To calculate the remaining amount of a radioisotope, use the following formula where A0 is
the amount of the radioisotope that existed originally, t is the amount of time the sample has had to decay and T is the half life:
Calculating the average mass of an element
That number beneath each element in the periodic table is calculated using percentages such as the carbon abundances mentioned earlier, which allow scientists to give an average atomic mass for the isotope. Certain elements, such as chlorine, have several commonly occurring isotopes, so their average atomic masses are rarely close to whole integers. Many elements, however, such as carbon, have one very commonly occurring isotope and several rare isotopes, resulting in an average atomic mass that is very close to the mass of the most common isotope. AA t
T = ×( ) 0 05.
Chapter 3: Looking Under the Atomic Hood: Atomic Structure 35
Comparing carbon masses Consider the element carbon, for example, which has three naturally occurring isotopes. carbon-12 (or carbon with six protons and six neutrons), written as: is boring old run-of-the-mill carbon, and it accounts for 99 percent of all of the carbon out there. carbon-13 (or carbon with six protons and seven neutrons), written as: is a slightly more exotic, though equally dull, isotope, which makes up most of the remaining 1 percent of carbon atoms. Taking on an extra neutron makes carbon-13 slightly heavier than carbon-12, but does little else to change it. However, even this minor change has some very real scientific consequences. Scientists compare the ratio of carbon-12 to carbon-13 in meteorites to help them determine where that meteorite came from. These ratios have been especially useful for identifying Martian meteorites. Earth is significantly more massive than Mars, and therefore, has a stronger magnetic field, allowing it to hold onto its atmosphere. Mars, on the other hand, is too small to hold onto the upper part of its atmosphere. carbon-12 is lighter than carbon-13, so it floats up to the upper atmosphere of Mars, where the solar wind comes along like the big bad wolf and blows it away. This leaves Mars with a higher percentage of carbon-13 than you would find on Earth. So, minerals on Mars that take carbon from the atmosphere and turn it into rock end up with a little more carbon-13 and a little less carbon-12 than similar minerals on earth. When a meteor from Mars lands on Earth, scientists can verify its origin by testing the ratio of carbon-12 to carbon-13. carbon-14, the most exotic and interesting isotope of carbon, has been very important in the process of radioactive dating. Carbon is one of the building blocks of organic matter, including the human body. Only one out of every trillion or so carbon atoms is the carbon-14 (or carbon with six protons and eight neutrons) radioisotope, which looks like You have many, many trillions of trillions of trillions of carbon atoms in your body, which means that you contain trillions of atoms of radioactive carbon! Now before you go checking the mirror to see if you have sprouted a third eye, rest assured that this radioactive carbon will not harm you in any way. In fact, it is what allows scientists to determine the age of fossils. As an example, take Matilda the Mammoth, who met her untimely end 4,500 years ago. While Matilda was alive, the carbon in her body was constantly being replenished, so she was always made of about 99 percent carbon-12, 1 percent carbon-13, and 0.0000000001 percent carbon-14. However, when poor Matilda kicked the bucket, the biological processes that were replacing the carbon in her body came to an abrupt end. With their supply of carbon-14 cut off, Matilda’s bones slowly lost their carbon-14 as it broke down through radioactive decay into nitrogen. Paleontologists digging up Matilda 4,500 years later will run straight to their friendly neighborhood chemist, Dr. Isotopian, and ask him to tell them how much carbon-14 is left in Matilda. Because carbon- 14 breaks down at a very predictable rate, Dr. Isotopian is able to guess to within a few hundred years exactly how long ago Matilda kicked the bucket. 6