state hybridisation

solid
andBondtahe.me/-ers
 JEE (MAIN + ADVANCED) 2023
NURTURE COURSE

RACE # 14 INORGANIC CHEMISTRY

TIME : 35 Min.

Q. 1 Draw the structure of the following molecules / ions.

(1) XeF2 (2) XeF4

① it
¥81s
E- ¥
a- "
(3) XeF5¯ (4) XeOF4
tf

÷
(5) PCl3 (6) PCl5

(7) SF2 (8) SF6 →

i.
(9) IF3 (10) IF5

(11) IF7 (12) OF2

(13) NO 3- g-
"
"
% ⑤
(14) SF4
in .
(15) I3+ %%
(16) I3- (17) OCl2
Go
I
(18) SnCl3– →

2–
§ ?i " (19) HPO32–

–
n' bio
-

(20) SO3
① ←
(21) IO3

%
-

o
ClO 3-
-
(22) XeO3 -
" (23)
i •
NI!
(24) ClO4–
¥%→ (25) NO 2 –
→ -

(26) PCl4+ (27) POCl3

(28) SO42– (29) XeF5+

←
Piet:
'
'

g f

Inorganic / R # 14 1/1
?⃝
?⃝
solidstatehyboidise.gl?onegPds-
a- p¥ CTBP )
,

1 ,

Pelf
clip
+
→
Patsies,
-0

critic
+

>
sp
.

, pay
+ pay ,,
a-

/
Ñ% ,
Ci 1
old
,
> ( octahedral)
sp

2 Palsies,
→ Pclyt + Pclj
Sps sf3d2
¥+0 at

attic
,

Cid
'
,

Td octahedral
(s)

CS )

"

( s)
Bondparameters
①
Thesmalstability !

heat reonuired to
Amount of

break bond in molecule .

is reached
If more energy
bonds it means
to break ,

molecule is thermally more

stable .

compare Thermal stability

I
el > H Br > h -2
④ H - f ? H -
-

-310 Is -410 Is -
Sfs
Is -210 is

ASH > sbttz

⑨ NH , > Phz 7 ,

sets , > sntsy

> situ >
② Chu
⑦ Sify > sicly > siBry > size

⑥ Bc > BBB
> 1323
Bfg > }

717123
④ AICI
,
> ALBI

< NEN
0=0
⑨ f -
f <
②
Bondordee.IT
is defined as number of
two atoms
between
.

bond

= I
H -
H B. O -

ch - n)
= 2
B. 0 o]
0=0
.

co -

=3
B. o.cn N)
N -

NE

I
B.0.cc Hj=

1¥
-

-
a
= I
% B.0.cc - c)

B. 0.cc -0--1+1-2
=3

% "
B. °
.cc/-oj
"
If
O

1+3-4
-

O
=

?
•
=É '
B -
O -

ee -
,
o
=
1+5=31
o
-

is
'

" •
Bois -
,
o
=/
+2g
-

o = 1.5
③Bmdangle- :

two bands is
between
Angle
known as bond angle .

( it while comparing bond angle ,

tsredict hybridisation
first we

species
in given
.

90s
In hybridisation ,
as

bond able
increases
character
also increases .

SH sp3
sp
259
50% 33.37
.

%s
120° 1090287
180°
B. A
.
I GmpareiB.A#
④
Befz 7 Bfz > cfy
Sp Sff sff
f B
§
f- Be
f -

4- 7-
-

c-

180° 120° 1090281

⑦
⑨ 7 My
Noa > Noj
⑦
=N=0 -0 N
It
flin
-

•
o

st Stf sp3
180° 120° 109^28
'
(ii. 1 In case of same hybridisation
decrease with
then bond angle
central
increase in lane pairs on

atom .

City
NH 7 H2O
> ,

⑨
¥
I
jinn
'

f n
n' him
sp3
sp3
sp3 104051
107°
109%81

→ Noj < Noj

③ NFL
8-
NÉE
. .

.
BI 120°
2<120
B. A .
 Due to Presence of steric
*
C. group repulsion]
crowding Bulky
Band increases
angle
.

is
Group repulsion
Bulky
central atom
when
dominating

secandbesiodands.org
÷:÷Em→ .
belongs
to
3N or downward

twosuch-
and at least
central atom .

attach to
stecies

egg
. •
clz

:@ ⑤ Go
§Écl f
f-

Sff
Sff
✗ < logo
07109%81
( No bulky
C bulky Got
aopxp ) .

repulsion psesatl
?⃝
 •
CCHz)z sclz

¥→st
'
s

Fc
0 Hz
Lisa
*
' sp3
02109028 2<1090

C. Bulky Goofs

repulsion present
?⃝
 ③ In case of same
d. b. B. D- depends
of
.

hyb same no .

,
,
and
electronegativity of A.
c.
on

5. A .

Compare B. A
II.
.

④ NH NFS
,
④
⑤ >
B. it
µ¥n÷H
.

f. I

H2O
•
fz
⑤
④
① >
F. j
B. D-
,É÷H
°

É
.

sp3
Sps
?⃝?⃝
 ② N Hz PH3
①
7
p
N
É 'n÷h
" '

"
in
-

te
n

Has
④ Hao

n¥÷n
•
>
% in
•

n
?⃝?⃝
?⃝
?⃝
④ Bts
Bfg Batz BBB

f- B =
9-
By
F1
=
Br
-
B
rBr
-
= ←
B
?z
B,

= 120

Cfy Ccly
④ ctly '
i
É e = 109£81
I =
=L :-c
Hicklin
,
,

= D- 123--120
⑤ Alclz = A IBB

z
?!
Al
2-
- Al
At Br
a- ,
,
 ① cloj cloj clog
⑨
en
I
" 0

"o¥0
c , -

" - o
" o -
o
o

✗ < Per

silty
② CHY
: -409%8
'

¥5m
s
=
finite
n'

③ ie
BEÉ 2<13
£ if
?⃝
Today 's
Homework

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