33-35, Mall Road, G.T.B. Nagar, Opp. G.T.B. Nagar Metro Station Gate No. 3, Delhi-110 009 Delhi-110 016

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www.careerendeavour.com
33-35, Mall Road, G.T.B. Nagar,

Opp. G.T.B. Nagar Metro Station
Gate No. 3, Delhi-110 009 Delhi-110 016
E : info@careerendeavour.com
South Delhi : 28-A/11, Jia Sarai, Near-IIT Hauz Khas, New Delhi-16, Ph : 011-26851008, 26861009
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North Delhi : 33-35, Mall Road, G.T.B. Nagar (Opp. Metro Gate No. 3), Delhi-09, Ph: 011-65462244, 65662255
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PART – A
1. In a certain code, SIKKIM is written as THLJJL. How is TRAINING written in that code?
(a) SQBHOHOF (b) UQBHOIOF
(c) UQBHOHOI (d) UQBHOHOF
2. The missing term in the series
3, 4, 0, 9, ____, +18, –18, 31 is
(a) 0 (b) –10 (c) –7 (d) 12
3. If Neena says, “Anita’s father Raman is the only son of my father-in-law Mahipal”. Then how is Bindu,
who is the sister of Anita, related to Mahipal?
(a) Niece (b) Daughter (c) Daughter-in-law (d) None of these
4. Starting from a point P, Sachin walked 20 meters towards south. He turned left and walked 30 meters.
He then turned left and walked 20 meters. He again turned left and walked 40 meters and reached
a point Q. How far and in which direction is the point Q from the P?
(a) 30 metres, west (b) 10 metres, west
(c) 30 metres, north (d) 10 metres, north
5. A, P, R, X, S and Z are sitting in a row. S and Z are in the centre. A and P are at the ends. R is
sitting to the left of A. Who is to the right of P?
(a) A (b) X (c) S (d) Z
6. Choose the box that is similar to the box formed from the given sheet of paper (X)
(X) (1) (2) (3) (4)

(a) 1 and 4 only (b) 3 and 4 only (c) 1 and 2 only (d) 2 and 3 only
2
7. By selling an article at of the marked price, there is a loss of 25%. The ratio of the marked price and
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the cost price of the article is.
(a) 2:5 (b) 5:2 (c) 8:15 (d) 15:8
8. In the given figure O is the centre  OBC = 50 and  OAC = 15. Then the value of the  AOB is
?
O
C
15
50
A
B
(a) 30 (b) 40 (c) 20 (d) 70
9. How many squares are there in the following figure?
(a) 124 (b) 25 (c) 26 (d) 227

10. Gold is 19 times as heavy as water and copper is 9 times as heavy as water. In what ratio should these be
mixed to get an alloy 15 times as heavy as water?
(a) 1:1 (b) 2:3 (c) 1:2 (d) 3:2
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PART – B
11. Number of signals in the Mössbaur spectrum of Fe3(CO)12 and Fe2(CO)9 is
(a) 1 and 2 (b) 2 and 3 (c) 4 and 1 (d) 2 and 1
12. The intensity pattern in the ESR spectrum of CD3 radical molecule is
(a) 1 : 4 : 6 : 4 : 1 (b) 1 : 3 : 6 : 7 : 6 : 3 : 1
(c) 1 : 5 : 10 : 10 : 5 : 1 (d) 1 : 2 : 3 : 3 : 2 : 1
13. A free Mössbauer nucleus of mass 100.6 amu emits radiation of wavelength 0.1 nm. The recoil velocity of
Doppler shift is
(a) 30.52 ms–1, 3.9×1010 m (b) 3.9×1010m, 35 ms–1
10 –1
(c) 40×10 m, 40 ms (d) 39.52 ms–1, 3.952×1010 m
14. The number of fine and hyperfine line in the ESR spectrum of [Fe(CN)5NO]–3 is [NO(I = 1)]
15. The transition that belongs to the Balmer Series in the hydrogen-atom spectrum is
(a) 3s  4d (b) 2s  4 p (c) 1s  4 p (d) 2s  2 p
16. In gas solid chromatography the fixed phase consists of a solid material such as
(a) Granular silica (b) Magnesium (c) Sodium (d) Calcium
17. The half life period of 53Y125 is 70 days. The percentage of the original radioactivity would be present after 280
days is
(a) 8.25% (b) 6.25% (c) 15% (d) 19%
18. Arrange the following in decreasing order of Rh–C bond length
(A) Rh  CO 2  Cl  PPh 3 2 (B) Rh  CO  2  Cl  PEt 3  2 (C) Rh  CO  2  Cl   P  C6 F5 3  2
(a) C > A > B (b) C > B > A (c) B > A > C (d) A > B > C
19. The most unstable beryllium alkyl compound is
(b) Be  CH 2 Bu 2
t
(a) BeMe2 (c) Be  Et 2 (d) Be  CH 2SiMe3  2
O
20. H
A=
O
O O
B= www.careerendeavour.com
The correct statement about reaction A and B
(a) A is catalysed by Rh(I) complex, RhCl(PPh3)3
(b) B is catalysed by Rh(I) complex, RhCl(PPh3)3
(c) A and B both are catalysed by Rh(I) complex, RhCl(PPh3)3
(d) None is catalysed by Rh(I) complex, RhCl(PPh3)3
21. In the reactions :
(1) graphite +K vapours 
High
(2) carbon  Ca 
Temp

the products and respectively are
(a) K 4 C and Ca 2 C (b) K 2 C 2 and CaC (c) KC8 and CaC2 (d) KC and CaC 4
4
22. The ores of Ti, Ta and Nb may be brought into solution near 800 ºC using Na 2S2 O 7 . A simplified reaction may
be as follows :
TiO 2  Na 2S2O7  Na 2SO 4  TiO  SO 4 
The acid and base in the reaction are :

(a) Ti 4  as base and Na in Na 2S2 O as acid
(b) S2 O72  as base and O2 as acid
(c) O 42  of TiO 2 (base) and SO3 in S2 O 7 (acid)
(d) Ti 4 as acid and S6 as acid
23. When alkali metal fluorides are dissolved in XeOF4 anion X is formed. The shape of anion X is
(a) distorted octahedral (b) pentagonal monopyramidal
(c) octahedral (d) square antiprismmatic
24. HOMO and LUMO of I3 respectively are

(a) bonding and antibonding (b) non-bonding and antibonding
(c) bonding and non-bonding (d) both non-bonding
25. Correct order of metal oxides in increasing order of their Neel temperature
(a) MnO  FeO  CoO  NiO (b) MnO  FeO  CoO  NiO
(c) CoO  NiO  FeO  MnO (d) NiO  FeO  CoO  MnO
26. Activity of catalase enzyme is inhibited by
(a) CO (b) O2 (c) N2 (d) CN–
2
27. The coordination number of complex  UO 2 18 crown-6  
(a) 8 (b) 11 (c) 9 (d) 12
28. The occupation factor  is 0 and 1/2 respectively for which of the following pairs of mixed oxides
(I) CuAl2O4 and Mn3O4 (II) NiCr2O4 and ZnFe2O4
(III) Co 3O4 and CoFe2O4 (IV) CoAl2O4 and ZnMn2O4
(a) I, II and IV (b) II and IV (c) III and IV (d) III only
29. Find the value of ‘x’ in –  Na 3Ba xSi5O15 2
(a) 7
(b)
7
(c) 14 (d) 2
2
30. The equilibrium constant for following reaction of ethylenediammine with Co2+, Ni2+ and Cu2+ are k1, k2 and k3
respectively.
2 AA 2
 M  H 2 O  2  AA  2    M  AA 3 
 
then select the correct statement from the following
(a) k 2  k1  k 3 (b) k 3  k 2  k1 (c) k 2  k 3  k1 (d) k 2  k 3  k1
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PART – C
31. The correct statement is/are
(1) For an odd nucleon in ‘H’ nuclear orbital and parallel to I. The spin and parity for this odd electron nuclear
11
is and (+).
2
(2) The electric dipole allowed transition in a d3 system is 4 F  4 D
(3) The ionisation energy for one-electron in Lyman series is 52 eV. The wavelength for this one electron ion
is 24 nm.
(4)   3 is allowed transition and if the ionisation energy of H atom is x. The ionisation energy of He+1 is
3
16x.
(a) 1, 2 (b) 1, 3 (c) 1, 4, 3 (d) 2, 3, 4
32. The correct statement about gas chromatography is/are
(1) A gas chromatography separates components of a gaseous mixture in a column and detects the compo-
nents as they are eluted.
(2) Useful absorbents for GSC will have very large surface areas or are very porus material
(3) In gas chromatographic methods are generally not applicable to highly non-polar substances
(a) 1, 2 (b) 1, 3 (c) 1, 2, 3 (d) 2, 3
33. The property measured in TGA is
(a) change in weight (b) rate of change in weight
(c) heat evolved or absorbed (d) change of temperature
34. The most difficult synthesis among the following synthetic transformation is
(a) PtCl2(PPh3)2 + Li Li
(b) ZrCl4 + 4PhCH2MgCl

(c) CH3Li + WCl6
(d) TiCl4 + 4 Li
35. Arrange the rate of substitution reaction in the following compound

Mo  CO  4 L 2  CO 
 Mo  CO 5 L  L
L  PhPMe 2 Ph 2 PMe PPh 3
A  B  C
(a) A > B > C www.careerendeavour.com
(b) C > B > A
(c) B > C > A (d) B > A > C
36. Match the following
Column-A Column-B
Complexs (fac isomers)  CO cm 1
(A) Mo  CO 3 dien (I) 2090, 2055
(B) Mo  CO 3  PPh 3 3 (II) 2040, 1991
(C) Mo  CO 3 P  OMe 3 (III) 1977, 1888
(D) Mo  CO 3  PF3 3 (IV) 1934, 1835
(E) Mo  CO 3  PCl3 3 (V) 1898, 1758

(a) A-5, B-4, C-2, D-1, E-3 (b) A-4, B-2, C-5, D-1, E-3
(c) A-5, B-4, C-3, D-1, E-2 (d) A-3, B-2, C-5, D-1, E-5
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37. Identify the correct statement
(A) The cluster electron count and number of M–M bond in Cp3 Co3 µ3  CS µ3  S is 48 electron and 3
M–M bond respectively.
(B) The complex OC  Mo  CO 5 is isolobal with OC  CH 2
3
(C)  Rh 7  CO 16  ,  Os 7  CO  21  are isostructural
(D) The ionic crystal Bi 35 is closo while Sn 94  is arachano structure

(a) A and B (b) C and D (c) A, B and C (d) A and C
38. 1.84 gm of IF3 reacts with 1.86 gm of [Me4N]F to form product X. The shape of anion and number of 19F
NMR signals in IF3 and X respectively are
(a) square planar, 2, 1 (b) TBP, 2, 2
(c) Pentagonal planar, 2, 1 (d) Td, 2, 2
39. Arrange the decreasing order of rate constants (k/dm3mol–1s–1) for following electron transfer reaction in aque-
ous medium and select the reaction(s) for which G 0  0
3 2 3 2
(I)  Ru  NH 3 6    Ru  NH 3  6  (II)  Co  NH 3 6    Ru  NH 3 6 
3 2
(III)  Co  NH 3 6    Co  NH 3 6 
(a) II > I > III, G 0  0 for I and III (b) I > II > III, G 0  0 for I and II
(c) I > II > III, G 0  0 for I and III (d) III > II > I, G 0  0 for I
40. Identify the incorrect statement(s)
(I) Each subunit in deoxyheamoglobin contain 5-coordinate Fe(II), but in cytochrome-c, the Fe centre is
always 6-coordinate
(II) Cytochrome-c oxidase contain more than one metal centre
(III) The binding of O2 to myoglobin exhibit a cooperative effect
(IV) Cytochrome P-450 is dioxygenase
(a) I, II and III (b) I, II, III and IV (c) I, III and IV (d) III and IV
41. The ground state term symbol and magnetic moment (BM) for Tm3+ is
(a) 3I6 and 9.58 (b) 2H5 and 7.56 (c) 3H6 and 7.56 (d) 3F7/2 and 9.58
42. www.careerendeavour.com
Egyptian blue, CaCuSi4O10 (I) is pale blue and spinel CuAl2O4 (II) is an intense blue-green. The difference in
colours is due to
(a) LMCT in I and d-d transition in II (b) d-d transition in both
(c) difference in geometry of Cu in I and II (d) d-d in first and LMCT in II
43. At low aqueous concentrations and at ordinary temperature the extent of exchange of ions in exchanger coloumn
is
(a) Li   Na   NH 4  K   Rb  Cs  (b) Li   Na   NH 4  K   Rb  Cs 
(c) Li   Na   NH 4  K   Cs   Rb  (d) Li   Na   NH 4  K   Rb   Cs 
44. Correct statement(s) regarding Uranium is
(1) most stable oxidation state of Uranium is +6
(2) in uranocene its oxidation state is +4
(3) in UO 2 colour is due to LMCT
(4) Electronic configuration of Uranium corresponds  Rn  5f 3 6d1 7s 2
(a) 1, 2 (b) 1, 2, 4 (c) 1, 2, 3, 4 (d) 2, 3, 4
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2
45. In a complex trans-  CuX4 Y2  the Cu  X bond is larger than that of Cu-Y bond, what is correct electron
arrangement of complex
2 2 2 1 1 2 2 2
   d yz   d xz 2  d x  y   dz 
(a) d xy 2 2 2    d yz   d xz 2  d x  y   d z 
(b) d xy 2 2 2
2 2 1 2 2 2 2 2
   d yz   d xz 2  d x  y   d z 
(c) d xy 2 2 2    d yz   d xz 1  d x  y   d z 
(d) d xy 2 2 2
46. Among the following metal oxides conductivity of which oxide corresponds to given molecular orbital
energy level diagram.
p-band
p eg
d t2g band
M2+ O2–
p-band
(a) FeO (b) MnO (c) TiO (d) NiO

47. Compound CoCl3.5NH3(A) treated with an excess of AgNO3 solution, two chloride ions are precipitated. A
on reaction with NaNO2 gives red colour compound B. Which react with warm HCl turns into yellow colour
compound C. The relation between B and C is
(a) B is octahedral compound while C is tetrahedral compound
(b) C is octahedral compound while B is tetrahedral compound
(c) B and C are constitutional isomers
(d) B and C are geometrical isomers
48. Consider the following reactions
NH 4Cl
S2 Cl2 
K or NaN 3
 A  B 
Ag wool, 450 K
(C)
Correct statement regarding above is/are
(1) A  S4 N 4 B  S3 N3 C  SN  x
(2) A  S3 N 3Cl3 B  S4 N 4 C  SN  x
(3) B is aromatic in nature and has 10 electrons.
(4)  SN  x is one dimensional metal
(a) 1, 4 (b) 2, 3, 4 (c) 2, 4 (d) 1, 3, 4
49. The number of isomer for P4N4Cl5F3 are
(a) 3 (b) 4 (c) 5 (d) 10
8
50. XeF4 on complete hydrolysis produces
(a) XeO2 (b) XeO3, O2 (c) XeO3, Xe and O2 (d) XeO3, XeO and O2
51. Correct statement(s) regarding alkali metal in liq. NH3 solution (Dilute) is/are
(1) Blue colour of solution is due to ammoniated cation
(2) Density of solution is more than density of liq. NH3
(3) On evapouration of NH3 pure metal can be obtained
(4) High conductivity of solution is largely due to ammoniated electron
(a) 1, 2, 3, 4 (b) 3, 4 (c) 2, 4 (d) 1, 4
3 3 3 2
52. For the complexes  CoL6  ,  CrL6  ,  MnL6  and  CrL6  (where L is a neutral monodentate
ligand), 0 and P values are given in the following table.
S.No. Complex 
 0 cm 1  P  cm 
1
3
 i  CoL6  16500 14000
3
 ii  CrL6  11500 13500
3
 iii   MnL 6  13500 12500
2
 iv  CrL6  13000 12000
The correct answer is
(a) i, ii inert and iii, iv labile (b) i, ii, iii inert and iv labile
(c) All are labile (d) All are inert.
53. FeCp 2  HF  A and Ni  Cp  2  HF  B
The product A and B, respectively
 
