CONFIDENTIAL ze ASIJUN 2019/CHM131/160 UNIVERSITI TEKNOLOGI MARA FINAL EXAMINATION COURSE : GENERAL CHEMISTRY/PRINCIPLES OF GENERAL CHEMISTRY COURSE CODE : CHM131/160 EXAMINATION : JUNE 2019 TIME 2 HOURS INSTRUCTIONS TO CANDIDATES 1 This question paper consists of two (2) parts: PART A (10 Questions) PART B (10 Questions) 2 ‘Answer ALL questions from all two (2) parts |) Answer PART A in the Objective Answer Sheet. ji) Answer PART B in the Answer Booklet. Start each answer on a new page 3. Do not bring any material into the examination room unless permission is given by the invigilator. 4 Please check to make sure that this examination pack consists of i) the Question Paper ii) aone— page Appendix iii) an Answer Booklet — provided by the Faculty iv) an Objective Answer Sheet — provided by the Faculty 5. Answer ALL questions in English, DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO This examination paper consists of 7 printed pages © Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL 2 ASIJUN 2019/CHM131/160 PARTA 1. Ammonium sulfate, (NH«)2SO., is a fertilizer widely used as a source of nitrogen, Find its molecular mass. A 132 amu B. 114 amu C. 148 amu D. 70 amu 2, Naturally occurring element Y exists in three isotopic forms: Y-28 (27.979 amu, 92.21% abundance), X-29 (28.976 amu, 4.70% abundance), and X-30 (29.974 amu, 3.09% abundance). Determine the average atomic weight of Y. 28.1 amu 35.3 amu 29.1 amu 86.9 amu vom> 3. Select the correct statement about ‘limiting reactant’ in a reaction A. The reactant with the least amount in grams. B. The reactant that has the lowest coefficient in a balanced equation. C. The reactant with the least number of moles. D. None of the above. 4. Choose a correct set of quantum numbers for an electron in a 3d orbital A n=3,¢=3,m=-1 B. c D. 5. Select the equation that correctly represents the process involved in the electron affinity of X. A X(g) > XQ) +e B. X"(g) > X*(aq) Cc. X@+e>X@) D. X(g) +e > Xi) (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL 3 ASIJUN 2019/CHM131/160, 10. The structure of 1,1-dichloroethene, CClsH. is shown below. Using VSEPR theory, identify the molecular geometry around the carbon atoms in the CCl:CH2 molecule. Cl. H \ f g q cl H A. Square planar B. Trigonal planar C. V-shaped D. See-saw Find the number of lone pairs around the central atom in the Lewis dot formula of ammonia, NHs. com> wrnao Select the substance that exhibit hydrogen bonding in the liquid state. A. PHs B. He Cc HS D. NHs Predict what will happen to the density of the gas, if two moles of chlorine gas at 20°C are heated to 350°C while the volume is kept constant. A. Increases B. Decreases C. Remains the same D. Insufficient information is given to answer the question correctly Select a correct statement of an equilibrium system The forward and back reactions have stopped. The limiting reactant has been used up. The forward and reverse rate constants are equal. The forward and reverse reaction rates are equal pom> (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL 4 ASIJUN 2019/CHM131/160 PARTB QUESTION 1 Iron ({ll) oxide and aluminium powder undergo a reaction to yield solid aluminium oxide and molten iron. a) Express a balanced chemical equation for the reaction (2 marks) b) Determine the mass of aluminium powder reacted in gram, if 0.005 kg of aluminium oxide formed in the reaction, (3 marks) QUESTION 2 Nickel chloride reacts with sodium hydroxide producing nickel hydroxide and sodium chloride. A balanced chemical equation for the reaction is shown below. NiClz + 2NaOH — Ni(OH)2 + 2NaCl a) Predict the limiting reactant if 25.9 g of NiCl and 10.0 g of NaOH were used in the reaction. (3 marks) b) Determine the maximum mass of nickel hydroxide, Ni(OH)2 produced in the reaction (2 marks) QUESTION 3 a) Find the energy of a mole of photons with a wavelength of 482.6 nm. (2 marks) b) Orbitals define regions in space where electrons are most likely to be found in an atom, Atomic orbitals have distinctive shapes, where all are centered on the atomic nucleus. ‘Sketch the shape of s-orbital and p-orbitals. (3 marks) (© Hak Cipta Universiti