‘Aga Khan Higher Secondary School, Karaehi + Preliminary Exa BIFK ~ XIT~ Chemistry ~ Paper 1 1 shift ‘Time: 30 Mioutes Max, Marks: 43, SECTION ‘A° (MULTIPLE CHOICE QUESTIONS). (M.C.Os3 Nore: |) This section consists of 43 parts questions and all are to be answered. Each question carries one mark 1i)Donot copy the part questions in your answer script. Write only the answer in full against the proper number ofthe question and its part. 1. Choase the correet answer for each from the given options. i. Which of the following transition meta ions shows the strongest paramagnetic behavior? ser Fett Fe? +20" ji Which ofthe following structural formulae is NOT an alcohol? R iii For the given complex whieh option is comect? HCH NI )3F* ‘Coordination number | ‘Type of figand x é Bidentare B 6 Tiexadentate c 3 Bidentate D. 3 Hexadentae wn a < a (i) Lithium isa good reducing agent de to its > ‘small ionic radius * low ionization enerey ‘+ ow heat of sublimation ? * low density\. The formula of the gas found in mashy places is wh oth rout Cte Vi An uincharged atom of an element X has a valence electron distribution of nS”. nP* The element X is expected tobe + “tit nom meta + ametaod * an actnide . vii Whenacetyen is passed tough ht hie in presence of erganonickeit poly erizes to + Polythene Benrene *Protcin * Polyaceylene Transition elements hve high melting an bling points duo he + Member of paired electrons, * member of unpaired electrons + Weak indiogen bonding Stony bing orees is. lon ydries re formed by + Transition metals A Berets of high elect positivity 2 Metilos * Elements of high electoneatvty % _ InAlumino-Thermite process Aluminium sets «xidizing gent + semperature reducing agent reducing agen + mire ining age Xi_The destructive dition of ol produces: 7 cake and coal pas charcoal * phenol ¢ wood spit @ _ Treeelocazaton of x eleston ina benzene ing is responsible for: + instability of aromatic ing 7 ity of aroma rng © stration of beeen * amsataton of benzene Xi Which ofthe following shows the ect ode of aly halide with magnesia? + ROC) R= BRT +R) R-C1)ReI + R-DR-cyR-Br PRD RBH R= se. The inetionl group at highest priority in TUPAC naming in he sven compound i: OHO sono 4 a +0. +on “coon xv. The compound in which each earbon show sp? hybridization is: UF CHKCHSCHS *cinc=cH 2 ances *cinech—cr-ch svi, The teacton of ety magnesium brome wth carbon doce resus in the Formation of «Benoa acid * butane acid A Forte acd * propionic cid rit. -Buten3.yne has ‘+ sixerand four ® bonds ~Azeven 0 and three x bonds + ight and to x bonds * nine cand one x bond Yet-tet-Bs boar 8 Ge ul § an 34 8 oy svi j 3 and petiod3 of the modern period able hen element is re 7 . Ast 25223 apt 3d pt 3 ‘ ‘ 3s.Ad!83p) V0 + Ist2shaph3sh3p VA @) _Anetement having low value oF ionization eneigy and low value of elecuon atin is ikely to belong to © Group ta A Group tla, * Group VA * Group VII XX In the diagram of the Downs Cell shown, the parts labelled X, Y and Z ave + X= positive electiode, ¥ = steel sauze, Z = negative ek +, X= negative electrode, Y = postive electrode, Z » stel gauze X = postive electrode, Y = negative electrode, Z = steel gauze ‘+X =nepative electrode, ¥ = stee! gauze, Z = postive electrode xxi, Name the metal which is protected from further corrosion by the oxide layer that forms on its surface + ion “Alun * Lithium * Sodium ‘xii, What isthe function ofthe steel gauzs inthe Downs Cell? AL be | } i stettGoure ‘+ Weacts asa catalyst during the process, A Toprevent the sodium and chlorine coming into contact and reacting ‘+ Itis the negative electrode, + Itremoves any impurities from the sodium, xxiii, Hydrogen resembles with carbon because of having: ‘= same number of electrons inthe valence shell similar physical state A remarkable reducing properties * show same valency, xxiv. Which statement about metals is FALSE + allthe metals are good conductor of electricity all he metals form acidic oxide + all the metals are good