You are on page 1of 10

Chemical Bonding

CHEMICAL BONDING

CONCEPT there was no way for Democritus to test his


Almost everything a person sees or touches in hypothesis even if he had wanted to: by their very
daily life—the air we breathe, the food we eat, the nature, the atoms he described were far too small
clothes we wear, and so on—is the result of a to observe. Even today, what scientists know
chemical bond, or, more accurately, many chem- about atomic behavior comes not from direct
ical bonds. Though a knowledge of atoms and observation, but indirect means.
elements is essential to comprehend the subjects Hence, Democritus and the few other
chemistry addresses, the world is generally not ancients who subscribed to atomic theory went
composed of isolated atoms; rather, atoms bond more on instinct than by scientific methods. Yet,
to one another to form molecules and hence some of them were remarkably prescient in their
chemical compounds. Not all chemical bonds are description of the bonding of atoms, in view of
created equal: some are weak, and some very the primitive scientific methods they had at their
strong, a difference that depends primarily on disposal. No other scientist came close to the
the interactions of electrons between atoms. accuracy of their theory for about 2,000 years.
AS C L E P I A D E S A N D LU C R E T I -
U S D I S C U SS B O N D S . The physician
HOW IT WORKS Asclepiades of Prusa (c.130-40 B.C.) drew on the
ideas of the Greek philosopher Epicurus (341-
Early Ideas of Bonding
270 B.C., another proponent of atomism. Asclepi-
The theory that all of matter is composed of ades speculated on the ways in which atoms
atoms did not originate in modern times: the interact, and discussed “clusters of atoms,”
atomic model actually dates back to the fifth cen- though, of course, he had no idea what force
tury B.C. in Greece. The leading exponent of attracted the atoms to one another.
atomic theory in ancient times was Democritus A few years after Asclepiades, the Roman
(c. 460-370 B.C.), who proposed that matter philosopher and poet Lucretius (c.95-c.55 B.C.
could not be infinitely subdivided. At its deepest espoused views that combined atomism with the
substructure, Democritus maintained, the mate- idea of the “four elements”—earth, air, fire, and
rial world was made up of tiny fragments he water. In his great work De rerum natura (“On
called atomos, a Greek term meaning “no cut” or the Nature of Things”), Lucretius described
“indivisible” atoms as tiny spheres attached to each other by
Forward-thinking though it was, Democri- fishhook-like appendages that became entangled
tus’s idea was not what modern scientists today with one another.
would describe as a proper scientific hypothesis. LAC K O F P R O G R E SS U N T I L
His “atoms” were not purely physical units, but 1 8 0 0 . Unfortunately, the competing idea of
rather idealized philosophical constructs, and the four elements, handed down by the great
thus, he was not really approaching the subject philosopher Aristotle (384-322 B.C.), prevailed
from the perspective of a scientist. In any case, over the atomic model. As the Roman Empire

S C I E N C E O F E V E RY DAY T H I N G S VOLUME 1: REAL-LIFE CHEMISTRY 263


Chemical
Bonding

ELECTRON-DOT DIAGRAMS OF SOME ELEMENTS IN THE PERIODIC TABLE. (Robert L. Wolke. Reproduced by permission.)

began to decline after A.D. 200, the pace of scien- elements are composed of tiny, indestructible
tific inquiry slowed and—in Western Europe at particles. These he called by the name Democri-
least—eventually came to a virtual halt. Hence, tus had given them nearly 23 centuries earlier:
the four elements theory, which had its own fan- atoms. All known substances, he said, are com-
ciful explanations as to why certain “elements” posed of some combination of atoms, which dif-
bonded with one another, held sway in Europe fer from one another only in mass.
until the beginning of the modern era. Though Dalton’s theory paved the way for
During the seventeenth century, a mounting enormous advances in the years that followed,
array of facts from the realms of astronomy and there were a number of flaws in it. Mass alone, for
physics collectively disproved the Aristotelian instance, is not really what differentiates one
model. In the area of chemistry, English physicist atom from another: differences in mass reflect
and chemist Robert Boyle (1627-1691) showed the presence of subatomic particles—protons
that the four elements were not elements at all, and neutrons—of whose existence scientists were
because they could be broken down into simpler unaware at the time.
substances. Yet, no one really understood what Furthermore, the properties of atoms that
constituted an element until the very beginning cause them to bond relate to a third subatomic
of the nineteenth century, and until that question particle, the electron, which, though it con-
was addressed, it was difficult to move on to the tributes little to the mass of the atom, is all-
mystery of why certain atoms bonded with one important to the energy it possesses. As for how
another. atoms bond to one another, Dalton had little to
say: in his conception of the atomic model, atoms
simply sit adjacent to one another without form-
Early Modern Advances in ing true bonds, as such.
Bonding Theory
AV O GA D R O A N D T H E M O L E -
D A LT O N ’ S AT O M I C T H E O R Y. C U L E . Though Dalton recognized that the
The birth of atomic theory in modern times structure of atoms in a particular element or
occurred in 1803, when English chemist John compound is uniform, he maintained that com-
Dalton (1766-1844) formulated the idea that all pounds are made up of compound atoms: thus,

