physical chemistry 11

Mole concept
Lecture # 1 41 min
Dalton atomic theory, isotope ,isobar, atomic mass, atomic mass unit amu,
molecule, molecular mass
Lecture # 2 48 min
molar mass. Gram atomic mass, gram molecular mass, avogadro law
Lecture # 3 44 min
Relative atomic mass, relative density, vapour density, specific gravity, average
atomic mass, average molar mass
Lecture # 4 30 min
Percentage composition, molecular formula, empirical formula, gay-lussac law
Lecture # 5 34 min
Stoichiometry, mole-mole analysis, combustion of hydrocarbon
Lecture # 6 39 min
limiting reagent, percentage yield , consecutive reaction
Lecture # 7 37 min
Principle of atomic conservation POAC
Lecture # 8 29 min
Percentage purity of sample, combustion of carbon, analysis of mixture
Lecture # 9 24 min
Numerical on analysis of mixture, law of mass conservation, law of definite
proportions, law of multiple proportions, law of reciprocal proportions
Lecture # 10 18 min
Solution, solute , solvent, mole fraction, %w/w/,
Lecture # 11 35 min
%w/v, % v/v, strength of solution, molarity, molality, ppm
Lecture # 12 46 min
Interconversion of concentration terms
Lecture # 13 35 min
Molarity of pure water , volume strength of hydrogen peroxide solution, relation
between volume strength and molarity
Lecture # 14 38 min
Silver salt method , Eudiometry ,
Lecture # 15 27 min
examples of eudiometry
Lecture # 16 42 min
Significant figure, rules for counting , rounding off, scientific notation,
addition/subtraction, multiplication of significant figure

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Equivalent concept
Lecture # 1 44 min
Oxidation number calculation, average O.N. individual O. N.
Lecture # 2 58 min
Oxidizing agent, reducing agent, disproportion reactions
Lecture # 3 46 min
Balancing of redox and disproportion reaction , balancing of molecular reaction
Lecture # 4 45 min
Equivalent concept. Law of chemical equivalence, relation between mole and
equivalent, equivalent mass, valence factor calculation for acid & base
Lecture # 5 49 min
n- factor for salt, n - factor for disproportion reaction
Lecture # 6 39 min
Titration, acid base titration, permanganate titration, dichromate titration
Lecture # 7 34 min
Back titration , double titration
Lecture # 8 33 min
Numerical on double titration, iodometric titration, limitation of equivalent concept
Lecture # 9 31 min
Bleaching powder and calculation of available chlorine from bleaching powder
sample
Lecture # 10 35 min
Hardne ss of water ( temporary & permanent hardness) strength of oleum
Lecture # 11 20 min
Volume strength of hydrogen peroxide solution

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Chemical equilibrium
Lecture # 1 1 hr 13 min
Reversible & irreversible reactions, physical and chemical eq, homogeneous and
heterogeneous eq, properties of eq, Kp, Kc, Kx, relation between Kp & Kc, relation
between Kp and Kx, degree of dissociation
Lecture # 2 38 min
Effect of stoichiometry on kp & Kc, examples of homogeneous equilibrium
Lecture # 3 29 min
Numericals of homogeneous eq.
Lecture # 4 53 min
Heterogeneous eq., homogeneous liquid eq., significance of value of k, reaction
quotient
Lecture # 5 53 min
Approximation during calculation, relation between vapour density and degree of
dissociation
Lecture # 6 38 min
Thermodynamics for chemical eq, factor affecting composition of eq mixture ,
le-chatelier's principle, effect of concentration , effect of temperature
Lecture # 7 36 min
Effect of change in pressure and volume , effect of catalyst
Lecture # 8 1 hr
Addition of inert gas at constant volume and constant pressure, le-chatelier's
principle for physical eq, evaporation of water, boiling of water, melting of ice , melting of
metal
Lecture # 9 42 min
Solubility of gas in liquid , allotropic change , simultaneous eq.

