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Redox practice worksheet

Name: Date:

1. In which substance is the oxidation number of 4. In the reaction 2K + Cl2 ! 2KCl, the species
nitrogen zero? oxidized is

A. NH3 B. N2 C. NO2 D. N2 O A. Cl2 B. Cl C. K D. K+

2. What is the oxidation number of carbon in 5. As an S2 ion is oxidized to an S0 atom, the


NaHCO3 ? number of protons in its nucleus

A. +6 B. +2 C. 4 D. +4
A. decreases B. increases

C. remains the same


3. In the reaction Al0 + Cr3+ ! Al3 + Cr0 , the
reducing agent is

A. Al0 B. Cr3+ C. Al3+ D. Cr0

6. Given the probable reaction for the nickel-cadmium battery:

2Ni(OH)3 + Cd (
+ 2Ni(OH)2 + Cd(OH)2

Which species is oxidized during the discharge of the battery?

A. Ni3+ B. Ni2+ C. Cd0 D. Cd2+

7. If element X forms the oxides XO and X2 O3 , the 10. In the equation


oxidation numbers of element X are Cu(s) + 2Ag+ (aq) ! Cu2+ (aq) + 2Ag(s),
the oxidizing agent is
A. +1 and + 2 B. +2 and + 3
A. Cu0 B. Ag+ C. Cu2+ D. Ag0
C. +1 and + 3 D. +2 and + 4

11. In the reaction Al + Cr3+ ! Al3+ + Cr, the


8. Oxygen has a positive oxidation number in the reducing agent is
compound

A. Al B. Cr3+ C. Al3+ D. Cr
A. H2 O B. H 2 O2 C. OF2 D. IO2

12. In the compound Na2 HPO4 , which element has a


9. What is the oxidation number of sulfur in H2 SO4 ? negative oxidation number?

A. 0 B. 2 C. +6 D. +4 A. H B. O C. P D. Na

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13. Which species undergoes a loss of electrons? 17. In the reaction Cl2 + 2Br (aq) ! 2Cl (aq) + Br2 ,
which half-reaction correctly represents oxidation?
Mg(s) + 2Ag+ (aq) ! Mg2+ (aq) + 2Ag(s)

A. 2Br ! Br2 + 2e B. Cl2 ! 2Cl + 2e


A. Mg(s) B. Ag+ (aq)
C. 2Br + 2e ! Br2 D. Cl2 + 2e ! Cl
C. Mg2+ (aq) D. Ag(s)

18. Which half-reaction correctly represents reduction?


14. Given the reaction:

2Na + 2H2 O ! 2Na+ + 2OH + H2 A. S2 + 2e ! S0

Which substance is oxidized? B. S2 ! S0 + 2e

C. Mn7+ + 3e ! Mn4+
A. H2 B. H+ C. Na D. Na+
D. Mn7+ ! Mn4+ + 3e

15. Which change occurs when an Sn2+ ion is


oxidized? 19. A solution contains 90 grams of a salt dissolved in
100 grams of water at 40 C. The solution could
be an unsaturated solution of
A. Two electrons are lost.

B. Two electrons are gained. A. KCl B. KNO3


C. Two protons are lost. C. NaCl D. NaNO3
D. Two protons are gained.
20. Which is an oxidation-reduction reaction?
16. A redox reaction always involves
A. 4Na + O2 ! 2Na2 O
A. a change in oxidation number B. 3O2 ! 2O3
B. a change in phase C. AgNO3 + NaCl ! AgCl + NaNO3
C. the transfer of protons D. KI ! K+ + I
D. the formation of ions

21. Which is a redox reaction?

A. CaCO3 ! CaO + CO2 B. NaOH + HCl ! NaCl + H2 O

C. 2NH4 Cl + Ca(OH)2 ! 2NH3 + 2H2 O + CaCl2 D. 2H2 O ! 2H2 + O2

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22. In the reaction 26. Which equation represents the half-reaction that
takes place at the fork?
3Cl2 + 6NaOH ! 5NaCl + NaClO3 + 3H2 O;

Cl2 undergoes

A. oxidation, only

B. reduction, only

C. both oxidation and reduction A. Ag+ + NO3 ! AgNO3

D. neither oxidation nor reduction B. AgNO3 ! Ag+ + NO3

C. Ag+ + e ! Ag(s)
23. In the reaction
AgNO3 (aq) + NaCl(aq) ! NaNO3 (aq) + AgCl(s), D. Ag(s) ! Ag+ + e
the reactants
27. Which half-reaction correctly represents a reduction
A. gain electrons, only reaction?

