Chemistry Arihant Handbook

Jr.
IIT (JEE) ADVANCED WEEKEND TEST - 07

ALPHORES IIT ACADEMY :: TELANGANA
Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07
DATE:01.08.2021
MAX.MARKS:300
TIME: 3.00.HOURS
Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

INSTRUCTIONS
SECTION - I ( Maximum Marks - 80 )

SINGLE Answer Type Questions - (Q.No. 01 - 20)
This section contains Twenty (20) questions.

Each question has FOUR options ONLY ONE of these four options is the correct answer.
You will be awarded 4 marks for correct answer and -1 mark (minus one mark) for wrong answer.
SECTION - II ( Maximum Marks - 20 )
Numerical Value Answer Type Questions - (Q.No. 21 - 25)
This section contains Five (05) questions.
The answer to each questions is a Numerical values comprising of positive or negative decimal numbers.
You will be awarded 4 marks for correct answer. There is no negative marking.
PHYSICS
01. The maixmum tension a rope can withstand is 60 kg-wt. The ratio of maximum acceleration with which two
boys of masses 20kg and 30kg can climb up to the rope at the same time is
1) 2 : 1 2) 1 : 2 3) 1 : 1 4) 4 : 1
02. A ball is suspended by a thread from the ceiling of a tram car. The brakes are applied and the speed of the car
changes uniformly from 36 kmh 1 to zero in 5 s. The angle by which the ball deviates from the vertical is
 g  10ms 2
1  1  1  1  1  1  1  1 
1) tan   2) sin   3) tan   4) cot  
3 5 5  3
03. A lift is going up. The total mass of the lift and the passengers is 1500 kg. The variation in the speed of the lift is
given by the graph (figure). What will be the tension in the rope pulling the lift after at 11 s.(use g=10 m/s2)
1) 17,700 N 2) 15,000 N 3) 12,300 N 4) 1230 N


1

04. In the arrangement shown, blocks A and B connected with an inextensible string move with velocities v1 and
v2
v 2 along horizontal direction. The ratio of v is
1

sin  sin  cos  cos 
1) 2) 3) 4)
sin  sin  cos  cos 
05. In the given arrangement, n number of equal masses are connected by strings of negligible masses. The tension
in the string connected to nth mass is :
mMg mMg
1) 2) 3) mg 4) mng
nm  M nmM
06. In the following figure, the pulley is massless and frictionless. There is no friction between the body and the floor.
The acceleration produced in the body when it is displaced through a certain distance with force ‘P’ will be
P P P P
1) 2) 3) 4)
M 2M 3M 4M
07. In figure, the blocks A, B and C of mass m each have acceleration a1 , a2 , and a3 , respectively. F1 and F2 are
external forces of magnitude 2mg and mg, respectively. Then
1) a1  a2  a3 2) a1  a2  a3 3) a1  a2  a3 4) a1  a2  a3


2

08. Block A of mass m/2 is connected to one end of light rope which passes over a pulley as shown in figure. A man
of mass m climbs the other end of rope with a relative acceleration of g/6 with respect to rope. Find the tension
in the rope.

18mg 13 m g 2mg mg
1) 2) 3) 4)
13 18 3 4
09. Two fixed frictionless inclined planes making an angles 300 and 600 with the horizontal are shown in the figure.
Two blocks A and B are placed on the two planes. What is the relative vertical acceleration of A with respect to
B?
1) 4.9 ms 2 2) 9.8 ms 2 3) 19.6ms 2 4) None of these

10. A chain consisting of 5 links each of mass 0.1 kg is lifted vertically up with a constant acceleration of 2.5 m/s2.
The force of interaction between 1st and 2nd links as shown
1) 6.15 N 2) 4.92 N 3) 9.84 N 4) 2.46 N

11. Two masses of 10 kg and 5 kg are suspended from a rigid support as shown in figure. The system is pulled
down with a force of 150 N attached to the lower mass. The string attached to the support breaks and the
system acceleration downwards.
In case the force continues to act. What will be the tension acting between the two masses ?
1) 300 N 2) 200 N 3) 100 N 4) zero