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Ionic equilibrium
Lecture # 1 31 min
Strong electrolyte, weak electrolyte, strong acids, weak acids, strong base, weak
base , acid base theory, arrhenius concept, bronsted lowry concept , amphiprotic
species
Lecture # 2 45 min
Lewis concept , pH scale, properties of water, ionisation constant of water, ionic
product of water
Lecture # 3 43 min
pH calculation for strong acid, strong base, mixture of strong acid , mixture of
strong acid and base , common ion effect
Lecture # 4 41 min
pH for monobasic weak acid, weak base, ostwald dilution law, pH for very dilute
strong acid
Lecture # 5 40 min
Very dilute weak base , mixture of weak acid and strong acid,polyprotic weak
acid
Lecture # 6 33 min
Numerical on polyprotic weak acid, mixture of two weak acids
Lecture # 7 52 min
Hydrolysis of salt, salt of strong acid and strong base, salt of weak acid and
strong base , salt of weak base and strong acid
Lecture # 8 39 min
Hydrolysis of salt of weak acid and weak base
Lecture # 9 37 min
pH for polyvalent anion, ph for amphiprotic anion , introduction of buffer solution
Lecture # 10 43 min
Acidic buffer and basic buffer
Lecture # 11 53 min
Buffer capacity, titration ( strong acid v/s strong base, strong acid v/s weak base
, weak acid v/s strong base)
Lecture # 12 35 min
Titration of H3PO4 v/s NaOH
Lecture # 13 38 min
Indicator, phenolphthalein, methyl orange, pH range for a buffer ,double titration
Lecture # 14 44 min
 Solubility of sparingly soluble salt, Ksp, effect of common ion on solubility,
simultaneous solubility
Lecture # 15 41 min
Ionic product v/s solubility product,selective precipitation,
Lecture # 16 37 min
solubility of salt in buffer solution, complex formation by salt
Lecture # 17 43 min
Solubility of amphoteric insoluble hydroxide, solubility of salt if cation is
hydrolyzed , solubility of salt if anion is hydrolyzed
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Thermodynamics & thermochemistry

Lecture # 1 41 min
System ,surrounding,open system, closed system, isolated system,
thermodynamic variable, process, open cycle ,closed cycle,intensive prop. Extensive
prop., state function, path function, heat, work, heat capacity, molar heat capacity,
specific heat capacity ,IUPAC , types of process, isothermal, isobaric, isochoric,
adiabatic process,convention for heat and work
Lecture # 2 56 min
Reversible and irreversible process, reversible isothermal compression, single
step isothermal compression, two stage isothermal compression
Lecture # 3 50 min
Reversible isothermal expansion, single stage isothermal expansion, two stage
isothermal expansion, internal energy, degree of freedom, first law of thermodynamics
Lecture # 4 46 min
Enthalpy change , phase transformation
Lecture # 5 43 min
Free expansion, reversible adiabatic process, work calculation for reversible
Adiabatic and irreversible Adiabatic processes
Lecture # 6 42 min
comparison between reversible adiabatic and irreversible adiabatic processes,
comparison between reversible adiabatic and reversible isothermal processes
Lecture # 7 55 min
Spontaneous and nonspontaneous process, entropy, second law of
thermodynamics , entropy change for system and surrounding
Lecture # 8 40 min
Numerical on entropy change , entropy change during free expansion
Lecture # 9 56 min
Gibbs energy change, heat pump, carnot cycle
Lecture # 10 48 min
Thermochemistry, enthalpy of formation, enthalpy of combustion
Lecture # 11 57 min
Enthalpy of fusion, vaporization,sublimation,bomb calorimeter, enthalpy of
neutralisation, enthalpy of ionisation
Lecture # 12 1 hr 7 min
Bond enthalpy, hess law, resonance energy. Lattice energy , hydration energy,
enthalpy of formation of ion, kirchhoff equation, integral enthalpy of solution, calculation
of lattice energy using born haber cycle