B. lose electrons, only


A. Sn0 + 2e ! Sn2+ B. Na0 + e ! Na+
C. both gain and lose electrons
C. Li0 + e ! Li+ D. Br2 0 + 2e ! 2Br
D. neither gain nor lose electrons

28. Which half-cell reaction correctly represents


24. In the reaction Mg + Cl2 ! MgCl2 , the correct oxidation?
half-reaction for the oxidation that occurs is

A. Pb2+ + 2e ! Pb B. Pb + 2e ! Pb2+
A. Mg + 2e ! Mg2+ B. Cl2 + 2e ! 2Cl
C. Pb2+ ! Pb + 2e D. Pb ! Pb2+ + 2e
C. Mg ! Mg2+ + 2e D. Cl2 ! 2Cl + 2e

29. Which represents the positive electrode of a


25. The reaction that takes place in a chemical cell is nickel-cadmium battery?
best classi ed as

A. Ni(OH)3 B. Cd
A. fusion B. redox
C. Ni D. Cd(OH)2
C. transmutation D. cracking

30. The diagram shown represents an electroplating


arrangement. In the setup shown, an object to be
plated with metal would be the

A. anode at A

B. anode at B

C. cathode at A

D. cathode at B

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31. In this electrolytic cell, electrode A is designated 34. Based on Reference Table N, what is the standard
as the electrode potential (E0 ) for the oxidation of Cu(s)
to Cu2+ (aq) ?

A. +0.52 V B. +0.34 V

C. 0.52 V D. 0.34 V

35. Which statement best describes the key?

A. anode and is positive

B. anode and is negative

C. cathode and is positive

D. cathode and is negative

32. The diagram shown represents a chemical cell at


298 K and 1 atmosphere.

Which species represents the cathode?

A. Zn B. Zn2+ C. Cu D. Cu2+

33. Which part of the electroplating system is provided A. It acts as the cathode and is negative.
by the fork?
B. It acts as the cathode and is positive.

C. It acts as the anode and is negative.

D. It acts as the anode and is positive.

A. the anode, which is the negative electrode

B. the cathode, which is the negative electrode

C. the anode, which is the positive electrode

D. the cathode, which is the positive electrode

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36. The diagram below shows a key being plated with 38. Where does oxidation occur in an electrochemical
copper in an electrolytic cell. cell?

A. at the cathode in both an electrolytic cell and


a voltaic cell
B. at the cathode in an electrolytic cell and at
the anode in a voltaic cell
C. at the anode in both an electrolytic cell and a
voltaic cell
Given the reduction reaction for this cell:
D. at the anode in an electrolytic cell and at the
Cu2+ (aq) + 2e ! Cu(s) cathode in a voltaic cell

This reduction occurs at


39. Base your answer(s) to the following question(s)
on the diagram and balanced equation below,
A. A, which is the anode which represent the electrolysis of molten NaCl.

B. A, which is the cathode

C. B, which is the anode

D. B, which is the cathode

37. Base your answer(s) to the following question(s)


on the diagram below, which represents a voltaic
cell at 298 K and 1 atm.

When the switch is closed, which electrode will


attract the sodium ions?

40. Base your answer(s) to the following question(s)


on the information and diagram below.

The apparatus shown in the diagram consists of


two inert platinum electrodes immersed in water.
A small amount of an electrolyte, H2 SO4 , must
Describe the direction of electron ow between the be added to the water for the reaction to take
electrodes when switch S is closed. place. The electrodes are connected to a source
that supplies electricity.

What particles are provided by the electrolyte that


allow an electric current to ow?

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41. Base your answer(s) to the following question(s) 43. Base your answer(s) to the following question(s)
on the diagram below. The diagram shows a on the information below.
voltaic cell with copper and aluminum electrodes
immediately after the external circuit is completed. Underground iron pipes in contact with
moist soil are likely to corrode. This
corrosion can be prevented by applying the
principles of electrochemistry. Connecting
an iron pipe to a magnesium block with a
wire creates an electrochemical cell. The
magnesium block acts as the anode and the
iron pipe acts as the cathode. A diagram of
this system is shown below.

As this voltaic cell operates, the mass of the Al(s)


electrode decreases. Explain, in terms of particles,
why this decrease in mass occurs.