264 VOLUME 1: REAL-LIFE CHEMISTRY S C I E N C E O F E V E RY DAY T H I N G S


Chemical
Bonding

HYDROGEN BONDING IN HF, H2O, AND NH3. (Robert L. Wolke. Reproduced by permission.)

water is a compound of “water atoms.” However, the molecule resurrected by Italian chemist
water is not an element, and therefore, there had Stanislao Cannizzaro (1826-1910). Cannizzaro’s
to be some structure—still very small, but larger work was occasioned by disagreement among
than the atom—in which atoms coalesced to scientists regarding the determination of atomic
form the basic materials of a compound. mass; however, the establishment of the molecu-
That structure was the molecule, first lar model had far-reaching implications for the-
described by Italian physicist Amedeo Avogadro ories of bonding.
(1776-1856). For several decades, Avogadro, who SYMBOLIZING ATOMIC BONDS.
originated the idea of the mole as a means of In 1858, German chemist Friedrich August
comparing large groups of atoms or molecules, Kekulé (1829-1896) made the first attempt to
remained a more or less unsung hero. Only in define the concept of valency, or the property an
1860, four years after his death, was his idea of atom of one element possesses that determines

S C I E N C E O F E V E RY DAY T H I N G S VOLUME 1: REAL-LIFE CHEMISTRY 265


Chemical
Bonding

“PURE” WATER FROM A MOUNTAIN STREAM IS ACTUALLY FILLED WITH TRACES OF THE ROCKS OVER WHICH IT
HAS FLOWED. IN FACT, WATER IS ALMOST IMPOSSIBLE TO FIND IN PURE FORM EXCEPT BY PURIFYING IT IN A LABO -
RATORY. (David Muench/Corbis. Reproduced by permission.)

its ability to bond with atoms of other elements. ing that it can bond to four other atoms. (The
A pioneer in organic chemistry, which deals with Latin prefix tetra- means “four.”) He also specu-
chemical structures containing carbon, Kekulé lated that carbon atoms are capable of bonding
described the carbon atom as tetravalent, mean- with one another in long chains.