(a) A   FeCp 2 H  , B   NiCp 2 H 
 
(b) A  FeCp 4 C5 H 6  , B   NiCp 2 H 
 
(c) A   FeCp  4 C5 H 6   , B   NiCp  4  C5H 6  
 
(d) A   FeCp 2 H  , B   NiCp  4  C5 H 6  
54. The electron count, formal oxidation state, and dn configuration of following respectively are

 R 3 P 3 Ru µ  Cl 3 Ru  PR 3 3  , Re H 92  , Me Re O3
(a) 16 e– (VII), d0 (b) 16e– (VII), d5
– 0
(c) 18e (VII), d (d) 18e– (VIII), d0
 2
55. The number of possible isomers for complexes  Cr  O  phen   NH3 2 Cl 2  and  Pt  bipy  2 BrCl 
respectively are
56. Select the correct statement(s) from following
(1) Blue copper proteins are not always blue
(2) The toxicity of CO is associated with binding to haemoglobin but that of CN– is not
(3) Coenzyme B12 reduces –CH(OH) group to –CH2 group
(4) Cadmium toxicity leads to a disease called Hai Itai
(a) 1, 4 (b) 1, 2, 3, 4 (c) 3 and 4 (d) 2, 3 and 4
9
57. Blue copper proteins consist of mon-nuclear copper center bound to 2 imidazole groups (histidine), one thiol
group (cysteine) and one thioether group (methionine). The coordination geometry around the metal ion is
distorted tetrahedral. What will be the relative value of the redox potential of the metal centre  Cu 2  / Cu   in
the protein compared to that of CuSO4 in water?
(a) More positive (b) More negative
(c) Equal (d) Redox potential of the metal centre in the protein will be zero.
58. Identify the acids in the following two reactions:
NOF + ClF3 = NO + ClF4–
XeO3 + OH– = HXeO4–
(a) ClF3 and XeO3 (b) ClF3 and OH–
(c) NOF and OH– (d) NOF and XeO3
59. The term symbol not possible for B2 is
(a) 3  g (b) 1 g (c) 1  g (d) 1  u
60. Choose the incorrect order of given properties
(a) BeCl2  LiCl  Electrical conductivity 
(b) NaF  MgF2  AlF3  Covalent character 
(c) BeSO 4  MgSO 4  CaSO 4  Thermal stability 
(d) HgCl2  HgBr2  HgI2 Solubility order 
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Space for rough work
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CSIR-UGC-NET/JRF | GATE CHEMISTRY
CHEMICAL SCIENCES Date : 21-11-2017

TEST SERIES-A
ANSWER KEY
PART-A
1. (d) 2. (c) 3. (d) 4. (b) 5. (b) 6. (a) 7. (d)
8. (d) 9. (c) 10. (d)
PART-B
11. (d) 12. (b) 13. (d) 14. (c) 15. (b) 16. (a) 17. (b)
18. (c) 19. (c) 20. (c) 21. (c) 22. (c) 23. (b) 24. (b)
25. (a) 26. (d) 27. (a) 28. (d) 29. (a) 30. (a)
PART-C
31. (d) 32. (a) 33. (a) 34. (d) 35. (b) 36. (c) 37. (c)
38. (c) 39. (c) 40. (d) 41. (c) 42. (c) 43. (a) 44. (c)
45. (a) 46. (c) 47. (c) 48. (d) 49. (c) 50. (c) 51. (b)
52. (d) 53. (d) 54. (c) 55. (c) 56. (b) 57. (a) 58. (a)
59. (d) 60. (d)
1

2
PART – A
1. A milk vendor has 2 cans of milk the first contains 25% water and the rest milk the second contains
50% water. How much milk should, He mix from each of the containers so as to get 12 litres of milk
such that the ratio of water to milk is 3:5?
(a) 4 litres, 8 litres (b) 6 litres, 6 litres
(c) 5 litres, 7 litres (d) 7 litres, 5 litres
2. Find out the missing number :
25 17 41
32 83 11
26 ? 31
(a) 26 (b) 25 (c) 34 (d) 38
3. Two trains, one from Howrah to Patna and the other from Patna to Howrah, start simultaneously. After
they meet, the trains reach their destinations after 9 hours and 16 hours respectively. The ratio of their
speeds is
(a) 2 : 3 (b) 4 : 3 (c) 6 : 7 (d) 9 : 16
4. A man gains 20% by selling an article for a certain price. If he sells is at double the price, the
percentage of profit would be
(a) 40 (b) 100 (c) 120 (d) 140
5. How many times are the hands of a clock at right angle in a day?
(a) 24 (b) 48 (c) 22 (d) 44
6. What is the smallest number of ducks that could swim in this formation - two ducks in front of a duck,
two ducks behind a duck and a duck between two ducks
(a) 3 (b) 5 (c) 7 (d) 9
 1  1   1   1
7. The product  1   1   1   .............  1   gives
 2  3   4   n
1 2 2  n  1 2
(a) (b) (c) (d) n  n  1
n n n
8. A speaks truth in 75% cases and B in 80% of the cases. In what percentage of cases are they likely
to contradict each other, narrating the same incident
(a) 5% www.careerendeavour.com
(b) 15% (c) 35% (d) 45%
9. A sphere of maximum volume is cut-out from a solid hemisphere of radius r. The ratio of the volume
of the hemisphere to that of the cut-out sphere is
(a) 3:2 (b) 4:1 (c) 4:3 (d) 7:4
10. How many rectangles are there in the figure below
(a) 6 (b) 7 (c) 8 (d) 9
3
PART – B
11. The incorrect statement among the following is
(a) In D.C. polarography, the interference from H+ is negligible due to high overpotential of H+ in mercury
electrode.
(b) Migration current is removed by adding supporting electrolyte.
(c) Purpose of passing inert gas through the solution in polarography is to dissolve the gas in solution
(d) Diffusion current is directly proportional to concentration of solution
12. The molar conductivity of an electrolytic solution is 326 Scm2mol–1. If the ratio of velocity of cation and anion
is 1.4. The molar conductivity of cation is
(a) 136.6 Scm2mol–1 (b) 190.1 Scm2mol–1
(c) 150 Scm2mol–1 (d) 176 Scm2mol–1
13. Fugacity coefficient for a gas is 1.25 at 2 bar pressure. The chemical potential of a gas at 2 bar and 300K is
(Given, µ0 for ideal gas is 335 Jmol–1)
(a) 2 kJ mol–1 (b) 1.5 kJ mol–1 (c) 2.6 kJ mol–1 (d) 700 J mol–1
14. Which of the following statement is correct
(a) At constant temperature and volume, the spontaneous direction is the decrease in Gibbs free energy.
(b) TS represents the energy used to do some useful work.
(c) It is possible to construct refrigerator with single reservoir but not carnot cycle
(d) At constant temperature, the Gibbs free energy is same as Helmholtz free energy
15. The number of component in the system
 CaO  s   CO 2  g 
CaCO3  s  
(a) 1 (b) 2 (c) 3 (d) 4
16. Calculate ionic strength of a solution having 0.4 M MgCl2 and 0.2 M AlCl3.
(a) 1.2 (b) 2.4 (c) 3.6 (d) 4.8
17. When
14
 
N 2 B  1.99 cm 1 is exposed to 340 nm light, then the stokes and antistokes lines for molecule in
second rotational state can be observed at
(a) 29412 cm–1 and 29410 cm–1 (b) 340.3 nm and 339.9 nm
(c) 14779.9 cm–1 and 58529.9 cm–1 (d) 29384 cm–1 and 29424 cm–1
18. The difference between energies of adjacent rotational energy levels of a molecule in rotational RAMAN
spectroscopy is given by (on following the convention that energy is represented in Joules)
(a) B(4J + 6) (b) Bhc (4J + 6) (c) 2B (J + 1) (d) 2Bhc (J + 1)
–1
where, B is in cm and J = 0, 1, 2)
 Bhc 
19. The rotational partition function for NH3 under high temperature approximation  r 
 R

, B cm 1 


T T T
(a) 2 (b) 3 (c)  (d) none of these
 r r
20. The number 0.0008 has significant figures :
(a) 3 (b) 8 (c) 4 (d) 1
21. Number of two fold degenerate irreducible representations for D4h point group is two. What is the correct
number of non-degenerate irreducible representation?
(a) Ten (b) Eight (c) Six (d) Five
4
22. In a cubic crystal, the value of d123 is 400 pm. The Edge length of the unit cell is approximately
(a) 1500 pm (b) 1000 pm (c) 500 pm (d) 50 pm
23. The polymer having random sequence of D and L configurations are
(a) isotactic polymers (b) syndiotactic polymers
(c) Atactic polymers (d) Grafted polymers
24. The commutation  x,  x, Hˆ   is equal to
2 2
(a)  2 (b)  (c)  (d) none
m 2m
2
25. The time derivative of the expectation value of x is
1 1 1
(a) Xpx (b) Xpx  px X (c) Xpx  px X (d) zero
2m 2m m
26. According to Hückel theory of conjugated systems, the free valence at any electron of benzene
is
(a) 0.20 (b) 0.40 (c) 0.60 (d) 0.80
27. For the following reversible reaction
 2 B
A 
t 0 a 0
t t x
The relaxation time    is
1 1 1 1
(a) k  k (b) k  k  x  (c) k  4a   k (d) 1
1 1 1 1 e 1 e 1 k1    k1  2 xe 
2
According to Arrhenius equation for nth order reaction
(a) t1/ 2 is indepedent of temperature (b) t1/ 2 increases with increase in temperature
(c) t1/ 2 decreases with increase in temperature (d) t1/ 2 decreases with decrease in temperature
29. The correct matches
Isotherm Adsorption equation
kP
(I) Langmuir 
1  kP
(II) Gibbs   kP1/ n
(III) Freundlich   c1n  c2 P 

(IV) Temkin  
u2
(a) II and III (b) I, II and IV (c) I only (d) II, III and IV
5
30. In case of lattice point at the face centre in a F.C.C. lattice, the C.N. is
(a) 6, 6 from adjacent edge centres
(b) 8, 4 from adjacent corners and 4 from adjacent face centres
(c) 12, 4 from adjacent corners and 8 from adjacent face centres
(d) 12, 8 from adjacent corners and 4 from adjacent face centres
PART – C
31. The dielectric constant of 0.1M NaCl and 0.2 M MgCl2 solution is 121 and 100. The Debye screening
length is same for both the solution if
(a) TNaCl  2.5 TMgCl2 (b) TNaCl  7.3 TMgCl2
(c) TMgCl2  2.5 TNaCl (d) TMgCl2  7.3 TNaCl
32. NO3 
 NO 2  acidic medium  E 0  0.8 V
NO3 
 NH 4 OH  acidic medium  E 0  0.74 V
The pH at which both the half cell have same Ecell is
(a) 8.23 (b) 1.16 (c) 4.23 (d) 3.28
33. The cell potential of the given half cell is
Pt | Cl2 10 atm  | HCl  0.1 M  E 0  1.36 V
(a) 1.45 V (b) 1.27 V (c) 1.56 V (d) 1.16 V
34. CP–CV for a gas following the equation P(V–nb) = nRT is
nR
(a) nR (b) 1 (c) nRT (d)
V  nb
35. If the pressure P(system) is less than the P(surrounding), then
(a) work is done by the system on the surroundings
(b) work is done on the system by the surrounding
(c) internal energy of the system decreases
(d) work done on the system by the surroundings is equal to the work done on the surroundings by the system.
36. The temperature of a mono atomic ideal gas raised from 300K to 400K at constant pressure reversibly. The
molar entropy change for the process is
(a) zero www.careerendeavour.com
(b) –5.97 JK–1mol–1 (c) 5.97 JK–1mol–1 (d) 10.8 JK–1mol–1
37. 0.1 mol of NaOH and 0.3 mol of Ca(OH)2 is added in a flask and volume is raised to 100 L. The pH of
resulting solution is
(a) 2.7 (b) 11.3 (c) 2.3 (d) 11.7
38. The phase diagram of A and B is of simple eutectic type. The eutectic composition is 74% by weight of A and
mixture gets freeze at 92ºC. The freezing point of A and B are 300ºC and 200ºC. The phase at 50% B and
100ºC are
(a) A(s) + B(s) (b) A(s) + Melt (c) B(s) + Melt (d) B(s)
39. For HCl molecule v  2989.7 cm 1 and vx  52.05 cm 1 , where v equilibrium vibrational frequency
and x = anharmonicity constant. The zero point energy under anharmonic potential of HCl and DCl is
(a) 1482 cm–1 and 1054 cm–1 (b) 1482 cm–1 and 1048 cm–1
–1 –1
(c) 1494.85 cm and 1057.18 cm (d) 1494.85 cm–1 and 1048 cm–1
6
40. The correct intensity pattern which H2 molecule show in rotational RAMAN spectrum (only stokes lines are
shown)
5
4 4
3 3
2 2
(a) 1 (b)
1
–
v(cm–1) –v -6B –v(cm–1) –v -6B
exc
exc
5 4
4 3
3 2
2 1
(c) (d)
1 –v -22B –v -14B –v -6B
exc exc exc
– –1
v(cm ) –v -6B –v(cm)–1
exc
41. The mean  x  variance  2  and standard deviation    for the numbers 2, 4, 6, 8 is respectively
(a) 5, 25, 5 (b) 5, 5, 5 (c) 4, 16, 4 (d) 5, 1, 1
42. For temperature T1 > T2, the qualitative temperature dependence of the probability distribution F(v) of the
speed v of a molecule in three dimensions is correctly represented by the following figure:
T2 T1
F(v)
F(v)
(a) T1 (b) T2
v v
T1
F(v)
F(v)
T2 T 1
(c) T (d) 2
v v
43. How much does the total angular momentum quantum number J change in the transition of Cr(3d6) atom
as it ionizes to Cr 2   3d 4  ?
(a) increases by 2 (b) decreases by 2 (c) decreases by 4 (d) does not change
44. In a Gouy-Chapman diffuse layer the incorrect option in the favour of thickness  rD  is
(1) Thickness is proportional to density
(2) Proportional to ionic strength
(3) Inversely proportional to dielectric constant.
(4) Proportional to temperature.
(a) 1, 2, 3 (b) 2, 3 (c) 1, 4 (d) 1 only
7
45. The character table of D3h group is given below. What is the symmetry type of normal modes given below.
F
F F
B
B F F B
F F F F
E 2C3 3C '2 h 2S3 3 v linear rotations quadratic

A '1 1 1 1 1 1 1 x 2  y2 , z 2
A '2 1 1 1 1 1 1 Rz
E' 2 1 0 2 1 0  x, y  x 2
 y 2 , xy 
A"1 1 1 1 1 1 1
A"2 1 1 1 1 1 1 z
E" 2 1 0 2 1 0 R x ,Ry   xz, yz 
(a) A '1 A"2 and E" respectively (b) A '1 E" and A"2 respectively
(c) A '1 A"2 and E ' respectively (d) A'2 E" and A"2 respectively
46. The surface tension of dilute solutions of a solute varies with the solute concentration as
   0  a ln c2
The surface excess is given by
RT  0    0   1
(a) aRT (b) (c)  ln c  RT (d)  ln c  RT
a  2   2 
–1
47. A solution of a compound (M = 250 gmol ) in Benzene contains 4g of the compound per litr. When this
solution is dropped on a water surface, the benzene evaporates and the compound forms a mono layer film of
the solid type. In order to cover an area of 400 cm2 with a monolayer, the volume of solution that should be
used in ltr is (The area covered by one molecule of the compound is 0.25 nm2)
(a) 21.6×10–5 (b) 12.16×10–5 (c) 16.6×10–5 (d) 1.66×10–5
1
48. E0 of cell reaction,
2 www.careerendeavour.com
Cl 2  g   Ag   aq   e 
 AgCl  s  is 1.90 V. If Ksp of AgCl is 10–10, then the
value of E0 for following reaction is

1
Cl2  e  
 Cl
2
(a) 1.35 (b) 1.3 (c) 2.5 (d) 2.2
49. Equal masses of polymer molecules with M1 = 10000 and M2 = 20000 are mixed. The P.D.I. (Polydispersity
Index) is
(a) 11.25 (b) 1.125 (c) 21.25 (d) 2.125
50. At higher concentrations, we observe deviations from Lamberts Beer law. Then the quantity which remains
constant in place of  is
 n   n   n  2
(c)  2
 (d)  2