42. Base your answer(s) to the following question(s)


on the information below. State the direction of the ow of electrons between
the electrodes in this cell.
A ashlight can be powered by a
rechargeable nickel-cadmium battery. In
the battery, the anode is Cd(s) and the 44. Base your answer(s) to the following question(s)
cathode is NiO2 (s). The unbalanced equation on the information below.
below represents the reaction that occurs as
the battery produces electricity. When a A voltaic cell with magnesium and copper
nickel-cadmium battery is recharged, the electrodes is shown in the diagram below. The
reverse reaction occurs. copper electrode has a mass of 15.0 grams.
Cd(s) + NiO2 (s) + H2 O(`) ! Cd(OH)2 (s) + Ni(OH)2 (s)
Determine the change in oxidation number for the
element that makes up the anode in the reaction
that produces electricity.

When the switch is closed, the reaction in


the cell begins. The balanced ionic equation for
the reaction in the cell is shown below the cell
diagram. After several hours, the copper electrode
is removed, rinsed with water, and dried. At this
time, the mass of the copper electrode is greater
than 15.0 grams.
State the direction of electron ow through the
wire between the electrodes when the switch is
closed.

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45. Explain, in terms of copper ions and copper 48. When the redox equation Cr3+ (aq)+3Mn(s) !
atoms, why the mass of the copper electrode 2+
Mn (aq) + Cr(s) is completely balanced,
increases as the cell operates. Your response must the coe cient of Cr3+ (aq) will be
include information about both copper ions and
copper atoms.
A. 1 B. 2 C. 3 D. 4

46. Base your answers to the following question(s) on


the information below. 49. Which redox equation is correctly balanced?
The diagram below represents an operating
electrolytic cell used to plate silver onto a nickel A. Cr3+ + Mg ! Cr + Mg2+
key. As the cell operates, oxidation occurs at
the silver electrode and the mass of the silver B. Al3+ + K ! Al + K+
electrode decreases.
C. Sn4+ + H2 ! Sn + 2H+

D. Br2 + Hg ! Hg2+ + 2Br

50. Given the reaction:

2Al0 (s) + 3Ni2+ (aq) ! 2Al3+ (aq) + 3Ni0 (s)

What is the total number of moles of electrons


lost by 2 moles of Al0 (s)?
Identify the cathode in the cell.
A. 6 B. 2 C. 3 D. 8

47. When the redox equation Cr3+ (aq)+3Mn(s) !


2+
Mn (aq) + Cr(s) is completely balanced,
the coe cient of Cr3+ (aq) will be

A. 1 B. 2 C. 3 D. 4

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Redox practice worksheet 05/09/2013

1. 20.
Answer: B Answer: A
2. 21.
Answer: D Answer: D
3. 22.
Answer: A Answer: C
4. 23.
Answer: C Answer: D
5. 24.
Answer: C Answer: C
6. 25.
Answer: C Answer: B
7. 26.
Answer: B Answer: B
8. 27.
Answer: C Answer: D
9. 28.
Answer: C Answer: D
10. 29.
Answer: B Answer: A
11. 30.
Answer: A Answer: D
12. 31.
Answer: B Answer: A
13. 32.
Answer: A Answer: C
14. 33.
Answer: D Answer: C
15. 34.
Answer: A Answer: D
16. 35.
Answer: A Answer: A
17. 36.
Answer: A Answer: B
18. 37.
Answer: C Answer: From the anode to cathode or
half-cell 2 to half-cell 1.
19.
Answer: D 38.
Answer: C
Teacher's Key Page 2

39.
Answer: negative electrode, cathode, or one on
the right

40.
Answer: ions, charged particles, H3 O+ , SO4 2

41.
Answer: Aluminum atoms are losing electrons
and becoming aluminum ions that are
entering the solution.

42.
Answer: from 0 to +2
43.
Answer: Acceptable answers but not limited to:
Electrons ow from the magnesium
block to the iron pipe. Electrons ow
from the Mg to the Fe through the
wire. Electrons ow from the anode to
the cathode in a voltaic cell. from the
block to the pipe

44.
Answer: The electrons ow from the Mg
electrode to the Cu electrode.
from anode to cathode
45.
Answer: Copper ions from the solution are
reduced to copper atoms at the
electrode, increasing the mass of the
electrode.
Copper ions become copper atoms.
The number of copper ions decreases,
and the number of copper atoms
increases.
46.
Answer: Ni(s) key
key
nickel
47.
Answer: B
48.
Answer: B
49.
Answer: D
50.
Answer: A

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