266 VOLUME 1: REAL-LIFE CHEMISTRY S C I E N C E O F E V E RY DAY T H I N G S


This was one of the first attempts to examine and, like a bee, it buzzes to and fro, carrying a Chemical
the subject of bonding using modern scientific powerful “sting”—its negative electric charge, Bonding
terminology, complete with hypotheses that which attracts it to the positively charged proton.
could be tested by experimentation. Kekulé also E L E C T R O N S A N D I O N S . Though
recognized that in order to discuss bonds under- the electron weighs much, much less than a pro-
standably, there needed to be some means of rep- ton, it possesses enough electric charge to coun-
resenting those bonds with symbols. He even terbalance the positive charge of the proton. All
went so far as to develop a system for showing the atoms have the same number of protons as elec-
arrangement of bonds in space; however, his sys- trons, and hence the net electric charge is zero.
tem was so elaborate that it was replaced in favor However, as befits their highly active role, elec-
of a simpler one developed by Scottish chemist trons are capable of moving from one atom to
Archibald Scott Couper (1831-1892). another under the proper circumstances. An
Couper, who also studied valency and the atom that loses or acquires electrons has an elec-
tetravalent carbon bond—he is usually given tric charge, and is called an ion.
equal credit with Kekulé for these ideas—created The atom that has lost an electron or elec-
an extremely straightforward schematic repre- trons becomes a positively charged ion, or cation.
sentation still in use by chemists today. In On the other hand, an atom that gains an elec-
Couper’s system, short dashed lines serve to des- tron or electrons becomes a negatively charged
ignate chemical bonds. Hence, the bond between ion, or anion. As we shall see, ionic bonds, such
two hydrogen atoms and an oxygen atom in a as those that join sodium and chlorine atoms to
water molecule would be represented thus: H-O- form NaCl, or salt, are extremely powerful.
H. As the understanding of bonds progressed in
ELECTRON C O N F I G U RAT I O N .
modern times, this system was modified to take
Even in covalent bonding, which does not involve
into account multiple bonds, discussed below.
ions, the configurations of electrons in two
atoms are highly important. The basics of elec-
REAL-LIFE tron configuration are explained in the Electrons
essay, though even there, this information is pre-
A P P L I C AT I O N S sented with the statement that the student should
Atoms, Electrons, and Ions consult a chemistry textbook for a more exhaus-
tive explanation.
Today, chemical bonding is understood as the In the simplest possible terms, electron con-
joining of atoms through electromagnetic force. figuration refers to the distribution of electrons
Before that understanding could be achieved, at various positions in an atom. However,
however, scientists had to unlock the secret of the because the behavior of electrons cannot be fully
electromagnetic interactions that take place predicted, this distribution can only be expressed
within an atom. in terms of probability. An electron moving
The key to bonding is the electron, discov- around the nucleus of an atom can be compared
ered in 1897 by English physicist J. J. Thomson to a fly buzzing around some form of attractant
(1856-1940). Atomic structure in general, and (e.g., food or a female fly, if the moving fly is
the properties of the electron in particular, are male) at the center of a sealed room. We can state
discussed at length elsewhere in this volume. positively that the fly is in the room, and we can
However, because these specifics are critical to predict that he will be most attracted to the cen-
bonding, they will be presented here in the short- ter, but we can never predict his location at any
est possible form. given moment.
At the center of an atom is a nucleus, con- As one moves along the periodic table of ele-
sisting of protons, with a positive electrical ments, electron configurations become ever
charge; and neutrons, which have no charge. more complex. The reason is that with an
These form the bulk of the atom’s mass, but they increase in atomic number, there is an increase in
have little to do with bonding. In fact, the neu- the energy levels of atoms. This indicates a
tron has nothing to do with it, while the proton greater range of energies that electrons can occu-
plays only a passive role, rather like a flower being py, as well as a greater range of motion. Electrons
pollinated by a bee. The “bee” is the electron, occupying the highest energy level in an atom are

