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Bogue calculation
The Bogue calculation is used to calculate the approximate proportions of
the four main minerals in Portland cement clinker.
The calculation assumes that the four main clinker minerals are pure
minerals with compositions:
Clinker is made by combining lime and silica and also lime with alumina
and iron. If some of the lime remains uncombined, (which it almost
certainly will) we need to subtract this from the total lime content before we
do the calculation in order to get the best estimate of the proportions of
the four main clinker minerals present. For this reason, a clinker analysis
normally gives a figure for uncombined free lime.
Thirdly, it is assumed that all the silica is present as belite and the next
calculation determines how much lime is needed to form belite from the
total silica content of the clinker. There will be a surplus of lime.
BOGUE CALCULATION
C3S = 4.0710CaO-7.6024SiO2-1.4297Fe2O3-6.7187Al2O3
C2S = 8.6024SiO2+1.0785Fe2O3+5.0683Al2O3-3.0710CaO
C3A = 2.6504Al2O3-1.6920Fe2O3
C4AF = 3.0432Fe2O3
Clinker analysis
SiO2 Al2O3 Fe2O3 CaO MgO K2O Na2O SO3 LOI
21.5 5.2 2.8 66.6 1.0 0.6 0.2 1.0 1.5
Free lime = 1.0% CaO
C3S = 4.0710CaO-7.6024SiO2-1.4297Fe2O3-6.7187Al2O3
C2S = 8.6024SiO2+1.1Fe2O3+5.0683Al2O3-3.0710CaO
C3A = 2.6504Al2O3-1.6920Fe2O3
C4AF = 3.0432Fe2O3
Therefore:
So:
C3S = 64.7%
C2S = 12.9%
C3A = 9.0%
C4AF = 8.5%
It should be stressed that the Bogue calculation does not give the 'true'
amounts of the four main clinker phases present, although this is
sometimes forgotten. The results of the Bogue calculation differ from the
'true' amounts (often called the phase proportions) principally because
the actual mineral compositions differ - often only slightly, but
occasionally more so and particularly in the case of the ferrite phase, from
the pure phase compositions assumed in the calculation.