Redox Reactions

ABOUT EDUCATORS

DR. SHARAD KOTHARI

• MSc., PhD, NET, JRF
• 18 year experience of IIT JEE in Organic Chemistry
• Ex. Senior Faculty of Vibrant Academy, Kota and Bansal Classes, Kota

PIYUSH MAHESHWARI
• BE (Hons.)
• 11 year experience of IIT JEE in InorganicChemistry
• Author of 'Super Problems in Inorganic Chemistry',
• Ex. HOD Bansal Classes, Kota
• Ex. Senior Faculty of Vibrant Academy, Kota and Allen Career Institute, Kota

BRIJESH JINDAL
• BTech Jaipur MNIT
• 11 year experience of IIT JEE in Physical Chemistry
• Ex. Senior Faculty of Vibrant Academy, Kota, Allen Career Institute, Kota and Bansal
Classes, Kota
 R E D O X R E A C T I O N S

EXERCISE-1 (Subjective Questions)

r ts
e r ts Balancing of Redox reactions
x pe
p E
E x try
Q.1 Balance the following equations

tr y i s
i s + Al (SO )  AlCl + BaSO . em
Ch
(i) BaCl

h em 2 2

KCN + H SO  K SO + HCN .
4 3 3 4

C(iii) BCl + P + H  BP + HCl .

(ii) 2 4 2 4

3 4 2

(iv)
ts
(NH4)2 Cr2O7   N2 + Cr2O3 + H2O .
r ts
p er p e
(v)
x
KMnO + HCl  MnCl
4 + H O + Cl + KCl 2
E x 2 2

ry E+ KI + HCl  I + CaCl + H O + KCl . tr y

(vi)
st
Ca (OCl) 2

Hi AsO + KI + HCl  H AsO + KCl + I + H O .

i s 2 2 2

e
(vii)
m 3 4
h em 3 3 2 2

Ch(viii) NaClO + KI + HCl  NaCl + I + KCl + H OC.

3 2 2

Q.2 Predict the product and balance the reaction.

r ts ts
(i)
e
Ag+ + AsH3  H3AsO3 + H+ + ______
r
E xp x pe
(ii)
ry E
H2S + K2CrO4 + H2SO4  S + ________ + ________ + H2O
t y
i s i s tr
(iii) mKMnO + H SO + H O  K SO + MnSO + H O + ________.
h e 4 2 4
em 2 2 2 4 4 2

C (iv) H S + Cr O + H  Cr O + __________ +CH Oh

2 2 7
2– +
2 3 2

r ts
xpe ts
yE r
is tr x pe
em ryE
C h i s t
hem
C
Page # 1
 R E D O X R E A C T I O N S

Eq. Mass calculations

r ts
r ts x pe
pe
Q.3 Find the n factor of underlined compound in following interaction
E
x try
(i) Pb(NO3)2 + Cr2(SO4)3  PbSO4 + Cr(NO3)3
E s
try i
(ii) KMnO4 + MnSO4  MnO2

i
(iii)s P4  H2PO2¯ + PH3
em
em Ch
Ch
Q.4 Calculate normality of a salt solution [of a metal sulphate] having concentration 21.6 % w/v if its superoxide
has 16 % by mass of oxygen.

Q.5 What is the equivalent weight of H2SO4 in the reaction ?

ts
H2SO4 + NaI  Na2SO4 + I2 + H2S + H2O
r ts
x p er x pe
E
Acid Base Titration

Q.6
stryE
i s
Calculate volume of 1N H3PO4 required to react with 20ml 2N Ca(OH)2 solution. try
mi em
Q.7
e h
Calculate volume of 1N H2SO4 required to react with 20ml 1M Al(OH)3 solution.

Ch
Q.8 C
Calculate volume of 0.4 M NaOH required to react with following mixture
HCl (1 mol) + H2SO4 (2 mol)

Q.9
ts
Calculate volume of 0.2 M H2SO4 required to ract with following mixture
r ts
pe
NaOH (1mol) + Ca(OH)2 (2 mol)
x per
Q.10
yE E x
A solution containing 4.2 g of KOH and Ca(OH)2 is neutralized by an acid. It consumes 0.1 equivalent
r
i s t
of acid, calculate the percentage composition of the sample.
try
em i s
h
Q.11
em
How many ml of 0.1 N HCl are required to react completely with 19 gm mixture of Na2CO3 and
C NaHCO3 containing equimolar amounts of two?
Ch
Q.12 H3PO4 is a tri basic acid and one of its salt is NaH2PO4. What volume of 1 M NaOH solution should be
added to 12 g of NaH2PO4 to convert it into Na3PO4?

r ts
pe
Redox Titration

E x r ts
try pe
Q.13 It requires 40 ml of 1M Ce4+ to titrate 20ml of 1M Sn2+ to Sn4+. What is the oxidation state of the

i s
cerium in the product.
E x
Q.14
hem try
A volume of 10.0 ml of 1 M SeO2 reacted with exactly 20 ml of 2 M CrSO4. In the reaction, Cr2+ was
i s
C em
oxidized to Cr3+. To what oxidation state was selenium converted by the reaction.

