PageNo

Date

ACRE
Odute

Extema Dittusion
PffectsO
OnLIe

erero9enoUs eäckions.

VUmericals
Constant $ize Hlm piuston
antrols Ash
Particle tonersion ffusionon.rols Chem Reactipn Contral
Flat Plat
XB Sg. Hlaif thickmess molar densiy f B Time tr
Fomplete qonverSion
i t e solid
L Haif kg.C C Conc of
Hhidkness
Moles V AinPHase
9aseous 26 De CAa bKCAR
mte þetieen uld 4 EFfective iffusipn codeff trsOrdet rate|
farei Const For 5ur face
2ginde 2 X
reactibn
e shrinkip -xe) 4n (1-) N2
LRK F8R Yaeusat| Ralaius of -C1-xB
Fore@to COYe
4b De Ag CA CAg

3Sphee 3 -3 -s c - 1-1-x

$R
CRg
 FlmTRFFusipnCpntyol Ash DusionContjol hem React Cortro
shonKng Sphere
Srma article -CIe) F -CxB3
Stokes Regime 2 Npt Applicable
T Ro oraina
Se R
Sire f K Chg9
2CA Particle

Large artiele
Not Applie4ble -Cx
const Padis Hhen
TE Const 9 GA CAg
CAg
 Page No
Date
uniform
1.A bateh ofspherical solidsof singlesize1
s
reakedby qas in a unifarmenviranment Salid
Sconveykedto a_tirm hon akinq product
Accordinq to ShrinkinqCore madel CScM_
The canversian is 87.S in a veaction time of ih
and it is camnplete (oo/) in_2h Determine
Ehe YaAecontrolling mechanis.m

alutioni
Sincethe produck is iim han lakinq it means
parkicle remain Unchanqed in Size After Ieackion

oY_Constant Size Spherical particle the time

Conversion expressions tor different mechànisms dre

ci ilm DIFFusian Controls.

Ci :1:3Cxe)
T
ta Cl-Xg) Ash DifRis Cantrl
cii tz1-0-Xe) checmica Reackion Contzal

far any mechânism to he rake Cantrollinq the

CaIYespondinq CpYe.ssia.n need ta he satisstie
Giveni- t i h T: 2hr and Xss o875

CiDJhenln diffusion control

087S

As peY dala the timecanYeisian expiession o

diftusiann doesa nnt match:
lo diisian is nat an ate contzallinq mech
 P.argy N.
Onto

CiDtar Ash Diffusion_Cantrals thetime ConyelSion

expression is
2
1-3 C1-X8)_+2C1-Xg)
1-3 C-o:815) 2 C1-875)

O 5 : o:5
LHS RHS

The yesistance to diffusi.an throuqh ash ayer

Contrals the overal rate.

Ciij Sar_chemical veactiancanbrolingthe overau Yate

Ne hare

- C-Xg)5

1- (-o.815)
0 S 0.5

Accardin to ScM data the time conNeision-

exp1ession sOY this mechaais.co

Sohere e have A caincienceHhee bath the

ashdiffusion 3 chemical Yeaction mechânisms
i he daBa
Contyols
Ash laCI diffusi6n
theaic Yedction control_
fot t hich both
Meeh Contral
 Pege No. b
Date

Ido Small Samples of Solidsare kept*n_a-

Constant enviroomentOYentar- periodof Lh.
nderthe
theconditians prevailina in the oven the
4mm particles are518/ converted the 2mro
particles are 87s conyered

adind the ate contrallinq mechânism o the

Conversian of Salids
b i n d the time required tor Complete conyersion
ot Imm particle in the Oyen

Saludiani
Data giveni
R mm

R , :4 - 2

AB2 .815
Ra2 2

cbGarln diffusian controlling e haveor Constant

SizeSpherical particlesi

Xee-

and
TR

toy 4mm particle

Tor 2mm palticle

 Page No 6
Dalc

G:cR CCanstant
I,:CR-
Xg AB, 2

XBC.R
XB Ri XB, RBe This should be Satisticd

Xs,R o:578 2 =58

SR 0:87SxI o815.

The condition is not satistied So l m

diffusion daesnot Contiol the rate.

Cior Ash diffusionControllinqe have

t 1-3 Ci-Xs +2C-Xa)

T
TR

t -2C1-Xg,)°tacl-Xg,) mm paticle
T
GcR

-3(1-Xg,) +21-XB, 2mmparticle

R T :cR
2
T-3C1-Xg,) + 2 CI-XB)
cR2
R2 - * 2 (-YB
 Pege No.7
Date

R 22 4
= O:25 LHHS
R2
3
-3C1-Xa +21-Xe) 1-2(1-0S18)+21-0S72)
3tt-B.) 2C-XB 3ttro875)2(-0-275
O 312 : RHS

LHs RHS
Sa ash diffusian contrallinais no 1ate contraling

Cii)Gar Chemical Yeackion ContrallingHe have

Cl-Xg)S
T
and & R

-C1-xg Amm Particles

CR

t-C-Xg,) 2.mm particles

T

CR
3
t :TCI-C1-X8, :Cl- I-Xg

Substitutinq R2mna Rlmm &Ag¥B

LHS: RHS 0:5-

contralliaq mechanism is Chem Rxn

heyate
 Page No 8-
Date

completion
time needed to bln to
33 Calculakethe
SmmSg2:2gmlcm

particles af graphite Ro
8aXugenSEYeam
K : 2ocmlsec in an
assume that tilm
highgas Velacitu used
tar the any_Yesistance o transto
diffusion daes not offer
RxnTemp Joo.c.
and Yeaction
SCM ie shiinKioq
SCM i.e Shtinking
Here Hc are hainq of
o-
Dolutioni thePossibility
and aspey
Particles
esistances, 2poasiblemechânis.msdr
are

c D dilo diffusion
Ci) Chem Rán

that siln ditusion does_not

Since it is given
offeyYesistance

ChemRxn contrallin-
Sa
1--Xg)3

T
T: Sa RRo
bKCA
Sp2.2gmlcm 0:183 malcm

129mmot n. .A
008 8:30-x1o mol
213 Cm3
A Lmal
22400cm 213+100

022_co-
ar Rxn of C+

in
Suhatituting-

Secz .53h
1 :5SLO