OBJECTIVE PROBLEMS (JEE MAIN) 1. a There is no S-S bond in (A) S,0," (8) 5,0, (C) 5,0," (0) S,0," Which of the following molecules are expected to exhibit intermolecular H-bonding L. Acetic acid IL. o-nitrophenot IIL. m-nitrophenol IV. o-boric acid (A) 1, 11, I (8) 1, 1, IV (C) 1, M1, IV (D) 11, 111, IV In which of the dimerisation process, the achieve- ment of the octet is not the driving force. (A) 2A1C1,—+ ALC], (B) BeCl, —+ BeC, (solid) (C) 2ICl,—+1,C), (DB) 2NO, + N,0, ‘A: tetracyanomethane B : Carbondioxide C: Benzene D : 1, 3-buta-di-ene Ratio of c and x bond is in order: (A)A=B, NO} (A) NO; > NO >NO; (8) NO; > NO; >No; (€) NO; > NO} > NO} (D) NO; > NO; > NO; The molecule is not having 3c-2e bond. (A) BeH, (dimer) (8) BeH, (solid) (OCH, (0) 8,4, 9. In which of the following molecules / ions all the bonds are not of equal length. (A) SIF, (B) SF, (C) XeF, (0) BH, 10. The critical temperature of water is higher than that of O, because the H,O molecules has : (A) fewer electrons than O, (B) two covalents bonds (C) V - shape (D) dipole moment 11. Among KO,, AIO; ,B80, and NO; unpaired electron is present in : (A) KO, only (B) NO; and Bad, (C) KO, and AIG; (0) B20, only 12. Which has riaximum dipole moment ? al a a “ (8) | a cl (c) (0) | 1 13. Statement-1 : é-bonds are formed by four lobes interaction of d-orbitals. Statement-2 : 4,2 orbital does not have nodal plane. (A) Statement-1 is true , Statement-2 is true and ‘Staternent-2 is correct explanation for Statement-1 (B) Statement-1 is true, Statement-2 Is true and Statement-2 NOT the correct explanation for Statement-1 (C) Statement-1 is true , Statement-2 is false (D) Statement-1 is false, statement-2 is true.14. Compound with maximum ionic characteris formed from: (A) Na and Cl (C) Cs and! (8) Cs and F (0) Na and F 15.Mg,C, reacts with water forming propyne, C,* has (A) two sigma and two pi bonds (B) three sigma and one pi bonds (C) two sigma and one pi bonds (D) two sigma and thee pi bonds 16. Which of the following has a geometry different from the other three species (having the same Geometry)? (A) BF; (8) soy (©) XeF, (0) PH; 17. Which of the following molecule does not have ‘open book structure. (A) 0,F, (©s,c, (8) 0, (H.C, 18.Among the following species, Identify the isostructural pairs : NF,, NO3 ,BF,,H,0*HN, (A) [NF,,.NO; }@nd [BF ,H,Or) (B) [NF,,HN,] and [NO3 ,BF,) (C) [NF,,H,O*) and [NO3 ,BF,) (D) (NF, H,O°] and [HN,,BF,) 19. Number and type of bonds between two carbon atoms in CaC, are : (A) one sigma (2) and one pl (x) bond (B) one @ and two x bonds (C) one a and one and a half x bond (D) one «bond 20.C - C bond in C,H, undergoes heterolytic fission, the hybridisation of two resulting carbon atoms is, fare (A) sp both (C) sp’, sp” (B) sp? both (D) sp, sp? 21. The hybridisation and geometry of BrF, molecules are: (A) sp°d and T shaped (8) sp?d? and tetragonal (C) sp°d and bent —_(D) none of these 22. Pick out the incorrect statement ? (A) N, has greater dissociation energy than N,* (B) 0, has lower dissociation energy than 0,* (C) Bond length in N,* is less than N, (D) Bond length in NO" is less than in NO. 23. The correct order of increasing X - O - X bond angle is (X = H, F or Cl) : (A)H,O>CI,O>F,0 (B)CO>H,0>F,0 (C)F,O>C10>H,0 (D)F,0>H,0>Ci,0 24. Hybridization of carbon