluble
in water forming a diluted corrosive solution. It has a boiling point between 104 – 124oC,
and a vapour pressure of 6.2mm Hg at 20oC.

15.3 Recommended Use


In solution it is used as an electrolyte for Lead Acid batteries.

15.4 Where Found


Starting and control batteries.

15.5 Constituents
Sulphuric acid battery quality 1140 – 1400sg (15-50%)
Aqueous solutions of sulphuric acid including all grades between 1140(10%) –
1400(50%)

15.6 Potentially Hazardous Constituents


Sulphuric Acid.

15.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

15.8 Hazardous Reactions


The product is considered to be stable. However it may give rise to hazardous fumes in a
fire. Violent reaction with water generates heat and may cause an explosion. Attacks
many metals liberating hydrogen gas. Combustion will generate oxides of sulphur.

15.9 Effects of Over-exposure


Avoid contact with body tissue. Causes destruction of body tissue, severe burns.
Inhalation of the spray mist may produce severe irritation of the respiratory tract. May be
fatal if swallowed, causing burns to mouth, throat and stomach. Corrosive to eyes.
Repeated or prolonged exposure to spray mist may produce chronic eye irritation, severe
skin irritation, and respiratory irritation leading to frequent attacks of bronchial infection.

Section 15 - Sulphuric Acid Page 15-1

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15.10 Storage / Transport


Store and transport only in correctly marked containers. Stock tanks should be bunded
separately, away from organic substances such as wood, paper, straw, and other reactive
chemicals. Prevent water or steam from entering container at all times. Store in rubber-
lined tanks for acid concentrations less than 70%. Suitable storage materials are:- PTFE,
glass. Do not store in:- metal drums, nylon, plasticised PVC.
Keep cool, out of sunlight and away from naked flames. Store well away from food-stuffs
and drinking water. Take special care to avoid discharge into drains, sewers and water-
courses

15.11 Protective Measures


Ensure good ventilation and avoid heat sources. Gas must be positively removed from
confined spaces by fume extraction.

15.12 Personal Protection Equipment


Total eye protection goggles, acid-resistant gloves (e.g. PVC), overalls, acid resistant
apron and rubber boots. Note that handling contaminated clothing may result in acid
burns.
No special respiratory precautions are necessary in normal use, however respiratory
protection should be used if there is a risk of uncontrolled exposure to vapour. Avoid
contact with acid mist if large quantities of batteries are being charged or if working close
to charging batteries.

15.13 Hygiene
Adopt a high standard of personal hygiene.

15.14 Environmental Protection


In case of spillage, contain using earth, sand or other inert material and transfer to
suitable containers. Arrange disposal in accordance with local regulations. Advise the
Emergency Services if the substance has entered a watercourse or sewer, or has
contaminated soil or vegetation.

15.15 Emergency Action


15.15.1 Fire
Keep containers and surroundings cool with water spray. Water must not enter tanks or
containers. Select extinguishing media appropriate to other materials involved.
It may give rise to hazardous fumes in a fire. Violent reaction with water generates heat
and may cause an explosion. Prevent run-off from entering waterways, drains and
drinking water supplies.
Fire-fighters to wear full protective clothing and use self contained breathing apparatus.

15.15.2 Ingestion
Do not induce vomiting. Wash out mouth with water. Gives sips of cold water or milk to
soothe the affected parts. Ingested acid must be diluted by approximately x 100, to render
harmless to tissues. Obtain medical advice immediately.

Page 15-2
Section 15 - Sulphuric Acid

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Issue 05 - June ‘03

15.15.3 Inhalation (of vapour)


Remove from further exposure. If breathing stops or shows signs of failing, give artificial
respiration. Do not use mouth to mouth ventilation. If there is difficulty in breathing, give
oxygen. Keep warm and at rest. Obtain medical attention urgently.

15.15.4 Aspiration (inhalation of liquid)


Obtain immediate medical assistance.

15.15.5 Eyes
Irrigate copiously with water or preferably eye-wash solution for at least fifteen minutes.
Seek medical advice.

15.15.6 Skin contact


Flush area with copious quantities of water, preferably under a shower. Remove
contaminated clothing, which should be washed or dry-cleaned before re-use.
Obtain medical attention if blistering or redness persists.