(a) 2 (b)     n  2     n  2  
n  2
8
51. The following Rice-Herzfeld mechanism has been proposed for the gas phase pyrolysis of methane
k1
(i) CH 4    H•
 CH (ii) CH 3•  CH 4 
k2
 C2 H 6  H •
3
k3
(iii) H •  CH 4   CH 3•  H 2 (iv) H •  CH 3•  M 
k4
 CH 4  M
In the last reaction M is a molecule  CH 4 or C2 H 6  which can carry away the energy of recombination of H •
and CH 3• . Assuming SSA for H • and CH 3• . The overall activation energy of the reaction is
1 1
(a)  E1  E2  E3  E4  (b)  E1  E3  E2  E4 
3 3
1 1
(c)  E1  E3  E2  E4  (d)  E1  E2  E3  E4 
2 3
52. In a B.C.C. lattice, the intensity of radiation for (111) planes is (f = atomic scattering factor)
(a) f2 (b) 4f2 (c) 16f2 (d) none
53. The fraction of volume unoccupied in the unit cell of the B.C.C. lattice is
8  3 3 6 2  
(a) (b) (c) (d)
8 8 6 3 2
54. A particle of mass ‘m’ is moving under a potential of the form
1 2 2
 m x x0
V  x   2
 x0
1 2
and the wave function of the particle is   x     0  1
5 5
where  0 and  1 are the eigen functions of ground state and first excited state respectively. The expectation
value of energy will be
11 13 25 31
(a)  (b)  (c)  (d) 
10 10 10 10
55. The translational, rotational and vibrational partition functions for a molecule are ftrans  1010 , f rotation  10 ,
f vibration  1 . k BT  1013 at room temperature, N A  6  1023 .

h www.careerendeavour.com
Using approximate data given above, the frequency factor (A) for a reaction type.
Diatomic molecule + Diatomic molecule = Non-linear transition state  P
According to conventional transition state theory is
(a) 2×105 (b) 2×1012 (c) 6×105 (d) 6×1014
56. Consider a heterodiatomic molecule AB. If the electron spends 90% of its time on ‘A’ and 10% of its time on
‘B’. The wavefunction for the bonding molecular orbital is
(a)   .90  A  0.10 B (b)   0.10  A  0.90 B
(c)   0.95  A  0.32 B (d)   0.32  A  0.95 B
9
57. Consider a particle in a potential as shown below
V 
E
x=0 x
V=0 V=0
V = –V0
x = L1 x = L2
The wave function of the particle (having energy eigen value E) for bound state for region in between L1  x  L2
is
2mE 2mE
(a) A e x  B e x with   (b) A e x  B e  x with  
2 2
2m V0  E  2m V0  E 
(c) A ei x  B e i x with   (d) A ei x  B e i x with  
 
58. The wavefunction of a particle in one dimension deep square potential well extending from x = 0 to x = L is
x  x  L
  x   30
Li
the value of i is
(a) 1 (b) 1.5 (c) 2 (d) 2.5
59. An atomic spectral line is observed to split into nine components due to Zeeman shift. If the upper state of the
atom is 3D2 then the lower state will be
(a) 3F 2 (b) 3F 1 (c) 3P 1 (d) 3P 2
 
60. If Li are the components of the angular momentum operator L , then the operator  i  1, 2,3   L, L  , L 
i i
equals
   
(a) L (b) 2L (c) 3L (d)  L
10
11

TEST SERIES-B
ANSWER KEY
PART-A
1. (b) 2. (a) 3. (b) 4. (d) 5. (d) 6. (a) 7. (a)
8. (c) 9. (b) 10. (c)
PART-B
11. (c) 12. (b) 13. (c) 14. (d) 15. (b) 16. (b) 17. (d)
18. (d) 19. (d) 20. (d) 21. (b) 22. (a) 23. (c) 24. (b)
25. (c) 26. (b) 27. (d) 28. (c) 29. (c) 30. (c)
PART-C
31. (d) 32. (b) 33. (a) 34. (a) 35. (b) 36. (c) 37. (d)
38. (c) 39. (a) 40. (a) 41. (b) 42. (a) 43. (c) 44. (a)
45. (c) 46. (d) 47. (d) 48. (b) 49. (b) 50. (c) 51. (c)
52. (d) 53. (a) 54. (d) 55. (c) 56. (c) 57. (d) 58. (d)
59. (c) 60. (b)
1

2
PART – A
1. What is the last digit of 773?
(a) 7 (b) 9 (c) 3 (d) 1
2. Find the missing number :
14 36 20 50 36 54
25 25 20 10 7 ?
(a) 1 (b) 0 (c) 2 (d) 3

3. If we plot the weight (w) versus age (t) of a child in a graph, the one that will never be obtained from
amongst the four graphs given below is
w w w w
(a) (b) (c) (d)

t t t t
4. What will be the day of the week 15th August 2010?

(a) Sunday (b) Monday (c) Tuesday (d) Friday
5. Which of the following is not the member of the series
3, 5, 11, 14, 17, 21
(a) 21 (b) 17 (c) 14 (d) 3
6. A motorboat, whose speed 15 km/hr in still water goes 30 km to downstream and comes back in a
total of 4 hours 30 minutes. The speed of the stream (in km/hr) is
(a) 4 (b) 5 (c) 6 (d) 10
7. If A and B together can complete a piece of work in 15 days and B alone in 20 days. In how many
days can A alone complete the work?
(a) 60 (b) 45 (c) 40 (d) 30
8. A is son of C while C and Q are the sisters to one another. Z is the mother of Q. If P is the son of
Z, which one of the following statements is correct?
(a) Q is the grandfather of A (b) P is the maternal uncle of A
(c) P is the cousin of A (d) Z is the brother of C
9.
If Ravi moves 20 meters in East direction and then turns to his left and then moves 25 metres and
then he turns to his right and moves 25 metres. After this he turn to his right and moves 15 meters.
Now, how far is he from starting point?
(a) 40 m (b) 50 m (c) 25 m (d) 45 m
10. Find the missing character?
A D G
D I N
I P ?
(a) V (b) X (c) W (d) Y
3
PART – B
11. Arrange the relative rate of acetolysis of the following norborane derivatives
H OTs H OTs TsO H
(A) (B) (C)

(a) A > B > C (b) C > B > A (c) B > C > A (d) A < B ~ C
12. Arrange the relative rates of oxidation of typical cyclohexanols
OH OH
OH OH
(A) (B) (C) Me (D) Me

Me Me Me Me
(a) D > A > C > B (b) B > C > A > D (c) C > A > B > D (d) A > B > C > D
13. The major product and the reaction involved is
hv
(P)
O Ph
O O
Ph Ph
(a) P = and N.T(I) (b) P = and N.T(II)
O
(c) P = www.careerendeavour.com
Ph
and N.T(II) (d) P = and N.T(I)
COOH HD
Ph HC
HA Ph
14.
HB COOH
(X)
The correct relation between HA, HB, HC and HD are
(a) HB and HC are homotopic ligand (b) HD and HC are homotopic ligand
(c) HA and HC are diastereotopic (d) HA and HC similarly HD and HB are enantiotopic
4
15. Arrange the rate of solvolysis of following compounds in 80% ethanol at 25ºC
Br
Br
Br
(I) (II) (III)
(a) I > III > II (b) II > I > III (c) I > II > III (d) II > III > I
D
NMe3 
(P)
16.
H
OH
H
The major product (P) in the above reaction is
D D
(a) (b) (c) (d) No elimination product
17. The following structures are the examples of
Me
H Me
(I)
(II) Me
Me
H
Me Me Me
Me OH
Cardinene Carotol
(a) (I) Sesquiterpene and (II) monoterepene (b) (I) Sesquiterpene and Sesterterpene
(c) both are Sesquiterpenes
(d) Both are Sesterterpenes
18. At pH = 10.0 and pH = 5.0 which two structures of Arg are likely to be exist
H H
H2N N H2N N
(a) NH2 O and NH2 OH

H2N H3N
O O
H H
H2N N H2N N
(b) NH2 O and NH2 O

H3N H2N
O O
5
H H
H2N N H2N N
(c) NH2 O and NH2 O

H2N H3N
O O
H H
H2N N H2N N
(d) NH O and NH2 O

H2N H2N
O O
19. The major product (P) is
O
O m-CPBA
(P)
Ph O H
O O
O
(a) (b)
HO H PhO O H
O
O
O
O
O O
(c) (d)
Ph O H Ph O H
20. The major product (P) formed in the following reaction is

O N
H2, [Ir(COD)Py(PCy3)]PF4
Product (P)
Me
O N O N
(a) (b)
Me Me
6
O N O N
(c) (d)
Me Me
21. The major product (P) formed in the following reaction
BH3. SMe2
Product (P)
Ph
N
Ph
B O
Me
HO HO HO HO
(a) (b) (c) (d)
22. The product formed in the following reaction is

Br Me
Me RuCl3, H2O
(P)
t NaIO4
Bu Me2SiO O CCl4, MeCN
pH7 buffer
Br Me Br Me
Me
Me
(a) tBu Me SiO OH (b) tBu Me SiO OH
2 O 2 O
Br Me Br CHO
Me Me
(c) (d)
t t
Bu Me2SiO O O Bu Me2SiO O
23. What will be the intensity ratio of molecular ion signal and its isotopic signal M+1 in mass spectrum of 18-
annulene molecule?
(a) 5 : 1 (b) 3 : 1 (c) 5 : 2 (d) 4 : 3
7
Me OH
Me OH
Me
NaH, THF
20ºC Me
24. TsO
OH O
Me
Me
The above synthetic transformation is an example of
(a) Peterson Olefination (b) Julia Olefination
(c) Corey-winter synthesis (d) Grob’s fragmentation
O
R OMe
O O OMe
OMe
MeO2C (P)
xylene, 150ºC
EtCO2H
OH
O O
O O O O
(a) MeO2C (b) MeO2C

H H
R R
CO2Me CO2Me
O O
O O O O
(c) MeO2C (d) MeO2C

H H
R R
CO2Me CO2Me
An organic compound exhibits the following spectral data:
IR : 1762 cm–1
H NMR :  1.37 18H , s  ; 1.27 18 H , s 
1
13
C NMR :  188.7, 60.6, 33.2, 33.1, 31.0, 30.2, 29.3
The structure of the compound is
O O
O O
O O O
(a) (b) (c) (d)
8
27. Four entities A, B, C and D are subjected to elimination reaction under identical. Which among them will
undergo elimination reaction readily
O O
O
(A) (B) (C) (D)

Br Br
Br Br
(a) A (b) B (c) C (d) D
OEt
+ H2N OEt
EtO OEt reflux
Me O
OEt
CO2Et CO2Et CO2Et
(a) (b) (c) (d)

N Me EtO N Me N Me EtO N Me
29. (+) - Mandelic acid has a specific rotation of +160º. The observed specific rotation of a mixture of 40% (–)
mandelic acid and 60%(+)–mandelic acid is
(a) –32º (b) +32º (c) +64º (d) +26º
30. Which of the following of molecule can not give conformational isomers?
(a) Methylcyclopentane (b) Cis-decalin
(c) Cyclohexane (d) Bicyclo[2.2.1]heptane
PART – C
31. The major product (P) is,
OAc
CO2Me
(i) xylene, 
+ (P)
(ii) OsO4
(iii) TsOH
SiMe 3
(iv) m-CPBA
OAc OAc
HO CO2Me HO CO2Me
(a) (b)
HO HO
SiMe3 SiMe3
OAc OAc
HO CO2Me HO CO2Me
(c) (d)
O O
9
(i) NCS, DCM, 0ºC

NH (P)
(ii) Hg–lamp
F3CCO2H, 5h, r.t.
(iii) KOH 5%, MeOH
reflux, 2hr
NH2
NH2
(a) (b)
Cl Cl
(c) N (d) N
33. Consider the following pair of compounds

COOH COOH NH2 NH2
H3C CH3 H3C CH3

; ;
H3C CH3 H3C CH3
NO2 NO2 NO2 NO2

(A) (B) (C) (D)
The most acidic compound among A and B and most basic among C and D will be
COOH www.careerendeavour.com
NH COOH
2 NH2
H3C CH3 H3C CH3 H3C CH3
; ;
(a) (b)
H3C CH3
NO2 NO2 NO2 NO2
COOH NH2 COOH NH2
H3C CH3
; ;
(c) (d)
H3C CH3 H3C CH3 H3C CH3
NO2 NO2 NO2 NO2
10
34. The reactivity of following compounds with proton will be in the order of
O
N N N N N
H H H H
(I) (II) (III) (IV) (V)
(a) I > II > V > IV > III (b) II > I > V > IV > III
(c) I > II > IV > V > III (d) III > IV > V > II > I
35. Choose the correct order against properties mentioned in bracket
O CH2 O OH
(Acidic behaviour)
(I) H3C OH < H3C CH3
O
(II) < (Basic behaviour)

N
N O H
O O
< OCH3 (stability)
(III)
OCH3
N(CH3)2 N(CH3)2 N(CH3)2 N(CH3)2
H3CO OCH3
(IV) > (Basic behaviour)
(a) I and III are correct (b) I, III and IV are correct
(c) III and IV are correct (d) none of the above
O
C
S www.careerendeavour.com

O
C
S

(P) (Q)
36. SMe SMe
The major product (P) and (Q) are respectively
(a) P = Q = (b) P = Q =
11
(c) P = and Q= (d) P = and Q=
MeO Me MeO Me
H Ag+ H
37. AcOH
Me Me
H Br H OAc
(A) (C)
MeO H H
Me OMe
Ag+ Me
Me AcOH H
Br AcO
H Me
(B) (D)
Optically pure isomer (A) and (B) were treated with silver acetate in acetic acid. The correct statement from
the following is
(a) (A) gives optically pure (C)
(b) (A) gives optically pure (C) and (B) give optically pure (D)
(c) (A) gives racemic mixture of (C) and (B) gives optically pure (D)
(d) (B) gives racemic mixture of (D)
OH
O
O
(i) Cl , Et3N , DCM
(P)
O
(ii) , TiCl4 , DCM
(iii) NaOH, MeOH
H2O, then HCl
O O
(a) (b) (c) (d)
O OH O OH OH
OH
HO2C OBn
(i) DPPA, Et3N

(P)
Toluene, heat
(ii) H2, Pd/C
OMe
12
O O
OH
O O
H2N OBn OH
HN OBn HN OH
H2N OH
(a) (b) (c) (d)
OMe
OMe OMe

CH3
(i) KMnO4/H+
(P)
(ii) SOCl2
N (iii) NH3
(iv) Br2/KOH
COOH NH2 CO NH2 CH3
(a) (b) (c) (d)

N N N N NH2
41. Products A and B in the following reaction sequence are

O
Cl
Me3SiCl, Et3N
(A) (B)
DMF, reflux TiCl4
CH2Cl2, 50ºC, 2.5h
OSiMe3 O OSiMe3 O
(a) A = B= (b) A = B=
O O
SiMe3
SiMe3
(c) A = B=
O O
SiMe3
(d) A = B=
13
(i) EtLi, Et2O

(P)
then B(OMe)3
O (ii) H2O
(iii)
Me I
Pd(OAc)2, Et3N, PPh3
Me
(a) (b) Me B(OMe)2

B(OMe)2 O
O
Me
(c) (d) Me
O O
(i) HNO3, H2SO4, 160ºC

(P)
(ii) NaOMe, MeOH
N (iii) Ac2O, reflux
(iv) H2O
O
OMe
OMe NO2
(a) (b) (c) (d)

N O
N O H
N OAc H N OMe
44. In the following compounds, the correct order of relative stability
Me •• ••
Me
H
N ••
N •• >
(a) H H > (b) N
N
H H Me
H
H Me
•• ••
••
•• ••
N N >
Me > Me
(c) Me H (d) O N O N
••
Me
Ph
CH3Li
HO H Product (A) and (B)
45.
C
Ph O
14
(A) Relationship between product formed A and B are enantiomers
(B) Relationship between product formed A and B are diastereoisomers
(C) Major product formed according to Cram’s rule
(D) Major product formed according to Anticram’s rule
(E) Relationship between product formed A and B are homomers
The correct statement(s) is
(a) B, C (b) D, E (c) B, D (d) A, C
46. The major product (A) formed in the given reaction is
OEt
I
O
0.1–0.2 equiv. Bu3SnCl
2 equiv. NaBH3CN
Product (A)
THF, hv, r.t.
SiMe3
t
Bu Me2SiO
C4H9
O
OEt
O
C4H9
OEt
O
O SiMe3
(a) (b) SiMe3