S C I E N C E O F E V E RY DAY T H I N G S VOLUME 1: REAL-LIFE CHEMISTRY 267


Chemical called valence electrons, and these are the only In ionic bonding, two ions start out with dif-
Bonding ones involved in chemical bonding. By contrast, ferent charges and end up forming a bond in
the core electrons, or the ones closest to the which both have eight valence electrons. In the
nucleus, play no role in the bonding of atoms. type of bond Lewis described, a covalent bond,
two atoms start out as atoms do, with a net
Ionic and Covalent Bonds charge of zero. Each ends up possessing eight
valence electrons, but neither atom “owns” them;
T H E G OA L O F E I G H T VA -
L E N C E E L E C T R O N S . The above dis-
rather, they share electrons.
cussion of the atom, and the electron’s place in it, L E W I S S T R U C T U R E S . In addition
refers to much that was unknown at the time to discovering the concept of covalent bonding,
Thomson discovered the electron. Protons were Lewis developed the Lewis structure, a means of
not discovered for several more years, and neu- showing schematically how valence electrons are
trons several decades after that. Nonetheless, the arranged among the atoms in a molecule. Also
electron proved the key to solving the riddle of known as the electron-dot system, Lewis struc-
how substances bond, and not long after Thom- tures represent the valence electrons as dots sur-
son’s discovery, German chemist Richard Abegg rounding the chemical symbols of the atoms
(1869-1910) suggested as much. involved. These dots, which look rather like a
While studying noble gases, noted for their colon, may be above or below, or on either side
tendency not to bond, Abegg discovered that of, the chemical symbol. (The dots above or
these gases always have eight valence electrons. below the chemical symbol are side-by-side, like
His observation led to one of the most important a colon turned at a 90°-angle.)
principles of chemical bonding: atoms bond in To obtain the Lewis structure representing a
such a way that they achieve the electron config- chemical bond, it is first necessary to know the
uration of a noble gas. This has been shown to be number of valence electrons involved. One pair
the case in most stable chemical compounds. of electrons is always placed between elements,
TWO DIFFERENT TYPES OF indicating the bond between them. Sometimes
B O N D S . Perhaps, Abegg hypothesized, atoms this pair of valence electrons is symbolized by a
combine with one another because they dashed line, as in the system developed by
exchange electrons in such a way that both end Couper. The remaining electrons are distributed
up with eight valence electrons. This was an early according to the rules by which specific elements
model of ionic bonding, which results from bond.
attractions between ions with opposite electric M U LT I P L E BONDS. Hydrogen
charges: when they bond, these ions “complete” bonds according to what is known as the duet
one another. rule, meaning that a hydrogen atom has only two
Ionic bonds, which occur when a metal valence electrons. In most other elements—there
bonds with a nonmetal are extremely strong. As are exceptions, but these will not be discussed
noted earlier, salt is an example of an ionic bond: here—atoms end up with eight valence electrons,
the metal sodium loses an electron, forming a and thus are said to follow the octet rule. If the
cation; meanwhile, the nonmetal chlorine gains bond is covalent, the total number of valence
the electron to become an anion. Their ionic electrons will not be a multiple of eight, howev-
bond results from the attraction of opposite er, because the atoms share some electrons.
charges. When carbon bonds to two oxygen atoms to
Ionic bonding, however, could not explain form carbon dioxide (CO2), it is represented in
all types of chemical bonds for the simple reason the Couper system as O-C-O. The Lewis struc-
that not all compounds are ionic. A few years ture also uses dashed lines, which stand for two
after Abegg’s death, American chemist Gilbert valence electrons shared between atoms. In this
Newton Lewis (1875-1946) discovered a very dif- case, then, the dashed line to the left of the car-
ferent type of bond, in which nonionic com- bon atom indicates a bond of two electrons with
pounds share electrons. The result, once again, is the oxygen atom to the left, and the dashed line
eight valence electrons for each atom, but in this to the right of it indicates a bond of two electrons
case, the nuclei of the two atoms share electrons. with the oxygen atom on that side.

268 VOLUME 1: REAL-LIFE CHEMISTRY S C I E N C E O F E V E RY DAY T H I N G S


The non-bonding valence electrons in the values form a covalent bond, this is described as Chemical
oxygen atoms can be represented by sets of two polar covalent bonding. Sometimes these are Bonding
dots above, below, and on the outside of each simply called “polar bonds,” but that is not as
atom, for a total of six each. Combined with the accurate: all ionic bonds, after all, are polar, due
two dots for the electrons that bond them to car- to the extreme differences in electronegativity.
bon, this gives each oxygen atom a total of eight The term “polar covalent bond” is much more
valence electrons. So much for the oxygen atoms, specific, describing a bond, for instance, between
but something is wrong with the representation hydrogen (2.1) and sulfur (2.6). Because sulfur
of the carbon atom, which, up to this point, is has a slightly greater electronegativity value, the
shown only with four electrons surrounding it, valence electrons will be slightly more attracted
not eight. to the sulfur atom than to the hydrogen atom.
In fact carbon in this particular configura- Another example of a polar covalent bond is
tion forms not a single bond, but a double bond, the one that forms between hydrogen and oxygen
which is represented by two dashed lines—a (3.5) to form H2O or water, which has a number
symbol that looks like an equals sign. By showing of interesting properties. For instance, the polar
the double bonds joining the carbon atom to the quality of a water molecule gives it a great attrac-
two oxygen atoms on either side, the carbon tion for ions, and thus ionic substances such as
atom has the required number of eight valence salt dissolve easily in water. “Pure” water from a
electrons. The carbon atom may also form a mountain stream is actually filled with traces of
triple bond (represented by three dashed lines, the rocks over which it has flowed. In fact,
one above the other) with an oxygen atom, in water—sometimes called the “universal sol-
which case the oxygen atom would have only two vent”—is almost impossible to find in pure form,
other valence electrons. except when it is purified in a laboratory.
By contrast, molecules of petroleum (CH2)
Electronegativity and Polar
tend to be nonpolar, because carbon and hydro-
Covalent Bonds
gen have almost identical electronegativity val-
Today, chemists understand that most bonds are ues—2.5 and 2.1 respectively. Thus, an oil mole-
neither purely ionic nor purely covalent; rather, cule offers no electric charge to bond it with a
there is a wide range of hybrids between the two water molecule, and for this reason, oil and water
extremes. Credit for this discovery belongs to do not mix. It is a good thing that water mole-
American chemist Linus Pauling (1901-1994), cules attract each other so strongly, because this
who, in the 1930s, developed the concept of elec- means that a great amount of energy is required
tronegativity—the relative ability of an atom to to change water from a liquid to a gas. If this were
attract valence electrons. not so, the oceans and rivers would vaporize, and
Elements capable of bonding are assigned an life on Earth could not exist as it does.
electronegativity value ranging from a minimum B O N D E N E R GY. The last two para-
of 0.7 for cesium to a maximum of 4.0 for fluo- graphs allude to attractions between molecules,
rine. Fluorine is capable of bonding with some which is not the same as (nor is it as strong as)
noble gases, which do not bond with any other the attraction between atoms within a molecule.
elements or each other. The greater the elec- In fact, the bond energy—the energy required to
tronegativity value, the greater the tendency of pull apart the atoms in a chemical bond—is low
an element to draw valence electrons to itself. for water. This is due to the presence of hydrogen
If fluorine and cesium bond, then, the bond atoms, with their two (rather than eight) valence
would be purely ionic, because the fluorine exerts electrons. It is thus relatively easy to separate
so much more attraction for the valence elec- water into its constituent parts of hydrogen and
trons. But if two elements have equal electroneg- oxygen, through a process known as electrolysis.
ativity values—for instance, cobalt and silicon, Covalent bonds that involve hydrogen are
both of which are rated at 1.9—the bond is pure- among the weakest bonds between atoms.
ly covalent. Most bonds, as stated earlier, fall (Again, this is different from bonds between
somewhere in between these two extremes. molecules.) Stronger than hydrogen bonds are
P O LA R C O VA L E N T B O N D I N G . regular, octet-rule covalent bonds: as one might
When substances of differing electronegativity expect, double covalent bonds are stronger than

