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Bala Subramanian 2019
Bala Subramanian 2019
CONTACT K.A. Subramanian subra@ces.iitd.ac.in Engines and Unconventional Fuels, Laboratory, Centre for Energy Studies, IIT Delhi, New Delhi, India
ß 2019 Informa UK Limited, trading as Taylor & Francis Group
2 R. BALASUBRAMANIAN AND K. A. SUBRAMANIAN
Nomenclature
aBDC After bottom dead center LHR Low heat rejection
aTDC After top dead center LTC Low-temperature combustion
bBDC Before bottom dead center NOx Oxides of nitrogen
BP Brake power (kW) PM Particulate matter
BS Bharat stage SI Spark ignition
BDC Bottom dead center TDC Top dead center
BSEC Brake specific energy consumption VCR Variable compression ratio
BSFC Brake specific fuel consumption (g/kWh-h) Symbols
bTDC Bottom top dead center A Pre-exponential factor
BTE Brake thermal efficiency (%) Ea/Ru Activation temperature (K)
CA Crank angle T Temperature (K)
CAD Crank angle degree CxHy Fuel concentration
CI Compression ignition O2 Oxygen concentration
CO Carbon monoxide sid Ignition delay
CR Compression ratio EA Apparent activation energy
CRDI Common rail direct injection A Constant
CV Calorific value (kJ/kg) n Constant
DI Direct injection R Universal gas constant
HC Hydrocarbon Vswept Swept volume (cm3)
HP Horsepower Vclearance Clearance volume (cm3)
IP Injection pressure B Cylinder bore (cm)
IT Injection timing
emission increased with increased CR and decreased with 46%. Higher CR and retarded IT reduced the CO emissions
retarded IT. Muralidharan and Vasudevan [10] compared by 45%, CO2 emissions by 19%, and HC emissions by 40%.
the performance, emission and combustion characteristics Kassaby and Nemit Allah [15] studied the impact of CR
of a variable CR engine using methyl esters of waste cook- and blending ratio on the performance of a diesel engine.
ing oil and diesel blends. The experiments were conducted Increasing the CR increased the BTE of B10, B20, B30 and
with different CRs of 18:1 to 22:1 at 1500 rpm. The test B50 by 18.39% 27.48%, 18.5% and 19.82%, respectively.
results proved that the BTE, exhaust gas temperature and CO2 and NOx emissions increased by 14.28% and 36.28%.
brake power are dependent on CR and the biodiesel blend. CO and HC were reduced by 37.5% and 52%. When the CR
It was observed that the optimum CR was 21:1, which increased from 14:1 to 18:1 the ignition delay decreased by
gives the maximum brake power of 2.07 kW with a B40 13.95%. Increasing CR improved the performance and cylin-
blend. The temperature of the exhaust gas decreases with der pressure of the engine and produced more benefits
higher CR for blends. Muralidharan et al. [11] studied the with biodiesel than with pure diesel.
performance, emission and combustion levels of waste Hirkude and Padalkar [16] investigated the effect of
cooking oil biodiesel–diesel blends at CR 21:1. It was change in CR on performance characteristics and emission
observed that the maximum BTE was 38.46%, which was of a CI engine operated with a fired oil–biodiesel blend.
The increase in CR improved the BTE for all blends. At high
4.1% higher than diesel. The BSFC values for B20 and B40
CR the improvement in performance characteristics of bio-
were 3.80 and 3.88 kg/kWh, respectively, when compared
diesel was better compared to diesel with increased NOx
to diesel which was 3.97 kg/kWh. Jindal [12] investigated
emission, reduced CO and particulate matter (PM). Bora
the effect of CR and IP in a diesel engine with karanja
et al. [17] studied the effect of CR on performance, com-
methyl ester. The experiments were conducted with differ-
bustion and emission characteristics of a dual-fuel diesel
ent CRs and IPs. It was demonstrated that an increase in
engine. The experiments were conducted at CR values
CR and IP improves the performance of the engine. The
from 16:1 to 18:1 and at IT 23 BTDC under full load condi-
best performance was at 250 bar IP and CR of 18:1. The
tions. The BTE increased from 16.42% to 20.04% while the
BSFC was improved by 2.94% and the BTE by 8.2%, for all
CR increased from 16:1 to 18:1. However, the NOx and CO2
combinations of CR and IP. HC, NOx, smoke emission and increased, by 66.65% and 27.18%.
