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  • Part 2 - Chemical Reaction Equilibria Tutorial Solutions

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    Solutions for tutorial 1

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    © All Rights Reserved
    Download as PDF or read online from Scribd
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    8 views11 pages

    Part 2 - Chemical Reaction Equilibria Tutorial Solutions

    Uploaded by

    Patrick
    Solutions for tutorial 1

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 11
    ENcHamhy Thermodynamics | 8 Solubens Tot Quection | The ]quilbaum reaction ig ! H =i Sez cg + Os tq = SOx cay Dart from Appecix co} es AG%a55/J.mor' | -300194 [0 _—*| 371060 JAH" p99/J.mol | -296830 0 -395720 A 5.699 3.639 0.000801 | 0.000506 | 0.001056 0 [EOS | -202800 a = CS8es] —$ Co. ~ Cso.] AGiag = —Heco — £0) + 300104 = —FoR6E FT /rol 44a = 315920 —$ Co) 4296626 = —98690 T/mol AA = 8.060 —F (G-634) — 5-699 °.s45 SB = cecowose —+ (0,000 506) —0.C80OB0| =0.ceDD020 sc = © Ab — 202860 + (22900) + lols5c0 —89150 — 46248 In 298, 2 S = 28.5686 as faq@ear + 7 =. A ~ E+@)r+ Se Sr Au ae using cite at 298.15 Kt 2 = -12aste au nk oe S Str + —s SS, a SF ae uae Ink = ae ot 4 Ale Sg ee using older ack 2.98.15 IC ‘ H15.438% x = Nos -eveluat= Ine at 453,.1SK In Kacaus. = Bias . Kees = BB.03645 Bet Ou vTc&) = K a = K A OS A a (@ay". 8, Now fer iden! gases ae remember Pp" Libary Ai = Mo +O0r.€ yo = ————. ¢ fg: =ENneo No +E oO eis —E 1-0,5e y 0.20 —0.SE Oar eee 1 o.Sé& e oo Sse = \—- OSE ne 7 € Ci-0.s€) Os te eee sea a (o20-0s€)" Co.16—e) os 5, €Ci-o.se be eee eananeemeeoee Et —eP Co.20 —-0.S€)” Co.iS—€) é £ce) o.14s3 ~4612 O.4sy ~2426 ON4sS 0.456 O.N4S6 \. Soy O.N4S4 2.460 6+ 0.1452 0.1453 0.1454 0.1455 (0.1456 e fom gmph € = 0.45522 Nous oo S05 AMaes is but ng, = E evauote AH at 452.15 K AW? = —418352 3.mol” asaac Se eS 6 Ab = -142iB 3. mel 0.1457 0.1458 Queston 2 a) the eyullibnum reachen is CaHe Ca) = StH @) + CHy tq) Data from Apperclix Cc? (0.028785 0.014394 -0.000008824 | -0.000004392 | -0.000002164 Pee cere creer) AG" p99 / Jmol" JAH’ peg /J.mol™ 2 = Coated tlc] — Coats] AG, = 68160 —Soteo +24290 = 42290 TImol Ating = 62510 —94620 + 104680 = 92640 Tlmol AA = L424 +1502 —121R = ).UB AB = 0.014394 +0,cO408| — 0.028785 = — ©,0063]) AC = -0,000TO 4342 — 0. 000002164 + 0.00000 8824 =0.00000 2248 ab = oO —4G2ag Ink, = aap ae = -Heeees AW = Pagar +7 AW? = 42 Z+tanr+ r+ S$ B => =z RK using clk ak 298,15 K a. aseq,c83 a seq, ° ; AH T+ 2D Ink = S55 2 4D +o Fe AB a = St 4 AAT + ST OT Ink = _ using deta ab 29815 K ! x = 4.4599 Now evalucte Ink at 625K: InKeas = ORO Wo Kens = 152356 Yeats Pos You. P P Scone aR esta + Ye Seat, Me +O € £0 Boe ye = te Ok Os Bo: 1 mol Ge fei € - You = Sctty = Ire ice U ‘ esis we Cre) e _ # Gear ~ F KE =o Cvg)e—$ C*/p) e= b+ ~*~) subdibite values , € = 0995 ————» the vowed? € is the achona| Conversion ) €& = 0.85 UK er wer K = 2.604 i a Ac Let for) = Gp + adler + Sr + rt 4 28 pT ine 20 = Soe fr Tr Using graph paper z Lo Goo a6 620 —eC.6640 oto 0.1635 660 0.3061 680 0.4445 400 1.1632 Bo THK Quesbon 3 The equilbrum reaction is! Caco, (s) = Cao cs) + CO, 63) Date fom Appenclix < CaCOs Cad CO; [AGP aog/ Jmol | -1128790 604030 -394359 [AH og /J-mot™ -1206920 -635090 -393509 12.572 6.104 3.457 0.002637 0.000443 0.001045 0 0 0 -312000 =104700 -115700 clo]a|> A = (co.} + (cao) — Ceaces) AGigg = 394354 —cotoz0 + 126790 = 130t0] T/mo} Hoag = -393509 — 635090 + 1206920 = !#8321 Timo] AA = S453 + Glo¢ — 12.542 = —LoN AB = ©.001045 + 0.070443 — 0.002634 = —0.00 149 Ac = O Ab = S400 -104F¢00 4+ 312000 = Albom In Koay = TAGs — —S2+ 606] nT AW = S4tper + FT a = e+ @Alr 4 ee ee eel using eda at 21B.ISK | is ZS = 22 co z los > InKo = JS Au" AT Te ny = aa i de a = ae mers: mK = ge ot Alte Sere eT +A + Using deta at 296.1SK } xr = 26.1609 Now each species

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