CONFIDENTIAL, ASIDEC 2018/CHM131/160 UNIVERSITI TEKNOLOGI MARA FINAL EXAMINATION COURSE : GENERAL CHEMISTRY/PRINCIPLES OF GENERAL CHEMISTRY ‘COURSE CODE CHM131/160 EXAMINATION DECEMBER 2018 TIME : 2HOURS INSTRUCTIONS TO CANDIDATES 1 This question paper consists of two (2) pars: PART A(10 Questions) PART B (10 Questions) 2 ‘Answer ALL questions from all two (2) parts i) Answer PART A in the Objective Answer Sheet. ii) Answer PART B in the Answer Booklet. Start each answer on a new page. 3 Do not bring any material into the examination room unless permission is given by the invigilator, 4, Please check to make sure that this examination pack consists of : i) the Question Paper ji) aone— page Appendix ill) an Answer Booklet - provided by the Faculty iv) _ an Objective Answer Sheet - provided by the Faculty 5. Answer ALL questions in English, DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO This examination paper consists of & printed pages © Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL 2 ASIDEC 2018/CHM131/160 PART A 1. The molecular formula of heptanal is C7H140. Find the molecular weight for heptanal. A. 112.g/mol B. 114 g/mol C. 121 gimol D. 141 g/mol 2. Select the correct name of V-Os compound. A. Vanadium oxide B. Vanadium(Il) oxide CC. Vanadium(V) oxide D. Vanadium pentaoxide 3. Find the number of atoms in 1.25 g of sodium. A. 3.13 x 10” atoms B. 3.27 x 10 atoms C. 3.72% 10% atoms D. 6.02 x 10% atoms 4. Select which atom has the greatest of ionization energy. A Na B. Al a Pp D. Ar 5. Indicate the number of electrons with quantum number n = 5, A 6 a 8 @ 9 D4 © Hak Cipta Universiti Teknologi MARA CONFIDENTIAL,CONFIDENTIAL 3 ASIDEC 2018/CHM131/160 6. Select which combination of the following pairs of molecule and ion that form a dative covalent bond in a reaction. A. NH and H* B. Mg andN Cc. CstandF D. CandS 7. __ State the number of bonding pairs of electrons in water, HzO molecule. pomp> aaon 8. __ Identify the substance that is being reduced in the following equation. Sn + 2Fe% — Sn + 2Fe* sn Fe* Sn** Fe* pom> 9. Select the correct statement for the following reaction once equilibrium is achieve. ASB K=320 [B] > (Al [A] > [8] (Al = [8] None pop> (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL 4 ASIDEC 2018/CHM131/160 10. Consider the following reaction: (NH,)2Se(s) = 2NHs(g) + HeSe(g) Select the correct equilibrium constant expression, Ke for the reaction above. A gg = INEAIIH2Se] [(NH«),Se] Bg = LUNH)Se] INH.F1H,Se] Ck _INH,IIH,Se] [(NH,),Se] D. Ke=[NHFLHSe] (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL 5 ASIDEC 2018/CHM131/160 PARTB QUESTION 1 In an experiment, 3.25 g of NHs is allowed to react with 3.50 g of O2 according to the following reaction’ ‘ANHs + 502 ~» 4NO + 6H:O a) Predict the limiting reactant of this reaction. (2 marks) b) Determine the amount of excess reactant remains after the reaction stops. (3 marks) QUESTION 2 Isobutene is a colorless gas with a faint petroleum-like odor. It is used in the production of octane aviation gasoline. If a 1.296 g sample of isobutene contains 1.112 g of carbon and the rest is hydrogen. a) Predict the empirical formula of isobutene. (3 marks) b) The molar mass of isobutene is 57 g/mol. Find the molecular formula of isobutene. (2 marks) QUESTION 3 a) Element X is located in period 2 and group 15 in periodic table. Show the sets of quantum numbers for all the unpaired electrons of element X. (3 marks) b) Write the condensed electron configuration and illustrate the orbital diagram for the sulfide ion (S*). (2 