One litre of a mixture of O2 and O3 at STP was allowed to react with an

excess of acidified solution of KI. The iodine liberated required 40 mL of

M/10 sodium thiosulphate solution for titration. What is the weight per cent
of ozone in the mixture?
1.00 g of a moist sample of a mixture of KCl and KClO3 was dissolved in water and made up to 250 mL. 25
mL of this solution was treated with SO2 to reduce the chlorate to chloride and excess SO2 was removed by
boiling. The total chloride was precipitated as silver chloride. The weight of the precipitate was 0.1435 g. In
another experiment, 25 mL of the original solution was heated with 30 mL of 0.2 N solution of ferrous
sulphate and unreacted ferrous sulphate required 37.5 mL of 0.08 N solution of an oxidising agent for
complete oxidation. Calculate the molar ratio of chlorate to chloride in the given mixture.
A sample of hydrazine sulphate N2H6SO4 was dissolved in 100 mL of water. 10 mL of this solution was
reacted with excess of ferric chloride solution and warmed to complete the reaction. Ferrous ion formed
was estimated and it required 20 mL of M/50 potassium permanganate solution. Estimate the amount of
hydrazine sulphate in one litre of the solution.
An aqueous solution containing 0.30 g of KIO3 (214 u) was treated with excess of KI solution. The solution was acidified
with HCl. The liberated iodine consumed 45 mL of thiosulphate solution to decolourize the blue starch-iodine complex.
Calculate the molarity of sodium thiosulphate solution.
20 mL of M/60 solution of KBrO3 was added to a certain volume of SeO32- solution. Br2 evolved was
removed by boiling and the excess KBrO3 was back titrated with 5.1 mL of M/25 solution of NaAsO2.
Calculate the weight (in mg) of SeO32- in the solution. [Se = 79 u]