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Lectura ChemicalBonding
Lectura ChemicalBonding
CHEMICAL BONDING
ELECTRON-DOT DIAGRAMS OF SOME ELEMENTS IN THE PERIODIC TABLE. (Robert L. Wolke. Reproduced by permission.)
began to decline after A.D. 200, the pace of scien- elements are composed of tiny, indestructible
tific inquiry slowed and—in Western Europe at particles. These he called by the name Democri-
least—eventually came to a virtual halt. Hence, tus had given them nearly 23 centuries earlier:
the four elements theory, which had its own fan- atoms. All known substances, he said, are com-
ciful explanations as to why certain “elements” posed of some combination of atoms, which dif-
bonded with one another, held sway in Europe fer from one another only in mass.
until the beginning of the modern era. Though Dalton’s theory paved the way for
During the seventeenth century, a mounting enormous advances in the years that followed,
array of facts from the realms of astronomy and there were a number of flaws in it. Mass alone, for
physics collectively disproved the Aristotelian instance, is not really what differentiates one
model. In the area of chemistry, English physicist atom from another: differences in mass reflect
and chemist Robert Boyle (1627-1691) showed the presence of subatomic particles—protons
that the four elements were not elements at all, and neutrons—of whose existence scientists were
because they could be broken down into simpler unaware at the time.
substances. Yet, no one really understood what Furthermore, the properties of atoms that
constituted an element until the very beginning cause them to bond relate to a third subatomic
of the nineteenth century, and until that question particle, the electron, which, though it con-
was addressed, it was difficult to move on to the tributes little to the mass of the atom, is all-
mystery of why certain atoms bonded with one important to the energy it possesses. As for how
another. atoms bond to one another, Dalton had little to
say: in his conception of the atomic model, atoms
simply sit adjacent to one another without form-
Early Modern Advances in ing true bonds, as such.
Bonding Theory
AV O GA D R O A N D T H E M O L E -
D A LT O N ’ S AT O M I C T H E O R Y. C U L E . Though Dalton recognized that the
The birth of atomic theory in modern times structure of atoms in a particular element or
occurred in 1803, when English chemist John compound is uniform, he maintained that com-
Dalton (1766-1844) formulated the idea that all pounds are made up of compound atoms: thus,
HYDROGEN BONDING IN HF, H2O, AND NH3. (Robert L. Wolke. Reproduced by permission.)
water is a compound of “water atoms.” However, the molecule resurrected by Italian chemist
water is not an element, and therefore, there had Stanislao Cannizzaro (1826-1910). Cannizzaro’s
to be some structure—still very small, but larger work was occasioned by disagreement among
than the atom—in which atoms coalesced to scientists regarding the determination of atomic
form the basic materials of a compound. mass; however, the establishment of the molecu-
That structure was the molecule, first lar model had far-reaching implications for the-
described by Italian physicist Amedeo Avogadro ories of bonding.
(1776-1856). For several decades, Avogadro, who SYMBOLIZING ATOMIC BONDS.
originated the idea of the mole as a means of In 1858, German chemist Friedrich August
comparing large groups of atoms or molecules, Kekulé (1829-1896) made the first attempt to
remained a more or less unsung hero. Only in define the concept of valency, or the property an
1860, four years after his death, was his idea of atom of one element possesses that determines
“PURE” WATER FROM A MOUNTAIN STREAM IS ACTUALLY FILLED WITH TRACES OF THE ROCKS OVER WHICH IT
HAS FLOWED. IN FACT, WATER IS ALMOST IMPOSSIBLE TO FIND IN PURE FORM EXCEPT BY PURIFYING IT IN A LABO -
RATORY. (David Muench/Corbis. Reproduced by permission.)
its ability to bond with atoms of other elements. ing that it can bond to four other atoms. (The
A pioneer in organic chemistry, which deals with Latin prefix tetra- means “four.”) He also specu-
chemical structures containing carbon, Kekulé lated that carbon atoms are capable of bonding
described the carbon atom as tetravalent, mean- with one another in long chains.
