SAHAJANAND ENGLISH MEDIUM SCHOOL VISNAGAR

chemical kinetics Std 12 : Chemistry Date : 17/02/24

Total Marks :50 marks Unit Test Time : 90 Minutes
Section A
//X
• Choose correct answer from the given options. [Each carries 1 Mark] [10]

1. ……… does not give Cannizzaro reaction.

CHO
(A) (B) CHO (C) HCHO (D) CH3CHO
CH3

2. In clemmensen reduction, carbonyl compound react with…..

(A) Zn(Hg) + HCl (B) Na(Hg) + HCl (C) Zn(Hg) + HNO3 (D) Na(Hg) + HNO3

3. Which of the following is not true for Tollen's reagent ?

(A) Tollen's reagent only react with ketone compounds.
(B) Tollen's reagent is a solution of ammoniated silver nitrate solution.
(C) Tollen's test is a test of aldehyde compound.
(D) In Tollen's test Ag+ of Tollen's reagent is reduced to Ag.
4. 40%
H2SO4 Isomerisation
CH3 – C º CH A CH3 – C – CH 3
1%
HgSO4 O
Structure of ‘A’ and type of isomerism in the above reaction are respectively.
(A) Prop-1-en-2-ol, metamerism (B) Prop-1-en-1-ol, tautomerism
(C) Prop-2-en-2-ol, geometrical isomerism (D) Prop-1-en-2-ol, tautomerism
5. The reagent which does not react with both, acetone and benzaldehyde ?
(A) Sodium hydrogen sulphite (B) Phenyl hydrazine
(C) Fehling’s solution (D) Grignard reagent

6. Which product is formed when the compound CHO is treated with concentrated aqueous
KOH solution ?
O
+ ||
(A) KO CHO (B) +
CHO – OK + CH2OH

O O
+ || + + || + +
(C) KO C – OK+ + KO OK (D) C – KO + OK

P2O5 , D
7. CH3COOH ¾¾¾¾® P (main product),
then what is P in the reaction ?
(A) CH3CH2OH (B) (CH3CO)2O (C) CH3CHO (D) CH3COOC2H5

8. Among the following which reaction is not true for the production of butanoic acid ?
Tollens
(A) CH3CH2CH2CHO ¾¾¾¾¾
® CH CH CH COOH
3 2 2
reagent
CrO – H SO
(B) CH3 CH2CH2CH2 OH ¾¾¾¾¾¾¾
3 2 4¾
® CH3CH2 CH2COOH
Jones reagent
H O+
(C) CH3 CH2 CH2CONH2¾¾¾¾
3 ®
CH3 CH2CH2COOH
D
H O+
(D) CH3 CH2CH2CH2Cl¾¾¾¾
3 ® CH CH CH COOH
3 2 2
Wish You - All The Best
 H O+
(C) CH3 CH2 CH2CONH2¾¾¾¾
3 ®
CH3 CH2CH2COOH
D
H O+
(D) CH3 CH2CH2CH2Cl¾¾¾¾
3 ® CH CH CH COOH
3 2 2

9. Which of the following compounds undergo aldol condensation ?

(A) H – CHO (B) –CO – CH3 (C) –CHO (D) –CO–

1.dil. NaOH
10. Ethanal + Benzaldehyde ¾¾¾¾¾¾® X
2. D ; - H 2O
identify product “X”.
(A) 3-phenyl prop-2-enal (B) 3-phenyl propanal
(C) 3-phenyl prop-2-enol (D) 2-phenyl prop-2-enal

Section B
//X
• Write the answer of the following questions. [Each carries 2 Marks] [12]

1. Write method for the preparation of aldehyde and ketone by dehydration of alcohol compound.
2. Write reaction of (a) acetaldehyde and (b) acetone with (i) NaHSO3 (ii) HCN

3. Write method of preparation of primary alcohol by reduction of aldehyde.

4. Write reaction of phthelic acid with ammonia.
5. Give importance of carbonyl compounds.
6. Write reactions to prepare carboxylic acid from amide compound.

Section C
//X
• Write the answer of the following questions. [Each carries 3 Marks] [9]

7. Give preparation of aldehyde and ketone compounds using Grignard reagent.

8. Give reaction of ethenal with (a) ethanol and (b) with ethylene glycol in presence of dry HCl.
9. Write about Wolff-Kishner reduction.

Section D
//X
• Write the answer of the following questions. [Each carries 4 Marks] [8]

10. Write about aldol condensation reaction.

11. Write about Cannizzaro reaction.

Wish You - All The Best