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a r t i c l e in fo abstract
Article history: The problem of electrostatic screening of the perturbation potential due to lattice imperfections by hot
Received 15 January 2010 electrons has been studied here in the presence of crossed electric and non-quantising magnetic fields
Accepted 5 February 2010 and under the condition when the lifetime of the carriers is controlled by deep repulsive trap. The
screening characteristics are calculated in the general case of any mechanism of energy and momentum
Keywords: scattering of the hot carriers in the strong and weak magnetic field limits. For some definite scattering
Semiconductors mechanisms, however, the characteristics are obtained in the presence of any finite value of the
Screening magnetic field. The results calculated for Ge seem to be interesting in that they are not only different
Non-equilibrium electrons from what can be obtained for an ensemble that is in thermodynamic equilibrium with the lattice
atoms but are also quite different from what one obtains under the condition when the lifetime of the
hot electrons in the presence of the crossed electric and magnetic fields are controlled by attractive
traps. It is seen that the presence of the magnetic field sometimes introduces significant changes in the
screening characteristics. The limitations of the present theory are explained and its possible
applicability is discussed.
& 2010 Elsevier B.V. All rights reserved.
0921-4526/$ - see front matter & 2010 Elsevier B.V. All rights reserved.
doi:10.1016/j.physb.2010.02.021
ARTICLE IN PRESS
2252 S. Midday, D.P. Bhattacharya / Physica B 405 (2010) 2251–2258
value qs(0). As a result, corresponding changes are effected in the under the condition when the lifetime of the hot carriers is
matrix elements for the electronic transitions and hence it would controlled by deep repulsive traps. The investigations have been
lead to interesting high-field characteristics of the material. The carried out here for the general case of any mechanism of energy
problem of electrostatic screening due to non-equilibrium and momentum scattering of the hot electrons in the presence of
electrons under various prevalent conditions is not yet well a weak, or a strong but non-quantising transverse magnetic field.
studied in the literature. However, the present authors recently The general expressions that describe the dependence of the
reported some of the results they obtained from such studies screening length upon the applied field and the lattice tempera-
[10–15]. ture have been obtained in an explicit form for some limiting
Under any prevalent condition the dominant scattering values of the magnetic field. For some definite scattering mecha-
mechanisms of the free electrons, the effective recombination nisms, the applied electric field dependence of the screening
processes and the type of trapping centers are mainly the factors length for any finite value of the magnetic field has also been
that determine the dependence of the screening length upon the obtained for relatively high values of the total electric field. The
electric field and the lattice temperature. It is seen that, when the numerical results for some characteristics of the screening length
non-equilibrium electrons are scattered by the deformation in n-Ge have been presented and analysed.
potential acoustic phonons, and in the absence of the recombina-
tion effects, the screening length drops significantly below its
thermodynamic equilibrium value, being inversely proportional
to the square root of the electric field, in some high field regime, at 2. Theoretical background
low lattice temperatures. Again, when the recombination effects
are taken into account, the characteristics of the screening length Let us consider an ensemble of non-equilibrium electrons
with respect to its field and lattice temperature dependences subjected to transverse electric E and magnetic H fields. f ð~
kÞ, the
become even more involved in that they are now significantly distribution function of the non-equilibrium electrons normalized
different from what follows under the condition when the to the concentration n, can be written as [3,6]
recombination of the non-equilibrium electrons does not come
into effect. f ð~
kÞ ¼ f0 ðeÞ þ k cos y:f1 ðeÞ ð1Þ
When the free carriers are subjected simultaneously to
transverse electric and magnetic fields, a Hall field may develop. where f0(e) and f1(e) are the isotropic and anisotropic parts of
The resulting heating field under this condition is the vector sum the non-equilibrium distribution function and y is the polar
of the applied field and the Hall field. The presence of the angle of ~
k.
magnetic field changes the energy distribution of the ensemble of The reciprocal screening length due to an ensemble of non-
the non-equilibrium carriers. The characteristics of the screening equilibrium carriers can be calculated from [10]
length due to an ensemble of non-equilibrium electrons in the Z
8p2 e2 3
1
@f0 1
presence of the magnetic field under the condition when the q2s ðE; HÞ ¼ ð2m kB TL Þ2 x2 dx ð2Þ
ed ‘ 3
0 @e
lifetime of the hot carriers is controlled by shallow attractive traps
has recently been obtained elsewhere [15]. The results showed
where m* is the effective mass of the free electrons ‘ ¼ 2hp, h is
interesting characteristic features that are quite different from
what one can obtain in the absence of the magnetic field. It has Planck’s constant, x ¼ kBeTL , e the energy of a free electron.