S C I E N C E O F E V E RY DAY T H I N G S VOLUME 1: REAL-LIFE CHEMISTRY 269


Chemical
Bonding
KEY TERMS

ANION: The negative ion that results CHEMICAL SYMBOL: A one-or two-
when an atom gains one or more electrons. letter abbreviation for the name of an
An anion (pronounced “AN-ie-un”) of an element.
element is never called, for instance, the COMPOUND: A substance made up of
chlorine anion. Rather, for an anion atoms of more than one element. These
involving a single element, it is named by atoms are usually joined in molecules.
adding the suffix -ide to the name of the
COVALENT BONDING: A type of
original element—hence, “chloride.” Other
chemical bonding in which two atoms
rules apply for more complex anions.
share valence electrons. Atoms may bond
ATOM: The smallest particle of an ele-
by single, double, or triple covalent bonds,
ment. An atom can exist either alone or
which, in representations of Lewis struc-
in combination with other atoms in a
tures, are shown by single, double, or triple
molecule.
dashed lines. (The double dashed line
ATOMIC NUMBER: The number of
looks like an equals sign.) When atoms
protons in the nucleus of an atom. Since
have differing values of electronegativity,
this number is different for each element,
they form polar covalent bonds.
elements are listed on the periodic table of
DUET RULE: A term describing the
elements in order of atomic number.
distribution of valence electrons when
BOND ENERGY: The energy required
hydrogen atoms—which end up with only
to pull apart the atoms in a chemical bond.
two valence electrons—experience chemi-
CATION: The positive ion that results
cal bonding with other atoms. Most other
when an atom loses one or more electrons.
elements follow the octet rule.
A cation (pronounced “KAT-ie-un”) is
ELECTRON: Negatively charged parti-
named after the element of which it is an
cles in an atom. Electrons, which spin
ion and thus is called, for instance, the alu-
around the protons and neutrons that
minum ion or the aluminum cation.
make up the atom’s nucleus, are essential to
CHEMICAL BONDING: The joining,
chemical bonding.
through electromagnetic force, of atoms
representing different elements. The prin- ELECTRONEGATIVITY: The relative
cipal types of bonds are covalent bonding ability of an atom to attract valence
and ionic bonding, though few bonds are electrons.
purely one or the other. Rather, there is a ELEMENT: A substance made up of
wide range of “hybrid” bonds, in accor- only one kind of atom. Unlike compounds,
dance with the electronegativity values of elements cannot be broken down chemi-
the elements involved. cally into other substances.

