NEET SAMPLE PAPER

NEET
SAMPLE PAPER

CHEMISTRY
QUESTION PAPER

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1. Standard reduction potentials of the half reactions are given below :

F2(g) + 2e–  2F–(aq) : E° = +2.85 V
Cl2(g) + 2e–  2Cl–(aq) : E° = +1.36 V
Br2(g) + 2e–  2Br–(aq) : E° = +1.06 V
I2(g) + 2e–  2I–(aq) : E° = +0.53 V
The strongest oxidising and reducing agents respectively are :
(A) Cl2 and Br– (B) Cl2 and I2 (C) F2 and I– (D) Br2 and Cl–

2. Structure of a mixed oxide is cubic close-packed (c.c.p.). The cubic unit cell of mixed oxide is composed of oxide ions.
One fourth of the tetrahedral voids are occupied by divalent metal A and the octahedral voids are occupied by a
monovalent metal B. The formula of the oxide is :
(A) A2B3O4 (B) AB2O2 (C) ABO2 (D) A2BO2

3. The orbital angular momentum of a p-electron is given as :-

3h h h h
(A) (B) 6. (C) (D) 3.
2 2 2 2

4. Two gase A and B having the same volume diffuse through a porous partition in 20 and 10 seconds respectively. The
molecular mass of A is 49u. Molecular mass of B will be :-
(A) 50.00 u (B) 12.25 u (C) 6.50 u (D) 25.00 u

5. 25.3 g of sodium carbonate. Na2CO3 is dissolved in enough water to make 250 mL of solution. If sodium carbonate
dissociates completely, molar concentration of sodium ion, Na+ and carbonate ions. CO32 are respectively (Molar
mass of Na2CO3 = 106 g mol–1)
(A) 0.477 M and 0.477 M (B) 0.955 M and 1.910 M (C) 1.910 M and 0.955 M (D) 1.90 M and 1.910 M

6. The number of atoms in 0.1 mol of a triatomic gas is :- (NA = 6.02 × 1023 mol–1)
(A) 1.800 × 1022 (B) 6.026 × 1022 (C) 1.806 × 1023 (D) 3.600 × 1023

7. If E Fe2 / Fe  0.441 V and


E Fe3
/ Fe2 
 0.771 V, the standard EMF of the reaction : Fe + 2Fe3+  3Fe2+ will be :-
(A) 0.330 V (B) 1.653 V (C) 1.212 V (D) 0.111 V

8. The correct order of decreasing acid strength of trichloroacetic acid (A), trifluoroacetic acid (B), acetic acid (C) and
formic acid (D) is :
(A) A > B > C > D (B) A > C > B > D (C) B > A > D > C (D) B > D > C > A

9. Predict the product in the given reaction.

CHO

50% KOH

Cl

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CH2OH COO CH2OH COO

+ +
(A) (B)
Cl Cl OH OH

CH2OH CH2COO CH2OH OH

+ +
(C) (D)
Cl Cl OH OH
10. Which of the following is not a fat soluble vitamin ?
(A) Vitamin A (B) Vitamin B complex (C) Vitamin D (D) Vitamin E

11. Consider the reaction :

C2 H5 OH
(i) (CH 3 )2 CH  CH 2 Br  (CH3 )2 CH  CH 2 OC2 H5  HBr

C 2 H5 O
(ii) (CH 3 )2 CH  CH 2 Br  (CH 3 ) 2 CH  CH 2 OC 2 H5  Br 
The mechanisms of reaction (i) and (ii) are respectively :-
(A) SN2 and SN1 (B) SN1 and SN2 (C) SN1 and SN1 (D) SN 2 and SN2

12. In a set of reactions, ethyl benzene yielded a product D

CH2CH3
KMnO 4 Br2 C2H5OH
KOH
B FeCl3
C H+
D

‘D’ would be :-

COOC2H5
CH2 CH COOC2H5
(A) (B) Br
Br

Br
COOH

(C) (D)
Br
OCH2CH3
CH2COOC2H5

13. Which of the following reactions will not result in the formation of carbon-carbon bonds ?
(A) Friedel-Crafts acylation (B) Reimer-Tieman reaction
(C) Cannizaro reaction (D) Wurtz reaction