marks) (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL, 6 ASIDEC 2018/CHM131/160 QUESTION 4 a) Explain why the negative ions are bigger than their parent atom. (2 marks) b) The wavelength of blue light is centered at 422 nm. Find the frequency and energy of this radiation. (3 marks) QUESTION 5 Cyanate ion, NCO" is an anion consisting of one oxygen atom, one carbon atom and one nitrogen atom. [n-czo} —~ [Nn=c-o]” j@ (ii) a) Referring to the resonance structure above, find the formal charge of the nitrogen atom (N) and oxygen atom (0) in both structures. (2 marks) b) From your answer in (a), predict the most correct Lewis structure of cyanate ion, NCO™ and justify your answer. (3 marks) QUESTION 6 a) Identify the intermolecular forces present in the following compounds: Propanol (CHsCH,CH2OH) Propane (CH;CH-CHs). (2 marks) b) Arrange the following in order of increasing boiling point and explain your reasoning. CO, CH;OH CH;Br HO (3 marks) (© Hak Cipta Universiti Teknolog! MARA CONFIDENTIAL,CONFIDENTIAL, 7 ASIDEC 2018/CHM131/160 QUESTION 7 Given the following reaction: CN’(aq) + MnO, (aq) — CNO, (aq) + MnO,(s) a) Identify the reducing agent and oxidizing agent in the redox reaction above. (2 marks) b) Express a balanced redox equation using the ion-electron method in a basic solution (3 marks) QUESTION 8 a) List two (2) evidences to show that gases do not behave ideally under all conditions. (2 marks) b) Write the equations of Charle’s law, Boyle's law and Avogadro's law. (3 marks) QUESTION 9 a) The equilibrium constant expression (K.) for the following reaction is 1.2 at 375°C. N.(g) + 3Ha(g) = 2NHs(g) Find the K, value for this reaction. (2 marks) b) For the reaction H,(g) + CO,(g) + H,0(g) + CO(g) A mixture of 0.30 mole of CO, 0.30 mole of HzO and 0.15 mole of CO, is heated in 10.0 L container at 300°C with K. = 0.63. Find the number of moles of H. that present at ‘equilibrium. (3 marks) (© Hak Cipta Universiti Toknolog! MARA CONFIDENTIAL,CONFIDENTIAL, 8 ASIDEC 2018/CHM131/160 QUESTION 10 The equilibrium constant (K;) for the following reaction is 1.5 x 10° at 220°C. H2(g) + Clg) = 2HCI(g) AH= -184.60 kJ In one experiment, the initial pressure of Hz, Cl, and HCl are 2.1 x 10° atm, 1.1 x 10? atm and 0.14 atm, respectively. a) Find the reaction quotient (Q,) of the reaction and predict the direction of the reaction with brief explanation. (3 marks) b) If the above reaction is an exothermic process, describe how the changes in the temperature can affect the concentration of HCI(g). (2 marks) END OF QUESTION PAPER (© Hak Cipta Universiti Teknologi MARA CONFIDENTIAL,CONFIDENTIAL APPENDIX ASIDEC 2018/CHM131/160 TABLE OF ATOMIC NUMBER AND RELATIVE ATOMIC MASS oe Element symbol _| Relative Atomic Mass 1 Hydrogen | HO [0 2 Helium He 40 3 Lithium Li 69 4 Beryliium Be 9.0 5 Boron B 6 ~ Carbon Cc - 7 Nitrogen N 8 Oxygen (Crseaene [eaten 9 Fluorine F 70 Neon Ne 20.0 4 Sodium Na 23.0 12 Magnesium Mg 24.0 13 ‘Aluminum Al 27.0 14 Silicon Si 28.0 15 Phosphorus P 31.0 [46 Sulphur s 32.0 17 Chlorine Ci 35.5 18 ‘Argon Ar 40.0 19 Potassium K 39.0 20 Calcium Cal 40.0 24 ‘Scandium Sc a 45.0 22 Titanium Ti 48.0 23 Vanadium Vv 51.0 24 Chromium | Cr 52.0 25 ____ Manganese Mn 55.0 26 Iron Fe 55.8 2B Nickel Ni 58.7 _| 29 Cu 63.5 30 - zn 65.4 a 35 Br 79.9 53 1 127.0 34 - Xe. 131.3 79 Au, 197.0 Pb 207.0 Constants Rydberg Constant, Ru = 1.097 x 10” m* or 2.18 x 10° J ‘Speed of Light, c = 3.00 x 10°ms Planck Constant, h = 6.63 x 10% Js Avogadro’s Number, Na = 6.02 x 10° mol* Gas Constant, R = 0.0821 L atm mot K* (© Hak Cipta Universiti Teknologi MARA CONFIDENTIAL,