270 VOLUME 1: REAL-LIFE CHEMISTRY S C I E N C E O F E V E RY DAY T H I N G S


Chemical
Bonding
KEY TERMS CONTINUED

ION: An atom that has lost or gained place in chemical bonding for most ele-
one or more electrons, and thus has a net ments, which end up with eight valence
electrical charge. Ions may either be anions electrons. Hydrogen is an exception, and
or cations. follows the duet rule. A few elements fol-
IONIC BONDING: A form of chemical low other rules, and some (most notably
bonding that results from attractions the noble gases) do not typically bond with
between ions with opposite electrical other elements.
charges. PERIODIC TABLE OF ELEMENTS:
LEWIS STRUCTURE: A means of A chart showing the elements arranged in
showing schematically how valence elec- order of atomic number. Vertical columns
trons are distributed among the atoms in a within the periodic table indicate groups
molecule. Also known as the electron-dot or “families” of elements with similar
system, Lewis structure represents pairs of chemical characteristics.
electrons with a symbol rather like a colon,
POLAR COVALENT BONDING: The
which—depending on the situation—can
type of chemical bonding between atoms
be placed above, below, or on either side of
that have differing values of electronegativ-
the chemical symbol. In the Lewis struc-
ity. If the difference is extreme, of course,
ture, the pairs of electrons involved in
the bond is not a covalent bond at all, but
chemical bonds are usually represented by
an ionic bond. Thus, although these are
a dashed line.
sometimes called polar bonds, they are
MOLECULE: A group of atoms, usual- more properly identified as polar covalent
ly, but not always, representing more bonds.
than one element, joined in a structure.
Compounds are typically made of up PROTON: A positively charged particle
molecules. in an atom.

NEUTRON: A subatomic particle that VALENCE ELECTRONS: Electrons


has no electrical charge. Neutrons are that occupy the highest energy levels in an
found at the nucleus of an atom, alongside atom. These are the only electrons involved
protons. in chemical bonding. By contrast, the core
NUCLEUS: The center of an atom, a electrons, or the ones at lower energy lev-
region where protons and neutrons are els, play no role in the bonding of atoms.
located, and around which electrons spin. VALENCY: The property of the atom of
OCTET RULE: A term describing the one element that determines its ability to
distribution of valence electrons that takes bond with atoms of other elements.

S C I E N C E O F E V E RY DAY T H I N G S VOLUME 1: REAL-LIFE CHEMISTRY 271


Chemical single ones, and triple covalent bonds are “Chemical Bonding” (Web site). <http://users.senet.
Bonding stronger still. Strongest of all are ionic bonds, com.au/~rowanb/chem/chembond.htm> (May 19,
2001).
involved in the bonding of a metal to a metal, or
“The Colored Periodic Table and Chemical Bonding” (Web
a metal to a nonmetal, as in salt. The strength of
site). <http://students.washington.edu/manteca/>
the bond energy in salt is reflected by its boiling (May 19, 2001).
point of 1,472°F (800°C), much higher than that
Ebbing, Darrell D.; R. A. D. Wentworth; and James P.
of water, at 212°F (100°C). Birk. Introductory Chemistry. Boston: Houghton Mif-
flin, 1995.
WHERE TO LEARN MORE Linus Pauling and the Twentieth Century: An Exhibition
(Web site). <http://www.paulingexhibit.org> (May
“Chemical Bond” (Web site). <http://www.science. 19, 2001).
uwaterloo.ca/~cchieh/cact/c120/chembond.html>
(May 18, 2001). “Valence Shell Electron Pair Repulsion (VSEPR).”
<http://www.shef.ac.uk/~chem/vsepr/chime/vsepr.
“Chemical Bonding” Oklahoma State University (Web html> (May 18, 2001).
site). <http://www.okstate.edu/jgelder/bondtable. White, Florence Meiman. Linus Pauling, Scientist and
html> (May 19, 2001). Crusader. New York: Walker, 1980.
“Chemical Bonding” (Web site). <http://pc65.frontier. Zumdahl, Steven S. Introductory Chemistry: A Founda-
osrhe.edu/hs/science/pbond.htm> (May 19, 2001). tion, 4th ed. Boston: Houghton Mifflin, 2000.

272 VOLUME 1: REAL-LIFE CHEMISTRY S C I E N C E O F E V E RY DAY T H I N G S

You might also like