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Gaseous State
Lecture # 01 32 min
State of matter (solid, Liq, gas) ideal gas equation, Boyle’s law.
Lecture # 02 33 min
Barometer, faulty Barometer
Lecture # 03 40 min
Problems on barometer,
Charles law
Lecture # 04 21 min
Gay-lussac’s law, Avogadro's law, ideal gas equation
Lecture # 05 45 min
Numerical
Lecture # 06 36 min
Graham’s law for diffusion.
Lecture # 07 40 min
Kinetic theory of gas, root mean square velocity
Lecture # 08 50 min
Compressibility factor (Z) pressure correction factor, volume correction factor,
excluded volume, van der waal gas equation
Lecture # 09 46 min
Virial equation, liquification of gas, critical temperature (Tc) Critical pressure (Pc)
Critical volume (Vc) Boyle’s temperature
Lecture # 10 52 min
Liquification of gas manometer
(Open end, Closed end, reduced equation of state), Collision diameter, Collision
frequency
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Atomic structure
Lecture # 01 33 min
Cathode tube experiment anode rays, radioactive decay.
Lecture # 02 51 min
Thomson plum pudding model. Rutherford model, Nearest distance of approach.
Lecture # 03 50 min
Electromagnetic theory, Planck Quantum Theory, Blackbody radiation, electron
volt.
Lecture # 04 41 min
Photoelectric effect, Work function, Threshold frequency stopping potential.
Lecture # 05 34 min
Photo current photo intensity, Bohr model, Bohr Radius
Lecture # 06 29 min
Velocity, Kinetic Energy, Total energy, Potential energy of electron in Bohr orbit
Lecture # 07 35 min
Time period, frequency, ionisation energy, ionisation potential, Excitation energy,
excitation potential Binding energy.
Lecture # 08 45 min
Spectrum, emission, line spectrum, band spectrum , H-spectrum, lyman series.
Lecture # 09 50 min
Balmer series, Paschen, Brackett, Pfund, humphrey series, maximum number of
spectral lines.
Lecture # 10 41min
Limitations of bohr model, dual nature of particle, de broglie's equation
Lecture # 11 39 min
Heisenberg’s uncertainty principle Difference between orbit & orbital
Lecture # 12 37 min
Types of orbitals {s, p, d, f}, quantum numbers, (principal, azimuthal, magnetic,
spin)
Lecture # 13 47 min
Electron filling rule, Aufbau principle, Hund’s rule, pauli’s exclusion principle,
magnetic nature, magnetic moment
Lecture # 14 42 min
Wave quantum theory, schrodinger wave equation, radial node, angular node.
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Physical chemistry class 12

Solution & colligative properties

Lecture # 01 33 min
Introduction
Different concentration terms interconversion, colligative properties, van’t hoff
factor calculation, osmotic pressure.
Lecture # 02 47 min
Osmosis , Osmotic pressure (different cases)
Lecture # 03 46 min
Numericals on osmotic pressure
Lecture # 04 41 min
Vapour pressure, relative lowering of vapour pressure,
Lecture # 05 40 min
Numericals on RLVP, Ostwald walker method
Lecture # 06 54 min
,Elevation in boiling point, calculation of Kb (molal elevation boiling point
constant)
Depression in freezing point, Calculation of Kf,
Lecture # 07 36 min
Numericals on elevation in boiling point and depression in freezing point
Lecture # 08 6 min
Thermodynamic explanation of 𝝙Tb & 𝝙Tf
Lecture # 09 49 min
Raoult’s law when two volatile liquids are mixed
Lecture # 10 34 min
Ideal and nonideal solution
Lecture # 11 58 min
Azeotropes, mixture of two immiscible liquids, solubility of gas in liquid, henry law
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Solid state
Lecture # 01 42 min
Types of solid, Crystal, Amorphous, unit cell, 2D, 3D, space,lattice.
Lecture # 02 47 min
Primitive, body centred, face centered contribution of atoms in cubic unit cell.
Packing fraction of square packing and hexagonal packing
Lecture # 03 44 min
Coordination Number, packing fraction, density of solid.,Simple cubic, BCC,
FCC, CCP
Lecture # 04 57 min
Closed packing in 3D HCP packing,
Linear void, Triangular void, Tetrahedral void, octahedral void, Cubical void
Types of void in FCC
Lecture # 05 47 min
Voids in FCC,Different radius ratio for ionic compounds.
Lecture # 06 29 min
Calculation of nearest, next nearest and next to next nearest atoms in SC, BCC,
FCC.
Lecture # 07 50 min
Structure of NaCl type, Zns type, CaF2 type, Na2O type, CSCl type, Diamond
Lecture # 08 39 min
Spinal structure, perovskite corundum structure, packing fraction of NaCl, Defect
In crystal, Schottky, Frenkel, Interstitial
Lecture # 09 31 min
Non stoichiometric defect, cation excess defect cation deficiency defect,
Paramagnetic, Diamagnetic Ferromagnetic, Ferrimagnetic, Antiferromagnetic
compound