15.15.7 Spillage
Wear appropriate protective clothing. Ventilate the area to dispel possible toxic
decomposition fumes. Contain and absorb using earth, sand or other inert material.
Transfer to suitable container for disposal in accordance with local regulations as directed
under Environmental Protection. Advise Authorities if spillage has entered water courser
or sewer, or has contaminated soil or vegetation.

15.16 Special Note: Identification of Usage


IMPORTANT: care must be taken to identify that the sulphuric acid 'battery electrolyte' or
'electrolyte' is the correct substance for use in a battery. A violent chemical reaction will
occur if sulphuric acid is accidentally mixed with alkaline battery electrolyte.

15.17 Special Note: Concentrated Sulphuric Acid


In some cases, sulphuric acid may be purchased in concentrated form. This is a clear
viscous liquid. Do not attempt to add this type of acid to batteries. Dilution should only be
attempted by experienced personnel. DO NOT ADD WATER TO ACID - a violent reaction
will occur. If spillage of concentrated acid occurs contact emergency services immediately
and quote hazard code 1830.

15.18 Special Note: Lead


Lead acid batteries contain significant quantities of metallic lead, which is harmful.
Provided that the battery is not dismantled in any way, there is no risk of heavy metal
poisoning from batteries. Use gloves when connecting and adopt a high standard of
personal hygiene. Batteries can be recycled, and used batteries should be disposed of in
accordance with local authority environmental health regulations.

Section 15 - Sulphuric Acid Page 15-3

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Page 15-4
Section 15 - Sulphuric Acid

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16 Potassium Hydroxide - Solid


16.1 Other Names
Caustic potash - solid

16.2 Appearance
White, odourless granules, flakes, pellets, powder, lumps, solid blocks or sticks.

16.3 Recommended Use


When added to distilled water it is used as battery electrolyte (NiCad batteries only).

16.4 Where Found


Starting and control batteries

16.5 Constituents
Potassium hydroxide.

16.6 Potentially Hazardous Constituents


Potassium hydroxide.

16.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

16.8 Hazardous Reactions


Highly corrosive.
Reacts with water to produce caustic solution and heat. (N.B. sufficient heat can be
generated with moisture to ignite combustible materials).
Reacts violently with acids. Attacks aluminium, lead, tin, zinc and their alloys, releasing
flammable hydrogen gas. Reacts with ammonium salts giving ammonia.
Non flammable and non combustible in bulk form but when in battery may be associated
with explosive gases.
Heating will cause pressure rise with risk of bursting - keep drums cool.

16.9 Effects of Over-exposure


Highly corrosive. Avoid contact with body tissue. Causes severe burns to eyes and skin.

16.10 Storage / Transport


Store and transport only in correctly marked containers. Keep cool, out of sunlight and
away from naked flames. Store well away from foodstuffs and drinking water. Take
special care to avoid discharge into drains, sewers and water-courses.

Section 16 - Potassium Hydroxide - Solid Page 16-1

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16.11 Protective Measures


Ensure good ventilation and avoid heat sources.

16.12 Personal Protection Equipment


Total eye protection goggles, plastic or rubber gloves (e.g. PVC), overalls, apron and
rubber boots. Note that handling contaminated clothing may result in damage to the skin.
It is advised to have an eyewash bottle with clean water in the vicinity.
No special respiratory precautions are necessary in normal use.

16.13 Hygiene
Adopt a high standard of personal hygiene.

16.14 Environmental Protection


Wearing total personal protection, cover a spillage with earth or sand and transfer to
another container. Arrange disposal in accordance with local regulations. If the substance
has entered a water course or sewer, or has contaminated soil or vegetation, please
advise the Emergency Services.

16.15 Emergency Action


16.15.1 Fire
Non-combustible. Keep drums cool to reduce risk of bursting.

16.15.2 Ingestion
Do not induce vomiting. Drink copious quantities of milk. In all cases obtain immediate
medical attention.

16.15.3 Inhalation (of vapour)


Remove from further exposure. In cases of irritation to lungs or throat seek medical
advice.

16.15.4 Aspiration (inhalation of liquid)


Obtain immediate medical attention.

16.15.5 Eyes
Irrigate copiously with water. In all cases obtain immediate medical attention.

16.15.6 Skin
Remove contaminated clothing and flush affected skin with copious quantities of water.
Cover with dry gauze. Change clothing if necessary and wash before re-use.

