Professional Documents
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MASONRYCLAD BUILDINGS
PAUL A. NOYCE
Impressed current cathodic protection (ICCP) has been used to mitigate corrosion damage in historic steel-frame
buildings since the early 1990s. This specific application of the technology originates from its use in concrete (1970s);
however, the discovery of cathodic protection dates to 1824.
The process of ICCP is the intentional application of current to a corroding piece of steel through an electrolyte. As
a redox reaction, oxidation and reduction occur simultaneously. The anodic reaction or oxidation is the loss of elec-
trons, which causes the steel to revert to rust. The volume of the rust can be as great as ten times the amount of steel
section loss. The accumulation of scale damages the exterior masonry cladding where the tensile forces of the corrosion
are greater than the masonry can withstand. Prior to large-scale losses and cracking, minor damages become appar-
ent, such as hairline cracking and open joints.
Simultaneous to this anodic reaction is the reduction reaction at the cathode site. The cathode reaction is harm-
less, and the cathode gains electrons that have been lost at the anode site. The electrons pass from the anode as ionic
current through the masonry, moisture, or mortar electrolyte to the cathode site. The electrons return to the anode site
as electrical current, creating a full circuit. This reaction is the basis of cathodic protection, whereby the corrosion cell
is controlled, thus limiting damage to historic building fabric and providing a life extension to steel-frame structures.
The presentation will discuss corrosion reactions, investigative procedures, design challenges, and installation
requirements to help the audience understand the applicability of this technique as a means of corrosion control.
The paper will cover the steel-frame construction, corrosion onset, corrosion reactions, and installation and design
requirements needed for successful installations, as well as case studies.
SPEAKER
GINA L. CREVELLO — ECHEM CONSULTANTS LLC
GINA CREVELLO is the principal of Echem Consultants. She was professionally trained in architectural materials
conservation, having studied at Columbia University’s Graduate School of Architecture Planning and Preservation.
Upon completing her master’s of science, she completed the postgraduate certificate in Conservation of Historic
Buildings and Sites as the program’s first graduate. Crevello has 15 years experience in building diagnostics, with seven
years of experience in electrochemical treatments and corrosion engineering. Now she exclusively focuses on corrosion
failures of steel-frame and reinforced-concrete structures and material degradation. This work includes corrosion diag-
nostics, nondestructive testing, life cycle assessments, durability engineering, and electrochemical remediation.
Crevello has been involved with the majority of installed impressed current cathodic protection systems on land-
mark structures in the U.S. to date. Her work has included iconic structures, such as the Guggenheim Museum and
the United States Holocaust Memorial Museum.
NONPRESENTING COAUTHOR
PAUL A. NOYCE — ECHEM CONSULTANTS LLC
Paul Noyce is vice president and chief electrochemist for Electro Tech CP, LLC. Paul is professionally trained in elec-
trical and electronic engineering from the University of Bristol and received a diploma in electrochemistry 1991. He has
since been practicing corrosion engineering, and is regarded as a pioneer in the field of concrete and steel-frame cor-
rosion diagnostics and electrochemical corrosion remediation. Noyce was instrumental in the first use of ICCP for her-
itage structures in both the United Kingdom and the United States and has extensive experience in galvanic cathodic
protection, electro-osmotic pulse, concrete realkalization, and electrochemical chloride extraction. He has been an advi-
sor on and designed electrochemical treatments for one-of-a-kind landmarks such as the Cutty Sark Clipper Ship, the
Thames Barrier, and Uxbridge Station. His traditional work includes transportation, civil, and industrial structures.
Noyce has designed and provided engineering oversight on the largest industrial and heritage ICCP protection systems
to be installed in the U.S to date. Noyce is chairman of NACE Committee NACE TG044 – (SP0290) Impressed Current
Cathodic Protection of Reinforcing Steel in Atmospherically Exposed Concrete, NACE TG460 – Testing and Evaluation
of Corrosion on Steel-Framed Buildings; vice chair of NACE TG048 – (SP0408) Reinforced Concrete Cathodic Protection
of Underground or Underwater Elements; and a member of NACE STG01 Reinforced Concrete, NACE TG047 – Sacrificial
Cathodic Protection of Reinforced Concrete Elements, NACE TG043X – Reinforced Concrete Cathodic Protection, ACI
201- Guide to Durable Concrete, ACI 365 – Service Life Prediction, and ACI 563 – Evaluation, Repair and Rehabilitation
of Concrete Buildings.