in C,0, is : (A) sp (B) sp* (C) sp (D)sp°d 25. Cyanogen , (CN),, hasa__ushape/structure : (A) Unear (8) Zig-Zag (C) Square (D) Cyclic '26.Ethanol has @ higher boiling point than dimethyl {ether though they have the same molecular weight. This Is due to : (A) resonance (C) hydrogen bonding (8) coordinate bonding (D) ionic bonding 27. Arrange the following in order of decreasing boiling point : (1) n-Butane (II) n-Butanol (If1) n-Butyl chloride (IV) Isobutane (A)IV>M> > (8)IV> I> MI>1 (C)I>t>t>v (0) U>Itl>I>1v 2B. Which of the following compounds would have sig- nificant intermolecular hydrogen bonding ? HF, CH,OH, N,O,, CH, (A) HF, N,O, (C) HF, CH,OH (B) HF, CH,, CH,OH (D) CH,OH, CH, 29. For H,0,, H,S, H,0 and HF , the correct order of decreasing extent of hydrogen bonding is : (A) H,O > HF > H,0, > HS (8) H,0 > HF > H,S > H,0, (C) HF > H,0 > H,0, > HS (D)H,0, > H,0 > HF > H,S30. A simplified application of MO theory to the hypo- thetical ‘molecule’ OF would give its bond order as (a2 (8)1.5 (21.0 (D)0.5 31. Which of the following contains electrovalent and covalent bonds ? (aycH, (C)NH,CI (8)H,0, (D) HCN 32. Which of the following species Is paramagnetic ? (A) NO (8) OF (C) CN" (0) CO 33. Bond order of Be, is aya (2 (c)3 (D)o ‘34.The shape of methy! radical (CH,) is : (A) linear (8) pyarmidal (C) planar (D) spherical ‘35. The structure of XeF,, Involves hybrdization of the type : (A) sp® (C) spd (8) dsp? (0) spr? 36.NH, and BF, combine readily because of the for- mation of : (A) 2 covalent bond —_(B) ahydrogen bond (C) a coordinate bond (D) anionic bond 37. The structure of diborane (B,H,) contains (A) Four (2C-2e") bonds and two (2C-3e")bonds (B) Four (2C-2e-) bonds and two (3C-2e")bonds (C) Four (2C-2e") bonds and four (3C-2e")bonds (D) None 38. Which of the following equilibria would have the lowest value of K, at a common temperature ? (A) Mgco, —— Mg0 + CO, (B) Caco, —— Cad + Co, (c) SrCo, —— Sr0 + Co, (0) Baco, —— Ba0 + co, 39. Which one of the following does not have inter- ‘molecular H-bonding ? (AHO (C) HF (B) o-nitro phenol ()CH,COOH 40. The order of strength of hydrogen bonds Is : (A) CIH...C1 > NH...N > OH...0 > FH...F (D) CIH...Cl < NH...N FH..F ‘41. The types of bond present in N,O, are (A) only covalent (8) only ionic (C) ionic and covalent (0) covalent & coordinate 42. Which of the following exhibits/s H-bonding ? (AycH, (B) H,Se ony (0)#,S 43. Select correct statement about hydrolysis of BCI, and NCI, (A) NCI, is hydfoysed and gives HOC! but BCI, is not hydrolysed: (8) Both NCI, and BCI, on hydrolysis gives HCI 9 NCI, on hydrolysis gives HOC! but BCI, gives ye Both NCI, and BCI, on hydrolysis gives HOC. ‘44, The state of hybridisation for the transition state of hydrolysis mechanism of BCI, and SF, are re~ spectively (A) 5p?, spd (C) sp, spa? (B) sp, sp* (D) sp, sp’d 45. The bond order depends on the number of elec- ‘rons in the bonding and antibonding orbitals. Which of the following statement is / are correct about bond order ? (A) Bond order cannot have a negative value. (8) It always has an integral value {C) It is a nonzero quantity. (D) It can assume any value-positive or negative, Integral or fractional, including zero. ‘48.1n the formation of N3 from N,, the electron is removed trom : (A) o orbital (C) o* orbital (B) x orbital (D) x* orbital47. The types of bonds present In CuSO,. SH,O are (A) electrovalent and covalent (8) electrovalent and coordinate covalent (C) covalent and coordinate covalent (©) electrovaient, covalent and coordinate covalent ‘48. The polarizibility of the following compounds is/are (Ah>Br>Ch>F (B)I'> Br >F >ct (Oh sp?