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(B) It is biodegradable
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2. When N and S both present the Lassaignes test is sometimes incomplete due to formation of
(A) Na(CNS) (B) Na(NCS) (C) NaCN (D) Na2S
3. Which of the vitamins given below is water soluble?
OCOCH3
COOH
4.
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is used as :
7. ? Product is:
(A) (B)
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8. A solution of (+) -1-chloro-1-phenylethane in toluene racemises slowly in the presence of small amount
of SbCl5, due to the formation of:
(A) Carbanion (B) Carbene (C) Free-radical (D) Carbocation
9. Identify the set of reagents / reaction conditions 'X' and 'Y' in the following set of transformation:
X Y
CH3 – CH2 – CH2Br Product CH 3 CH CH 3
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Br
(A) X = dilute aqueous NaOH, 20°C; Y = HBr / acetic acid, 20°C
(B) X = concentrated alcoholic NaOH, 80°C; Y = HBr/ acetic acid 20°C
(C) X = dilute aqueous NaOH, 20°C; Y = Br2 / CHCl3, 0°C
(D) X = concentrated alcoholic NaOH, 80°C; Y = Br2/CHCl3, 0°C
+
H / KMnO4
10. A B Pthlic Anhydride ; A is :
Me Me
Me
(A) (B) (C) (D)
Me Me Me
Me
11. Consider the reaction of HI with the following:
I. II
12. Cellulose upon acetylation with excess acetic anhydride / H2SO4 (catalytic) gives cellulose triacetate
whose structure is :
AcO
AcO
H O O–
H O O– H
H AcO
AcO OH H
OAc H H O O H
H O O H H
H AcO
AcO OH H H OH
OAc H H OAc O O
O O H H H
H H H
OH H H OH
OAc H H OAc
(A) –O
(B) –O H
H
H OH
H OAc
AcO AcO AcO AcO AcO
O H H O H AcO
H H
H
H O O–
H H O H H O H H
H O O–
(C) OAc H OAc H OAc H
(D) H H
H
H
H
–O O H
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O H –O O H H
O H
H OAc H OAc H OAc OAc OAc OAc OAc OAc OAc
13. The reactivity of compound Z with different halogens under appropriate conditions is given
below :
OH
mono halo substituted derivative when X2=l2
X2
di halo substituted derivative when X2=Br2
C(CH3)3
Br
(1)CH3COONa /
(C) Ph–CHO + CH3COOCOCH3
(R) Product is a carboxylic acid with aromatic ring
(2)H3O /
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(D) HgCl + KI + KOH (aq. sol.) (S) Molisch's Reagent