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❖ 11 years of Experience

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gold medalists
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Society

Mohit Ryan Sir


BIT Sindri
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Top 10 performer

Vishvesh Shatalwar
Gamerz Point
Apramya
Ronit Chawla
Indrajit Roy
Divy Kalyani
Subhi Kureel
Aarushi Gaur
Jaismeen Kaur
Abhinav Thapliyal
CHEMICAL BOND

Force of attraction that holds atoms and molecules


together is called as “Chemical bond”
Chemical
Bond

Interatomic Intermolecular
Chemical Bond Chemical Bond

Covalent bond Metallic Bond Vander Waal’s Hydrogen


force bonding
Ionic Bond
LEWIS APPROACH

● Every atom has a tendency to complete its octet in outer


most shell.
● H has the tendency to complete its duplet.
● To acquire inert gas configuration atoms loose or gain
electron or share electron
LEWIS OCTET RULE

The tendency of atoms to achieve eight electrons in their


outermost shell is known as Lewis octet rule
LEWIS OCTET RULE

Positive Kernal
( Nucleus)

Dots
(Representing e’s)
Steps to write Lewis dot structure

❏ The total number of electrons = sum of valence electrons of the


combining atoms.
-
❏ For each charge of anions = 1 e more & Cation = 1 e less
-
❏ It is important to know Elemental symbols and it’s valence
electrons
❏ Depending on the number of electrons (2,4,6) shared
single, double & triple bonds are formed
Lewis dot structures

Valence
electrons
Lewis dot structures

Valence
electrons
Lewis dot structures

Valence
electrons
Limitations of Octet Rule
Incomplete octet molecules :- or (electron deficient molecules)

Compound in which octet is not complete in outer most orbit of


central atom.
Example - Halides of IIIA groups, BF3, AlCl3, BCl3 etc.
Limitations of Octet Rule

Expansion of octet or (electron efficient molecules)

Compound in which central atom has more than 8e–in outermost


orbits.
Example - In PCl5, SF6 and IF7 the central atom P, S and I contain
10, 12, and 14 electrons respectively.
Limitations of Octet Rule
Odd electron molecules :-
Central atom have an unpaired electron or odd no (7e-, 11e- etc) of electrons in
their outermost shell.
e.g. NO, NO2, ClO2 etc
Limitations of Octet Rule

❏ Formation of noble gas compounds


Ex: XeF2 , XeOF2
❏ Doesn’t discuss shapes of molecules
❏ Doesn’t discuss stability of molecules
The octet rule is not obeyed in

A CO2

B BCl3

C H2O

D SiF4
The octet rule is not obeyed in

A CO2

B BCl3

C H2O

D SiF4
Which is not an exception to octet rule?

A BF3

B SiCl4

C BeCl2

D ClO2
Which is not an exception to octet rule?

A BF3

B SiCl4

C BeCl2

D ClO2
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