DWALY Pda CA CHEM Aralysts of Group IV Conus @ A Guice. Ingormanien- «AIR ee Giroup” ov * agmmonlm Caveonate Grp” = Tce fons form insoluble carbonates @BepP Mg tt Ly cats of careenle- acids > Jone of. Baty SEA) CA Mg ax OmECHVE OF EXPERIMENT V D seperate £ idemity muse fox Group N cAtons eo Ger precipitant 5wu Nitucy armmoniim chloride, 15M NIV 4O" ammoniym vydeondte Cure) 2. cos ammotivn —carkorstt po eas Fest Colvvons : Ug (vos)2 — Magnestim vitae 88 CNOs)2 Barium Nitfare Se (NOs), StroAtun Nirah Ca (Nos): Calum Nitrete Menions Foe THE DETENTION OF REV IV ions A. Flawe Tes} B. Precigttahion~ corwmation af white Solids COMBINATION “FORTHE SCHEMATIC. Rain + SHOAIU ( eel Castillo) franium + Calcium Cqeve)d) Barium + Magnesium (torn) Stroqtiom + Magmesim (v4) Ca\civn + magnesium (gatan) Calcium + Grantion (Galan)EXP. Anarysis of GI tons ® © Prep of “Uaenoun” galthion Ame tg (Nos): Amt 8a (NO3)2 te St CnOs)1 Tm Ca (Nos) + Add distilteA WoO unt mL © Teansrer \enoon” = prepped @ PRECIPTTATION OF GIV Cations 3.\) 0 Teameger mL of yaengan Gol Ih a Wal © Add Amt 5A ammyncaiumeCiionide drupiaise We Why cl Cammontin hydride) © reducers OW- concumrahon of he why’on and tus prevents precipitation oF Mg (OH) 2 ® Add red Vitmoe paper * AAA Is M aranomun Hydroxide dropwise Umit wasic (red blue) © Rad 3 extra Arps aummternlnyaroetde * NEG Ol make fe Sowell asic nae von © prevent yds of (com) 2 Ne Capittion of a ted g adden of he He end te Wydrortde awion of water) © lreaks Londs @ Pelraces « “7 2 Heat coluhon 42 ALMOST oiling (x 00 Nor BOIL) ? ORDA Amml of SeatOnTUM COT beKatE, \ x wmdacos "SON of (CO3)°L to precipitate Unie precipitate fovms x o Let Soluiryn gla por a PeBSt Cwnins to cmplete fle peccipitahon 8 Come guge© Crest gor compreteness of precipitation) © > Add feud drops of ammaniim carkawrate +0 WM Ceniguptd xture % AF cloudiness fons, Sr, yarw, gently, Haun cent elf again % REPEAT UNTIL WO LORE cLove\NEsS FORMS) ° Hecont supernatimtatiquid ave ceyoe for TEST for MecweCUny, Lim Cereae quid akore overlying Moterisl via Setting, precipitalinn pene (qradvatly pour Pre ligutoe pen one Container fo awotiar yout disturbing Rae sediment) ° Valet Supernatant liquid. fer procedure C CONFIRMATORY WEBUATIONS © eatvos}. ORL), COs —b Bacos | F ANY NOs nite Q@ se (Weg d © (Wha) C4 — Seco; ye @NAANOS ite (2 (NOs) CF (Ni) 2 COs > .Ca.COs b HaWthy NO, ‘white > wiite per 1s COmpered op Fao, , Sr COs, Ca COs > Mg! does not form a carbonate , Pax, comaiar in tee CURE Maa Vital D washiig of PPT o * Wash ppt wo/ Ame dstitd water » Centofune * Discard svpernstont Hgutd used in washing, P ReCIE Sheps por and waching > washed ped Test ee BARI ION © Rad GV seeHelBIA dcopmIst Until cold (s fissolved - Or ut io drope Wave been add (Cah Be nUMmvEm oF AMES) sie: c 240 add SCITY Lat oe Jo He extent frat fe Mon will eecowe acidic. eine BaCrO% 4 WW solve fo acidic. gotutin© Add equal number of dps gor 3M amnmonivemacatate? Le & Ny be. © ° fo Wffer USS HOKE by decreasing HY eoneyntrantn, © ted distilled Water Amt. © Contriuge F Discard colids v 4rere aft, Save ft Gpernatant liquid © Heat to woiling © Add Me drop of IM potassium chromate HAE ppt gorms, eat again and add Grd Ame oF IM potascion chromate © WO Ppt BARIUM AS =ABSENT. Treat sol lay 62 (ro idea wrote B2 to! A Check Hmestamp Q:gc, f vet us eros) Centauge © (Supernatant should