exhaust gas temperature were lower with biodiesel com- Amarnath et al. [18] investigated the thermal perform-
pared to diesel. Amartnath and Prabakaran [13] investi- ance and emission characteristics of jatropha and karanja
gated the performance characteristics and emission methyl esters on a VCR diesel engine. It was observed that
characteristics of a VCR engine running on karanja bio- the BTE decreased by 4.4% for karanja biodiesel, and by
diesel. With an increase in load, IP and CR it was found 4.5% for jatropha biodiesel, when compared to diesel at
that fuel consumption decreased for all blends. The BTE for full torque of 20 N-m. The CO and HC emissions were con-
B100 was lower by 2.92%; with an increase in CR from 14:1 siderably less when compared to base diesel. The NOx
to 18:1 the BTE value increased to 7%. The results show emission was higher at full torque when compared to die-
that the optimum values of CR and IP were 18:1 and 247 sel. The results show that the performance of karanja bio-
bar. Debnath et al. [14] evaluated the impact of CR and IT diesel is superior to that of jatropha or mahua biodiesel.
on performance characteristics of a diesel engine operated Sharma and Murugan [19] studied the effects of varying
with palm oil methyl ester. The maximum value of BTE CR at optimal IT and nozzle opening pressure on a diesel
achieved was at CR 17.5:1 and 18:1 with retarded IT 20 engine with a blend of biodiesel and oil from tire pyrolysis.
BTDC. With increased CR the NOx emission was reduced by The diesel engine was tested with different CRs (16.5:1,
BIOFUELS 3
the BTE is lower in the case of biodiesel than the base die-
sel. The decrease in BTE of biodiesel is largely because of
the automatic advancement of the start of combustion.
This advance occurred because of the decrease in ignition
delay caused by the higher CN of biodiesel than the base
diesel. The BTE improved from 27.2% to 29.92% for diesel
and B100 from 25.43% to 27.84% when the CR increased
from the base CR of 19:1 to 21:1. At a CR of 21:1, the effi-
ciency increased by about 9.9% for base diesel and 9.5%
for B100 compared to the base CR of 19:1 at an engine
speed of 2200 rpm.
The increase in CR increases the reaction rate. Reaction
rate is a function of activation energy, temperature of
reactant, concentration of oxygen and fuel, as shown in
Figure 1. Layout of experimental setup. Equation (1).
d½Cx Hy Ea
the copper washer for increasing the CR. The minimum ¼ A exp CxHym ½O2 n (1)
thickness of copper washer available was 0.5 mm. So, for dt RuT
increasing the CR, a copper washer with its extended inner where A is the pre-exponential factor, Ea/Ru is the acti-
diameter was specially machined in such a way that the vation temperature, CxHy is the fuel concentration, O2 is
clearance volume was reduced. In this case the higher CR the oxygen concentration, and m and n are constants. The
is achieved by considering the maximum possible inner effect of the temperature of the reactant on the reaction
diameter of the copper washer. The calculation for the rate is significantly greater compared to the other factors
reduction and increase of CR is given in Appendix A. such as concentration of oxygen and concentration of fuel.