MASONRYCLAD BUILDINGS
INTRODUCTION masonry, or surface moisture as an elec- struction could be from 1) the use of deicing
The use of impressed current cathodic trolyte through which corrosion current salts at the sidewalk, thereby only affecting
protection has been employed on masonry- flows. The corrosion reaction will be depen- the base; 2) marine mist, affecting coastal
clad steel-frame heritage buildings since the dent upon various elements: oxygen, mois- buildings; and 3) the use of calcium chlo-
mid-1990s. The work originated out of ture, chlorides, and temperature, to name a rides or other curing agents used in “winter”
England, when the Department of the few. To halt the corrosion reaction, the envi- construction. These would most likely be
Environment, English Heritage, and ronment or the reaction must be changed. found in concrete floors or roof slabs tied
Historic Scotland sought alternative treat- The conceptual aspect of the ICCP as into a steel frame.
ments to large-scale stripping of “listed”1 applied to historic buildings is the same as To control corrosion, the anode, the
steel-frame heritage buildings for corrosion when ICCP is applied to reinforcing steel in cathode, or the environment must be con-
mitigation. This endeavor employed the concrete. Construction details and cladding trolled. If the steel cannot be protected by a
knowledge base used by the corrosion engi- materials differ, though the corrosion barrier (coating), corrosion will occur in the
neering community. Applicable investigative process is the same. It is most often a gen- presence of oxygen and moisture. To paint
methods and electrochemical treatments eral carbonation-related (drop in pH), the steel, significant amounts of masonry
traditionally used for corrosion of reinforc- atmospheric corrosion reaction that affects are required to be removed. As this further
ing steel in concrete were studied over a steel-frame construction. damages landmarked buildings and expen-
three-year period. The results were the first Chlorides are very important as corro- sive cladding, ICCP was tested for its use in
use of impressed current cathodic protec- sion accelerants. While chlorides have the steel-frame construction.
tion (ICCP) for steel frames embedded in ability to break down the oxide layer and Cathodic protection is the intentional
masonry structures. cause accelerated reactions, they are not a application of DC current to the steel. This
Steel embedded in a highly alkaline primary cause of steel-frame corrosion. The provides electrons from an external source.
environment, such as new mortar or con- presence of chlorides in steel-frame con- This is called the anode. Thus, the anodic
crete, is in a “passive” state and protected
by the formation of an oxide layer.
Additionally, steel is “immune” from corro-
sion at specific voltages, e.g., -500 mV vs.
standard hydrogen electrode (SHE) for steel
in an aqueous solution. Pourbaix diagrams
can help better explain the relationship of
pH vs. Eh (voltage) and its significance to
corrosion, immunity, and passivity of steel
within a specific environment, as seen in
Figure 1.
The onset of corrosion of steel in a mor-
tar/concrete electrolyte occurs after the
passive oxide layer breaks down. The
breakdown of the oxide layer occurs
through a neutralizing reaction with carbon
dioxide, called carbonation, which lowers
the concrete pH.2 As moisture and oxygen
enter the concrete matrix at cracks in the
concrete or through diffusion, corrosion ini-
tiation has begun. A corrosion reaction gen-
erates a chemical change as well as an elec-
trical potential change (electrochemical).
The electrochemical reaction that occurs at
the steel surface utilizes the backup mortar, Figure 1 – Pourbaix diagram for steel in an aqueous environment.