be gelian’) “Waioritss, teil ad 9°4 oop oF IU petasmion chromate. cee 4 We cuperratant © Yella», decant aed great with 62 © Laloel superiatant gor Bz © Wash PRY Hwice with dyn distilled water. Discard washings , * Yellow) gpk of aru chromate CONFIRMATORY EaUATIGNS © eacog ea GrOq crpace og} FT +H c0s-2 getles © Dissolve yellav ppt ie mL GM HCL ace 0, = © pacroy + ane BEC2 +H, Cr Oy (C Flame! Test gor gant lon Uslg Rat gupecnatent gor 62") © AAA 2 AMPS of GM Qipie acid to fre «olution © Contnipuge ° White pyr congicms Barium lonCONFIRVATORY "EQUATION © © wag rRsoy = BelOy | + AHCI bite pet TEST FoR STRONTIUM ION) © Adjust volume to 2m either wy eWaperatian or dilvhoa Ce decrease eoncontiahon Va) ad@ing vnore . SoWent Clite varer) Add 15 drops of spieyhanolsmine” (TER) Le gooms more stable complex ton with Cats dhan cc t+, Thus, Under Heese condthoy | SeSOy precipitate oF bt Casoy remaiiit {a He olvhon ® Stic with fod uri (aoenogenous CONFIRNISTORY EQUETION © Gort ran CerqOh snr ca LN CceoH) se Tex Caleiun TER Comprex 2 Ada tm of 2M armani syiEate * Sie and boi) © Combriuge % ‘Wulaite ppt Conginms tron ton « CONFIRMATORY EQUATION” ® See CHR: Soy > srSoy bP AN YT tulnite. © Decant SuREMatart toad filter, Save FH for Bs, * Wash pet tunce with tml distilled water, Centepuge. S Add tml awmmonivm Catkonate , meat, Stic, @ySrSOqry Cathy), COs —e SeCos b+ (Nae SOy waiteTEST FoR CALCIUM iON) © 2 Add 10 dps 0-2M armmonim oxalate to gittered sol. Bs 2 Comtripge , decant g discard Hee supernaioor 1iquid CONRRMIATORY "ESUKTION @ & Cwcortyowls] * (N22 Ce Oy = Coczou b+ TEs ( white * yey P Cerop ial why ts 1 We6) (uitun e488) TEST FOR MAGNESIUM ON 2 AAA S Amps ISM ammonin Wydrride to Ae supernatant fm ppt OF Group IW Coheny © Add 20 drops of O-£M disodivm hydrogen phosphate ° Mix. Stand for alas 10 ming © CentifUHe..Discarcl supernatant quid | Wash HICK Va tm portions . ONFIRMATORYHEAUATION Mat + Wikyok + OW P04 —- Ri 4 ay HPO4 wg hituitan VeRO mag ts Cums no fergormed due to lace of cao reagent) Man Ha fou + 2RCV rug tle + aM + NY POY Ma Cleon A N20H ang Comet a aNaN vite gulakaes ptGray N Canons Bs rt, set! a", Mgtt BM wiycl 15M nity oH Wu) 2 coy, PPE BaCOs, SrCO9, Cates GM RO be 3M ity Re 1M erCroy Sern. Pets Sct, Gi ba Grou Telethanolamine GEA) NCCeRRONDS Cnty) Sow GM fel y re Sel'ns Cate att —F S504 ‘orm e & F Onaga a ‘ah F (a), Ws Ray | \ Pres pa Su yulo- secos onite yt Were tare ou aa re ae Ng ** |. 15 NAY on 0.54 waLHPoy Ppt: Mg Wit, Py i Guncy S20 reagen) GU Naoy Mg Conde (white) + dupe Cove) \ Ma pres[Branyas o¢ Grade IV caxons CFteme rest) ] Preparanon oF Concentrated ‘ondun Selwhon’ Cwore concentrated ais 8 Bank Nate © hdd A dep of PotassIUN Chiomate. * Barilm chromate (yellad ppt) © Heat St rey a ees © Steontium iteate © Kdd Ame of aenmoninn sulgate end anmonvn cartoonae * Stroakiven sulgate Then to strontium carkonete ume ppt) © heat oR) 2 A OM «es Boe ot nw © Calcium Nitrate. 9 Add tw of aummtoniim pyalate = Calcium ox aiste Cumie Per) & centriage aA THREE D Cu TALL AS @ Cecant atl THREE D © GMHCL & AdA HC\ to fe pers Csolutione Fam prewious experiments (pages age) 2 Pee new more corcemiated ones | Fue test Borimmarreshesotwt) = yetan green pone anion Cod sot) (us nas mo Sent CEresSolvhion) = orimson ved Steontium (Ord qpon) cite wale rim GolcivenlsesmetOE) ~ dp red foragered Colom (Ore SoH) sais «4s