Figure 3 shows the copper washer for standard (19:1) This leads to better combustion which gives a high rate of
and increased (21:1) CR. The tests were conducted with a heat release and high quality of heat. This enhanced max-
reduced CR of 17:1, base CR of 19:1 and increased CR of imum heat release rate leads to a high temperature in the
21:1. Table 4 gives the details of the accuracy and uncer- cylinder and improved Carnot efficiency. Improved effi-
tainty of measurements. The properties of diesel and bio- ciency implies that a higher amount of available heat
diesel (B100) are summarized in Table 5. energy is converted into useful work. Carnot efficiency at
an engine speed of 2200 rpm increased from 52.55% at
base CR to 54.69% with 21:1 CR. The quality of heat
Experiments with retarded IT to reduce the increases with increase in in-cylinder temperature and pres-
NOx emission sure, and this is one of the main reasons for the higher
The retarded IT is achieved with the addition of timing thermal efficiency at higher CR compared to the base case.
shims between the mounting and the injection pump Figure 5 shows the variation of BTE with CR at 3000 rpm
body. In this study, an extra shim of 0.25 mm thickness engine speed for biodiesel (B100) and base diesel. The results
was added to retard the IT. The experiments were carried show that the BTE at 3000 rpm follows a similar trend to
out with the retarded IT for the biodiesel and base diesel that for an engine speed of 2200 rpm. The BTE improved
to reduce the NOx emission from the engine. from 25.3% to 26.49% for diesel and from 24.5% to 25.95%
for B100 when the CR increased from the base value 19:1 to
21:1 at an engine speed of 3000 rpm. The efficiency
Results and discussion increased by about 4.62% for base diesel and 4.63% for B100
at 21:1 CR compared to the 19:1 base CR. This lower effi-
Effect of CR on BTE
ciency at 3000 rpm was attributed to the poor conversion of
Figure 4 shows the BTE variation with CR at 2200 rpm heat energy into work when compared to the conversion at
engine speed with biodiesel (B100) and diesel. The results 2200 rpm. Apart from the above reasons, the degree of con-
show that with the increase in CR, the BTE of the engine stant-volume combustion increases with increase in CR.
increased. This enhanced efficiency is because of better
combustion at high CR and higher quality of heat energy.
The effect of CR on NOx emission
With an increase in CR, the engine in-cylinder pressure
increased, which causes higher in-cylinder temperature NOx emissions that form in a CI engine directly depend on
leading to improved combustion and higher BTE. However, in-cylinder pressure, in-cylinder temperature and the
BIOFUELS 5
Table 5. Properties of diesel and biodiesel blends [23]. 28 Speed 3000 rpm
Property Diesel Biodiesel 27 Load : 100%
Calorific value (MJ/kg) 44.05 40.75 26
Viscosity (cSt) 2.64 5.8
Density (kg/m3) 821.5 893.6 25
BTE (%)
21
20
17 19 21
Compression ratio
26
Diesel speed of 2200 rpm. The other cause of the increase in NOx
24 emission is the content of oxygen in the biodiesel which
B100
increases the in-cylinder temperature, resulting in high NOx
22
emissions [25]. It may be noted that the adiabatic flame
20 temperature of biodiesel (B100) is higher (2432 C) than
17 19 21 that of base diesel (2196 C). Also, with the increase in CR,
Compression ratio
the number of intermediate products formed during the
Figure 4. Variation of brake thermal efficiency (BTE) with compression ratio. combustion process was reduced because of better com-
bustion, resulting in higher NOx emission formation.
Figure 7 shows the NOx emission variation with an
concentration of oxygen inside the cylinder. Figure 6 shows increase in CR at an engine speed of 3000 rpm. At this
the variation in NOx emissions with different CR at an speed, when the CR increased, the NOx emission increased
engine speed of 2200 rpm for both biodiesel (B100) and for both biodiesel and base diesel. The NOx emission for
6 R. BALASUBRAMANIAN AND K. A. SUBRAMANIAN
10 Speed 2200 rpm with increasing CR. Smoke emission is a function of equiva-
Load : 100%
9 lence ratio, oxygen content, temperature and mixing rate
8 of air and fuel. The major cause for smoke emission is
7
incomplete combustion of the fuel. For biodiesel, the
NOx (g/kW-h)
6
molecular content of oxygen led to an enhancement in the
5
4
Diesel fuel/oxygen ratio locally during combustion, reducing the
3 B100 smoke opacity. When there is a decrease in the rich-mix-
2 ture region locally the formation of smoke is limited by the
1 oxygen content. The increase in CR increases the peak tem-
0 perature, which results in superior burning of fuel, and this
17 19 21
Compression ratio reduces the smoke emission. Smoke emission for biodiesel
Figure 6. NOx emission variation with compression ratio at 2200 rpm. was lower when compared to diesel due to the presence
of oxygen which enhances the oxidation of fuel. Smoke
emission decreased by 10% for diesel and 27.5% for B100
10 Speed 3000 rpm
Load :100% when the CR was increased from 19:1 to 21:1 due to more
9
complete combustion as a result of high in-cylinder
8
7
temperature.