Teknologi MARA CONFIDENTIAL,CONFIDENTIAL 5 ASIJUN 2019/CHM134/160 QUESTION 4 Given the following element. xi a) Give the full electron configuration of element X. Iilustrate the orbital diagram of the valence electrons of element X. (2 marks) b) The reaction between element X and chlorine produces a compound with melting point -68.74°C. Using Lewis dot symbol, show the formation of that compound. (3 marks) QUESTION 5 a) In the atmosphere, many chlorine atoms combine with oxygen atom to form chlorine monoxide, ClO radical. Two possible Lewis structures of CIO are shown below. Find the formal charges of Cl and O atoms in both Lewis structures. CI-G6: Structure 1 Structure 2 (2 marks) b) The first and second ionization energies of calcium, Ca are both relatively low, but the third ionization energy of that element jumps to five times than the previous level. Explain this phenomenon. (3 marks) QUESTION 6 a) State the number of electrons shared between two atoms in: i) adouble covalent bond ii) a triple covalent bond (2 marks) b) Sketch and name the molecular shape of the following molecules. PCls PCle (3 marks) (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL 6 ASIJUN 2019/CHM131/160 QUESTION 7 a) Consider the chemical equation of the following redox reaction. Determine the oxidation number of sulfur, S in each of the reactants in the following chemical equations: 3H2S(g) + SO2(g) — 38(s) + 2H20(1) (2 marks) b) Express a balanced redox equation using the ion-electron method in basic solution for the following equation. Cr(OH)s + ClOs—> Cro? + Ct (3 marks) QUESTION 8 a) Determine the molar mass of unknown gas that diffuses at 0.5 times the effusion rate of Oz gas. (2 marks) b) Calcium carbide reacts with water to produce acetylene gas, Catz. The chemical ‘equation for the reaction is given below: CaC2(g) + 2H20(|) + Ca(OH)2(aq) + C2H2(g) Determine the volume of acetylene produced at 35°C and 680 mmHg from 0.07 mol of CaCo. (3 marks) QUESTION 9 a) The Kp value of the reaction between sulfur dioxide, SO2 and oxygen gas is equal to 4.55 at 627°C. Below is the balanced chemical equation for the reaction. $02(g) + 402(g) = SO3(9) Determine the Kevalue at this temperature. (2 marks) b) Express the equilibrium constant expressions, K» for the following equilibria i) NH,Cls) > NHo(g) + HCI(g) ii) PCIs(s) 5 PCl(I) + Ch(g) ill) 3Fe(s) + 4H.0(g) + FesO.(s) + 4H2() (3 marks) (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL, 7 ASIJUN 2019/CHM131/160 QUESTION 10 a) b) Consider the following equilibrium. ‘4NHs + 302 = 2Ne + 6H;O + 1531 kJ State whether the concentration of the reactants and products would increase, decrease, or remain constant when: i) the temperature of the system is increased. ii) 2mol of ammonia are added to the system. (2 marks) Phosgene is a highly toxic gas with the formula COCh. CO(g) + Ch(g) = COCH(a) The equilibrium constant Ke for this reaction at 400°C is 1.20 x 10°. Predict the direction of the reaction when a mixture contains 0.012 mol CO, 0.025 mol Ck and 0.03 mol COCI: in 500 mL container. (3 marks) END OF QUESTION PAPER (© Hak Cipta Universiti Teknologi MARA CONFIDENTIALCONFIDENTIAL APPENDIX 1 ASIJUN 2019/CHM131/160 TABLE OF ATOMIC NUMBER AND RELATIVE ATOMIC MASS Atomic Element Symbol | Relative Atomic Mass Number | Hydrogen’ | # I 10 Helium He 40 Lithium i - 69 Beryllium Be 9.0 Boron - B 11.0 Carbon c 12.0 Nitrogen N 14.0 [Oxygen eeeeatee |e 16.0 Fluorine F 19.0 Neon Ne 20.0 Sodium Na 23.0 Magnesium Mg 24.0 ‘Aluminum Al 27.0 Silicon : Si 28.0 Phosphorus P 31.0 ‘Sulphur s 32.0 Chlorine ci 35.5 Argon | Ar sEemr40 0 RREEnEEa = Potassium K 39.0 Calcium “Ca 40.0 Scandium [Se 45.0 Titanium Ti 48.0 I Vanadium: Vv 51.0 ‘Chromium Cr 52.0 Manganese Mn 55.0 Iron [Fe 55.8 Nickel Ni 58.7 Copper Cu 63.5 Zine Zn 65.4 Bromine Br 79.9 Silver Ag 107.9 lodine I 127.0 Barium Ba 137.3 Gold Au 197.0 Lead Pb 207.0 Constants Rydberg Constant, Ru = 1.097 x 107 m* or 2.18 x 10°° J Speed of Light, c = 3.00 x 10°ms" Planck Constant, h = 6.63 x 10% Js ‘Avogadro's Number, Na = 6.02 x 10 mol Gas Constant, R = 0.0821 L atm mot* K* (© Hak Cipta Universit Teknologi MARA CONFIDENTIAL