ORGANIC CHEMISTRY : MS CHOUHAN & TEAM TIME : 35 MIN.

DPP-60

1. No. of possible product shown by given compound ?

S. No. Compound SN1 SN2 E1 E2

(a)
Br

(b)

Br

(c) Cl

Cl

(d)

(e)
Br
Br
(f)

2. Calculate the total number of SN1 + E1 products including stereoisomers ?

S.No. Compound SN1 + E1 products

(a)
Cl

(b) Br

Br
(c)

Br

(d)

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3. Which of following is correctly matched

CH3 +
CH3 +
H2O/H 1
H2O/H 1
(A) H3C–CH2–O–C–CH3 SN (B) H3C–C–CH2 SN
CH3 O

Cl NaNH2
E1
(C) H D KSH
SN
1
(D)
H D Br
CH3

4. Identify correct order of reactivity for SN1 reaction

Br Br Br

(i) (ii) (iii)

(A) i > ii > iii (B) ii > iii > i (C) i > iii > ii (D) iii > i > ii

5. Which of the following is an example of SN1

–  –
(A) CH3Br + OH– 
 CH3–OH + Br– (B) H3C–CH–CH3 + OH CH3–CH–CH3 Br
Br OH

CH3
 H2 O – –
(C) H3 C – CH2 – OH  H2C  CH2 (D) H3C–C–Br + OH (H3C)3C–OH + Br
CH3

ANSWER KEY
1. (a) 2, 1, 3, 3 (b) 3, 1, 3, 1 (c) 1, 1, 0, 0 (d) 2, 1, 1, 1
(e) 3, 1, 3, 1 (f) 3, 1, 4, 3
2. (a) 3+3=6 (b) 4+3=7 (c) 0 (d) 4 + 2 = 6
3. A 4. C 5. D

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