O
C4H9
t
Bu Me2SiO
O
EtO EtO
O O www.careerendeavour.com
O O
SiMe3 SiMe3
(c) (d)
C4H9 C4H9
t O t O
BuMe2SiO Bu Me2SiO
15
47. Products (A) and (B) in the following reaction sequence are respectively
N
(i) LiTMP sBuZnBr
(A) (B)
(ii) [PdCl2(dppf)]
N Cl OHC
OMOM
(iii) LiTMP
(iv) I2
I N OMOM N OMOM
,
(a)
N N
OH OH
N OMOM N OMOM
,
(b) I N N
OH OH
OH OH
I N N
(c) ,
N Cl OMOM N Cl OMOM
OH OH
N N
,
(d) I N Cl
OMOM N Cl OMOM
48. Which will be the most appropriate technique to differentiate molecule A and B ?
H H
N N
O O
O
H H H
H HO
OH
(A) (B) O
(a) 13C NMR Spectroscopy (b) 1H NMR Spectroscopy
(c) 1H NMR NOE experiment (d) 13C DEPT Experiment
16
49. The following reaction are the examples of
O OH Ph
O Ph C CH2Ph Ph
O
(I) hv (II) hv
C6H12
(a) Paterno bucchii and Norrish Type (I) reactions respectively

(b) Paterno bucchii and Norrish Type (II) reactions respectively
(c) Norrish Type (I) and Norrish Type (II) reactions respectively
(d) both are Norrish Type (II)
50. Consider the following reaction
> 380ºC H3C Cl /AlCl3

(A) (B)
CS2; –15ºC
In the given reaction sequence A and B formed respectively will be

O
C
CH3
(a) and
COCH3
(b) and
COCH3
(c) and
COCH3
(d) and
Ph Et
H AcOH
51. Me
(P)
H OTs

Me Ph Et Et
H Ph H Me
(a) Et (b) Me (c) Mixture of (a) and (b) (d)
AcO H H OAc H H
17
SiMe2Ph
HO OH
(i) NaH
(P)
52. (ii) H2/Pd-C
HO OBn
OBn
HO OH
(a) HO OH (b) HO OH
OH OH
HO
(c) HO OBn (d) mixture of (a) and (b)
OBn
53. DNA and RNA are structurally smilar in some ways but difference in others. Choose the statements which
is/are correct for DNA but incorrect for RNA
(I) DNA contains the 2-Deoxyribose sugar (II) DNA contains pyramidine cytosine
(III) DNA contains purine adenine (III) DNA contains pyramidine thymine
(a) I and II (b) I and III (c) I and IV (d) I only
54. Treatment of D-fructose with 5-moles of HIO4 gives
(a) 3 moles of HCHO, 2 moles of HCOOH and one mole of CO2
(b) 3 moles of HCOOH, 2 moles of HCHO and one mole of CO2
(c) 4 moles of HCOOH and 2 moles of HCHO
(d) 2 moles of HCOOH and 4 moles of HCHO
55. Aromatic compounds among (I to V) are O
O
(I) (II) (III) (IV) (V)

(a) I, III and IV (b) I, II and IV (c) III and IV (d) III, IV and V
(i) O3
(P)
(ii) NaOH then HCl
18
CHO OHC CHO OHC
(a) (b)
CHO OHC COOH HOOC

COOH HOH2C COOH HOOC
(c) (d)
CH2OH HOOC COOH HOOC

Me Me
OTf
SiMe3
57. + Me3Sn Pd(PPh3)4
(X)
Me CO, THF, LiCl
The major product in the above synthetic transformation
O
O Me Me
Me Me
(a) (b)
SnMe3 Me
Me Me3Si
Me Me O Me Me
SiMe3
(c) (d)
SiMe3 Me
Me
O3
58. O [X] –30ºC [Y]
–78ºC
O
The characteristics peak in IR spectrum of compounds [X] and [Y] are given below
IR (cm–1); for [X] 1820, 1830
[Y] : 2140 cm–1
The structure of compound [X] and [Y] are, respectively
HO O OH
(a) , H C C (b) , H C C
O H CO2H O O CO2H
O O
O ,
H2C C O
(c) O , H2C C CH2 (d) O
H H O
59. A n A X 2 system gave 5 lines at 5.80, 5.65, 5.50, 1.15 and 1.00 ppm away from the TMS using an NMR
spectrometer operating at 500 MHz. The value of J AX 2  in Hz  and  AX 2 (in ppm) respectively
(a) 0.15 Hz and 7.5 ppm (b) 75 Hz and 4.575 ppm
(c) 45 Hz and 7.5 ppm (d) 0.56 Hz and 1.5 ppm
19
60. The major product formed (A) and (B) are, respectively
OR (i) (MeO)2P(O)CH2CO2Me/NaH (iii) (+) DET, Ti(Oipr)4
(A) tBuOOH, 3A
(B)
(ii) DIBAL sieves
CHO (iv) HO–, PhS–
OR OR OR OR
OH OH
(a) (b) OH
OH
HO
OH SPh SPh
OR OR
OR OR
OH
OH
(c) OH (d)
HO
O SPh OH SPh
20
21

TEST SERIES-C
ANSWER KEY
PART-A
1. (a) 2. (d) 3. (a) 4. (a) 5. (c) 6. (b) 7. (a)
8. (b) 9. (d) 10. (c)
PART-B
11. (c) 12. (a) 13. (b) 14. (d) 15. (c) 16. (c) 17. (c)
18. (c) 19. (c) 20. (d) 21. (c) 22. (c) 23. (a) 24. (d)
25. (a) 26. (b) 27. (a) 28. (a) 29. (b) 30. (d)
PART-C
31. (c) 32. (c) 33. (b) 34. (a) 35. (d) 36. (c) 37. (c)
38. (a) 39. (c) 40. (b) 41. (b) 42. (d) 43. (b) 44. (d)
45. (c) 46. (c) 47. (d) 48. (c) 49. (b) 50. (c) 51. (c)
52. (a) 53. (c) 54. (b) 55. (d) 56. (c) 57. (c) 58. (d)
59. (b) 60. (b)
1

2
PART-A
1.
25 26

27
Which of the following numbers will completely divide 3  3  3  3
28

(a) 11 (b) 16 (c) 25 (d) 30
1
2. Four different electronic devices make a beep after every 30 minutes, 1 hour, 1 hour and 1 hour 45 minutes
2
respectively. All the devices beeped together at 12 noon. They will again beep together at
(a) 12 midnight (b) 3 A.M. (c) 6 A.M. (d) 9 A.M.
3. A two digit number becomes five-sixth of itself when its digits are reversed. The two digits differ by one. The
number is
(a) 45 (b) 54 (c) 56 (d) 65
4. Milk contains 5% water. What quantity of pure milk should be added to 10 litres of milk to reduce this to 2%?
(a) 5 litres (b) 7 litres (c) 15 litres (d) 18 litres
5. A man sells two flats at the rate of Rs. 1995 lakh each. No one he gains 5% and on the other he loses 5%. His
gain or loss percent in the whole transaction is
(a) 0.25% loss (b) 0.25 % gain (c) 2.5% loss (d) 25 % loss
6. An article was sold for Rs. y after giving a discount of x %. Then its list price is
100 y 100 y 100 y
(a) (b) (c) 1   x / 100  (d) none of these
100  x 1 x
7. The speeds of three cars are in the ratio 5 : 4 : 6. The ratio between the time taken by them to travel the same
distance is
(a) 5 : 4 : 6 (b) 6 : 4 : 5 (c) 10 : 12 : 15 (d) 12 : 15 : 10
8. If x men, working x hours per day, can do x units of work in x days, then y men, working y hours per day
would be able to complete how many units of work in y days?
x2 x3 y2 y3
(a) 3 (b) 2 (c) 3 (d) 2
y y x x
9. A train x starts from Meerut at 4 P.M. and reaches Ghaziabad at 5 P.M. While another train y starts from
Ghaziabad at 4 P.M. and reaches Meerut at 5 : 30 P.M. The two trains will cross each other at
(a) 4 : 36 P.M. (b) 4.42 P.M. (c) 4 : 48 P.M. (d) 4 : 50 P.M.
10. If the side of an equilateral triangle is decreased by 20% then its area is decreased by
(a) 36% (b) 40% (c) 60% (d) 64%
11. The radius of a wire is decreased to one-third and its volume remains the same. The new length is how many
times the original length?
(a) 1 times (b) 3 times (c) 6 times (d) 9 times
12. If the number from 1 to 45 which are exactly divisible by 3 were arranged in ascending order minimum number
being on the top, which would come at the ninth place from the top?
(a) 18 (b) 24 (c) 21 (d) 27
13. Find the missing number
5 8
3 28 2 8 12 ?
4 4
(a) 2 (b) 3 (c) 4 (d) 5
3
14. Statement : (I) Some players are singers
(II) All singers are tall
Conclusion: (I) Some players are tall
(II) All players are tall
(a) Only conclusion (I) follows (b) Only conclusion (II) follows
(c) Both (I) and (II) follows (d) Neither (I) nor (II) conclusion
15. An object is projected from south-east direction to north-west direction with a certain force. Air exerts an
equal force from south-west direction to north-east direction. What will be the new direction of the object?
(a) towards south-east (b) towards north-east
(c) towards east (d) towards south-west
16. A man and his wife appear in an interview for two vacancies in the same post. The probability of husband’s
selection is (1/7) and wife’s selection is (1/5). What is the probability that only one of them is selected?
4 2 8 4
(a) (b) (c) (d)
5 7 15 7
17. In the following figure, AB be diameter of a circle whose centre is O. If AOE  150º , DAO  51º then
the measure of CBE is D
E
A O B C
(a) 115º (b) 110º (c) 105º (d) 120º

18. The perpendiculars drawn from the vertices to the opposite sides of a triangle, meet at the point
(a) incentre (b) circumcentre (c) centroid (d) orthocentre
19. The diagram is frequency polygon for the scores of students in a test. What is the total number of students
appeared in the test?
40
35
35
30 30
30
25
25
20
22.5
22.5
15 15
10
400 450 500 550 600 650 700 750 800

Scores 
(a) 180 (b) 200 (c) 250 (d) 150
20. Three taps A, B and C can fill a tank in 12, 15 and 20 hours respectively. If A is open all the time and B and C
are open for one hour each alternately, the tank will be full in
2 1
(a) 6 hrs (b) 6 hrs (c) 7 hrs (d) 7 hrs
3 2
4
PART-B
21. In 1-D simple harmonic oscillator  n  x  will be non-zero. For x = 0 for

(a) Ground state (b) First excited state
(c) Both (d) None
22. The Hermitian operator(s) is/are
d 
(a) ed / dx (b) i  dx  (c) Both (d) None
e
23. The second order reaction is represented by
–1
1
Ct Ct Ct
(a) (b) (c) (d) None
t t t
24. The fluorescence quantum efficiency is given by
1 knon-radiative 1 k non-radiative
(a)   1  kf (b)   1  kf
f f
1 1 1 k sv
(c)   1  k (d)   1  k
f f f f
25. The angle between the planes (100) and (110) is

(a) 30º (b) more than 30º but less than 45
(c) 45º (d) more than 45º
26. Which of the following is not an addition polymer
(a) ORLOM (b) DECRON (c) PVC (d) POLYSTYRENE
1
27. In Freundlich adsorption isotherm, the value of is
n
(a) 1 in case of physiosorption (b) 1 in case of chemisorption
(c) Between ‘0’ and ‘1’ in all cases (d) Between ‘2’ and ‘4’ in all cases
28. The symmetry ooperation S62 brings same molecule in an orientation that can also be obtained by performing
(a) Inversion centre (b) A two-fold axis of symmetry
(c) A three fold axis of symmetry (d) A six-fold axis of symmetry
29. The chemical potential among the following is
 U   U   H   U 
(a)  ni  (b)  ni  (c)  ni  (d)  n 
T ,P,n j S ,V ,n j T ,P,n j  i T , P ,ni
30. A carnot engine waste 4kJ of energy from 10 kJ which is it absorbs from hot reservoir. If the temperature of
cold reservoir is 99ºC, the temperature of hot reservoir is
(a) 500K (b) 610 K (c) 820 K (d) 930 K
31. The incorrect statement is
(a) On doubling the coefficient of reaction, G gets double but Ecell remain same
(b) On dubling the coefficient of reaction, G and Ecell gets double
(c) The temperature dependence of Ecell is given by Nernst equation
(d) Lower the pH, higher the concentration of H+.
5
32. For the given phase diagram
•a
The number of phase at point ‘a’ is

(a) 1 (b) 2 (c) 3 (d) 4
H2 H2
Q (P)
33. Pd-C RhL3Cl
L = PPh3
The major hydrogenation products (P) and (Q) in the above reaction are
H H
(a) P = Q = (b) P = Q=
H H
H
(c) P = and Q = (d) P = Q =
H
Co2(CO)8
(P)
34. H2
423K, 200 Bar
CHO
(a) CHO
(b)
(c) www.careerendeavour.com
(d)
CHO CHO
CH3
H2
(P)
35. [(COD)Ir(Pcy3)py]+
OHC CH3
CH3 CH3
(a) HO (b)
CH3 OHC CH3
CH3 CH3
(c) (d)
OHC CH3 OHC CH3
6
36. Find out the isostructural pair among the following homoleptic carbonyl complex
(a) Co 2  CO 8 solid and Co 2  CO 8 in hexane (b) Co 4  CO 12 and Ir4  CO 12
(c) Co 4  CO 12 and Co 6  CO 16 (d) Co 4  CO 12 and Rh 4  CO 12

37. Which of the following statement is correct in terms of dipole moment regarding compound P, Q, R and S
Br O O
Br
Br Br
Br Br
(P) (Q) (R) (S)
(a) P > Q and R < S (b) P > Q and R > S (c) P < Q and S > R (d) P = Q and S = R
R H
R H
OCOAr N
H
38. 
N
The product is an example of reaction

(a) SN2 (b) SN2 ' (c) SN1 (d) SNi
39. Which ones of the following statements are true for given reaction,
9 3
4 Be  1 H  11
 1
5 B  0n
(1) It is fusion reaction (2) It is fission reaction
(3) It is natural radioactivity decay (4) Total neutron number is conserved
(a) 1, 2 (b) 2, 3 (c) 1, 4 (d) 2, 4
O
CH3
O
(i) H CI , Et Zn 2 2 2
(P)
toluene, r.t.
(ii) H2, PtO2, AcOH
CH3
O O
CH3 CH3
O O
(a) (b)
H3C
H3C CH3 CH3
7
OH
O H
CH3 CH3
O O
(c) (d)
H3C
CH3 H3C
CH3
(i) m-CPBA
OR (P)
(ii) (MeO)P, MeOH
t
Bu-S
OR OR
(a) (b)
OH OH
OR OR
(c) (d)
OH t
Bu- S
O
hv
(P)
O O O O
(a) (b) (c) (d)

43. The products (A) and (B) in the following reaction is
(i) NaCN, HCl
D-xylose (A) + (B)
(ii) H 2, Pd/BaSO 4
(iii) H2O/HCl
(a) A = D-allose, B=D-altrose (b) A=D-glucose, B = D-mannose
(c) A = D-gulose, B = D-iodose (d) D-galactose and D-tallose
O
(i) R Cl
BF3, 0ºC
(P)
(ii) LiAlH4, Et2O
N (iii) H3O+
H
8
H OH
H
R R
(a) (b)
N N
H H
O H
R R
(c) (d)
N N
H
45. The value of  max in the following molecule is
O
(a) 260 (b) 280 (c) 373 (d) 273
46. The total number of allowed transitions between terms in the following normal electronic emission spectrum of
many electron atom is/are
3
D2  3 P1 , 3
P2  1S0 , 3 F4  3 D3
2
P3/2  2 S1/2 , 3
P0  3S1 , 3 D3  1P1
(a) 4 (b) 2 (c) 3 (d) 6
Cl
(i) 2 eq. BuLi