16.15.7 Spillage
Wearing protective clothing, cover spillage with earth or sand. Transfer to another
container in accordance with local regulations as directed under Environmental
Protection.

Page 16-2
Section 16 - Potassium Hydroxide - Solid

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Control of Substances Hazardous to Health Publication 3334

Issue 05 - June ‘03

17 Potassium Hydroxide - Solution


17.1 Other Names
Nicad battery electrolyte, electrolyte.

17.2 Appearance
Clear colourless liquid. Readily soluble in water forming a diluted corrosive solution. Non
flammable and non combustible in bulk form but when in battery may be associated with
explosive gases.

17.3 Recommended Use


Battery electrolyte (NiCad batteries only).

17.4 Where Found


Starting and control batteries

17.5 Constituents
Potassium hydroxide.

17.6 Potentially Hazardous Constituents


Potassium hydroxide.

17.7 Personnel Likely to Encounter Substance


Installers, operators and maintainers.

17.8 Hazardous Reactions


Highly corrosive. Reacts violently with acids. Attacks aluminium, lead, tin, zinc and their
alloys, releasing flammable hydrogen gas. Reacts with ammonium salts giving ammonia.
When in battery it may be associated with explosive gases.

17.9 Effects of Over-exposure


Highly corrosive. Avoid contact with body tissue. Causes severe burns to eyes and skin.

17.10 Storage / Transport


Store and transport only in correctly marked containers. Keep cool, out of sunlight and
away from naked flames. Store well away from foodstuffs and drinking water. Take
special care to avoid discharge into drains, sewers and water-courses.

17.11 Protective Measures


Ensure good ventilation and avoid heat sources. The gas given off when batteries are
charging is an explosive mixture of hydrogen and oxygen. Gas must be positively
removed from confined spaces by fume extraction. Use insulated tools when fitting
batteries or making connections. Avoid sparks or naked flames in vicinity of battery,
especially when charging.

Section 17 - Potassium Hydroxide - Solution Page 17-1

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Publication 3334 Control of Substances Hazardous to Health
Issue 05 - June ‘03

17.12 Personal Protection Equipment


Total eye protection goggles, plastic or rubber gloves (e.g. PVC), overalls, apron and
rubber boots. Note that handling contaminated clothing may result in damage to the skin.
No special respiratory precautions are necessary in normal use. Avoid contact with
electrolyte mist if large quantities of batteries are being charged or if working close to
charging batteries.

17.13 Hygiene
Adopt a high standard of personal hygiene.

17.14 Environmental Protection


Cover a spillage with earth or sand and transfer to another container. Arrange disposal in
accordance with local regulations. If the substance has entered a water course or sewer,
or has contaminated soil or vegetation, please advise the Emergency Services.

17.15 Emergency Action


17.15.1 Fire
Extinguishing media: CO2, dry powder, or Halon. DO NOT use water or water based
foam.
Fire fighters to use self contained breathing apparatus. Keep fire exposed containers
cool. Prevent run-off from entering waterways drains and drinking water supplies.

17.15.2 Ingestion
Do not induce vomiting. Drink copious quantities of milk. In all cases obtain immediate
medical attention.

17.15.3 Inhalation (of vapour)


Remove from further exposure. In cases of irritation to lungs or throat seek medical
advice.

17.15.4 Aspiration (inhalation of liquid)


Obtain immediate medical attention.

17.15.5 Eyes
Irrigate copiously with water. In all cases obtain immediate medical attention.

17.15.6 Skin
Remove contaminated clothing and flush affected skin with copious quantities of water.
Cover with dry gauze. Change clothing if necessary and wash before re-use.

17.15.7 Spillage
Wearing protective clothing, cover spillage with earth or sand. Transfer to another
container in accordance with local regulations as directed under Environmental
Protection.

Page 17-2
Section 17 - Potassium Hydroxide - Solution

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Cummins Power Generation Limited
Manston Park
Columbus Avenue
Manston, Ramsgate
Kent CT12 5BF
England
Main Office: Tel: +44 (0) 1843 255000
Fax: +44 (0) 1843 255902
Spares Dept: Tel: +44 (0) 1843 255575
Fax: +44 (0) 1843 255913
E-Mail cpg.uk@cummins.com
Web Sites www.cumminspower.com

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