MAL201E MATERIALS SCIENCE Diffusion 1. Calculate the diffusivity of carbon in FCC iron at 940°C, {Use D9=2.0x10 m?/s, Q=142 ki/mol, and R=8.314 J/(mol.K)) Te 940°C +273 = 1213 % . — 14.2, 000 jel ~/RT -5 ~ Do. = 20 x0 mys x LP | ——— — De do. & # x10 ms % EXP 8.304 Jit) [213 °k 2. The diffusivity of copper atoms in the FCC copper lattice is 8.0x10"! m*/s at 400°C and 6.0x10" m/s at 800°C. Calculate the activation energy in joules per mol for the diffusion of copper atoms in the FCC copper lattice in this temperature range. R=8,314 J/(mol.K), Dye sox 07” mh <> The 400 4273 = 673 °K Don 60x fo m/s > Te= 800 4273 = 1073 °K be Rixbc lena eet AS ae lo pp gly 6713 }073 Ga 203,12) j/melMAL201E MATERIALS SCIENCE Diffusion 3+ Phosphorus is diffused into a thick slice of Silicone with no previous phosphorus in it at a temperature of 1100°C. Ifthe surface concentration of the phosphorus is 10 atoms/cm? and its concentration at 1yim is 10® atoms/em*, how long must the diffusion time be? D=3,0x10" cm?/s for P diffusing in Si at 1100°C. ab b=-0 C,+)= to ats? es vt -13 Da3.0xI0 om é _ b70 X= Ayn = 10Fem is ae ete el 1 a a 0.448 ya = | a OAMo ye RoR BAE H T Aetiient 19S See vo L38, 10 bn > te- 1504 seconds , or : 2.yo0ei x t 2 25.1 minutes: at 2n