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14. The correct order of increasing reactivity of C–X bond towards nucleophile in the following compounds is :-

X X
NO2
(CH3 )3C X (CH3)3CH X

NO2
(I) (II) (III) (IV)

(A) III < II < I < IV (B) I < II < IV < III (C) II < III < I < IV (D) IV < III < I < II

15. In which of the following molecules all the bonds are not equal :-
(A) CIF3 (B) BF3 (C) AlF3 (D) NF3

16. Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them :
(A) C 22   He 2  O 2  NO (B) He 2  O 2  NO  C 22

(C) NO  O 2  C 22  He 2 (D) O 2  NO  C 22  He 2

17. In which of the following arrangements the given sequence is not strictly according to the property indicated
against it ?

(A) NH 3  PH3  AsH 3  SbH 3 : (B) CO 2  SiO 2  SnO 2  PbO 2 :

Increasing acidic character Increasing oxidising power

(C) HF  HCl  HBr  HI : (D) H 2 O  H 2S  H 2Se  H 2 Te :

Increasing acidic strength Increasing pK a values

18. Which of the statements is not true ?

(A) K2Cr2O7 solution in acidic medium is orange
(B) K2Cr2O7 solution becomes yellow on increasing the pH beyond 7
(C) On passing H2S through acidified K2Cr2O7 solution, a milky colour is observed
(D) Na2Cr2O7 is preferred over K2Cr2O7 in volumetric analysis

19. Which one of the alkali metals, forms only, the normal oxide. M2O on heating in air ?
(A) Li (B) Na (C) Rb (D) K

20. What is the value of electron gain enthalpy of Na+ if IE1 of Na = 5.1 eV :-
(A) +0.2 eV (B) –5.1 eV (C) –10.2 eV (D) +2.55 eV

21. Which of the following carbonyls will have the strongest C–O bond ?
(A) Fe(CO)5 (B) Mn(CO)6+ (C) Cr(CO)6 (D) V(CO)6–

22. Which of the following alkaline earth metal sulphates has hydration enthalpy higher than the lattice enthalpy ?
(A) SrSO4 (B) CaSO4 (C) BeSO4 (D) BaSO4

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1 mole
23. PhCH 2 OPh 
conc.HI
product . Final product is :-
(a) PhCH2OH (b) PhCH2I (c) PhOH (d) Ph–I
(A) a, c (B) a, d (C) b, d (D) b, c

24. Gabriel phthalamide synthesis is used for preparation of :-

(A) RNH2 (B) R2NH (C) R3N (D) PhNH2

NaCN Ni / H 2 Acetic
25. CH 3 CH 2 Cl   X   Y 
anhydride
Z
Z is :-
(A) CH3CH2CH2NH2 (B) CH3CH2CH2NHCOCH3 (C) CH3CH2NHCOCH3 (D) CH3CH2CH2CONHCH3

26. Match list one (I) and two (II) and select the correct answer using the codes given below the lists :-
List-I List-II
(a) Nylon (i) Polyester
(b) Terylene (ii) Polytetra fluoroethylene
(c) Teflon (iii) Synthetic rubber
(d) Neoprene (iv) Polyamide
(a) (b) (c) (d)
(A) ii iii i iv
(B) ii iii iv i
(C) iv i iii ii
(D) iv i ii iii

27. Which of the following samples contains the largest number of atoms ?
(A) 1 g of Ni(s) (B) 1 g of Ca(s) (C) 1 g of N2(g) (D) 1 g of B(s)

28. In how many elements does the outer most electron has quantum numbers n = 4,  = 0, m = +1
(A) 2 (B) 14 (C) 0 (D) 12

29. Calculate the molar solubility of AgCl in a 1 L solution which contains 10.0 g of CaCl2 [Ksp (AgCl) = 1.6 × 10–10]
(A) 8.9 × 10–10 (B) 8.9 × 10–11 (C) 8.9 × 10–9 (D) 8.9 × 10–12