3

12. Two masses each equal to m are lying on X-axis at  a,0  and  a,0  ,respectively, as shown in fig. They are
connected by a light string. A force F is applied at the origin along vertical direction.As a result, the masses move
towards each other without loosing contact with ground. What is the acceleration of each mass ? Assume the
instantaneous position of the masses as  x,0  and  x,0  , respecitvely

2F x F x F x
1)
2F a 2
 x2 
2) m 3) 2m 4) m
m x a 2
 x2  a 2
 x2  a 2
 x2 
13. The block is placed on a fricionless surface in gravity free space. A heavy string of a mass m is connected and
force F is applied on the string, then the tension at the middle of rope is
m  m 
  M  .F   m  .F M.F
1)  2  2)  2  3) zero 4)
mM mM mM
14. A string of negligible mass going over a clamped pulley of mass m supports a block of mass M as shown in the
figure. The force on the pulley by the clamp is given by
2 2
1) 2Mg 2) 2mg 3)  M  m  m2 g 4)  M  m  M2 g
15. A light string passing over a smooth light pulley connects two blocks of masses m1 and m2 (vertically). If the
acceleration of the system is g /8, then the ratio of the masses is
1) 8: 1 2) 9: 7 3) 4: 3 4) 5: 3


4

16. A uniform sphere of weight W and radius 5 cm is being held by a string as shown in the figure. The tension in the
string will be

W W W W
1) 12 2) 5 3) 13 4) 13
5 12 5 12
17. In which of the following cases is the contact force between A and B maximum
mA  mB  1 kg all surfaces smooth
1) 2) 3) 4)
18. Three blocks are connected by massless strings on a frictionless inclined plane of 300 as shown in the figüre. A
force of 104 N is applied upward along the incline to mass m3 causing an upward motion of the blocks. What
is the acceleration of the blocks? (Assume, acceleration due to gravity, g=10 m/s2)
1) 6.0m / s2 2) 4.5m / s2 3) 3.0m / s2 4) 1.5m / s2

19. In the figure shown a3  6m / s2 (downwards) and a2  4m / s2 (upwards). Find acceleration of 1.
1) 1m / sec 2 upwards 2) 2m / sec 2 upwards

3) 1m / sec 2 downwards 4) 2m / sec 2 downwards


5

20. Three masses of 16kg, 8 kg and 4kg are placed in contact as shown in Figure. If a force of 140N is applied on
4 kg mass, then the force on 16 kg will be

1) 140 N 2) 120 N 3) 100 N 4) 80 N
21. By what acceleration the boy must go up so that 100 kg block remains stationary on the wedge. The wedge is
fixed and is smooth  g  10m / s 2  ( in ms2 )
1) 4 2) 6 3) 2 4) 1
22. Consider the system shown in figure. The system is released from rest, find the tension in the cord connected
between 1 kg and 2 kg blocks.  g  10m / s 2  ( in N)
1) 6 2) 2 3) 8 4) 10
23. A monkey A (mass = 5 kg) is climbing up a rope tied to a rigid support. The monkey B (mass = 2 kg) is holding
on the tail of monkey A. If the tail can tolerate a maximum tension of 30 N, what maximum force should monkey
A apply on the rope in order to carry monkey B with it?  g  10ms 2  ( in N)


6

1) 80 2) 55 3) 95 4) 105
24. Two bodies of masses 4kg and 6kg are attached to the ends of a string which passes over a pulley, the 4kg mass
is attached to the table top by another string. The tension in this string T1 is equal to  g  10m / s 2  ( in N)
1) 10 2) 10.6 3) 25 4) 20
25. Two blocks of mass M1  20 kg and M2  12 kg are connected by a metal rod of mass 8 kg. The system is
pulled vertically up by applying a force of 480N as shown. The tension at the mid-point of the rod is
 g  10m / s  ( in N)
2
1) 144 2) 96 3) 240 4) 192

CHE MIS TRY
You will be awarded 4 marks for correct answer. There is no negative marking. 