been seen that depending on the dominant momentum and Thus, to calculate qs(E,H), one should know the isotropic part of
energy relaxation processes of the free electrons in the material, the distribution function, and the field dependence of the carrier
and the strength of the applied electric field, the presence of the concentration when their lifetime is controlled by deep repulsive
magnetic field sometimes brings in significant changes in both trap. The distribution function of the carrier ensemble can be
the qualitative and quantitative aspects of the characteristics obtained from the solution of the Boltzmann transport equation
of the screening length with respect to its field and temperature when the energy band structure of the material and the dominant
dependences. interaction processes under the prevalent conditions are known.
The study of the effects of trapping of the non-equilibrium The field dependence of the concentration of the non-equilibrium
carriers by repulsive traps has received much attention because carriers can be calculated from the solution of the steady-state
such trapping gives rise to the well-known phenomenon of rate equation, subject to charge neutrality condition [7].
domain instability in semiconductors [16]. Hence it would be of At the low lattice temperatures of interest here (TL r20 K),
importance to make a detailed quantitative study of how the the free electrons are perturbed from the state of thermo-
above results [15] would change if the lifetime of the free carriers dynamic equilibrium in relatively weak fields. Such electrons
is controlled by repulsive traps instead of the attractive ones. are confined to a short segment of the energy dispersion curve
Generalising Lucovsky’s model [17], a repulsive trap is near the minimum of the conduction band. As such, one can
described by repulsive Coulomb potential. The trapping of the assume the band structure to be parabolic without any serious
electrons by repulsive centers is affected by the quantum loss of accuracy in the succeeding calculations. The anisotropy
mechanical tunneling of the potential barrier produced by the and the many valley effects are known to effect just some changes
latter [18–20]. As the applied electric field is increased, the energy in the numerical coefficients in the analysis. Hence a scalar
of the electron increases and unlike the case of attractive traps, effective mass of the electrons may also be assumed in the
the capture coefficient increases. This results in a decrease in the formulation [21].
carrier concentration with the increase of the applied electric Let the carrier lifetime be much longer than all other relevant
field. Thus on changing the nature of the traps from attractive to characteristic times. We consider the general case when the
repulsive, an opposite trend in the electric field dependence of the quasi-elastic scattering of the energy and momentum of the
screening length is expected in the range of the electric field over carriers are dominated by the kth and ith mechanisms, respec-
which the effect of carrier trapping is felt. tively. Then in the presence of a strong heating field limited by the
Hence the purpose of this paper is to formulate the character- condition
istics of the electrostatic screening length due to an ensemble of x1
non-equilibrium electrons in the presence of a magnetic field ðaik =Zzi Þcx ½Gð3=2xÞ=Gð5=2xÞð1xÞx ð3Þ
ARTICLE IN PRESS
S. Midday, D.P. Bhattacharya / Physica B 405 (2010) 2251–2258 2253
any prevalent condition. Thus the above formulation provides the presence of any finite value of the magnetic field for those definite
general solution of the problem for the limiting ranges of the combinations of scattering mechanisms that satisfies the condi-
magnetic field. But the solution of the problem cannot be tion t + t0 = 2 and t 40. Hence it is clear that unlike what follows
obtained for such strengths of the magnetic field when the under the thermodynamic equilibrium condition, the screening
applied field and the Hall field are of the same order of magnitude. length now becomes dependent on the total heating field E and
However, both the distribution function and the solution of the shows rather complicated temperature dependence. Moreover,
equation connecting the applied field with the heating one may the screening length characteristic is now quite different from
be obtained for any non-zero magnetic field (Zi a0) for some what has already been obtained under the condition when the
definite combinations of the energy and momentum scattering electrons are captured by attractive traps [15].