THF, –78ºC
(P)
(ii) DMF
N CONHPh
Cl
Cl
Ph
(a) N (b)
N
CH2OH
HO C N CONHPh
H2
O
Cl
Cl
OH
N Ph Ph
(c) (d) N N
N
O HO O
9
O
Bu3SnH/AlBN
N
(P)
C6H6
O
SPh
O O O
(a) N (b) N
(c) N (d) NH
O
O O O
O CO2Et
(i) LiAlH4
(P)
(ii) TsCl
(iii) Base
O
O
(a) (b) (c) CHO (d)
(i) MeCO3H/AcOH
(P)
(ii) LiAlH4, H3O+
OH
(a) (b) OH
HO
HO
O www.careerendeavour.com
CHO
(c) (d) OHC
HO
51. If the leading anharmonic correction to the energy of the nth vibrational level of a diatomic molecule is
2
 1
 xe  n    with xe  0.003 . The total number of energy levels possible is approximately
 2
(a) 166 (b) 200 (c) 366 (d) 416
52. Classify the following carboranes by structural type

(1) C2 B9 H12 (2) C2 B7 H13 (3) C4 B2 H 6
(a) 1–nido, 2-arachano, 3-nido (b) 1-nido, 2-closo, 3-nido
(c) 1-closo, 2-arachano, 3-nido (d) 1-closo, 2-nido, 3-nido
10
53. Predict the product (equimolar mixture)

 C 2 H 4  PtCl3   NH 3 

(a) cis  Pt  C2 H 4  NH3Cl2  (b) trans   Pt  NH3 2 Cl2 
(c) trans   Pt  C 2 H 4   NH 3  Cl2  (d) cis   Pt  NH 3 2 Cl2 

54. Which statement is correct description of hemerythrin
(a) A heme protein with one Fe centre at the active site
(b) A metalloprotein containing two Fe centre at the active site
(c) The non-heme protein with one Fe centre at active site
(d) A heme protein without Fe centre at the active site
55. The enzyme which contain cubane like ferrodoxin is
(a) carbonic anhydrase (b) urease
(c) zymase (D) nitrogenase
56. Which of the following carbide on hydrolysis produce CH 4 as product?
(A) CaC2 (b) Mg2C3 (C) Be2C (D) Al4C3
(a) A and B (b) only D (c) C and D (d) only C
57. The alkaline hydrolysis of P4 with NaOH produces
(a) Na2H2PO2 (b) Na2H2PO3
(c) P(OH)3 (d) NaH2PO2 and PH3
58. Which of the following pair of halide show metallic conductivity
(a) LaI3 and CeI3 (b) ThI2 and LuI3
(c) GdI3 and LaI2 (d) ThI2 and LaI2
59. NCl3 hydrolyzes readily in water, forming
(a) NH2OH and HCl (b) NH4+ OH– and HOCl
+ –
(c) NH4 OH and HClO4 (d) NH3 and HCl
60. Assign the R/S configuration at chiral centre, the correct option is
H OH
OH
(a) 1S, 5S, 6S (b) 1S, 5R, 6S (c) 1R, 5R, 6R (d) 1R, 5S, 6R
PART-C
61. Consider a particle of mass ‘m’ moving under a potential of the form
1 2
 kx for x  0
V  x   2
 otherwise
The third excited state corresponds to n equals
(a) 3 (b) 5 (c) 7 (d) none
3 
62. An electron is confined in a cubic box of side a. The degeneracy of the state having momentum is
a
(a) 1 (b) 3 (c) 6 (d) none
11
63. Consider a particle of mass ‘m’ confined in a infinite potential well in between ‘0’ and ‘L’. A constant perturba-
tion is applied as shown beloiw
V0
0 L/2 L
The first order correction to the ground state is
3V0 V0
(a) (b) (c) 0 (d) none
4 4
64. For the following sequence of reactions
k1

2 A   k3
 4 B  3C , 2 B  P
k2
d  B
the is given by
dt
1 2 1 4 3 1 2 1 2 1 4 3 2
(a) k1  A  k2  B  C   k3  B  (b) k1  A  k2  B  C   k3  B 
4 4 2 2 2
2 4 3 2 2 4 3 2
(c) 2k1  A  2k2  B  C   k3  B  (d) 4k1  A  4k2  B  C   2k3  B 
65. The data obtained from two sets of experiment A and B have the following characteristics
Experiment A B
Mean 25 units 50 units
Standard Deviation 4 units 4 units
It may be concluded that
(a) A is more precise than B (b) A is less precise than B
(c) A and B are the same precision (d) Relative precision of A and B can not be assessed
66. The rate dependence for a particular reaction at a particular temperature is given by
13000
ln k  5 
T
The activation enegy at 130 K is (R = 2 cal K–1 mole–1)
(a) 100 kcal K–1 mole–1 (b) 100 kcal mole–1
–1
(c) 26 kcal mole (d) 26 kcal K–1 mole–1
67. The co-ordination number of anion in case of sphelerite and wurtzite structure are respectively
(a) 4 and 4 (b) 4 and 8 (c) 8 and 4 (d) none
68. The plane(s) which show allowed reflection in both bcc and fcc lattices is/are
(I) (100) (II) (111) (III) (110)
(a) II (b) III (c) I (d) None
69. The probability of link is given by
kav  1 kav k av  1 kav
(a) k (b) k  1 (c) k (d) k  1
av av av av
12
70. The incorrect statement regarding physiosorption is
(a) It occurs because of Vanderwalls forces
(b) More easily liquiefiable gases are adsorbed readily
(c) Under high pressure it results into multimolecular layer on adsorbent surface
(d) Enthalpy of adsorption is low and positive
71. The characters of reducible representation of SF4 molecule w.r.to basis of 3N-coordinate are
(a) 3, –1, 1, 1 (b) 3, –1, 3, 3 (c) 15, –1, 1, 1 (d) 15, –1, 3, 3

72. If  is thermal expansion coefficient and  represents compressibility factor then for ideal gas is

1 1  P 
(a) (b) (c)   (d) 1
TP P  T V
 U 
73.   for an ideal gas is
 P V
   
(a) CV (b) C P (c) CV (d) C P
   
74. On titrating, 10 mL of HCl solution with 0.2 M NaOH solution conductometrically following plot is observed.
The molarity of HCl is
Conductance
20 mL
Vol. of titrant 
(a) 0.1 M (b) 0.2 M (c) 0.3 M (d) 0.4 M
2+
75. The maximum current measured while determining M using dropping mercury electrode is 1.2 µA. Current
observed before applying voltage is 0.2µA. When –0.4V is applied, the current is 0.8µA. The E1/2 will be
(a) -0.395 (b) -0.405 (c) -0.390 (d) -0.410
76. Which of the following statements is incorrect in regard to boron nitride?
(a) Both boron nitride and graphite are slippery solids
(b) Both boron nitride and graphite have layered structures with sheets made up of hexagonal rings
(c) The hexagonal ring in boron nitride is made up of alternate B and N atoms joined together
(d) Both boron nitride and graphite are electrical condutors
77. The mean number of molecules per unit volume with a speed v in the range between v and v + dv is given
by a function F(v)dv as
2
F (v)dv  C  v 2ev /T dv
then mean speed is
8T 4T 2T T
(a) (b) (c) (d)
   
13
Br
78. (Cp)2Fe2(CO)4 2Na (A) (B)
hv
(C)
The product A, B and C, respectively are

(a) A : 5CpFe  CO  2    
B : 5CpFe 1C3H 5  C : 5CpFe 3C3H5 
    

(b) A : 5CpFe  CO  2  B :  CpFe   C H   CO   C :   CpFe   C H   CO 
5 1
3 5
5 3
3 5
   2 

(c) A : 5CpFe  CO  2  B :  CpFe   C H   CO   C :   CpFe   C H   CO  
5 1
3 5
5 1
3 5
   2  2

(d) A :  HFe  CO 4  B :  HFe   C H   CO   C :  HFe  CO    C H  
1
3 5
3
3 5
   4  2
C 6H 5R
 5CpFe  CO  Br  
79.  2  AlBr3   P 
The major product in the above reaction is

5
(a)   CpFe  CO 2 R  
(b)  5CpFe 5C5H5 
  
5 6

(c)   CpFe  C6 H5 R  AlBr4  (d)   CpFe   C H R  
5 6
6 5
Me H
H Me H Me
 
(P) (Q)
H H Me H
80. NMe2 NMe2
O O
The major product (P) and (Q) are respectively
Me Me Me H
(a) P = Q = (b) P = Q =
H H H Me
H H Me H
(c) P = and Q=
Me Me H Me
Me H Me Me
(d) P = and Q=
H Me
H H
81. In the following reaction
(1) 92 U 238  234
 90 Th   (2) 12 Mg 24     24
 13 Al (3) 4 Be9  24 He 
 12
6 Cn
The artificial radioactive decay is/are
(a) 2, 3 (b) 1, 2 (c) 1, 3 (d) none of these
CHO
CO2Me
(i) DABCO
+ (P)
(ii) AcCl, Py
(iii) NaBH4, tBuOH
(iv) KOH, MeOH
OMe
14
OAc OAc
CO2Me CO2H
(a) (b)
MeO MeO
CO2H CO2Me
(c) CH3 (d) CH3
MeO MeO
O
O
(i) PPh3, Et2O

(P)
(ii) BnO2CCHO
N3 O THF, then
NaBH3CN, MeOH
OMe
O O
O O
BnO O BnO O
(a) (b)
N O O N O
H H
OMe OMe
O O
O O
(c) (d)
H2N O www.careerendeavour.com
H N OH 2
OMe OMe

O
N Cl O
SiMe3 (P)
0ºC
xylene, reflux
O O O O
O O O
N O N N N
(a) (b) (c) (d)
15
O
hv
(P)
O O O O
(a) (b) (c) (d)

NH2
(i) NaNO2, HCl then 
(P)
(ii) Furan/ 
CO2H (iii) H+ then H2, Pd/C
(iv) H2SO4, 160ºC
SO3H
SO3H
(a) (b)
OH SO3H
SO3H OH
(c) (d)
87. A pentapeptide Ala-Val-Gly-Lys-Asp upon two cycles Edmann degradation gives a tripeptide (X). Treatment
of tripeptide with sangers reagent and followed by hydrolysis gives (y). The product (y) is
CH3 H2N
(a)
O2N N
H www.careerendeavour.com
COOH
(b)
O N N
H
COOH 2
NO2 NO2
H3C CH3
O2N N COOH
H
(c) (d) O2N N COOH
H
NO2
NO2
Me
Me2C=CHCOMe
H2SO4, aq. EtOH
(P)
N
Me
16
Me
Me
Me
(a) (b)
Me Me Me O
N
N
Me Me
Me O
Me Me Me Me
Me Me
(c) (d)
N O N O
H H
Me Me
89. The correct match for isomer shift in the following complex in Mossbauer spectrum is/are
Complex Isomer shift
(A) K 3  Fe  CN 6  (P) 0.119
(B) K 2  Fe  CN 5 NO  (Q) 0.085

(C) FeCl3  6H 2 O (R) –0.012
(D) FeSO 4  7H 2O (S) –0.027
(a) A  P, B  R, C  S, D  Q (b) A  R, B  S, C  Q, D  P
(c) A  Q, B  P, C  R, D  S (d) A  S, B  Q, C  P, D  R
3
90. Total number of ESR line in the ESR spsectrum of [AlH3] radical,  Mo
  13
  
CN  , radical, NO2 SO3
8
 ,
2
cycloctatetraene radical (A = 3.21 G), (Al, I = 5/2)
(a) 24, 9, 3, 8 (b) 20, 8, 4, 9 (c) 24, 3, 9, 8 (d) 24, 9, 3, 9
91. In a potentiometric titration the end point is not obtained by observing
(1) change in colour (2) jump in potential
(3) increase in current (4) increase in turbidity
The correct option is
(a) 1, 2 (b) 2, 3 (c) 4, 2 (d) 1, 3, 4
O O
NaH
92. + www.careerendeavour.com
C
(B)
EtO OEt
(A)
In the following transformation the 1H NMR signal difference between compound A and B is/are
(a) 0 (b) 2 (c) 5 (d) 3
NaBH4, H2O
(P)
hv
(A)
93.
N (Q)
hv, H2O
17
H
(a) H H2NHC CHCH CHCHO

N
H
H
(b) H2NHC CHCH CHCHO
N
H
H
(c) H2NH2C CH2CH2 CH2 CHO

N
H
H2 H2
(d) H2N C C C CHCHO
N H

OH
(i) H2SO4
(P)
(ii) H2O
O O
H2N O
C OH
HN CH3 NH N
(a) (b) (c) (d)
O
(i) NaBH4, CeCl3 (v) 70ºC
(ii) Ac2O, Et3N (vi) PhSeCl, CH2Cl2
95. (A) (vii) H O (B)
(iii) LDA, THF 2 2
(iv) TBSCl
O
OTBS O
(a)
O
O
OTBS
O
O
(b)
O
O
18
OTBS
O
O
(c)
O
O
O
O
O
(d) TBSO
O
O
(i) H+
(P)
(ii) H2O
OH
HO
(a) (b) (c) (d)
H
OH
OH
(i) tBuOOH, (iPrO)4Tl
Major product
(+)–DET
(P)
(ii) PrCOCl
O O
O O
(a) (b)
O O
O O
OHC
(c) (d) Cl
O
98. The major product (P) is www.careerendeavour.com
COOH
(i) NaHCO3
+ (P)
(ii) I2
O O O O
O O O
O
(a) (b) (c) (d)
I
I I I
19
O
Ph O Et3SiH
O (P)
BnO BF3.OEt2
CH2Cl2
OBn
OMe
O H H
O
Ph O
(a) O OMe (b) Ph O
O
BnO
BnO
OMe
BnO HO
O Ph O
HO O OMe
(c) BnO (d)
OBn OMe H OH
100. In the [M L 4] spherical rotor the M–L bond length is 200 pm. The moment of inertia of ML4 would be close to
[Mass of M = 9.5×10–27 kg, L = 6.5×10–27 kg]
(a) 69×10–20 kg mtr2 (b) 69×10–47 kg mtr2 (c) 60×10–51 kg mtr2 (d) 59×10–50 kg mtr2
101. The number of possible isomers for complexes Re  arphos 2 Br2

As(CH3)2
arphos =
P(CH3)2
(a) 3 (b) 4 (c) 6 (d) 8
102. On the basis of VSEPR, the structures of
Xe  OTeF5 4 and Xe  O   OTeF5  4 respectively are
(a) Td and trigonal bipyramidal (b) square planar and trigonal bipyramidal
(c) Td and square pyramidal (d) square planar and square pyramindal
103. Consider the correct statement for diatomic cation Br2 and I2
(1) The bond order of these cation is smaller than corresponding neutral diatomic molecule
(2) The bond length of these cation is smaller than corresponding neutral diatomic molecule
(3) They are coloured due to electronic transition from *g (HOMO) to *u (LUMO)
(4) I2+ is bright red while Br2 + is blue
(a) 2, 3 and 4 (b) 1, 2 and 3 (c) 2 and 3 (d) 3 and 4
2 2 2
104. Solution of the complexes (A)  Co  NH 3 6  , (B) Co  H 2O 6  &  C  CoCl4  are coloured. One is
pink, another yellow and third is blue, select the colour match from following
(a) A-Blue, B-yellow, C-pink (b) A-yellow, B-pink, C-blue
(c) A-pink, B-blue, C-yellow (d) A-yellow, B-blue, C-pink
20
105. The electronic absorption spectra of a series of complexes of formula
Re  CO 3  L  DBSQ , where DBSQ = 3, 5 ditert-butyl-1, 2-benzosemiquinone
Show a single maximum in visible region. The absorption maximum for three of these complexes in benzene
solution are shown below (molar absorptivity are in range of 5, 000 to 6, 000 L mol–1cm–1).
L vmax, cm–1
P(OPh3)3 18250
PPh3 17300
NEt3 16, 670
Are these band are more likely due to
(a) MLCT (b) LMCT (c) d-d transition (d) ILCT
106. Consider the correct statement from following
4
(a) The complex  Co  NO 2 6  have one unpaired electron and LFSE (in 0 ) is –1.8
3
(b) The magnetic moment of  Co  NH3 6  is non-zero