Figure 9 shows the smoke emission variation with CR
NOx (g/kW-h)
6
5
increase at a speed of 3000 rpm. At this speed, the smoke
Diesel emission decreases with the increase in CR. Smoke emis-
4
B100
3
sion decreased by 42.5% for diesel and 53.3% for B100
2 because of the increase in the CR from 19:1 to 21:1.
1 Compared to 2200 rpm, the smoke reduction at 3000 rpm
0 was higher because of higher in-cylinder temperature
17 19 21 which increases the fuel oxidation, leading to a major drop
Compression ratio
in smoke emission.
Figure 7. NOx emission variation with compression ratio at 3000 rpm.
45
in HC emissions with varying CR at a speed of 2200 rpm
35 for diesel as well as biodiesel (B100). It can be seen from
Diesel
the figure that the increase in CR leads to an increase in
25
B100 the HC emission for both diesel and B100. HC emissions
15 increased due to the increase in CR. The accumulation of
fuel in the cylinder causes the higher HC emission. A slight
5
17 19 21 increase in HC emission may be correlated with the reduc-
Compression ratio tion in CO with an increase in CR. However, the HC emis-
Figure 8. Smoke variation with compression ratio at 2200 rpm. sion is lower for B100 at all CR values, compared to base
diesel. The HC emission at CR of 17:1, 19:1 and 21.1 was
diesel increased to 8.73 g/kWh from 7.63 g/kWh and for 0.0077, 0.0088 and 0.0095 g/kWh, respectively, for diesel.
B100 and the increase was to 8.92 g/kWh from 7.73g/kWh The HC emission for B100 decreased to 0.0056, 0.0059 and
when the CR increased from base CR 19:1 to 21:1. The NOx 0.0087 g/kWh compared to base diesel.
emission increased by about 14.41% for base diesel and Figure 11 shows the variation in HC emissions with CR
15.39% for B100. NOx emission is a function of residence for both diesel and biodiesel at a speed of 3000 rpm. With
time, temperature and equivalence ratio. The percentage the CR increase the HC emission increased. The HC emis-
increase in NOx emission was higher at an engine speed of sions at CR 19:1 and 21:1 were 0.0076 and 0.0091 g/kWh,
3000 rpm compared to 2000 rpm because of the higher in- respectively, for diesel. For B100, the HC emission values
cylinder temperature. With the engine speed at 3000 rpm, were 0.0064 and 0.0072 g/kWh when CR was increased.
The percentage of CO emission decreases due to proper-
the cycle time decreases from 54.5 milliseconds to 40 milli-
ties of the fuel, rising temperature in the combustion cham-
seconds, resulting in a decrease in the residence time of
ber, lack of oxygen at high speed, air:fuel ratio and less time
the products of combustion inside the cylinder. So, the
available for complete combustion. CO emissions reflect the
NOx emission decreases with an engine speed of 3000 rpm
amount of unburned fuel, mixture temperature, decompos-
compared to a speed of 2200 rpm.
ition rate of fuel and rate of oxidation. If sufficient oxygen is
available, the CO emissions can be converted to CO2. Figure
12 shows the variation of CO emission with CR at 2200 rpm
Effect of CR on smoke emission
for diesel and biodiesel (B100). It can be seen from Figure 12
Figure 8 shows the variation of smoke emission with CR at that CO emission decreased with higher CR. The cause for
2200 rpm for biodiesel (B100) and base diesel. It can be this trend is that increasing the CR leads to an increase in the
observed that the smoke emission of the engine decreases temperature of the reactant, resulting in complete
BIOFUELS 7
7
50
CO (g/kW-h)
6
40 5
Diesel Diesel
30 4
B100 B100
20 3
2
10
1
0
0
17 19 21
17 19 21
Compression ratio
Compression ratio
Figure 9. Variation of smoke with compression ratio at 3000 rpm.