30. Which of the following solutions has the highest pH ?

(A) 0.10 M KNO3 (B) 0.10 M AlCl3 (C) 0.10 M NH4Cl (D) 0.10 M CH3NH2

31. Given that G° for the reaction below is –5.40 kJ mol–1, calculate G at 298 K when the pressure is 0.50 atm for NO2(g)
and 2.0 atm for N2O4(g) . 2NO 2 N 2O 4
(A) –250 J mol–1 (B) –8800 J mol–1 (C) –1900 J mol–1 (D) –11000 J mol–1

32. Which is correct statement :-

(A) Benzyl amine is more basic than acetanilide
(B) Nitrobenzene is purified by steam-distillation method
(C) Aniline does not prepare from Gabriel phthalimide reaction but it gives Hoffmann’s isocyanide test
(D) All the above

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33. Glucose CH2OH – (CHOH)4 – CHO, on oxidation with HIO4 gives :-
(A) Six moles of HCOOH (B) Five moles of HCOOH + one mole of HCHO
(C) Four moles of HCOOH + two moles of HCHO (D) Six moles of HCHO

34. CH3NH2 + CHCl3 + KOH  Pungent smell compound + KCl + H2O.

Pungent smelling compound is :-
   
(A) CH3 – C  N (B) CH3 – NH – CH3 (C) CH 3  N  C (D) CH 3  N  C

35. Which of the following arrangements of electrons is mostly likely to be stable ? (z  30 for this atom) :-

3d 4s 3d 4s
(A) (B)

3d 4s 3d 4s
(C) (D)

36. The value of vander Waal’s constant ‘a’ for the gases O2N2, NH3 and CH4 are 1.360, 1.390, 4.170 and 2.253 L2 atm
mol–2 respectively. The gas which can most easily be liquified is :-
(A) O2 (B) N2 (C) NH3 (D) CH4

37. In the standardization of Na2S2O3, using K2Cr2O7 by iodometry, the equivalent weight of K2Cr2O7 is :-
(A) (Molecular weight)/2 (B) (Molecular weight)/6 (C) (Molecular weight)/3 (D) Same as molecular weight

38. When the same amount of zinc is treated separately with excess of sulphuric acid and excess of sodium hydroxide,
the ratio of volumes of hydrogen evolved is :-
(A) 1 : 1 (B) 1 : 2 (C) 2 : 1 (D) 9 : 4

39. Metal are generally hard, opaque, shiny and good conductor of heat and electricity. Which of the following
elements has highest density ?
(A) Os (B) Ir (C) Fe (D) Ru

40. Arrange these substrate in case of dehydration.

H
OH OH OH OH
(I) (II) (III) (IV)

(A) I < II < III < IV (B) III < IV < II < I (C) I < II < IV < III (D) II < III < IV < I

41. [Co(NH3)4(NO2)2] Cl exhibits

(A) ionisation isomerism, geometrical isomerism and optical isomerism
(B) linkage isomerism, geometrical isomerism and optical isomerism
(C) linkage isomerism, ionisatin isomerism and optical isomerism
(D) linkage isomerism, ionisation isomerism and geometrical isomerism

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42. Select correct statements and choose the correct code out of the following.
I. CH3 – C – CH3 angle in (CH3)2C = CH2 is smaller and the CH3 – C = CH2 angle is larger than trigonal 120°.
II. O – I – F angle is less than 90° (89°) in IOF4 .
III. In SeOCl2 , Cl – Se – Cl angle is less than the Cl – Se – O angle.
IV. POCl3 is tetrahedral with a double bond between P and O, there is no lone pair on central atom.
(A) I and II are correct (B) II and III are correct (C) I, II and III are correct (D) All are correct

43. Carbon sub-oxide (C3O2) has recently been shown as a component of the atmosphere of Venus. Which of the
following formulation represents the correct ground state Lewis structure for carbon suboxide ?
(A) O C C C O (B) O C C C O (C) O C C C O (D) O C C C O

44. Which graph represents auto catalysis ?

% Reaction

% Reaction

% Reaction

% Reaction
(A) (B) (C) (D)

Time Time Time Time

45. On the basis of different possible values of ,  and  and different axial distances or edge lengths a, b and c
following seven types of three dimensional primitive cells or crystal systems. Which of the following represents
triclinic crystal ?
(A) a = b = c,  = 90° (B) a  b = c,  = 90°
(C) a  b  c,  = 90° (D) a  b  c,   90°

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