mechanisms. These are the mechanisms that satisfy the condition To know how the screening length depends on the applied
t +t0 = 2 and t40. The symmetric part of the distribution function field EX under any prevalent condition it is required to express
then has the form [24] E in terms of EX under similar conditions. As has already been
explained the total electric field is always equal to the applied
k
f0;i ðxÞ ¼ N0 x1=aik exp½Zi xt =aik t ð14Þ
field, E= EX in the fixed field regime. In the fixed current regime,
where N0 is the normalization constant. however, the dependence of the screening length upon Ex for the
Putting Eq. (14) in Eq. (2), the normalized screening length general case of any mechanism of energy and momentum
may now be obtained as scattering may be obtained using Eq. (13) for the weak (x = x1;
z = 0) and the strong (x = x2; z =1) magnetic fields, taking into
q2s ðE; HÞ nðE; HÞ
¼ ðZi =aik Þq1 t 1q GðpÞ=2GðqÞ ð15Þ account, respectively, the upper and the lower signs in Eq. (4).
q2s ð0Þ nð0Þ
Thus, under the condition of low magnetic field, the heating
For such combinations of the scattering mechanisms using electric field is again seen to be nearly equal to the applied field in
k
Eq. (14) for the distribution function f0;i ðxÞ one can carry out the the fixed current regime. Since, the magnetic field does not occur
integration in Eq. (8). For in the expression for the screening length under these conditions,
irrespective of the experimental regime, the characteristic
g
exp pffiffiffi c1 ð16Þ dependence of the screening length upon the applied field at
x
any temperature, under the condition of low magnetic field,
1=t h i
where x now assumes the form x ¼ t aik =Zzi GðrÞ appears to be independent of the strength of the latter. Under the
GðqÞ and p =
condition when the magnetic field is strong, the total heating field
(1/2t) (1/aikt); q= (3/2t) (1/aikt); r= (5/2t) (1/aikt) and for
in the fixed current regime indeed depends upon the magnetic
electric fields
! field. The field dependence of the screening length for any
H
1 þ 2t g t combination of the scattering mechanisms that satisfy the
E{ðt þ 2Þ 2 E0 ð17Þ conditions x 40, x2 4t is determined by the factor (aik/Zi). Now
2 Hi0 ik
from Eq. (13) it follows that for such a combination of scattering
one can get [23] mechanisms like t =t0 = 1, i.e. when both the energy and the
5
!1=2 2 momentum of the free carriers are scattered by deformation
4pðgaik =2Zi Þ1 þ 2t gaik aik ð2t þ 1Þ acoustic (a) phonons, x2 = 1 and (aaa/Za) turn out to be indepen-
I1 ¼ N0 pffiffiffiffi
gðt þ 2Þ 2Zi dent of the magnetic field, being equal to ð3 p=8ÞðEX =E0aa Þ. Hence
ð1 þ2tÞg 1 for such a combination of scattering mechanisms, even in the
exp ðgaik =2Zi Þð1 þ 2tÞ ð18aÞ
2t presence of a high magnetic field, the characteristic dependence
of the screening length upon the applied electric field also appears
The integral I2 however remains the same. But I3 is now given to be independent of the magnetic field in the fixed current
by regime. In the same fixed current regime, for those definite
p scattering mechanisms governed by the conditions t+ t0 =2 and
aik t40, the dependence of the screening length upon the applied
I3 ¼ N0 t q1 GðqÞ ð18bÞ
Zi field EX at any finite value of the magnetic field may be known
In order to obtain a relation between the total field E and the using Eq. (19), which relates E with EX under these circumstances.
applied field Ex for these combinations of the scattering mecha- Under any prevalent conditions, the ranges of the electric and
nisms one can calculate the mobility coefficients using Eq. (14) magnetic fields for which the formulation here is applicable
and thus obtain depend upon the lattice temperature. At any lattice temperature,
these ranges may be found from Eqs. (3), (4), (9), (10) and (13),
E2 ¼ E2x =½1ðEx =Exc Þ2 ð19Þ for the general case of any scattering mechanism in the weak
pffiffi
where Exc ¼ E0ik Gððt þ 3Þ=2tÞ= t Gðð2t þ3Þ=2tÞ. and strong magnetic field limits. For those definite scattering
mechanisms (t+ t0 =2; t 40) however, the electric field range may
be found from the condition aik b1 and Eqs. (16), (17) and (19) at
3. Results and discussions any finite value of the magnetic field.
For an application of the above formulation, a high purity
Thus we have obtained the characteristics of the screening sample of n-Ge is considered. The material parameters used in the
length due to non-equilibrium carriers in the presence of crossed numerical calculations are: m* = 0.12m0, m0 being the free mass of
electric and magnetic fields and under the condition when the the electron, cl =5.39 105 cm s 1, density of the material
lifetime of the carriers is controlled by deep repulsive trap. r =5.326 gm cm 3, ed/e0 = 15.8, e0 being the permittivity of the
The dependence of the screening length upon the total electric free space.