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Chemical kinetics
Lecture # 1 57 min
 Fast reaction , slow reaction, moderate reaction, average rate of reaction,
instantaneous rate of reaction, relation of rate of reaction between various reagents ,
order
Lecture # 2 35 min
Order law, zero order reaction
Lecture # 3 28 min
First order reaction
Lecture # 4 27 min
Half life period for first order reaction
Lecture # 5 24 min
Average life period for first order, generation time , first order bacterial growth,
second order reaction
Lecture # 6 35 min
nth order reaction, pseudo first order reaction
Lecture # 7 32 min
Rate of reaction of two or reactant are taken, calculation of order by half life
method
Lecture # 8 40 min
Initial rate method , integrated rate law, ostwald isolation method to determine
order
Lecture # 9 30 min
Monitoring of first order reaction using pressure measurement
Lecture # 10 42 min
Monitoring of first order reaction using titration and optical rotation
Lecture # 11 29 min
Arrhenius transition state theory
Lecture # 12 32 min
Arrhenius equation
Lecture # 13 39 min
Effect of catalyst on rate constant, temperature coefficient for reaction
Lecture # 14 29 min
Simple and complex reaction, molecularity, rate determining step RDS
Lecture # 15 48 min
Determination of rate if RDS is given , steady state approximation,complexity in
first order reaction, parallel first order reactions
Lecture # 16 29 min
Reversible first order reaction
Lecture # 17 19 min
Consecutive first order reaction
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Radioactivity 15 min
Lecture # 01
Cause of radioactivity belt of stability , comparison between alpha particle, beta
particle and gamma rays
Lecture # 02 28 min
Group displacement law soddy fajan rule,, k– electron capture ,first order decay.
Lecture # 03 28 min
Radioactive decay
Lecture # 04 53 min
Carbon dating, Age of rock using U & Pb,Age of rock using U & He
Lecture # 05 51 min
Mass defect ,Binding energy, Binding energy per nucleon. Nuclear fission and fusion.

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Surface chemistry
Lecture # 01 47 min
Adsorption, Adsorbate, Adsorbent, Thermodynamics of Adsorption, Adsorption
v/s Absorption, Physical Adsorption.
Lecture # 02 48 min
Freundlich & Langmuir isotherm, catalytic action of Homogeneous catalyst &
Heterogeneous catalyst, Positive & negative catalyst, Homogeneous catalyst,
Promoters, Catalytic poison, zeolites, enzyme catalyst, Types of solution, Dispersed
phase & Dispersion medium.
Lecture # 03 43 min
Types of colloidal solution, Lyophobic, Lyophilic, macromolecular,
micromolecular, Associated colloid/ micelle, cleansing action of soap, Bredig’s arc
method,Peptization
Lecture # 04 53 min
 Chemical method to prepare colloidal solution, Tyndall effect, Brownian motion,
Electrophoresis, coagulation, protection of colloid.
Lecture # 05 22 min
Gold number, Helmholtz double layer theory ,emulsion.

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Electrochemistry
Lecture # 01 1 hr 05 min
Electrochemical cell, Oxidation half cell, Reduction half cell, Galvanic cell
Lecture # 02 44 min
Salt bridge, Daniel cell net cell reaction reaction Quotient cell representation
relation between DG & E properties of DG & E,nernst equation
Lecture # 03 44 min
Spontaneity of reaction in cell, nernst equation cell at equilibrium, concentration
cell. Hydrogen electrode and standard hydrogen electrode
Lecture # 04 1 hr 14 min
Metal + insoluble salt + soluble anion type half cell
Eg. Ag + AgCl + Cl–
Lecture # 05 59 min
Calomel electrode, electrochemical series, thermodynamics for electrochemical
cell, 𝝙G, 𝝙H, 𝝙S
Lecture # 06 1 hr 11 min
Electrolysis & electrolytic cell, electrolysis of nacl, nabr, H2SO4,H2O, first
law of electrolysis Faraday law

Lecture # 07 51 min
Examples of first law of faraday, second law of faraday

Lecture # 08 50 min
Primary cell ,leclanche cell, secondary cell, lead storage battery , Ni-Cd
cell , H2-O2 fuel cell, electrolytic conduction
Lecture # 09 54 min
 Molar conductivity, equivalent conductivity , relation between molar cond.
And equv. Cond., kohlrausch law, calculation of molar cond using wheatstone bridge ,
relation between molar cond. And concentration for weak electrolyte and strong
electrolyte ,huckel onsager equation
Lecture # 10 51 min
Ionic mobility, conductometric titration for strong acid V/s strong base ,
strong acid v/s weak base and other examples

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