7

26. Which of the following is least volatile ?
1) HF 2) HCl 3) HBr 4) HI
27. Which of the following molecule have intramolecular hydrogen bonding ?

OH
OH
1) H3BO3 2) 3) NO2 4) ICl
NO2
28. Which of the following statement is incorrect ?

1) The density of ice is less than that of water due to formation of hexagonal honeycomb structure.
2) Hydrogen bond is present in anionic part of KHF2
3) Intermolecular hydrogen bonding exists between H2O molecules in solid, liquid and vapour
phases.
4) The boiling point of H2O is more than that of HF
29. Arrange the following in order of decreasing N-O bond length : NO2 ,NO2 and NO3
1) NO3  NO2  NO2 2) NO3  NO2  NO2
3) NO2  NO3  NO2 4) NO2  NO3  NO2
30. Which of the following is the correct statement for ClO 4 ion ?
1) three Cl  O bonds are of equal length and one longer
2) two Cl  O bonds are of same length which are longer compared to other two Cl  O bond
length.
3) all bond lengths are different
4) All Cl  O bonds lengths are equal due to resonance.
31. In XeF2 molecule the angle between two lone pair orbitals is  , the angle between lone pair orbital
and bond pair orbital is  and the angle between bond pair orbitals is  . Which of the following is
correct order ? (all are hybrid orbitals of Xe)
1)      2)      3)      4)     
32. Which of the following has higest bond angle ?
1) H2O 2) OF2 3) Cl2O 4) All have equal bond angle
33. In which choice are the molecules listed in order of increasing bond angle ?
1) H2O,CH4 ,NH3 2) CH4 ,NH3 ,H2O 3) H2O,NH3 ,CH4 4) NH3 ,H2O,CH4
34. If ‘A’ represents the central atom, in which molecule is the F-A-F angle the smallest ?
1) BF3 2) CF4 3) NF3 4) BF4


8

35. Which of the following has least bond length ?
1) F2 2) Cl2 3) Br2 4) I2
36. Which of the following molecule (or) ion has different bond lengths ?
1) XeF4 2) BF4 3) SF4 4) SiF4

37. Which of the following is correct regarding BrF5 molecule ?
1) All  FBr F bond angles are equal to 90 0 2) It has square pyramidal shape
3) all Br-F bond lengths are equal 4) two axial Br-F bond length are equal
38. Which of the following C  H has least bond length ?
1) spC3  H 2) spC2  H 3) C
sp
H 4) all are equal
H  H
39. In C  the correct order of magnitude of bond angles , ,  is

F  F
1)      2)      3)      4)     
40. Which of the following represents correct order of O  O bond length ?
1) O2  O2  O22 2) O22  O2  O2 3) O2  O2  O22 4) O2  O22  O2
41. Which of the following is non existent according to molecular orbital theory ?
1) H2 2) He2 3) O2 4) O2
42. If x- axis is bonding axis then the shape of molecular orbital formed by 2px  2px will be ?
1) 2)
3) 4)
43. If the filling of electrons in the molecule orbital of O2 does not obey Hund’s rule then which of the
following property in O2 gets changed ?
1) Bond order 2) Magnetic behaviour
3) Number of electrons in bonding MO 4) Number of electrons in antibonding MO
44. Which of the following is paramagnetic ?
1) O2 2) CN 3) CO 4) NO 
45. Which of the following posses highest bond order ?
1) ClO 4 2) PO34 3) ClO3 4) NO3
46. Find the number of species having bond angles less than 1090281 in the following.
NH3 ,SiH4 ,NH4 ,PF3 ,SO3 ,H2S,PH3 ,NH2
1) 4 2) 3 3) 5 4) 6 

9

47. The angle between equitorial bonds present in IF7 molecule is .....degree
1) 90 2) 72 3) 120 4) 180
48. If the bond order of N2 is ‘x’, the bond order of N2 is ‘y’ and the bond order of CO is ‘z’, then what
is the value of  x  y  z  is ....
1) 8 2) 2 3) 6 4) 2.5