Figure 13. CO emission variation with compression ratio at 3000 rpm.
0.01 Speed 2200 rpm Figure 13 shows the variation of CO emission with CR at
Load : 100%
3000 rpm for biodiesel (B100) and base diesel. The CO emis-
0.008
sion at CR values of 19:1 and 21.1 was 6.99 and 3.55 g/kWh,
respectively, for diesel. The CO emission for B100 was 3.96
HC (g/kW-h)
0.006
and 2.84 g/kWh at CR values of 19:1 and 21.1, respectively.
Diesel
0.004
B100
0.002
Combustion analysis
The pressure–CA data is used to evaluate the combustion
0
17 19 21 process of the engine because the in-cylinder pressure
Compression ratio affects the performance parameters as well as the emis-
Figure 10. Hydrocarbon (HC) emission variation with compression ratio sions of the engine. Figure 14 shows the in-cylinder pres-
at 2200 rpm. sure with CR of 17:1, 19:1 and 21:1 for base diesel and
B100 at a speed of 2200 rpm. The peak pressure mainly
0.01 Speed 3000 rpm depends on combustion in the premixed combustion
Load : 100% stages. It also depends on the amount of fuel burned in
0.008 the premixed combustion stage. If CR is increased, there is
an increase in the in-cylinder pressure. This is because of
HC (g/kW-h)
0.006
the volume reduction in the cylinder with an increase in
0.004 Diesel CR. The peak pressure of B100 is higher than that of diesel
B100 at all CRs due to a lower ignition delay. The decrease in
0.002 ignition delay makes the combustion early, leading to ele-
vated peak pressure. Because of the lower calorific value of
0
17 19 21
biodiesel during the premixed combustion, a large amount
Compression ratio of fuel needs to be burned. This also leads to higher peak
Figure 11. Hydrocarbon (HC) emission variation with compression ratio pressure. The peak pressure observed for diesel was 57.49,
at 3000 rpm. 69.29 and 71.97 bar at CR values of 17:1, 19:1 and 21:1,
respectively, and for biodiesel the peak pressure was 64.56,
25 Speed 2200 rpm 69.74 and 72.65 bar, respectively. The pressure is higher
Load : 100% because of the fast and complete combustion of biodiesel.
20
CO (g/kW-h)
15 Ignition delay
Ignition delay is measured in CA from the start of injection
10 Diesel
to the start of combustion. It is a function of parameters
B100 such as the duration of injection, fuel quality, in-cylinder
5
pressure, IP, speed of the engine and CR. The ignition delay
with activation energy of the fuel ignition process is shown
0
17 19 21 in Equation (2):
Compression ratio
n EA
Figure 12. Variation of CO emission with compression ratio at 2200 rpm. sid ¼ A p exp (2)
RT
where sid is the ignition delay, EA is the apparent activation
combustion of fuel and leading to a decrease in the CO emis- energy, R is the universal gas constant, and A and n are
sion [24]. The CO emission at CR of 19:1 and 21.1 was 4.14 constants dependent on the fuel. With high-CN fuel, the
and 2.04 g/kWh, respectively, for diesel. The CO emission for ratio of EA/R e is lower.