conductor ot heat + all the metals form positive ions xxv. Tonic hydrides are formed by: ‘+ transition metals + metalloids animal material only * Petrolium plants material only plants and anions’ material xxix. Which ofthe following isan electrphile? €* (AIMS. APES F + cho ec NHS rch Xxx Which of the following is NOT a heteroeyelie compound N a + + Ve 2esxi, Which ofthe following is the IUPAC name ofthe given compound’? HO aC CH= HCH, 4. mesy -1-petene 4-yne 7: meth 2ipeinene tyne ‘+ Smetiyl-l-penhne ene ¢ Smal 2-pentyne 4 ene rox, Matkovnikovs addition of Isnt applicable to + Propene * butene * Lpentene A utene ssl, The essential component of ferlie is + Ammonia niogen 4 ety aines + atk nies cet Cel soni, Ethylene and acetylene can be distinguished by sing: + Bromine in CCl A Toles reagent & Bacyers reagent * Phenyhydrazne rixy, Predict the two most likly mechanins which occur when 2-Jodohexane is heat ingthanol pO? + SN2and SNI * El and E2 + SN2 and E2 ‘Ei and SNI aux ake is obtained from “Phenol and formaldehyde * Adipic acid and hexamethylene diamine Dimethyl terephthalate and eliylene glycol * Neoprene sexxvii Polymers which soften on heating and harden when cooled are + Crosslinked polymers * Copolymers * Thermosetting polymers ThermoplasticsSxwvil) Tonic hyries eset with water and produce in sotto + ow vw “n to Xxx, Which of the fllowing group VIA hydrides isa neutral hydride 1S. iho *hSe *tbTe XL The following given structure contain: 2H ‘+ 6 sigma and 5 pi bonds SA 7 sigma ond 3 pi bonds + 12 sigma and 6 pi bonds +12 sigma and 3 pi bonds as follows, Xl, Annueleophilic substitution reaction is summarized in the form of ts rate equ Rate MR XPOW | Swe Which ofthe following ltement it BALSE fo the yen reaction? ‘+ The overall reaction is 2™ order. 7 OW attacks on Re in final step Thera determining step ie biolecular * Olle atocks RX before RX bois broken Alii The correct mame of Nas{Co(Nttne is S020" iorvanrine sabilteste (D «Disadium pert chloroammine cob) * Sodium penta chlorine amine cobalt 1 | 2% Sodium pentachloro ammine cobaltate (HI) * Cobalt ammine penta chloro Sodium (111) Which ofthe ftlowig is teria alcoho!” + CHACHOH) Cals + HO.CH-C(CtI»-CHs Ma {NOs}. ¢ 2CH) xy SfH)+tHNOs — + Tho 1OUNs + 49 —a YMG (NOsha + Nad 9 4‘Aga Klnan Higher Secondary School, Karachi vi shirt ‘Time: 2 Hours Max. Marks: 85 SECTION ‘BY (SHORT ~ ANSWER QUESTIONS) (25 MARKS) NOTE: Attempt FIVE questions from this section in all, selecting atleast TWO questions from inorganic chemistry and TWO from organie chemistry. All questions carry equal marks, 2 INORGANIC CHEMISTRY \A™ Hydrogen closely resembles halogens with respect ls properties, but its not a member ofthe hhalogen family. Justify the statement (write any four points) HCeone) + HNO3(cone) > Cut HNOSUil) > HS +Ch > Sit HNO: > @ @ 8) Describe the produetion of Chlorine gas by Nelson's cell method. Draw a neat and labeled diagram of the cell to support your answer. ) Referring to the following diagram answer the following questions A B co ‘© Label the diferent parts in sequence of alphabets ‘© Name the process and Write in detail the processes occurring at “A, D and F ‘Also write equations of reactions involved. G @ “KG NNEC CHE MINTY 4) Wore m detail molec orbial stucture of benzene Also draw all the stuctutes to support your angwer io} 'b) Wate the IUPAC nantes of the following structures a © HOOC-CHb-CHy-CHy Cl COOHt © CHO-CH(OH)-CHEOH)-CHLON Cle CHCL-CO-CH:-CHO. © CHSCH-C(OCI))-CH-CO.CI, 48) Define enzymes, discuss enzymatic ati ity and factors which influence rate oFenzyme acon (3) 8) Give chemical equations with sutable conditions forthe preparation of following compounds: (4) + Ethene from vicinal dichloride Mustard gas fom ethane # Oxime ftom methanol + lodoform from ketone 6) +2HA03 ——> Si0r +20, + 204] mids + (1) —» ND, + tho 7? + ONO; ——> Bi0.4 “Nd. + 2D an \ By, oe ay o=¢- CH=CH Ch - 0H CHy- (Het ehh gro y oH u Q-CH3 6 (His -CH, ~~ CHL -& CH e ! oe tH;