49. The maximum number of hydrogen bonds formed by one H2O molecule is ....
1) 2 2) 1 3) 4 4) 3
50. The magnetic moment ( in Bohr magneton ) of NO according to MOT is .......
1) 1.73 2) 2.83 3) zero 4) 4.89
MATHEMATICS
You will be awarded 4 marks for correct answer. There is no negative marking.
 1 0
51. If P   1  then 50 is equal to
P
 1
2 
 1 0  1 0
 1 0  1 0    
1)   2)   3)  1 1 4)  1 1 
50 1   25 1   250  2 
 1 j i , i  j

A   2 , i  j , then the value of 3 Adj 2 A1
52. If elements of matrix A is defined as A   aij  33 where  i j
 
   1 , i  j
is
1) 72 2) 108 3) 36 4) 208
1 0  2021
53. If A  0 1 ; B   Ar then the value of B is

  r 1
2
1) 2021 2)  2021 3) 2021 4) 0


10

1 1 1 
  3  ;
54. If A   0 2
if xyz  60 and 8 x  4 y  3 z  20 then A  adjA   .......
 2 1 0 
1) 64 I 33 2) 68 I 33 3) 48 I 33 4) 58 I 33

55. If the system of linear equations x  y  z  5, x  2 y  2 z  6, x  3 y   z     ,   R  has infinitely
many solutions, then the value of    is
1) 12 2) 9 3) 10 4) 7
56. If the system of linear equations 2 x  2ay  az  0, 2 x  3by  bz  0, 2 x  4cy  cz  0 where a, b, c  R

are non zero and distinct; has a non zero solution, then
1 1 1
1) , , are in A.P.. 2) a, b, c are in G.P.. 3) a  b  c  0 4) a, b, c are in A.P..
a b c
57. Let S be the set of all   R for which the system of linear equations 2 x  y  2 z  2; x  2 y   z  4;
x   y  z  4 has no solution. Then the set S
1) Contains more than two elements 2) is an empty set
3) is a singleton set 4) Contains exactly two elements
 2 1 1 
adj A   1 0 2 
58. Let ‘A’ be a 3  3 matrix such that and B  adj  adj A . If A   and
 1 2 1
1 T
B    , then the ordered pair.   ,   is equal to
 1  1  1 
1)  9,  2)  3,  3)  3,81 4)  9, 
 9  81   81 
2 when i  j
59. If A   aij  44 such that aij   then det  adj  adj A  is....
0 when i  j
1) 16 2) 162 3) 169 4) 1616
60. If adj B  A and P  Q  1 then adj  Q 1 BP 1  

1) PAQ 2) APQ 3) Q 1 BP 1 4) P 1 BQ 1
 cos  sin  0
A  ,      sin  cos  0  1
61. then  A  ,     .....
 0 0 e  
1) A   ,    2) A   ,   3) A  ,   4) A  ,  
2 2 1 
A  1 3 1  ,
62. If then A3  7 A2  10 A  .....
1 2 2 
1) 5I  A 2) 5I  A 3) A  5I 4) 6I


11

1 2 2 
 1  ,
63. If A    2 2
then A1
 2 1 2 
1 1 T
1) A 2) AT 3) A 4) A
9 9

3 2   3 1
Let matrix A and B definied as A   and B    . If det  2 A B   2, then the number of
9 1
64. 
 2    7 3
distinct possioble real values of ' ' is
1) 0 2) 1 3) 2 4) 3
1
65. If ‘A’ is an idempotent matrix satisfying  I  0.4 A    I   A  where I is the unit matrix of the same order
as that of ‘A’ the the value of ' ' is equal to
2 2 2 1
1) 2) 3)  4)
5 3 3 2
50
1 2r  1  1 2r  1
66. For matrix A  
1 
, the value of  0 1 
is equal to
0 r 1 
 1 100   1 4950  1 5050   1 2500 

