John Mark R.

Allas
BS CHE – 3

1. A
2. A
3. B
4. C
5. D
6. A
7. B
8. C
9. A
10. D
11. C
12. A
13. D
14. B
15. D
16. B
17. D
18. C
19. A
20. B
II. Problem solving
1. What is the rate law for this reaction?
−𝑟𝐴 = 𝐾⌈𝐶𝑎⌉𝑥 ⌈𝐶𝑏⌉𝑦
1.19 0.50 𝑥
𝑋= = ( )
4.79 1.00
0.24 = 0.5𝑥
𝑆ℎ𝑖𝑓𝑡 𝑠𝑜𝑙𝑣𝑒
X=2.32

9.59 1.00 𝑦
𝑦= = ( )
4.79 0.50
2.00 = 2𝑦
𝑦=2

−𝑟𝐴 = 𝐾 ⌊𝑁𝑜⌋2.32 ⌈𝐶𝑙2 ⌉2

2. Given:
T1= 25°C = 298.15k
T2= 80 °C = 353.15k
Solution:
𝐾2 −𝐸𝑎 1 1
𝑙𝑛 ( ) = ( − )
𝐾1 𝑅 𝑇2 𝑇1
7.35𝑥10−2 −𝐸𝑎 1 1
𝑙𝑛 ( −3
)= ( − )
4.27𝑥10 𝑅 353.15 298.15

Ea=45292.48 J/mol
3. Solution:
-ln (1-Xa) = Kt
-ln (1-0.675) = K(540min)
K=2.0814x10-3min
At 25% reactant has decomposed
-ln (1-0.25) = (2.0814x10-3) (t)
T= 138.22 min
4. Mean specific rate constant = 8.5