SYMPOSIUM ON B U I L D I N G E N V E L O P E T E C H N O L O G Y • O C T O B E R 2 0 1 2 CREVELLO • 45
sure that over- This was the first historic building in the
protection and United States to have ICCP installed. The
hydrogen em- area protected was the 1914 Wabash build-
brittlement do ing’s pilaster colonnade at the Randolph
not occur. Power and Wabash Street elevations at the 11th to
supplies with 13th floors. The work on Daniel Burnham’s
multiple chan- Marshall Field’s flagship store in Chicago
nels can provide came about from the engineers’ previous
protection to a corrosion investigations and ICCP system
number of design carried out on Selfridges’ Depart-
“zones,” as each ment Store in London, also designed by
zone requires Burnham. Both buildings had the same
independent detailed pilaster colonnades along the
power. All units façade; both buildings were suffering from
must have ad- corrosion of the embedded steel columns.
justable control, The engineers working on the repair
accommodate scope of the Marshall Field’s flagship store9
monitoring cells, were looking for a method to mitigate corro-
Figure 6 – ICCP schematic.
record and store sion, minimize masonry removal, and pro-
data, and they vide the owner with a long-term corrosion
repairs. must provide power interruptions for test- solution. This was the third repair cycle for
• Anodes are usually situated parallel ing requirements. Units can be independent the pilaster columns. Any further damages
to beam and columns. of one another or be linked to a main con- sustained to the terra cotta could have
• There is minimal internal disturbance. trol that manages and stores the collective caused irreparable damage requiring full
data from the independent units. replacement and posed a life safety risk for
Cathodes A schematic is provided below in Figure pedestrians. The estimated cost savings to
While anodes are installed to provide 6, showing the layout of a system in a the client was $500,000.00 where the ICCP
electrons to the steel, the areas of the steel masonry-clad, steel-frame building. The rod was installed.
frame targeted for treatment become the anodes are attached to the [+] of the power In keeping with standard design proto-
cathode. Wire connections to the steel frame supply (red), and the steel frame (cathode) is col, the system was designed to have four
provide a return path to the power supply connected back to the [-] of the power supply. “zones” or independently powered areas.
unit, as the negative portion of the circuit. Zones are defined by the amount of steel
TRACK RECORD AND CASE surface area to be protected, the proximity
Monitoring Cells STUDIES of the steel elements to one other, and the
Reference electrodes or half-cell poten- The first cathodic protection system for even distribution of current within the zone.
tial electrodes are permanently embedded the prevention of steel beam corrosion in a Each zone has two monitoring cells to pro-
as part of the system. All systems require masonry structure was designed by vide data for polarization and potential
performance evaluations according to the Taywood Engineering Ltd. and completed in decay. All wiring was routed internally and
National Association of Corrosion Engineers 1991. The CP system provided protection distributed to the power supply units,
(NACE) and British Standards European for the entrance colonnade of the Royal which were then linked by a communica-
Norm (BSEN) standards, and all perfor- College of Science, Dublin. The entrance tions cable to a main control unit (MCU).
mance is based upon the native potentials colonnade is a limestone structure contain- The MCU has an independent phone line,
and changes in Ecorr once the system is ing two parallel structural I-beam members. providing dial-up access for remote moni-
commissioned. Since its completion in 1991, regular toring.
remote monitoring via embedded reference The project posed a unique installation
Power Supplies electrodes has shown no corrosion prob- challenge, as the materials and installations
All external wiring is brought into the lems. This has also been confirmed via procedures require a DC electrical system
building and routed to the power supply annual visual inspections. Since the devel- to be embedded in masonry. This crosses
units (PSU) or where most suitable for the opment of this first CP system for masonry, “union-owned” work, and it required full-
structure, roof, etc. PSUs are generally over 150 systems have been designed and time installation support. Though the
placed on the interior of a building in a installed for masonry buildings in the UK. anodes and wiring should be installed by an
maintenance closet, drop-ceiling space, electrician, the components are embedded
basement, etc. Commercial Department Store, within mortar and grout, which is “owned”
PSUs or transformer rectifiers (T/Rs) Chicago, IL by the masonry union. The design engineers
utilized in steel-frame cathodic protection In 2003, UK corrosion engineers8 were were on site full-time to assist in the train-
require finite control of current output and engaged to carry out corrosion investiga- ing and installation process in order to
voltage limitation. The systems require so tions and testing, design services, and appease the trades, the owner, and to
little current to polarize the steel that there installation support for an ICCP system on ensure that all work was carried out seam-
must be adequate control measures to en- the Marshall Field’s Building in Chicago, IL. lessly. The design team worked on the
U.S. Government
Museum Adminis
tration Building,
Washington, DC
The Ross Admin-
istration Building at Figure 7 – Image of cornice to be protected.