> sp? (B) sp?> sp? > sp (C) sp? > sp > sp? (D)sp?> sp > sp?61. When 2s - 2s, 2p - 2p and 2p - 2s orbitals over- jap, the bond strength decreases in the order : (A)p-p>s-s>p-s (B)p-p>p-s>s-s (C)s-s>p-p>p-s (0)s-s>p-s>p-p 62.How many sigma and pi bonds are present in tetracyanoethylene ? (A) Nine cand ninex (8) Five xand nine o (C) Nine o and Seven x (D) Eight o and eight x 63. The volatility of HF is low because of : (A) its low polarizability (B) the weak dispersion interaction between the molecules, (C) its small molecular mass (0) its strong hydrogen bonding 64, The shapes of IF, and IF, are respectively (A) tetragonal pyramidal and pentagonal bipyramidal (B) octahedral and pyramidal (C) trigonal bipyramidal and square antiprismatic (D) distorted square planer and distorted octahe- oral 65. Which of the following has been arranged in order of decreasing dipole moment ? (A) CH,Cl > CH,F > CH,Br > CHL (B) CHF > CH,CI > CH,Br > CHIT (C) CHI > CH,Br > CH,L> CH, (0) CHF > CH,CI> CH, > 66. Which of the following has the least dipole mo- ment (ANF, (8)cO, (Cc) So, (D)NH, The experimental value of the dipole moment of HCI is 1.03 D. The length of the H - Cl bonds Is 1.275 A. The percentage of ionic character in HCI is: (a) 43 (B) 21 (c)17 (0)7 68. The dipole moment of Is 1.5D. The dipole a moment of cl (oo (@)150 (C)2.86D (D)2.25D 69. Which of the following sets of characteristics leads to the increase in solubility of ionic substances ? (A) High dipole moment, Strong attraction by an on and high solvation energy (B) Low dipole moment, weak attraction by an ion and high solvation energy (C) High dipole moment, Strong attraction by an ion and low solvation energy (0) High dipole moment, weak attraction by an ton and large solvation energy 70.The correct order of increasing s-character (in percentage) in the hybrid orbitals of following mol- ecules/ions is : ( coe (I) XeF, (ay 5 (yy nc, (V) Bec, (aylsill> (2) Si,0,~ (34. What is the state of hybridisation of Xe in cationic part of solid XeF, (Aysp’? — (B) spd? 32. Rotation around the bond (between the underlined atoms) is restricted in : (A) CH, (B) H,0, (C)sp'd (0) sp? (C) CH, (D) CH, 33. According to MOT (Molecular Orbital Theory), the molecular orbitals are formed by mixing of atomic orbitals through LCAO (linear combination of atomic orbitals). The correct statement(s) about molecular orbitals is/are ‘Statement (A) :bonding molecular orbitals are formed by addition of wave-functions of atomic orbitals of same phase ‘Statement (8) : anti-bonding molecular orbitals are formed by subtraction of wave-functions of atomic orbitals of same phase ‘Statement (C) : non-bonding molecular orbitals do not take part in bond formation because they belong to inner shells Statement (D) : anti-bonding molecular orbitals Provide stability to molecules while bonding molecular orbitals make the molecules unstable. (A) Statement a, (B) Statement a, b, c (C) Statement a, b,d (0) Statement a, b