ANION: The negative ion that results CHEMICAL SYMBOL: A one-or two-
when an atom gains one or more electrons. letter abbreviation for the name of an
An anion (pronounced “AN-ie-un”) of an element.
element is never called, for instance, the COMPOUND: A substance made up of
chlorine anion. Rather, for an anion atoms of more than one element. These
involving a single element, it is named by atoms are usually joined in molecules.
adding the suffix -ide to the name of the
COVALENT BONDING: A type of
original element—hence, “chloride.” Other
chemical bonding in which two atoms
rules apply for more complex anions.
share valence electrons. Atoms may bond
ATOM: The smallest particle of an ele-
by single, double, or triple covalent bonds,
ment. An atom can exist either alone or
which, in representations of Lewis struc-
in combination with other atoms in a
tures, are shown by single, double, or triple
molecule.
dashed lines. (The double dashed line
ATOMIC NUMBER: The number of
looks like an equals sign.) When atoms
protons in the nucleus of an atom. Since
have differing values of electronegativity,
this number is different for each element,
they form polar covalent bonds.
elements are listed on the periodic table of
DUET RULE: A term describing the
elements in order of atomic number.
distribution of valence electrons when
BOND ENERGY: The energy required
hydrogen atoms—which end up with only
to pull apart the atoms in a chemical bond.
two valence electrons—experience chemi-
CATION: The positive ion that results
cal bonding with other atoms. Most other
when an atom loses one or more electrons.
elements follow the octet rule.
A cation (pronounced “KAT-ie-un”) is
ELECTRON: Negatively charged parti-
named after the element of which it is an
cles in an atom. Electrons, which spin
ion and thus is called, for instance, the alu-
around the protons and neutrons that
minum ion or the aluminum cation.
make up the atom’s nucleus, are essential to
CHEMICAL BONDING: The joining,
chemical bonding.
through electromagnetic force, of atoms
representing different elements. The prin- ELECTRONEGATIVITY: The relative
cipal types of bonds are covalent bonding ability of an atom to attract valence
and ionic bonding, though few bonds are electrons.
purely one or the other. Rather, there is a ELEMENT: A substance made up of
wide range of “hybrid” bonds, in accor- only one kind of atom. Unlike compounds,
dance with the electronegativity values of elements cannot be broken down chemi-
the elements involved. cally into other substances.
ION: An atom that has lost or gained place in chemical bonding for most ele-
one or more electrons, and thus has a net ments, which end up with eight valence
electrical charge. Ions may either be anions electrons. Hydrogen is an exception, and
or cations. follows the duet rule. A few elements fol-
IONIC BONDING: A form of chemical low other rules, and some (most notably
bonding that results from attractions the noble gases) do not typically bond with
between ions with opposite electrical other elements.
charges. PERIODIC TABLE OF ELEMENTS:
LEWIS STRUCTURE: A means of A chart showing the elements arranged in
showing schematically how valence elec- order of atomic number. Vertical columns
trons are distributed among the atoms in a within the periodic table indicate groups
molecule. Also known as the electron-dot or “families” of elements with similar
system, Lewis structure represents pairs of chemical characteristics.
electrons with a symbol rather like a colon,
POLAR COVALENT BONDING: The
which—depending on the situation—can
type of chemical bonding between atoms
be placed above, below, or on either side of
that have differing values of electronegativ-
the chemical symbol. In the Lewis struc-
ity. If the difference is extreme, of course,
ture, the pairs of electrons involved in
the bond is not a covalent bond at all, but
chemical bonds are usually represented by
an ionic bond. Thus, although these are
a dashed line.
sometimes called polar bonds, they are
MOLECULE: A group of atoms, usual- more properly identified as polar covalent
ly, but not always, representing more bonds.
than one element, joined in a structure.
Compounds are typically made of up PROTON: A positively charged particle
molecules. in an atom.