(c) The geometry of  Co  CO 4  is square planar
(d) K 2  NiF6  is diamagnetic while K 3  CoF6  is paramagnetic
O
n-BuLi ClCH2OMe H+
107. (OC)5Cr (A) (B) (D)
The major product (B) and (D) is

O
H
B = (OC)5Cr D = (OC)5Cr C OH
(a)
CHOMe
MeOHC
O
H
D = (OC)5Cr C
(b) B = (OC)5Cr OH
CH2OMe O
MeOH2C
O O
(OC)5Cr
D = (OC) Cr
(c) B = 5
H
MeOH2C
H
O
(d) B = (OC)5Cr D = (OC)5Cr

H
MeOH2C O
MeOH2C
21
108. Match the Column-I with Column-II
Column-I Column-II
(P) Ferritin (I) Electron transport
(Q) Vitamin B12 (II) Ionophore
(R) Cytochromes (III) Oxygen transport
(S) Valinomycin (IV) Nitrogen fixation
(V) Organometallic enzyme
(VI) Iron storage
(a) P-VI, Q-IV, R-II, S-I (b) P-I, Q-III, R-VI, S-IV
(c) P-III, Q-V, R-IV, S-VI (d) P-VI, Q-V, R-I, S-II
109. Select the correct statement among following
(1) Ferroquin is an anti-malerial drug and contain ferrocene an organometallic moiety
(2) In Coenzyme B12 , the sixth ligand is a cyanide group
(3) Fe2S2 invovle in electron transfer in photosynthesis and it has two acid labile sulphur
(4) Ceruloplasmin is intensely blue glycoprotein and it act as Cu transfer protein and has role as Fe storage
protein
(a) 1, 2 and 3 (b) 1, 2 and 4 (c) 1, 3 and 4 (d) only 4
110. For a gaseous reaction,
2AB  g   D 2  g   non-linear T.S.  2ABD
The pre-exponential factor in the rate constants is proportional to
(a) T–7/2 (b) T–5/2 (c) T–1/2 (d) T1/2
111. If the change in entropy from the collection of an amount I of information (measured in bits) is
s   k log e 2 I then decrease in entropy of a reader’s brain during the reading of book. (The book uses
only latin alphabets and puncfuation mark which requires 25 different characters, so 5 bits are needed to
specify anyone character. Consider the book has 400 pages in which each page has 50 lines of 70 characters.
Hint: Calculate I from the additional information]
(a) –10–10 J K–1 (b) 1010 J K–1 (c) –10–16 J K–1 (d) 10–16 J K–1
2
112. Correct order of rate of electron transfer in following pair  Co  NH 3 5 X  / Eu 2  aq  , with respect to X
(X= Cl, Br, I, F) is
(a) I > Br > Cl > F (b) F > Cl > Br > I
(c) I > Br > F > Cl (d) Br > I > Cl > F
113. Consider the following reaction,

n 1 n 
 Co  en 2 L Cl  H 2O   Cl 
 Co  en 2 L  H 2O  
 trans   cis trans 
The correct order of ligand with respect to percentage cis-product is [when L  OH  , NH3 , NO2 , Br  ]
(a) NH 3  OH   NO 2  Br  (b) OH   Br   NH3  NO 2
(c) Br   OH   NO2  NH 3 (d) NO 2  Br   OH   NH 3
114. Which of the following statement(s) are TRUE?
(1) Sm2+ > Yb2+ > Eu2+ (reducing power)
(2) Eu > Yb > Ce > Ho (metallic radii)
(3) Ce3+ (aq) and Yb3+ (aq) are coloured
2
(4) Coordination number of Th in  Th  CH 3COO 6  is 12
(a) 1, 2, 3, 4 (b) 2, 4
(c) 1, 4 (d) 1, 2, 4
22
115. Incorrect statement about following compounds
(A) 1, 2 difluoroethane
(B) n-butane
(C) 1, 2-dihydroxyethane
(a) Most stable conformation of n-butane is anti
(b) Most stable conformation of 1, 2-difluoroethane is anti
(c) Most stable conformation of 1, 2-dihydroxyethane is gauche
(d) Most stable conformation of 1, 2-difluoroethane is gauche.
116. Molecular formula : C9H8O
UV : max 285 nm
IR (cm–1) : 3090-3000, 1680, 1630, 1610-1455
NMR :  6.62 doublet of doublet, 1H J = 16.3 and 7.4 Hz
 7.41 , doublet, 1H, J = 16.3
 7.40 , multiplet, 5H
 9.66 , doublet, 1H, J = 7.4 Hz
Mass (m/z) : 132, 131, 103, 91, 77, 51
The correct possible structure is
H CH2 CHO
Ph H H
C C H
(a) H C H (b) CHO(c) (d) C C
O H CH2 CHO
117.
1 5
 
The number of 1H NMR signals appear for the compound   Cp   Cp Fe  CO 2 at –80ºC with 
intensity ratio.
(a) 3 signals with 5 : 2 : 1 intensity ratio. (b) 4 signals with 5 : 2 : 2 : 1 intensity ratio
(c) 2 signals with 5 : 5 intensity ratio (d) only one signal of 10 Hs.
118. The number of isomers in carboranes, C2 B3H 5 , C 2 B4 H 6 , C2 B5 H 7 respectively are
(a) 4, 2 and 3 (b) 3, 2 and 5 (c) 3, 2 and 4 (d) 2, 4 and 3
OTs
N
(i) Base
H3C (P)
C2H5 (ii) H2O
H H
H
O NH2
N
NH2
H3C H3C
H3C C2H5 (d)
(a) C2H5 (b) H3C (c) C2H5
C2H5
OH NH2 O
23
O
HCl
(P)
O
O O
Cl
(a) (b)
O O
Cl
O
O
(c) HO Cl (d)
O Cl
24
25

TEST SERIES-D
[FULL LENGTH TEST-1]
ANSWER KEY
PART-A
1. (d) 2. (d) 3. (b) 4. (c) 5. (a) 6. (a) 7. (d)
8. (d) 9. (a) 10. (a) 11. (d) 12. (d) 13. (a) 14. (a)
15. (b) 16. (b) 17. (c) 18. (d) 19. (a) 20. (c)
PART-B
21. (a) 22. (b) 23. (b) 24. (b) 25. (c) 26. (b) 27. (c)
28. (c) 29. (b) 30. (d) 31. (b) 32. (a) 33. (c) 34. (a)
35. (b) 36. (d) 37. (b) 38. (b) 39. (c) 40. (a) 41. (b)
42. (a) 43. (c) 44. (a) 45. (b) 46. (a) 47. (c) 48. (b)
49. (c) 50. (b) 51. (a) 52. (a) 53. (c) 54. (b) 55. (d)
56. (c) 57. (d) 58. (d) 59. (b) 60. (b)
PART-C
61. (c) 62. (b) 63. (a) 64. (d) 65. (b) 66. (c) 67. (a)
68. (d) 69. (c) 70. (d) 71. (d) 72. (c) 73. (a) 74. (d)
75. (a) 76. (d) 77. (b) 78. (b) 79. (c) 80. (c) 81. (a)
82. (c) 83. (a) 84. (c) 85. (d) 86. (a) 87. (c) 88. (c)
89. (b) 90. (d) 91. (d) 92. (c) 93. (b) 94. (c) 95. (b)
96. (c) 97. (b) 98. (d) 99. (c) 100. (b) 101. (d) 102. (d)
103. (c) 104. (b) 105. (a) 106. (d) 107. (c) 108. (d) 109. (c)
110. (a) 111. (c) 112. (b) 113. (b) 114. (d) 115. (b) 116. (a)
117. (b) 118. (c) 119. (c) 120. (d)
1

2
PART-A
1. A man earns Rs. 20 on the first day and spends Rs. 15 on the next day. He again earns Rs. 20 on the third day
and spends Rs. 15 on the fourth day. If the continuous to save like this, how soon will he have Rs. 60 in hand?
(a) on 17th day (b) On 27th day (c) On 30th day (d) On 40th day
2. The average age of students of a class is 15.8 years. The average age of boys in the class is 16.4 years and that
of the girls is 15.4 years. The ratio of the number of boys to the number of girls in the class is
(a) 1 : 2 (b) 2 : 3 (c) 3 : 4 (d) 3 : 5
3. The age of father 10 years ago was thrice the age of his son. Ten years hence, father’s age will be twicec that
of his son. The ratio of their present ages is
(a) 5 : 2 (b) 7 : 3 (c) 9 : 2 (d) 13 : 4
4. In a fraction, if numerator is increased by 40% and denominator is increased by 80% then what fraction of the
original is the new fraction?
(a) 1/2 (b) 7/9 (c) 7/18 (d) data inadequate
5. In the following figure, a part of the figure is missing. Find out the missing figure
(a) (b) (c) (d)
6. Some articles were bought at 6 for Rs. 5 and sold at 5 for Rs. 6. Gain percent is
1
(a) 30% (b) 33 % (c) 35% (d) 44%
3
1
7. In a school, 10% of the boys are same in number as th of the girls. What is the ratio of boys to girls in that
4
school?
(a) 3 : 2 (b) 5 : 2 (c) 2 : 1 (d) 4 : 3
3 pumps, working 8 hours a day, can empty a tank in 2 days. How many hours a day must 4 pumps work to
empty the tank in 1 day?
(a) 9 (b) 10 (c) 11 (d) 12
1 1
9. If A can do of a work in 3 days and B can do of the same work in 4 days. How much will A get if both
4 6
work together and are paid Rs. 180 in all?
(a) Rs. 36 (b) Rs. 60 (c) Rs. 108 (d) Rs. 120
10. What is the number of dots on the face, opposite to the face that contains 2 dots
• • • • •
•
• • • ••
• • •
• • •
• • •
(a) 1 (b) 3 (c) 4 (d) 6
3
6
11. Walking th of his usual speed, a man is 12 minutes too lage. The usual time taken by him to cover that
7
distance is
(a) 1 hour (b) 1 hour 12 min
(c) 1 hour 15 min (d) 1 hour 20 min
12. The area of the target triangle that can be inscribed in a semi-circle of radius r is
(a) r2 (b) 2r2 (c) r3 (d) 2r3
13. If the radius of a circle is diminished by 10% then its area is diminished by
(a) 10% (b) 19% (c) 20% (d) 36%
14. 12 spheres of the same size are made from melting a solid cylinder of 16 cm. Diameter and 2 cm height. The
diameter of each sphere is
(a) 3 cm (b) 2 cm (c) 3 cm (d) 4 cm
15. How many times in a day, are the hands of a clock in straight line but opposite in direction?
(a) 20 (b) 22 (c) 24 (d) 48
16. In this figure B  38º , AC  BC and AD = CD then find D

A
38º
B C D
(a) 26º (b) 28º (c) 38º (d) 52º
17. A box contains 5 green, 4 yellow and 3 white marbles. Three marbles are drawn at random. What is the
probability that they are not of the same colour
3 3 52 41
(a) (b) (c) (d)
44 55 55 44
18. ‘Sailor’ is related to ‘Ship’ in the same way as ‘Lawyer’ is related to
(a) legal (b) law (c) court (d) ruling
19. In the following figure PQ is tangent and QOR is the diameter of circle, if QPO  35º then POR is equa
to
Q
O 35º
P
R
(a) 125º (b) 120º (c) 70º (d) 115º
20. Which number will come in place of ‘?’
3 5 4 7 3 5
39 51 ?
6 3 5 4 5 4
(a) 35 (b) 37 (c) 45 (d) 47
4
PART-B
21. The geometry and coordination number for  UO 2  MeCO 2 2  2H 2O complex is

(a) octahedral and 6 (b) hexagonal bipyramidal and 8
(c) square antiprismatic and 8 (d) pentagonal bipyramidal and 7
22. A possible geometry for an eight coordinate complex ML8 might be a hexagonal bipyramidal. For this geom-
etry. Assuming low spin, which of following configuration expected to show Jahn-Teller distortion?
(a) d1, d2, d4, d9 (b) d4, d9 (c) d1, d3, d5, d7 (d) d1, d4, d5, d7
23. The pair of Ln3+ that show strongest luminiscence is
(a) La3+ and Gd3+ (b) Lu3+ and Gd3+ (c) Eu3+ and Tb3+ (d) Sm3+ and Ce3+
24. BiCl3 on hydrolysis produces a white turbidity due to formation of
(a) Bi(OH)3 (b) BiOCl (c) BiCl2(OH) (d) Bi(OH)2Cl
25. The major product ‘A’ formed in the following reaction,
O
H2, Pd-C
Ph Product (A)
MeOH
OH OH O
Ph
(a) Ph (b) Ph (c) Ph (d)
26. Consider the statement

R H hc
(1) The degeneracy of an hydrogenic orbital having energy  is 25 (If spin is involved)
25
27h 2
(2) The degeneracy of a particle confined to move in 3D cubic box having energy is 1.
8m2
6 2
(3) The degeneracy of a particle rotating with energy is 7.
r 2
Which of the following statement(s) is false?
(a) 1, 2 (b) 2, 3 (c) 1, 3 (d) 3 only
Br
(i) n-BuLi/–78ºC
(P)
(ii) DMF
S (iii) Br2/AcOH
Br O O O
Br
H H H H
(a) (b) (c) (d)
S
Br Br
O S S S
5

28.   ClF2   PtF6
(I) PtF5  ClF3 
(II) Pt  XeF4 
 PtF4  Xe

(III) NOF  ClF3    NO   ClF4 
Identify the correct statement about above reaction
(a) I is correct, PtF5 behave as base
(b) II is correct, XeF4 behave as acid
(c) III is correct, NOF behave as acid
(d) I, II, III are correct, and in II, Pt behave as acid.
29. Consider the correct statement among the following
2 3 3 4
(a)  Co  H 2 O 6    Co  H 2 O 6    Fe  CN 6    Fe  CN 6  increasing order of 0

(b)  AgF4  ,  NiCl 2  PPh 3  2  , are square planar complexes y
2
(c) The spectroscopic ground state term symbol and total number of electronic transition for  Ti  H 2O 6 
are 3T1g and 3 respectively.
(d) Arphos is an pentadentate ligand
30. Consider the correct statement(s) among the following
(1) The enthalpies of hydration for Na  , K  and Rb  are –296, –321 and –404 kJ mol–1, respectively
(2) The pyroxene CaMg Si2O6 and CaFeSi2O6 are isomorphous
(3) The carbide ThC2 liberate C2H2 and C2H6 when treated with water
(4) The structure of SNF3 is planar
(a) 1 and 2 (b) 2 and 3 (c) 1, 2 and 4 (d) 1 and 4
SPh
MeO2C
(i) 120ºC
+ O (P)
(ii) m-CPBA
(iii) P(OMe)3
CO Me
CO Me
2 2
O O
(a) (b)
HO HO
H H
R R
OH CO2Me
CO2Me
O
O
(c) (d) HO
H
H R
R
6
32. The correct order of pKa values of the following compounds
HN
(I) N
(II) (III) (IV)
N N N
H H H H H H
(a) I > II > III > IV (b) I > III > II > IV (c) I > III > IV > II (d) IV > II > III > I
O
(i) ClB(C-Hex)2, Et3N
Ph (P)
(ii) R-CHO
(iii) Hydrolysis
O OH O OH
(a) Ph R (b) Ph R
(c) both (a) and (b) in equal amounts (d) none of these
O2N
(i) NaN3, H2SO4

C O (P)
(ii) , H2O
MeO
O O
(a) O2N C NH OMe (b) MeO C NH NO2
O2N
NH2
(c) (d) MeO C N
MeO
O
(i) LDA, THF, -78ºC
(P)
(ii) Me3SiCl
35. (iii) CH3–CH2–Cl
ZnBr2, CH2Cl2
O O O
O
(a) (b) (c) (d)
7
36. Which among the following gives negative Tollen’s test and will not form osazone with phenylhydrazine
(a) D-Galactose (b) Maltose (c) D-fructose (d) Sucrose
37. In the following reaction the products (P) and (Q) are
hv
(P)
(I) O (II) hv
(Q)
O
O O O O
(a) P = Q= (b) P = Q=
O O
(c) P = Q = (d) P = Q =
OMe
O3, MeOH
(P)
38. Me2S, –78ºC
Me then NaBH4
OH HO Me
(a) (b)
Me OH HO
OMe HO OMe
O O
(c) (d)
Me OH Me
R S
CHO

