JEE (MAIN

JEE (Main + ADVANCED)

+ Advanced) 2023
2023
GUIDED REVISION LEADER + ENTHUSIAST COURSE
LEADER + ENTHUSIAST COURSE

ORGANIC CHEMISTRY GR # 08 GUIDED REVISION PLAN

Only one correct :

1. Select the incorrect statement about Nylon 2-nylon-6 :
(A) It is a copolymer

(B) It is biodegradable

(C) It is an alternating polyamide

(D) It is made up of CH 3 CH COOH and H2N(CH2)5COOH
|
NH 2

2. When N and S both present the Lassaignes test is sometimes incomplete due to formation of
(A) Na(CNS) (B) Na(NCS) (C) NaCN (D) Na2S
3. Which of the vitamins given below is water soluble?

(A) Vitamin E (B) Vitamin K (C) Vitamin C (D) Vitamin D

OCOCH3
COOH
4. is used as :

(A) Insecticide (B) Antacid (C) Antihistamine (D) Analgesic

5. Which of the following is an anionic detergent ?
(A) Glyceryl oleate (B) Sodium stearate
(C) Sodium lauryl sulphate (D) Cetyltrimethyl ammonium bromide
HCO 3H H3O Pthalic Anhydride
6. Acetophenone A B+C Indicator (D) ; C & D are :
H

(A) CH3OH & (B) PhOH &

(C) PhOH & (D) CH3OH &

ORGANIC CHEMISTRY / GR # 08 (Set-3) E-1/4

 JEE (MAIN + ADVANCED) 2023
GUIDED REVISION LEADER + ENTHUSIAST COURSE

7. ? Product is:

(A) (B)

(C) (D) No reaction

8. A solution of (+) -1-chloro-1-phenylethane in toluene racemises slowly in the presence of small amount
of SbCl5, due to the formation of:
(A) Carbanion (B) Carbene (C) Free-radical (D) Carbocation
9. Identify the set of reagents / reaction conditions 'X' and 'Y' in the following set of transformation:
X Y
CH3 – CH2 – CH2Br Product CH 3 CH CH 3
|
Br
(A) X = dilute aqueous NaOH, 20°C; Y = HBr / acetic acid, 20°C
(B) X = concentrated alcoholic NaOH, 80°C; Y = HBr/ acetic acid 20°C
(C) X = dilute aqueous NaOH, 20°C; Y = Br2 / CHCl3, 0°C
(D) X = concentrated alcoholic NaOH, 80°C; Y = Br2/CHCl3, 0°C
+
H / KMnO 4
10. A B Phthalic Anhydride ; A is :
Me Me
Me
(A) (B) (C) (D)
Me Me Me
Me
11. Consider the reaction of HI with the following:

I. II

Which forms di-iodide on reaction with HI (excess)?

(A) I and II both (B) II only (C) I only (D) none

ORGANIC CHEMISTRY / GR # 08 (Set-3) E-2/4

 JEE (MAIN + ADVANCED) 2023
GUIDED REVISION LEADER + ENTHUSIAST COURSE

12. Cellulose upon acetylation with excess acetic anhydride / H2SO4 (catalytic) gives cellulose triacetate
whose structure is :
AcO
AcO
H O O–
H O O– H
H AcO
AcO OH H
OAc H H O O H
H O O H H
H AcO
AcO OH H H OH
OAc H H OAc O O
O O H H H
H H H
OH H H OH
OAc H H OAc
(A) –O
(B) –O H
H
H OH
H OAc
AcO AcO AcO AcO AcO
O H H O H AcO
H H
H
H O O–
H H O H H O H H
H O O–
(C) OAc H OAc H OAc H
(D) H H
H
H
H
–O O O H H H
H –O O O
H H
OAc H OAc H OAc OAc OAc OAc OAc OAc OAc
13. The reactivity of compound Z with different halogens under appropriate conditions is given
below :
OH
mono halo substituted derivative when X2=l2
X2
di halo substituted derivative when X2=Br2
C(CH3)3
Z tri halo substituted derivative when X2=Cl2

The observed pattern of electrophilic substitution can be explained by -

(A) The steric effect of the halogen (B) The steric effect of the tert-butyl group
(C) The electronic effect of the phenolic group (D) The electronic effect of the turt-butyl group
Matrix Match Type :
14. Match the column-
Column-I Column-II
COOEt (1) EtONa
(A) Ph–CHO + CH2 (2)H3O / (P) Perkin’s reaction.
COOEt
(1) Zn
(B) Ph–CHO + CH2–COOCH3 (2) H3O /
(Q) Reformatskii reaction.
Br

(C) Ph–CHO + CH3COOCOCH3 (1)CH3COONa /

(R) Product is a carboxylic acid with aromatic ring
(2)H3O /

O O within the same molecule.

(D) Ph–C–C–Ph + NaOH (2) H

(S) Double bond equivalent of the product formed

is less than or equal to 8.

(T) The major product cannot show optical isomerism

ORGANIC CHEMISTRY / GR # 08 (Set-3) E-3/4

 JEE (MAIN + ADVANCED) 2023
GUIDED REVISION LEADER + ENTHUSIAST COURSE

15. Match the column

Column I Column II
(Component of mixture) (Reagent)

(A) Crystalline Na2CO3 + (P) Fehling solution

Sodium citrate + CuSO4(aq. sol.)

(B) CuSO4 + Rochelle Salt + NaOH(Aq. sol.) (Q) Nesseler's Reagent

(C) 10% - naphthol in alcohol (R) Bennedict's solution

(D) HgCl + KI + KOH (aq. sol.) (S) Molisch's Reagent

ORGANIC CHEMISTRY / GR # 08 (Set-3) E-4/4