1)   2)  3)  4) 
0 1  0 1  0 1  0 1 

 cos  , i  j

  j 
3 bij  cos   , i  j
67. For   , let B  bij  be a square matrix of order 2 such that   2  . The trace of
5   j 
sin    , i  j
  2 
matrix B5 is equal to
1)  2 2)  1 3) 1 4) 2
1 1 1
adj  AB   1 P 1 
68. If A and B are non-singular matrices of order three such that and B 2 adj A  P 2  3
1 1 P 
then P is.......
1
1) 0 2) 3) 4 4) 2
2
69. If A33 X 31  D31 is a consistent system of equations having unique solution then rank(A) is .......
1) 1 2) 2 3) 3 4) 0
70. If x  y  z  1, ax  by  cz  k , a 2 x  b 2 y  c 2 z  k 2 has unique solution then x 
 k  c  a  k   k  b  c  k   k  a  b  k 
1) b  c c  a 2) a  b c  a 3) b  c c  a 4)  k  a  k  b  k  c 
        


12

 3 1 0
 
A   1  3 0

71. Let 0  and det  2 AT  AAT  adj A   ....
0 2
 
1) 44 2) 54 3) 64 4) 74
72. The number of 3  3 skew symmetric matrices A such that A   aij  33 and aij  3, 4, 7 , if i  j , is.......
1) 116 2) 216 3) 316 4) 416
 3 4 5
A   4 5 3  ,
1
73. If then the value of 15tra  adj A  is......
 5 3 4 
1) 5 2) 3 3) 1 4) 4
74. If the equations a  y  z   x, b  z  x   y , c  x  y   z have non trivial solutions, t hen

1 1 1
  
1 a 1 b 1 c
1) 1 2) 2 3) 3 4) 4
75. Let M be a 3  3 matrix with real entries. If M T M  I 3 where I 3 is a 3  3 identity matrix, then the value of
det  M 2  I 3  is
1) 2 3) 5 3) 0 4) 3


13

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Jr.

IIT (JEE) ADVANCED WEEKEND TEST - 07

Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

SECTION - I ( Maximum Marks - 80 )

This section contains Twenty (20) questions.

1) 17,700 N 2) 15,000 N 3) 12,300 N 4) 1230 N

Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

1) 4.9 ms 2 2) 9.8 ms 2 3) 19.6ms 2 4) None of these

1) 6.15 N 2) 4.92 N 3) 9.84 N 4) 2.46 N

Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

1) 6.0m / s2 2) 4.5m / s2 3) 3.0m / s2 4) 1.5m / s2

1) 1m / sec 2 upwards 2) 2m / sec 2 upwards

Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

1) 144 2) 96 3) 240 4) 192

Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

28. Which of the following statement is incorrect ?

1) three Cl  O bonds are of equal length and one longer

3) all bond lengths are different

4) All Cl  O bonds lengths are equal due to resonance.

correct order ? (all are hybrid orbitals of Xe)

32. Which of the following has higest bond angle ?

1) H2O 2) OF2 3) Cl2O 4) All have equal bond angle

1) H2O,CH4 ,NH3 2) CH4 ,NH3 ,H2O 3) H2O,NH3 ,CH4 4) NH3 ,H2O,CH4

1) BF3 2) CF4 3) NF3 4) BF4

Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

39. In C  the correct order of magnitude of bond angles , ,  is

Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

53. If A  0 1 ; B   Ar then the value of B is

1) 64 I 33 2) 68 I 33 3) 48 I 33 4) 58 I 33

Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

56. If the system of linear equations 2 x  2ay  az  0, 2 x  3by  bz  0, 2 x  4cy  cz  0 where a, b, c  R

60. If adj B  A and P  Q  1 then adj  Q 1 BP 1  

Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

 1 100   1 4950  1 5050   1 2500 

70. If x  y  z  1, ax  by  cz  k , a 2 x  b 2 y  c 2 z  k 2 has unique solution then x 

Jr. IIT (JEE) ADVANCED WEEKEND TEST - 07 (01-08-2021)

1) 116 2) 216 3) 316 4) 416

74. If the equations a  y  z   x, b  z  x   y , c  x  y   z have non trivial solutions, t hen

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