392 CHAPTER ASSIGNED PROBLEMS Problem 8:11 MASS 1624 3 1003 164 7 4 ay 7 r a 1 3 50 34 734 125g , fr ele 50 6070 80-90-1009, 110120 130140150160 IR ° E a @ L Abad fu od goo ‘ 3000 , 2000 , 1000 ’ ire NRta ee Mere Wavenumber (cm-1) | — FW - 2 — SERIES Un LUUInEIDS RI UIREEDS DURE SED 14 72 70 68 66 64 62 60 58 56 54 5.2 ppm SC/DEPT NMR 75.5 MHz. | | ~~ a pot aaa ahhh hanna anni 7 r 7 1 155 150 145 140 135 130 125 120 5 ppmProblem 8.364, ASSIGNED PROBLEMS 427 MASS 3 87 —— 2 1003 104 & 00 sy is. 130 ee } 40 50 60 70 80 90 100 110 120 130 mR m/z 5 £30] I —e” : 5 T T T = T T 1 4000 3000 2000 1000 1 Wavenumber (em-1) ‘HNMR 600 MHz I ( Wel alk MM A the oN. NWA. AWWA Woo 2350 Hz 2300 He 1000 He 850 He 700 He 550 He In the above insets each tick mark is 10 Hz S St S hit oT 3.0 28 20 Ls “C/DEPT NMR 150.9 MHz. — 11 \ | | LI | | 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 ppm428 cHaPTERs ASSIGNED PROBLEMS. Problem 8,368 ppmtS 40 35 30 25 20 15 10 ppm COSY 600 MHz pe 104 "TTF Lio seed 154 eo LS . eere 2.04 . £2.0 c Fl 255 [2.5 3.0 3.0 3.575 3.5 wi : Lio == F2 | HMQC 600 MHz || ool 104 | . 10 wo Ny 10 ' 20 _- ' H20 | 304 8 30 = . 095 090085 ppm 404 ue +40 Fl 504 50 604 F-60 704 ” £70 45 40 35 30 25 20 15 10 ppm F2m 837A, AsstUNeDeMUsLEMS 429 MASS Inyo Mt 4 Toler) 973 4 i00 15201000 4 ISB (Men) 12.7 3 ia) $2124 ‘s 50 “3 “1 nd f | reer rere eee ee ete eee HT 50 60 70 80 90 100 «110-120. :130. 140150 m/z IR g 2 LF é Lig ° & a 6% r T T T T 7 1 4000 3000 2000 1000 1 Wavenumber (em-1) 'H NMR 600 MHz if i Ih V | Whe. vy \ \ viv SJ es JN 460" He 4860 He | 260 He 1520 Hz 740720 Hz 600 He 75 70 65 60 55 50 45 40 35 rem *C/DEPT NMR 150.9 MHz i 4 180 160 140 120 100 80 60 40 20 ppm430 cHapteRs ASSIGNED PROBLEMS Problem 8378 ppm COSY 600 MHz 34 3 mn 44 ba 3 5 64 6 ba 3 F F2 TIMQC 600 MHz vom |} | _ 20-4 F 20 [- 405 r 40 60 r 60 FL L 804 fF 80 1005 + 100 120 120460 CHAPTERS ASSIGNED PROBLEMS Problem 8.484 ES MASS 038 24 2 4 Ha" = 34 136 oT 450, "HNMR 600 MHz in D,O M40 He 2800 ody oN wht, AA Li le al 55 50 450 4035 15 1.0 ppmProblem 8.488 ppm 1.0 15 2.0 25 iti 35 40 45 5.0 55 ppm 2.0: Fl 45 3.0 60 55 50 45 40 35 30 25 De hi ASSIGNED PROBLEMS 461 a 15 1.0 ppm COSY 600 MHZ F at . wa . # fio @ Fis oe FOE se Foo L . Los LC | b30 ne bas bo te = b4o an "6 ¢ bis = . , ‘ > Tae . . faa . . e Le 4 25 4 +30 ‘ = Las eo " o> ' 3 Sea a T T T T T T7740 4.0 35 3.0 25 20 1s 1.0 ppm462 CHAPTERS ASSIGNED PROBLEMS Problem 848C ®C NMR 150.9 MHz 155184 153 ppm qa 4aq ————————————————— 160 150 140 130 120 110 100 90 80 70 60 HMQC 600 MHz ppm ppm 10 20 304 40 50 Fl 60. 70 ‘ ,. 7B et 30 e 904 4 ° 604 too # 38-37 26 38 34 32 32 3.1 ppm 6:0 eS see Oe Seal ees gee Opera oe eT Se 1) ppmProblem 8.48D ASSIGNED PRoaLems 463 ppm if HMBC 600 MHz 10 PY 20 . os 304 . . an E ar) . ‘ . . "¢ - | 50 A ; 8 m . * 8 . eo 604 nw4 4 . . . | = . ‘ 804 904 1005 ‘ | ppm Tt = = = 7 a = 7 a f 1555 L \ ( ‘ : = 1605 1655 ' VI pT 60 55 50 45 40 35 30 25 20 15 10 ppm r22s Chapter 8 Additional Problems 114 MASS é ; a. ft x20 a 104 1 4 $ & 0a | T ge pata u | 50 150 IR 100 sd | g 04 ; 2 80 a4 i Lod aA Li = a8 Ba o8 & & T r T T T T 1 4000 3000 2000 1000 ‘Wavenumber (em-1) 'H NMR 600 MHz ir x64 f 13 12 11 10 9 ppm fo ~ =" th Tada IL eT TT a] 29 2.8 2.7 26 25 2423 22 21 2019 18 17 L615 14.13 12 L110 ppm *C/DEPT NMR 150.9 MHz | | (ewe | LIL 200 180 «160 «140120 1008040 ppmChapter 8 Additional Problems 118 26 ppm30 28 26 24 22 20 18 16 14 12 ppm COSY 600 MHz po . + 10-4 1.0 124 . fiz . L 144 ° pia 16-4 16 rly +18 olf « gf Loo 224 . 2.2 244 Ss $24 = 264 26 284 +28 . om = F2 HMQC 600 MHz ppm lk 1s4 Fis 204 +20 254 b25 304 . . +30 Fl 354 - £35 404 | | 40 ppm 454 bas so 3004 | | Eso 54° 305 P55 24 22 20 18 16 14 12 ppm aa nL nL ne a ne ne 3.0 28 26 24 22 20 18 16 14 12 10 — ppm F2Chapter 8 Additional Problems 11 27 HMBC 600 MHz Lo ke ie a Oe 32.30 28 26 24 22 20 18 16 14 12 10 08 ppm ppm “ ‘ L 204 " wn t— 254 304 o ’ — as e Fl om te ‘ 4 - 404 wee '‘ ‘ ppm 1804 _ 1904 2004 2104 30 28 26 24 22,90 18 16 14 12 10 08 — ppm