B100 was 1.57 g/kWh and 1.02 at the respective CR values. Figure 15 shows the variation of ignition delay with CR
The CO emission is lower for B100 at all CR values compared at a speed of 2200 rpm. It was found that when the CR
to diesel. increases, the delay period decreases for both base diesel
8 R. BALASUBRAMANIAN AND K. A. SUBRAMANIAN
Combustion duration
12
Speed 2200 rpm Combustion duration is defined as the time between the
Load : 100% beginning of the heat release and the end of the heat
10
Ignition delay (Deg CA)
8
The combustion duration was 57, 56 and 54 CA for base
diesel and 60, 58 and 55 CA for B100 at CR values of 17:1,
6 19:1 and 21:1, respectively, at an engine speed of
Diesel
4 2000 rpm.
B100
Figure 18 shows the variation of combustion duration
2 with CR at a speed of 3000 rpm. It can be noted from the
0 figure that the duration of combustion decreases with
17 19 21 enhanced CR for both base diesel and B100 at 3000 rpm.
Compression ratio
The reasons for this were already explained above.
Figure 16. Variation of ignition delay with compression ratio at 3000 rpm. However, with the increase in speed, the combustion dur-
ation increased compared to the results with an engine
61 speed of 2200 rpm. The combustion duration was found to
Speed 2200 rpm
60 be 60, 59 and 55 CA for base diesel and 63, 60 and 57 CA
Combustion duration (Deg CA)
Load : 100%
59
for B100 at CR of 17:1, 19:1 and 21:1, respectively, at an
58
engine speed of 3000 rpm.
57
56
Diesel
55
Peak heat release rate
54 B100
53
The variation of peak heat release rate with the increase in
52 CR is given in Figure 19. The peak value of heat release
51 rate is the maximum for base diesel compared to biodiesel.
17 19 21 This is because of the higher calorific value of base diesel.
Compression ratio
Because the ignition delay of base diesel is more than that
Figure 17. Combustion duration variation with compression ratio
of biodiesel, a greater amount of fuel is accumulated. The
at 2200 rpm.
amount of fuel burned in the premixed phase increases,
causing a high rate of heat release. The combustion start is
and B100. The reason for this is that the increase in CR advanced because of higher bulk modulus of B100 result-
increases the air temperature in the cylinder which advan- ing in a change in the combustion pattern of biodiesel,
ces the start of combustion, resulting in reduced ignition leading to a decrease in the peak heat release rate. The
delay. The high CN of biodiesel is one reason for the peak heat release rate increases with lower CR, whereas it
reduced ignition delay. The CN of biodiesel (CN: 58) is decreases with higher CR. The peak heat release rate of
BIOFUELS 9
58
56 Diesel
54 B100
52
50
17 19 21
Compression ratio
Figure 18. Combustion duration variation of with compression ratio
Figure 22. Maximum rate of pressure rise variations with compression ratio
at 3000 rpm.
at 3000 rpm.
140 Speed 2200 rpm release rate was high at lower CR values and low at higher
Peak heat release rate (J/ deg
120 Load : 100% CR values. The maximum heat release rate at 21:1 CR for
100 B100 was 74.85 J/ CA compared to 66.45 J/ CA at the base
80 CR of 19:1 at an engine speed of 3000 rpm.
CA)
Load :100 % ture. The values for maximum pressure rise rate at CR val-
120
ues of 17:1, 19:1 and 21:1 are 6.2, 6.5 and 7.9 bar/ CA for
100
diesel and 5.5, 5.6 and 6.1 bar/ CA for B100, respectively, at
80 an engine speed of 2200 rpm. The maximum pressure rise
60 Diesel rate in the engine cylinder has the greatest effect on the
B100 maximum in-cylinder pressure and smooth operation of
40
the engine.
20
0
17 19 21 Maximum pressure rise rate
Compression ratio
The maximum rate of pressure rise variation with different
Figure 20. Variation of peak heat release rate with compression ratio CR values is shown in Figure 22. The maximum pressure
at 3000 rpm.
rise rate at CR values of 17:1, 19:1 and 21:1 was 5.2, 6.2
and 6.8 bar/ CA for diesel and 4.8, 4.4 and 3.98 bar/ CA for
9 Speed 2200 rpm
B100 at 3000 rpm.
Maximum rate of pressure rise
8 Load : 100%
7
(bar/ deg CA)