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Grant, good Jesus, that I may live in you and for you.
Protect me in the midst of danger; comfort me in my
afflictions; give me health of body, assistance in my
temporal needs, your blessings on all that I do, and the
grace of a holy death. Within your heart I place my
every care. In every need let me come to you with
humble trust saying, Heart of Jesus, help me AMEN.
Name of Student:_________________________________________
Learner’s Reference Number (LRN): ___________________
Grade & Section:_________________________________________
Subject : GENERAL CHEMISTRY 2
Subject Teacher: ______________________________
Worksheet # 1
Date Received:_____________Date Returned:_______________
ELECTROCHEMISTRY AND ITS APPLICATIONS
Good day! I hope your day is always fine as you embrace
the beauty of life through God’s grace and mercy. Be silent for
a while and say a little prayer.
Now, as we go all the way to our exploration and discovery
journey, I want you to read and understand these standards that
we are going to meet within this quarter.
Conversion of Kc to Kp
To convert Kc to Kp, the following equation is used:
Kp=Kc(RT)Δngas(12)(12)Kp=Kc(RT)Δngas
where:
R=0.0820575 L atm mol-1 K-1 or 8.31447 J mol-1 K-1
T= Temperature in Kelvin
Δngas= Moles of gas (product) - Moles of Gas (Reactant)
Changes in Concentration
According to Le Chatelier’s principle, adding additional reactant to
a system will shift the equilibrium to the right, towards the side of
the products. By the same logic, reducing the concentration of any
product will also shift equilibrium to the right.
The converse is also true. If we add additional product to a system,
the equilibrium will shift to the left, in order to produce more
reactants. Or, if we remove reactants from the system, equilibrium
will also be shifted to the left.
Thus, according to Le Chatelier’s principle, reversible reactions
are self-correcting; when they are thrown out of balance by a change
in concentration, temperature, or pressure, the system will naturally
shift in such a way as to “re-balance” itself after the change.
This can be illustrated by the equilibrium of this reaction, where
carbon monoxide and hydrogen gas react to form methanol.
Changes in Pressure
A change in pressure or volume will result in an attempt to restore
equilibrium by creating more or less moles of gas. For example, if
the pressure in a system increases, or the volume decreases, the
equilibrium will shift to favor the side of the reaction that involves
fewer moles of gas. Similarly, if the volume of a system increases,
or the pressure decreases, the production of additional moles of gas
will be favored.
Consider the reaction of nitrogen gas with hydrogen gas to form
ammonia:
Note the number of moles of gas on the left-hand side and the
number of moles of gas on the right-hand side. When the volume of
the system is changed, the partial pressures of the gases change. If
we were to decrease pressure by increasing volume, the equilibrium
of the above reaction would shift to the left, because the reactant
side has greater number of moles than the product side. The system
tries to counteract the decrease in partial pressure of gas molecules
by shifting to the side that exerts greater pressure.
Copyright © 2020 APO Jose Catholic Educational System Foundation, Inc.
GENCHEM 2 Worksheet 7
(ACES). All Rights Reserved. No part or portion of this module may be
reproduced, copied, or transmitted in any form or by any means, electronic
or mechanical, without written permission of the copyright holder.
Similarly, if we were to increase pressure by decreasing volume, the
equilibrium would shift to the right, counteracting the pressure
increase by shifting to the side with fewer moles of gas that exert
less pressure.
Lastly, for a gas-phase reaction in which the number of moles of gas
on both sides of the equation are equal, the system will be unaffected
by changes in pressure, since [latex]\Delta n =0[/latex].
Changes in Temperature
The effect of temperature on equilibrium has to do with the heat of
reaction. Recall that for an endothermic reaction, heat is absorbed in
the reaction, and the value of [latex]\Delta H[/latex] is positive.
Thus, for an endothermic reaction, we can picture heat as being a
reactant.
For an exothermic reaction, the situation is just the opposite. Heat is
released in the reaction, so heat is a product, and the value.
If we picture heat as a reactant or a product, we can apply Le
Chatelier’s principle just like we did in our discussion on raising or
lowering concentrations. For instance, if we raise the temperature
on an endothermic reaction, it is essentially like adding more
reactant to the system, and therefore, by Le Chatelier’s principle, the
equilibrium will shift the right. Conversely, lowering the
temperature on an endothermic reaction will shift the equilibrium to
Example
In which direction will the equilibrium shift if the temperature is
raised on the following reaction?
Our heat of reaction is positive, so this reaction is endothermic.
Since this reaction is endothermic, heat is a reactant. By Le
Chatelier’s principle, increasing the temperature will shift the
equilibrium to the right, producing more NO2.
Le Chatelier’s principleThis lesson shows how Le Chatelier’s
principle predicts changes in an equilibrium. It also demonstrates an
easy and convenient method for making predictions about the
effects of temperature, concentration, and pressure.
HA(aq)⇌A−(aq)+H+(aq)
Acid Ionization Constant:
•
Ka=[A−][H+][HA]
• Base dissociation:
B(aq)+H2O(l)⇌HB+(aq)+OH−(aq)
Water as an Acid
When water acts as an acid, it donates a hydrogen ion to other
molecules and becomes a hydroxide (OH-) molecule itself. Let's
look at an example. Let's say you want to dilute a cleaning product
made mostly of ammonia, NH3, with water. Ammonia is a base that
accepts a hydrogen atom to become ammonium, or NH4+. When
ammonia is mixed with water, ammonia is a stronger base, so water
donates a hydrogen ion forming ammonium and hydroxide ions.
Determining and Calculating pH
The pH of an aqueous solution is the measure of how acidic or basic
it is. The pH of an aqueous solution can be determined and
calculated by using the concentration of hydronium
ion concentration in the solution.
The pH of an aqueous solution is based on the pH scale which
typically ranges from 0 to 14 in water (although as discussed below
this is not a formal rule). A pH of 7 is considered to be neutral. A
pH of less than 7 is considered acidic. A pH of greater than 7 is then
considered basic. Acidic solutions have high hydronium
concentrations and lower hydroxide concentrations. Basic solutions
have high hydroxide concentrations and lower hydronium
concentrations.
Well done.
Fe2+(aq)Fe2+(aq)
Ag(s)+H2S⟶Ag2S(g)+H2(g)Ag(s)+H2S⟶Ag2S(g)+H2(g)
[Figure 3]
Step 5: Check the balancing for both atoms and
charge. Occasionally, a coefficient may need to be placed in front
of a molecular formula that was not involved in the redox process.
In the current example, the equation is now balanced.
Fe2O3(s)+3CO(g)→2Fe(s)+3CO2(g)
A blast furnace is where iron ore is processed and turned into iron
metal. First, air is blown through a mixture of iron ore and coke
(carbon). The carbon monoxide produced reduces the Fe3+ ions in
the iron ore to metallic iron.
Suggestion/s :____________________________________
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Teacher’s Signature Over Printed Name
REFERENCES:
Petrucci, Ralph H., Herring, Goeffrey F., Madura, Jeffrey D., and Bissonnette, Carey. General
Chemistry: Principles and Modern Applications. 10th ed. New Jersey
General Chemistry 2 Phoenix Textbook