field E can be obtained from Eqs. (6), (7), (8) and (11) for the For such high purity sample, where ND +NA r1013 cm 3, both
general case of any mechanism of energy and momentum the energy and the momentum of the free carriers are scattered
scattering of the hot electrons in the strong and weak magnetic by the deformation acoustic phonons around a lattice tempera-
field limits provided x 40 and x2 4t. Likewise the expressions ture of 5 K [21], and hence t= t0 = 1 in this case. For the case of
(15), (7), (8), (11b) and (18) give the same dependence in the the strong electric field and the weak magnetic field x x1 =2 and
ARTICLE IN PRESS
S. Midday, D.P. Bhattacharya / Physica B 405 (2010) 2251–2258 2255
z = 0. Hence, q2s ðE; HÞ is just inversely proportional to the applied dependence of the screening length upon EX turns out to be
electric field for both the experimental regimes when the similar to that for the weak magnetic field case and the char-
recombination effects are absent. However the field dependence acteristic is independent of the magnetic field strength. However,
of the screening length turns out to be much involved when for the fixed field regime, the same characteristics do depend
recombination effects are taken into consideration. Now the upon the strength of the magnetic field and the results are plotted
condition of strong electric field as given by Eq. (3) assumes the in Fig. 2.
simple form E2 b9.4 10 4T3L and the same for the weak It is well known that the effects of recombination, which make
magnetic field as given by Eq. (4) with the upper sign there the concentration field dependent, are felt more and more the
assuming the form H2 5349.7T3/2 E. The inequalities (9) and (10) lower the lattice temperature. The recombination effects, in the
L
90:86TL
1=4
1=2 presence of deep repulsive traps, make the screening length
may now be simplified to exp E1=2
c1 and E o 21334:12TL ,
assume a smaller value at any field if the lattice temperature is
respectively. We have already seen from Eq. (13) that for such low enough. As a result of the recombination effects, the concen-
fields E EEX even in the fixed current regime. Thus at the lattice tration of the non-equilibrium carriers in the presence of the deep
temperatures between 4 and 20 K, our formulation is applicable repulsive traps initially falls very rapidly with the increase of the
for the applied electric field range 0.5–25 V/cm and the magnetic applied electric field. But the rate of fall gradually slows down and
field ranges between 30 and 100 Oe. the concentration tends to a lower saturation value as the electric
On the other hand, if both the electric and magnetic fields are field is increased. The other factor in the expression for the
strong, x x2 = 1 and z = 1. The condition of the strong electric field screening length that arises due to heating of the carriers is
now takes the simple form E2 b8.75 10 5H2 and the same for inversely proportional to the square root of the applied field. As
the strong magnetic field is given by H2 4409.4T3/2 L E. The such, initially this factor also decreases at a fast rate with the
inequalities (9) and (10) under these conditions may be expressed increase of the applied field and then the rate slows down readily.
As a result, at relatively lower temperatures, when the effects of
as exp 4:15 c1 and Eo 3:3H , respectively. In the fixed field
1=2
TL E
1=2
TL recombination are quite strong, initially the screening length
regime E= EX. Thus at lattice temperature between 4 and 20 K, the decreases rather fast with the increase of the electric field and
applicable range of the applied electric field for this formulation then nearly tends to a lower saturation value.
turns out to be 1.2–10 V/cm and the magnetic field should lie It may be noted that the presence of a magnetic field produces
between 100 Oe to a few hundred Oe. However, in the fixed significant effects on the characteristics of the screening length
current regime one can see from Eq. (13) that the applied field, due to hot electrons. One can see from Eq. (6) that the screening
corresponding to a total field in this case, may be obtained from length increases linearly with the magnetic field, if the effects of
3 1=2 recombination are not taken into account.
E ¼ 0:45TL 4 Ex H. Hence at the same range of lattice temperatures,
The qualitative nature of the field dependence of the screening
the applied electric field should lie between 0.6 and 3.7 V/cm.
length however remains the same, always being inversely
The dependence of the normalized screening length upon the
proportional to the electric field. But both the qualitative and
applied field EX thus obtained for any arbitrary regime over the
stated field ranges at the lattice temperatures TL = 4,10 and 20 K,
for the case of weak magnetic fields presented in Fig. 1.
