ORGANIC CHEMISTRY : MS CHOUHAN & TEAM TIME : 35 MIN.

DPP-57
Dear Students,
This DPP gives you an idea about products obtained in elimination reaction (including stereochemistry).
(A) Dehydrohalogenation
TOTAL PRODUCTS
Excluding Stereo isomer Including Stereo isomer

alc. KOH
1. Br
E2

alc. KOH
2. E2
Br

alc. KOH
3.
E2
Br

alc. KOH
4. E2
Br

Br

5. alc. KOH
E2

Br alc. KOH
6. E2

Cl

7. alc. KOH
E2

Cl
8. alc. KOH
E2

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 (B) Dehydration of alcohol
Excluding Stereo isomer Including Stereo isomer

+
H
9. (E1)
OH

+
H
10. (E1)
OH

OH
+
11. H
(E1)

+
H
12. (E1)
OH

OH
+
13. Ph H
(E1)

OH
+
14. H
(E1)

15. Total number of products of chlorination of ethane including and excluding stereoisomers respectively.
(A) 6, 7 (B) 9, 10 (C) 9, 9 (D) 8, 9

16. H2SO4
Product is

OH

(A) (B)

(C) (D)

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 O
17. H2SO4
Product is
H 2O

O
(A) (B)

OH

(C) (D) None of these

HO

1.excess CH3I/K2CO3
18. Product
2.Ag2O, H2O
N 3. 
H

(A) H2C=CH–CH2–CH=CH2 (B) H2C=CH–CH2–CH2–CH2–CH=CH2

(C) H 3C–N–CH 2–CH 2–CH=CH 2 (D) H3C–N–CH=CH–CH=CH2

CH3 CH 3

ANSWER KEY
(A) Excluding Stereo Including Stereo (B) Excluding Stereo Including Stereo
1. 1 1 9. 2 3
2. 2 3 10. 3 3
3. 2 2 11. 5 6
4. 2 4 12. 2 2
5. 3 4 13. 2 3
6. 3 5 14. 2 3
7. 3 4
8. 1 1
15. C 16. A 17. C 18. A

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