SECTION – C (21 MARKS)

(From Chapters 15-20)

Q3. Attempt any SEVEN parts. All parts carry equal marks. (7×3=21M)
i. How would you detect Carbon and hydrogen in an organic compound? Elaborate your
answer with suitable chemical equations.
ii. Acetic acid is more acidic than phenol. Give reason.
iii. Write down the reactions of propene with H2SO4/H2O, O3/H2O.
iv. Write down three differences between E1 and E2 reactions.
v. How acetone does reacts with HCN and formaldehyde reacts with NaOH.
vi. Write the structures of the following compounds:
a. Cis-1,2-dimethylcyclopentane
b. Lactic acid
c. Durene
vii. Classify the following compounds if these are primary, secondary and/or tertiary halides.
a. 2-Bromo-3-methylypentane
b. 1-Bromo-2-methylpentane
c. 2-Bromo-4-methylpropane
viii. (a) What is resonance energy?
(b) Draw the resonating structures and resonating hybrids of benzene.

ix. Benzene gives electrophilic substitution reactions. How does it substitute bromine?

Explain your answer with mechanism of the reaction.

x. Draw the structure of the following compounds:

a. 3 – Methyl cyclohexanone b. 𝛼 - Methyl propionaldehyde c.

Acetophenone