N PPh
(P)
3
O
CO2R'
R S
R S
CH OH
N CO2R'
(a) (b) N
O
CO2R' O
R S R SH
N N
(c) (d) OH
O O
CO2R' CO2R'
8
THPO(H2C)8 Br Pd(PPh3)4
40. + (X)
Sia2B C2H5 
The major product (X) in the above reaction is
C2H5
THPO(H2C)8
(a) THPO(H2C)8 (b) C2H5
THPO(H2C)8
THPO(H2C)8
(c) C2H5 (d)
C2H5
82
Br
NaF
82 (P)
41. Br
Br
82
(a) (b) (c) (d) Br
82
Br Br Br Br
42. Which of the following pairs of complexes shows labile and inert complexes respectively
3 2 3 3
(a)  Co  H 2O 6  and  Cu  H 2 O 6  (b)  Cr  H 2 O  6  and Co  H 2 O 6 
2 3 3 2
(c)  Co  H 2O 6  and  Co  H 2 O  6  (d)  Ti  H 2 O 6  and  Cr  H 2 O 6 
43. If the temperautre is halved and the mass of the gaseous molecule is double. The rms speed of the molecular
will change by a factor of
(a) 1 (b) 2 (c) 1/4 (d) 1/2
44. The selection rules for the appearence of R branch in the rotational vibrational absorption spectra of a diatomic
molecule with in rigid rotor-harmonic oscillator model are
(a) v  1 and J  1 (b) v  1 and J  1
(c) v  1 and J  1 (d) v  1 and J  1
45.
The J  0  1 rotational transition of 1H 37Cl occurs at 700 GHz. Assuming the molecule to be a rigid rotor
the J  5  6 transition occurs at
(a) 140 cm–1 (b) 4200 cm–1 (c) 240 cm–1 (d) 180 cm–1
46. Consider N particles at a temperature T, Pressure P, volume V and chemical potential µ having energy E. The
parameters that are kept constant for a Grand canonical ensemble are
(a) V, T, N (b) V, T, µ (c) V, E, N (d) N, P, T
47. The molecular formulae of the fragments of a molecule in its mass spectrum are given below.
(P) C4H5Cl (Q) C10H9NO2 (R) C7H7 (S) C5H5Cl
Assign the incorrect statement for the above fragments
(a) Fragment P is a cation and it is even electron species.
(b) Fragment Q is a radical cation and it is odd electron species.
(c) Fragment R is a cation and it is odd mass species.
(d) Fragment S is a cation and it is even mass species.
9
48. Gas A and B are mixed in a container. The condition at which Gmix is minimum
(a) nA  nB (b) x A  xB (c) nA  nB (d) nA  1 mol , nB  2 mol
49.  F2C
CF2 = CF – CF = CF2  CF2
FC CF
For this reaction, H  49 kJ mol 1 and S  40.2 J mol 1K 1 . The temperature upto which the for-
ward reaction is spontaneous
(a) 1492ºC (b) 946ºC (c) 1219ºC (d) 1080ºC
50.  2NH 3  g 
Given : N 2  g   3H 2  g   k1
 2NO  g 
N 2  g   O2  g   k2
1
 H 2O  g 
H 2  g   O2  g   k3
2
5
 2NO  g   3H 2O  g 
The equilibrium constant for 2NH3  g   O2  g  
2
k1k 2 k1k 32 k 2 k 33
(a) k1k 2 k 3 (b) k (c) (d)
3 k2 k1
51. Migration current in polarographic experiment can be taken care of by
(a) allowing the solution to come at rest (b) increasing the rate of flow of mercury
(c) decreasing the temperature (d) none of these
52. Consider a first order reaction, A  P with half life of 20 mins. If reaction was carried out with 4M of ‘A’’
initially, then the concentration of product in units of mole litre–1 after 3.6×103 sec from the start of the reaction
will be
(a) 0.5 (b) 2.5 (c) 3.0 (d) 3.5
53. The Langmuir theory of adsorption is more applicable at
(a) low pressure and high temperature (b) low pressure and low temperature
(c) high pressure and low temperature (d) high pressure and high temperature
54. The value of Mark-Houwink exponent for which viscosity average molar mass and mass average molar mass
become equal is
(a) 0 (b) 0.5 (c) 1 (d) none
55.
The miller indices of the following planes (in a BCC lattice)
z
is
(a) (100) (b) (200) (c) (010) (d) (020)
56. Benzoic acid is titrated against NaOH conductometrically, graphical representation will be
Vol Vol Vol Vol

(a) (b) (c) (d)
G G G G
10
57. The alcohol campherlol on treatment with acid, afforded product ‘X’
Me
H+ (X)
Me
OH
For product (X), which of the following statement is correct.
Me
13
(a) X is and exhibits 9 C NMR signals in its spectrum
Me
Me Me
13
(b) X is , and exhibits 4 C NMR signals in its spectrum
Me
13
(c) X is , and exhibits 5 C NMR signals in its spectrum
Me
Me 13
(d) X is , and exhibits 8 C NMR signals in its spectrum.
Me
58. Consider the potential energy diagram for reaction about the C(2)–C(3) bond in n-butane
a g
c e
6.9 kcal/mole
b 3.4 f
0.6 kcal/mole d
0 60 120 180 240 300 360

Dihedral angle (degrees) 
The energy difference between partially eclipsed and skew conformation in kcal/mole is
(a) 2.8 (b) 2.9 (c) 3 (d) 5.4
59. Which of the following complex do not follow 18 electron rule.

(a) Fe3  CO 12 (b) Mn 2  CO 10 (c)  Cp 2 Co  (d)  Re  CO 5 
60.
3

The structure of Tc   B3H10  CO 3 is 
(a) Arachno (b) Nido (c) Closo (d) Hypho
11
PART-C
61. Consider the correct statement(s) from following?

(I) Thorium forms iodide of formula ThI 2, ThI3 and ThI4 having Th(IV) in all iodides
2
(II) In solid state, salts of  UO 2  contain linear cation. This cation has colour due to LMCT
(III) Stability of Lanthanoid dihalide with respect to disproportionation into LnX3 and Ln is greatest for X = I
(Iodine)
(IV) Reaction of NaOR with UCl4 leads to monomeric U(OR)4 complexes when R group is very bulky.
(a) I, II, III, IV (b) II, III, IV (c) I, II, III (d) I, II
62. Consider the true statement(s) from following?
(I) Electrical resistivity of metal-graphite compound increases with increase in temperature
(II) Reactivity of alkali metal graphite decrease with decrease in ionization energy of graphite (Li > Na > K >
Rb > Cs, reactivity order)
(III) Under controlled condition hydrolysis of alkali metal graphite produces hydrocarbon such as C2H2.
(IV) In alkali metal graphite, graphite layers remain intact but are stacked vertically in .....ABAB.... fashion
The correct statment is
(a) I, II, III, IV (b) II, III, IV (c) I, II, III (d) I, II
63. Consider the true statement(s) from the following
  2
(I)  Mn  CO 6   Cr  CO 6    V  CO 6    Ti  CO 6   energy for MLCT
(II) RuO 24  FeO 24  MnO34  CrO 44   t
(III) FeO 24  MnO34  CrO44  wavelength for LMCT
(IV) FeO 24  MnO34  CrO 44  energy for LMCT
(a) III, IV (b) I, II, IV (c) II, III, IV (d) I, II, III, IV
64. Products ‘A’ and ‘B’ in the following reaction are, respectively
O
B H
O (i) Br2
C6H13 C C H (A) (B)
then H2O (ii) NaOMe
C6H13 C6H13 C6H13 C6H13 Br
, ,
(a)
B(OH)2
Br
(b)
B(OH) 2
C6H13
C6H13 B(OH)2
, C6H13 C6H13 Br
(c) (d) B(OH)2
,
Br
65. Major product A and B formed in the given reaction sequence are, respectively
(i) H2B , THF, 0ºC (i) CO, H2O, 50ºC, 70 atm

(A) (B)
(ii) CO2Et (ii) H2O2, NaOAc
O
(a) B CO2Et
,
A= H B= CO2Et
12
O
(b) A = B CO2Et , B = CO2Et

H
O
(c)
A= B CO2Et , B = CO2Et
CO2Et
(d) A = B CO2Et , B =
66. In the given reaction sequencec, the major products X and Y are respectively
O
m-CPBA (Me3SiO)2
(X) CH2Cl2 (Y)
BF3, CH2Cl2
O O
O O
O O
O O
(a) , (b) ,
O O O O
O
O , O O ,
(c) (d)
67. Consider the correct statement

(a) The geometry of InCl52 is trigonal bipyramidal
(b) As > Se > Br, correct order of ionisation energy
(c) I2Cl6 is fully planar species
(d) LiF < LiCl < LiBr, correct order of melting point.
68. Treatment of an aqueous solution of NiCl2 with H2NCHPhCHPhNH2 give a blue complex (A) (µeff = 3.30 µB).
Which loose H2O on heating to form a yellow diamagnetic compound (B). The geometry of compound (A) &
(B) and number of isomer in (A) respectively are
(a) square planar, square planar and 2
(b) octahedral, tetrahedral and 2
(c) octahedral, square planar and 3
(d) square planar, octahedral and 3
69. Identify the correct statement among following
2 
(a) The room temperature magnetic moment of  CoI4  (e.g. 5.01 µB for the  Et 4 N  salt) is larger than
2
that of salt of  CoCl4 
 2
(b) The first charge transfer band for  MnO 4  occurs at 22940 cm–1 and that for  MnO4  at 18320
cm–1
2
(c) The electronic spectrum of  Ni  DMSO 6  exhibits two absorption band
(d) F  H 2O  NH 3  en  CN   I  , decreasing order of nephelauxetic effect.
13
70. Identify the fast dissociation rate constant (ks–1) of CO, cis to those ligand in given complexes follow the order
(reaction proceed via square pyramidal transition state)
  
1 Cr  CO 6  2  Cr  CO 5  PPh 3   3 Cr  CO 5 Cl   4  Cr  CO 5 Br   5  Cr  CO 5 I 
(a) 2 > 5 > 4 > 1 > 3 (b) 1 > 2 > 3 > 4 > 5
(c) 2 > 4 > 5 > 3 > 1 (d) 3 > 4 > 5 > 2 > 1
(i) NaH, (Boc)2O

(P)
(ii) H2C=C=CHSO2Ph
N
H 90º
H2 H2
C C
C SO2Ph
H2 H2
C SO2Ph
C C
(a) N H2 H2 (b)
N
Boc
Boc
Boc
N Boc
CH2 N
H
(c) (d) C
SO2Ph
SO2Ph
Me
CO2Et
(i) 130ºC, PhMe
Me
(ii) H+/H2O
(P)
(iii) H2SO4, CrO3/Acetone
N
Boc OSiMe2 tBu
Me
CO2Et Me
CO2Et
(a) (b)
N tBu CO2H
OSiMe2 N
Boc H
Me Me
CO2Et CO2H
(c) (d)
N CO2H
N
H OH H
14
73. Suggest a suitable reagents for the following conversion
OH MeO2C
OCO2Me
OCO2Me
O O O O
(a) H3C  C  OMe 3 | H  then  and 3,3 -S.T.R.
(b) H3C  C  OMe 3 | H  then  and  2,3 -S.T.R.
(c) Et  C  OMe 3 | H  then  and 3,3 -S.T.R.


(d)  Et  C  OMe 3 | H then  and  2,3 -S.T.R.
OH O
O
(i) NOCl, Py
(P)
CH3 (ii) hv
OH O OH O
OH
O O
N OH
N
(a) (b)
CH3 CH3
O www.careerendeavour.com
O
OH O
O
OH O
O
CH3
(c) (d)
HC N OH O
O
N
OH
15
HO
(i) (Boc)2O/base
OH (P)
H2N (ii) Ts-Cl/Py
(iii) Ph SH / NaH
O
(iv) Bn–Cl/Na2CO3
(v) H+
Ph S Ph S
OBn OBn
(a) (Boc)HN (b) H2N
O O
Ph S Ph S
OBn OH
(c) H2N
(d) (Boc)HN
O O
HO OH
(i) (imid)2C=S, toluene

O OH then TBSOTf, Py, DCM
(P)
(ii) P(OEt)3, reflux
N (iii) H2, Pd, EtOAc
O (iv) F3CCO2H, H2O
HO TBSO
HO O
(a) (b)
N N
HO O
TBSO www.careerendeavour.com
TBSO
HO O
(c) (d)
N N
HO O
77. In the following compounds, which one is resolvable?
(a) cis 1, 2-dimethyl cyclohexane (b) cis 1, 3-dimethyl cyclohexane
(c) trans1, 4- dimethyl cyclohexane (d) trans 1, 2-dimethyl cyclohexane
H
(i) t-BuOK, t-BuOH

(ii) C2H5I
(P)
O
H
16
H H
(a) O (b) O
H H
C2H5 C2H5
H H
C2H5 C2H5
(c) (d)
O O
H H
O O
N O (i) Bu2BOTf, iPr2NEt

(P)
(ii) PhCHO
Me Ph
OH O O OH O O
Ph N O Ph N O
(a) (b)
Me Ph Me Ph
OH O O OH O O
Ph N O Ph N O
(c) (d)
Me Ph Me Ph
SiMe2Ph
(i) Mg, Et2O, heat (V) TsOH

(A)
C5H11 Cl (B)
80. (ii) CuBr, SMe2
(iii) C4H9COCl
(iv) MeLi
The major product (A) and (B) are respectively
SiMe2Ph C4H9 SiMe2Ph C4H9
C4H9 C4H9
(a) C5H11 C5H11 Me (b) C5H11 C5H11 Me
Me Me
OH OH
SiMe2Ph Me SiMe2Ph Me
C4H9 C4H9
(c) C5H11 C5H11 C4H9 (d)
C5H11 C5H11 C4H9
OH Me
Me OH
17
81. Which of the following statements about hemoglobin is not true
(a) There is a H-bonding between an imidazole N–H of a histidine and bound O2 group.
(b) In the deoxy form, the Fe(II) atom is in the high spin state and out of the heme plane in the direction of the
histidine group.
2
(c) The dioxygen unit is bound in a bent fashion similar to the   superoxo type.
(d) Hemoglobin an  2  2 heterotetramer that binds O2 co-operatively, is found in red blood cells.
82. The enzyme nitrogenase catalyze the activation and reduction of dinotrogen to ammonia, the nitrogenase are
composed of two metalloproproteins which are commonly referred to as the Fe protein and the MFe (M =
Mo, V and Fe) co-factor. The Fe-protein commonly in the nitrogenase is
(a) Fe2S2 (b) Fe4S4 (c) dimer of Fe4S4 (d) Fe3S4
83. Which is correct for reaction with
N
P
(a) BF3 and B(CH3)3 both will add to ‘N’
(b) BF3 and B(CH3)3 both will add to ‘P’
(c) BF3 will add to ‘N’ while B(CH)3 will add to ‘P’
(d) BF3 will add to ‘P’ while B(CH3)3 will add to ‘N’.
84. In the first excited state  x