For the case of strong magnetic field in the fixed current
regime, as has already been explained, the qualitative nature of
Fig. 2. Dependence of the normalized screening length upon the applied electric
field Ex in n-type Ge at different lattice temperatures for strong magnetic fields
(z = 1) in the fixed field regime and under the condition when both the energy and
momentum of the free electrons are scattered by deformation acoustic phonons
(i.e. t = t0 = 1). Curves 1a, 2a and 3a are obtained considering the recombination
Fig. 1. Dependence of the normalized screening length upon the applied electric effects at the lattice temperatures of 4, 10 and 20 K for the magnetic field strengths
field Ex in n-type Ge at different lattice temperatures for weak magnetic fields (z =0 of 100, 250 and 580 Oe, respectively. Curves 1b, 2b and 3b are obtained at the
and hence for an arbitrary regime) under the condition when both the energy and same lattice temperatures but without considering the recombination effects.
momentum of the free electrons are scattered by deformation acoustic phonons Curves 4a and 5a are obtained considering the recombination effects at the lattice
(i.e. t = t0 = 1). Curves 1a, 2a and 3a are obtained considering the recombination temperature of 10 K and for the magnetic field values of 120 and 150 Oe,
effects at the lattice temperatures of 4, 10 and 20 K, respectively. Curves 1b, 2b and respectively. Curves 4b and 5b are obtained at the same lattice temperature 10 K
3b are obtained at the same lattice temperatures but without considering the and for the same magnetic fields, respectively, but without considering the
recombination effects. recombination effects.
ARTICLE IN PRESS
2256 S. Midday, D.P. Bhattacharya / Physica B 405 (2010) 2251–2258
quantitative changes in the characteristics are effected with the the recombination effects are taken into account. The electric field
change of the magnetic field if the processes of recombination range over which our formulation is valid depends upon the
of the hot electrons are taken into account. The recombination lattice temperature as before. The range turns out to be between
effects also make the screening length increase with the magnetic 10 and 20 V/cm for the lattice temperatures within 10–20 K. The
field, but the rate of increase is now rather complex. dependence of the screening length upon the applied field thus
Under the condition when the impurity content in the sample obtained for NI = 1014 cm 3 is plotted in Fig. 3. It may be noted
is high enough, the non-equilibrium electrons would interact with from the figure that the qualitative nature of the field dependence
acoustic mode lattice vibrations and ionized impurity (I) centers of the screening length turns out to be distinctly different as one
at low lattice temperatures [21]. The carrier energy would be takes recombination effects into account. The recombination
scattered by deformation acoustic phonons (t0 = 1) if the average effects give rise to lower values of the screening length for any
normalized energy x{ðkB TL =m cl2 Þ. The momentum would be field at lower temperatures. The rate of change of the screening
dominantly scattered by ionized impurities (t =3) if ðxÞ2 {ðl0a =l0I Þ. length with the increase of the applied field is higher, the lower
Under these conditions since t + t0 = 2 and t 40, one can calculate x the lattice temperature.
using Eq. (14) for the isotropic part of the distribution function As follows from Eq. (19), the heating field E in the fixed current
and thus can obtain these conditions in terms of the total heating regime under the prevailing conditions initially increases rather
electric field. slowly with the applied field Ex but the rate of increase becomes
The screening length in this case may be calculated from Eqs. quite sharp as Ex-Exc at any lattice temperature. The value of
(15), (7), (8), (18) and (11b) for any non-zero value of the the critical field Exc, which increases with temperature, may now
magnetic field. Here p= 1/6, q= 1/2 and r = 5/6. It may be seen from 1=2
be obtained from EXC ¼ 1:48flnð1 þ 0:093TL2 g . This is one of the
Eq. (15) that in the absence of recombination effects, unlike the characteristics of the combination of the partially restrictive
case of acoustic scattering (t =t0 = 1), now the screening length scattering mechanisms [12]. In this fixed current regime the
increases linearly with the electric field and is inversely propor- condition of the strong electric field assumes the form
tional to the magnetic field. Since the rate of fall of the field 1=2
dependent concentration n(E,H) with the increase of the electric EX 4 1:24flnð1þ 0:093TL2 Þg . The range of the applied field in
field largely exceeds the constant rate of increase of the second which this formulation is valid thus appears to be quite narrow
factor in Eq. (15), the screening length fast decreases with the and lies between 2.15 and 2.82 V/cm for lattice temperatures
increase of the electric field if the recombination effects are taken within 10–20 K. The variation of the heating field with the applied
into account. In the fixed field regime, as before E =EX. Hence the field at different lattice temperatures has been given in Fig. 4. The
dependence of the normalized screening length upon the applied
condition of strong
1=2aIa b1 now
electric field assumes the simple
field in the fixed current regime under the prevailing conditions,
form EX 4 2:28 lnð1 þ 0:093TL2 Þ . Thus q2s ðE; HÞ EHX , if recombi-
nation effects are absent. However, the screening length depends for different lattice temperatures and for different magnetic field
upon the electric and magnetic fields in an involved manner when strengths, are plotted in Fig. 5.