P1/2 of chlorine lies at energy of 200 cm–1 above the ground state  x

P3/2 . The
fraction of chlorine atoms in the first excited state at kBT = 210 cm–1 is close to
1 1 1 1
(a) (b) (c) (d)
1 e 1  4e 1  2e 2e
16 –1
85. The rotational constant of O is 10 cm . The wave number of incident radiation in a Raman spectrometer is
20891 cm–1. What is the wave number of second scattered stokes line (in cm–1) and second anti-stokes line (in
cm–1) is
(a) 21071 cm–1, 20711 cm–1 (b) 20791 cm–1, 20991 cm–1
(c) 20711cm–1, 21071 m–1 (d) 20971 cm–1, 20811 cm–1
86. A metal (atomic weight = 26.08) crystallises in the cubic system with a = 4.05Å. Its density is 2.7 gcm–3. The
radius of the atom of the metal is
(a) 1.4Å (b) 2.4Å (c) 3.4Å (d) none
87. The vibrational frequency of homo-nuclear diatomic molecule is v. The temperature at which the population of
1
the first excited state will be that of the ground state is given by [degeneracy of grand = 1 and degeneracy
4
of excited state = 3]
3hv 3hv hv hv
(a) 2k ln 2 (b) k ln 2 (c) 3k ln 4 (d) 2k ln 2
B B B B
88. What will be the number of hyperfine lines and intensity ratio for NH2 radical? Given that Hyperfine coupling
constant due to nitrogen and hydrogen are 2.5mT and 1.25mT respectively.
(a) Seven 1:2:2:2:2:2:1 (b) Nine 1:2:1: 1:2:1: 1:2:1
(c) Seven 1:2:3:4:3:2:1 (d) Nine 1:2:3: 4:5:4: 3:2:1
89. Which is the incorrect statement
(a) Mossbauer source for iron-57Fe can be prepared by electron capture reaction of cobalt-57
(b) Both Iron-57 and Sn-119, gives six lines in Mossbauer spectrum in magnetic splitting
(c) Both Iron-57 and Sn-119, gives six lines in Mossbauer spectrum in quadrupole splitting
(d) Both Iron-57 and Sn-119, shows opposite effect of S-electron density on Isomer shift
18
90. Number of signals in proton and carbon NMR of the above molecule will be
H3C CH3
O O
O
(a) Five and five (b) Five and six (c) Six and Six (d) Three and five
91. A compound w ith molecular formula C21H18O6 shows following spectral data. IR(KBr) 1647, 1734 cm–
1 1
. H NMR (300 MHz, CDCl3) 1H 1.35 (t, 3H, J = 7.2 Hz), 3.81 (s, 3H), 4.31-4.37 (q, 2H), 5.09 (d,
1H, J = 5.1 Hz), 5.20 (d, 1H, J = 5.1 Hz), 6.90-6.95 (m, 2H), 7.10 (d, 1H, J = 7.2 Hz), 7.26-7.43 (m,
3H), 7.58-7.64 (m, 1H), 7.79 (d, 1H, J = 7.2 Hz).
13
C NMR (75 MHz, CDCl3) 13C 14.1, 21.1, 50.2, 62.2, 89.3, 104.8, 112.1, 117.0, 123.1, 124.1,
127.0, 129.8, 132.9, 136.6, 137.7, 155.4, 159.3, 166.4, 168.8
Element C, 68.85; H, 4.95 %. Found C, 68.75; H, 5.07%. The correct structure of the compound is
CH2CH3
EtO
O O
O
OMe
OMe O
(a) OEt (b)
O O
O O
Me Me
O O
O O
OEt OEt
O O
(c) (d)
O O www.careerendeavour.com
O O
92. In C3v point group, NH3 molecule has the following symmetry operations, E , C31 , C32 ,  v ,  'v ,  v "
v
H
C31
C32
v" H H v'
The similarity transformation of C31 with respect to E , C31 and C32 are respectively
(a) E , C31 and C32 (b) C31 ,C32 and E
(c) C31 , E and C32 (d) none
19
93. The nuclear reaction accompanied with emission of neutron(s) are
27
(i) 13 Al  2 He 4 
 P30 12 1
 N13
(ii) 6 C  1H  (iii) 15 P
30
 Si30  1e0

15 7 14
(iv) 96 Am 241  2 He4   97 Bk 244  1e0

(a) only (i) (b) (i) and (iv) (c) (ii) and (iv) (d) Only (iii)
94. K sp of Fe(COH)3(s) is 10–38. If Fe|Fe3+ = 0.036V then calculate the potential of following reaction
Fe  s   3OH   aq   Fe  OH 3  s   3e
taking 0.0591  0.06
(a) 0.724 V (b) – 0.724 V (c) 0.796 (d) – 0.796
95. For the cell, Mg | Mg 2  0.01M  || pH  1, H  | Pt  H 2  , E0cell  2.37V

0.0591
(a) Ecell  2.37  V (b) Ecell  2.37  0.0591 V
2
(c) Ecell  2.37V (d) none of these
96. Observe the following electronic transition of a diatomic molecule.
 3   1  1 1  
(A) 1
 g
  g
(B) 1  u   g
(C)  u   g (D) 1  g 1  u
The allowed transitions are

(a) (A) and (C) only (b) (B) and (D) only (c) (A), (B) and (C) only (d) (A), (C) and (D) only
97. Match the following Column-A with Column-B
Column-A Column-B
(1) UV spectroscopy (P) Xenon flash lamp
(2) AAS (Q) Thermal conductivity detector
(3) Gas chromatography (R) Hallow cathode lamp
(4) Fluoroscence and phosphorescence (S) Deuterium discharge lamp
spectrophotometry
(a) 1-S, 2-Q, 3-P, 4-R (b) 1-S, 2-R, 3-Q, 4-P
(c) 1-Q, 2-R, 3-S, 4-P (d) 1-Q, 2-P, 3-S, 4-R
98.   N r  6  Z r  e  Zr /3 cos  , is a proposed hydrogenic wavefunction, where Z = atomic number, r = radial
distance from the nucleus,  = azimuthal angle, N is a constant. The CORRECT statement about  is
(1)   0 in the xy-plane

(2) one nodal plane are presenet in 
(3) two radial node are present in 
(4) one angular node are present in 
(5) the size of the orbital increases with increase in atomic number
(a) 1, 2, 4 (b) 1, 2, 3, 4 (c) 1, 2, 4, 5 (d) 1, 2, 3, 4, 5
99. Suppose  1 and  2 , are two hybrid orbitals:
 1  0.12  3s  0.63 3 px  0.77 3 p y and  2  0.12  3s  0.63 3 px  0.77 3 p y

The angle (in degrees) between them is
(a) 170 – 180 (b) 140–150 (c) 190–200 (d) 150–160
20
1
100. For a particle confined in a 1-D box of length a, find the location where wavefunction is of its maximum
2
value in its lowest energy level
a a a a
(a) x  (b) x  (c) x  (d) x 
2 6 18 3
101. The masses recorded when a substance is weighed 4 times are 15.8, 15.4, 15.6 and 16.0 mg. The variance
(square of the standard deviation) is closest to
(a) 0.02 (b) 0.05 (c) 0.10 (d) 0.20
102. An aqueous mixed solution of NaCl and HCl is exactly neutralized by an aqueous NaOH solution. The number
of components in the final mixture is
(a) 1 (b) 2 (c) 3 (d) 4
103. Which of the following statement is true about rate of acetolysis of compound P, Q, R and S
H OTs TsO H
H Br
Br H
(P) (Q) (R) (S)
F F
(a) P > Q and S > R (b) Q > P and R > S (c) P > Q and R > S (d) P ~ Q and S~R
104. Consider the statement
2
(1) If ground stationary state of a harmonic oscillator is given by  0  e  zx . Z should increase with decrease
in mass.
3 L3
(2) For the particle in box problem in  0,   the value of x in the n   limit would be
6
The true statement is
(a) 1 (b) 2 (c) 1 and 2 (d) None of these
105. www.careerendeavour.com 
Using the expression for the compressibility factor z of a vanderwall gas as Z  1   b 
a  P
RT  RT
.

The fugacity coefficient for the gas is
 a  P  a  P  a  P  a  P
(a) P e b  RT  RT (b) P e b  RT  RT (c) e b  RT  RT (d) e  b  RT  RT
106. Consider the following graphs for a zero order reaction
y1 y2
a a
The terms y1 and y2 are respectively.
(a) half life time and log (half life time) (b) quarter life time and log (quarter life time)
(c) quarter life time and half life time (d) half life time and quarter life time.
21
107. Consider the following
Number of molecules Molar mass
10 1000
20 2000
20 7000
The polydispersity index P.D.I is
(a) 0.535/361 (b) 5.35/361 (c) 53.5/361 (d) 535/361
108. The character table of Td point group is
the normal modes of vibration are

(a) A1 + 2T2 (b) A1 + E + T2 (c) A1 + E + 2T2 (d) E + 2T2
109. Which one of the following is correct when an ideal gas is expanded adiabatically
(a) q = 0, w = nCVdT, U = nCVdT, dT = –ve
(b) q = 0, w = 0, U = nCVdT, dT = – ve
(c) q = 0, w = nCVdT, U = nCVdT, dT = +ve
(d) q = 0, w = nCVdT, U = 0, dT = +ve
110. The spectrophotometric response for the titration of a mixture of M+ and A2+ ions against EDTA is as follow
c d
Absorbance
a b
Vol. of EDTA 
The correct statement is
(a) Volume ab represents A2+ and volume bc represent M+
(b) Volume ab represents M+ and volume bc represents A2+
(c) Volume ab represents M+ and volume bc represent excess of EDTA
(d) Volume ab represents M+ and volume bc represent deficiency of EDTA
Me
Me
9-BBN I CO2Et
(A) (B)
111. TMSO THF, 0ºC to rt Pd(PPh3)4
K3PO4
dioxide, 85ºC
22
The major product (B) and the name of reaction is
Me Me
(a) TMSO CO2Et , hydroboration-oxidation followed by Suzuki coupling.
Me Me
(b) TMSO , hydroboration-oxidation followed by Suzuki coupling.

CO2Et
Me Me
(c) TMSO , hydroboration-oxidation followed by Heck reaction.

CO2Et
Me Me
(d) TMSO , hydroboration reaction followed by Suzuki coupling.

CO2Et
112. Na-Hg Br 
Mn2(CO)10 (A) (B) (C)
The major product (C) and 1H NMR spectrum at room temperature are
(a) (OC)5Mn , 3 signals (b) , 3 signals

Mn(CO)5
(c) , 3 signals (d) , 2 signals.

Mn(CO)4 Mn(CO)4
 i LiNEt
113. Fe  CO 5 
2

  P
 ii  Me3O
The major product (P) and the nature of product in the above reaction are, respectively
NEt2
(a) (OC)4Fe C and Schrock carbene

OMe
NEt2
(b) (OC)4Fe C and Fischer carbene
OMe
(c)  CO 4 Fe  NEt 2  OMe  and Schrock carbene
NEt2
(d) (OC)4Fe C and Grubb’s catalyst.
OMe
114. (PPh3)2Pt (Ph3P)2Pt +
The mechanism involves in the formation of the product

(a) oxidative addition followed by  -elimination
(b)  -elimination followed by oxidative addition
(c)  -elimination followed by reductive elimination
(d) reductive elimination followed by migratory insertion
23
115. L2Pt

L2Pt
The major product formed in this reaction is

(a)  elimination followed by  -elimination
(b)  elimination followed by reductive elimination
(c) reductive elimination followed by  -elimination
(d)  -elimination followed by migratory insertion
116. The products P and Q formed in the reaction given below are
PhSeOH, CH2Cl2 d-BuOOH
(P) Q
OH
,
(a)
SePh
OH
,
(b)
SePh
OH OH
,
(c)
SePh
OH OH
,
(d)
SePh
O
Me Me2CuLi
(P)
Br
O O
Me Me
(a) (b)
Me Me
O Me
Me O
Me
(c) (d)
Me
24
(i) Zn, PPh3, CBr4

(ii) DIBAL-H (P)
CHO
(iii) BuLi (excess)
CO2Et (iv) H2O
(v) ClCO2Me, Py
C C
(a) (b)
C C
OCO2Me CO2Me
H H
C C
(c) (d)
C C
OH OH
CO2Me H
O
CO2Me
CuSO4
(P)
N2
O O
CO2Me CO2Me
(a) , carbene (b) , carbanion
H
H
O
O
CO2Me
CO2Me
(c) , carbene (d)
, carbene
H
120. One mole of helium is mixed with 2 mole of neon, both at the same temeperature and pressure. What is Smix
for this process if total volume remains constant.
(a) 9.136 JK 1 (b) 6.743 JK 1 (c) 15.897 JK 1 (d) 2.393 JK 1
All t he very Best for NET “17t h Dec. 2017” Exam
25
26

TEST SERIES-E
[FULL LENGTH TEST-2]
ANSWER KEY
PART-A
1. (a) 2. (b) 3. (b) 4. (b) 5. (d) 6. (d) 7. (b)
8. (d) 9. (d) 10. (a) 11. (b) 12. (a) 13. (b) 14. (d)
15. (b) 16. (b) 17. (a) 18. (c) 19. (a) 20. (b)
PART-B
21. (b) 22. (c) 23. (c) 24. (b) 25. (c) 26. (d) 27. (c)
28. (d) 29. (c) 30. (b) 31. (d) 32. (d) 33. (b) 34. (a)
35. (c) 36. (d) 37. (d) 38. (c) 39. (c) 40. (b) 41. (a)
42. (c) 43. (d) 44. (b) 45. (a) 46. (b) 47. (d) 48. (c)
49. (d) 50. (d) 51. (d) 52. (d) 53. (a) 54. (c) 55. (c)
56. (b) 57. (c) 58. (a) 59. (d) 60. (a)
PART-C
61. (a) 62. (d) 63. (d) 64. (b) 65. (c) 66. (b) 67. (c)
68. (c) 69. (a) 70. (d) 71. (c) 72. (d) 73. (a) 74. (c)
75. (b) 76. (a) 77. (d) 78. (d) 79. (b) 80. (c) 81. (c)
82. (c) 83. (c) 84. (c) 85. (c) 86. (a) 87. (a) 88. (a)
89. (c) 90. (b) 91. (b) 92. (d) 93. (b) 94. (c) 95. (c)
96. (b) 97. (b) 98. (a) 99. (a) 100. (b) 101. (b) 102. (b)
103. (a) 104. (d) 105. (c) 106. (d) 107. (d) 108. (c) 109. (a)
110. (a) 111. (d) 112. (d) 113. (b) 114. (c) 115. (b) 116. (d)
117. (b) 118. (a) 119. (c) 120. (c)
All t he very Best for NET “17t h Dec. 2017” Exam

33-35, Mall Road, G.T.B. Nagar, Opp. G.T.B. Nagar Metro Station Gate No. 3, Delhi-110 009 Delhi-110 016

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1

33-35, Mall Road, G.T.B. Nagar,

(X) (1) (2) (3) (4)

(a) 124 (b) 25 (c) 26 (d) 227

The acid and base in the reaction are :

24. HOMO and LUMO of I3 respectively are

(b) ZrCl4 + 4PhCH2MgCl

35. Arrange the rate of substitution reaction in the following compound

L  PhPMe 2 Ph 2 PMe PPh 3

(B) Mo  CO 3  PPh 3 3 (II) 2040, 1991

(C) Mo  CO 3 P  OMe 3 (III) 1977, 1888

(D) Mo  CO 3  PF3 3 (IV) 1934, 1835

(E) Mo  CO 3  PCl3 3 (V) 1898, 1758

(D) The ionic crystal Bi 35 is closo while Sn 94  is arachano structure

(a) FeO (b) MnO (c) TiO (d) NiO

(d) HgCl2  HgBr2  HgI2 Solubility order 

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CHEMICAL SCIENCES Date : 21-11-2017

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(a) 6 (b) 7 (c) 8 (d) 9

24. The commutation  x,  x, Hˆ   is equal to

The relaxation time    is

(c) TMgCl2  2.5 TNaCl (d) TMgCl2  7.3 TNaCl

E 2C3 3C '2 h 2S3 3 v linear rotations quadratic

value of E0 for following reaction is

f vibration  1 . k BT  1013 at room temperature, N A  6  1023 .

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(a) 1 (b) 0 (c) 2 (d) 3

(a) (b) (c) (d)

4. What will be the day of the week 15th August 2010?

(A) (B) (C)

(A) (B) (C) Me (D) Me

17. The following structures are the examples of

(a) NH2 O and NH2 OH

(b) NH2 O and NH2 O

(c) NH2 O and NH2 O

(d) NH O and NH2 O

20. The major product (P) formed in the following reaction is

(a) (b) (c) (d)

22. The product formed in the following reaction is

(a) MeO2C (b) MeO2C

(c) MeO2C (d) MeO2C

(a) (b) (c) (d)

(A) (B) (C) (D)

CO2Et CO2Et CO2Et

(a) (b) (c) (d)

(i) NCS, DCM, 0ºC

33. Consider the following pair of compounds

H3C CH3 H3C CH3

H3C CH3 H3C CH3

NO2 NO2 NO2 NO2

H3C CH3 H3C CH3 H3C CH3

NO2 NO2 NO2 NO2

COOH NH2 COOH NH2

NO2 NO2 NO2 NO2

(II) < (Basic behaviour)

N(CH3)2 N(CH3)2 N(CH3)2 N(CH3)2

The major product (P) and (Q) are respectively

(c) P = and Q= (d) P = and Q=