From a comparison of Figs. 3 and 5, it follows that significant
changes have been effected in both the quantitative and
qualitative aspects of the characteristics compared to which have
already been obtained earlier in Figs. 1 and 2, that represent the
same characteristics, when both the energy and momentum are
scattered by deformation acoustic phonons (t = t0 = 1). There has
been considerable increase in the value of screening length at any
electric field under the condition when the momentum is
Fig. 3. Dependence of the normalized screening length upon the applied electric
field Ex in n-type Ge at different lattice temperatures for any finite value of the
magnetic field in the fixed field regime, under the condition when the carrier
energy is scattered by deformation acoustic phonons (t0 = 1) and momentum by
ionized impurities (t = 3). Curves 1a, 2a and 3a are obtained considering the
recombination effects at the lattice temperatures of 10, 15 and 20 K, respectively,
and for the magnetic field strength of 400 Oe. Curves 1b, 2b and 3b are obtained for
the identical conditions with respect to the magnetic field and the same lattice
temperatures, respectively, but without considering the recombination effects.
Curves 4a and 5a are obtained considering the recombination effects at the lattice Fig. 4. Dependence of the heating electric field E upon the applied field Ex in
temperature of 10 K and for the magnetic field values of 425 and 450 Oe, n-type Ge at different lattice temperatures under the condition when the carrier
respectively. Curves 4b and 5b are obtained at the same temperature 10 K and for energy is scattered by deformation acoustic phonons (t0 = 1) and momentum by
the same magnetic fields, respectively, but without considering the recombination ionized impurities (t = 3). Curves 1, 2 and 3 are obtained at the lattice temperatures
effects. of 10, 15 and 20 K, respectively.
ARTICLE IN PRESS
S. Midday, D.P. Bhattacharya / Physica B 405 (2010) 2251–2258 2257
factors are to be given due consideration in further investigations [3] B.R. Nag, Theory of Electrical Transport in Semiconductors, Pergamon Press,
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controlled by deep repulsive traps in the presence of a magnetic for Communication, CODEC-04, Calcutta, Institute of Radio Physics and
Electronics, University of Calcutta, 2004.
field at low lattice temperatures.
[12] D.P. Bhattacharya, S. Midday, N. Paul, in: Sudakshina Kundu, Anupam
Karmakar, (Eds.), Proceedings of the International Conference on Electronic
ad Photonic Materials, Devices and System, EPMDS-2006, Calcutta, Depart-
Acknowledgements ment of Electronic Science, University of Calcutta, 2006.
[13] D.P. Bhattacharya, S. Midday, J. Phys. Chem. Sol. 70 (2009) 360.
[14] S. Midday, D.P. Bhattacharya, Physica B 404 (2009) 1190.
One of the authors (S. Midday) is indebted to the University [15] S. Midday, D.P. Bhattacharya, Can. J. Phys. doi: 10.1139/P09-101.
Grant Commission, New Delhi, India for the award of a Teacher [16] V.L. Bonch-Bruevich, I.P. Zvyagin, A.G. Mirnov, Electric Instability due to
Domains in Semiconductors, Izd. Nauka, Moscow, 1972.
Fellowship under Faculty Development Programme. The financial
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support of Jadavpur University in the form of a research grant is [18] Z.S. Kachlishvili, Sov. Phys. Semicond. 1 (1965) 649.
gratefully acknowledged. The authors also acknowledge the help [19] V.L. Bonch-Bruevich, Sov. Phys. Solid State 6 (1964) 2047.
[20] R.C. Pratt, B.K. Ridley, J. Phys. Chem. Solids 26 (1965) 21.
rendered by S. Nag.
[21] Z.S. Kachlishvili, Phys. Status Solidi (a) 33 (1976) 15.
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