Q.15
C h
Potassium acid oxalate K2C2O4 · 3H2C2O4·4H2O can be oxidized by MnO4– in acid medium. Calculate
the volume of 0.1M KMnO4 reacting in acid solution with 5.08 gm of the acid oxalate.

Page # 2
 R E D O X R E A C T I O N S

Q.16 A 1 g sample of H2O2 solution containing x % H2O2 by mass requires x cm3 of

s
a KMnO4 solution for

r t
s pe
complete oxidation under acidic conditions. Calculate the normality of KMnO4 solution.
r t x
Q.17
pe E
Metallic tin in the presence of HCI is oxidized by K2Cr2O7 to stannic chloride, SnCl4. What volume of

E x
s try
try
deci-normal dichromate solution would be reduced by 11.9 gm of tin. [Sn = 119]

s mi
Q.18
i e
Calculate the number of millimoles of K2Cr2O7 which will completely react with 40 ml 0.1 M KI solution.

em Ch
Ch
Q.19 Calculate volume of 0.4 M KMnO4 required to react with following in acidic medium.
KHC2O4 (1 mol) + H2C2O4 (2 mol)

Q.20 Calculate volume of 0.4 M NaOH required to react with following mixture.

ts
KHC2O4 (1 mol) + H2C2O4 (2 mol)
r ts
x p er x pe
E
Q.21 Calculate volume of 0.2 M KMnO4 required to react with following mixture in acidic medium.

stryE KHC2O4 (128 gm) + H2C2O4 (180 gm)

i s try
Q.22
mi em
520 gm mixture of Fe2O3 & FeO reacts completely with 158 gm KMnO4 in acidic medium. Calculate
e h
Ch C
the mole % of Fe2O3 in mixture.

Q.23 Calculate the millimoles of Br2 produced when 10 ml of 0.1 M BrO3¯ reacts with excess of Br¯.

Q.24 5g sample of brass was dissolved in one litre dil. H2SO4. 20 ml of this solution were mixed with KI,

r ts s
liberating I2 and Cu+ and the I2 required 20 ml of 0.03 N hypo solution for complete titration. Calculate
t
pe
the percentage of Cu in the alloy.
x per
ryE E x
t y
Q.25 A 0.96 g sample of Fe2O3 solid of 50% purity is dissolved in acid and completely reduced by heating the

i s s tr
solution with zinc dust. The resultant solution is cooled and made upto 100.0 mL. An aliquot of 25.0 mL
i
h em m
of this solution requires 30 mL of 0.01 M solution of an oxidising agent for titration. Calculate the
e
C Ch
number of moles of electrons taken up by 1 mol of oxidising agent in the reaction of the above titration.

Q.26 0.84 g iron ore containing x percent of iron was taken in a solution containing all the iron in ferrous
condition. The solution required x ml of a dichromatic solution for oxidizing the iron content to ferric
state. Calculate the normality of dichromatic solution.

r ts
Q.27
x pe
5g of pyrolusite (impure MnO2) were heated with conc. HCl and Cl2 evolved was passed through

ts
E N
r
try pe
excess of KI solution. The iodine liberated required 40 mL of hypo solution. Find the % of MnO2 in
10
i s E x
em y
the pyrolusite.

h i s tr
C
Q.28 A 5.0 cm3 solution of H2O2 liberates 0.508g of iodine from an acidified KI solution. Calculate the

em
h
strength of H2O2 solution in terms of volume strength at STP.

C
Page # 3
 R E D O X R E A C T I O N S

Q.29 One litre of a mixture of O2 and O3 (O3  O2

r ts
+ O2– )at NTP was allowed to react with an excess

s pe
of acidified solution of KI. The iodine liberated required 40 ml of M/10 sodium thiosulphate solution for
r t x
pe
titration. What is the percent of ozone in the mixture? Ultraviolet radiation of wavelength 300 nm can
E
x try
decompose ozone. Assuming that one photon can decompose one ozone molecule, how many photons
E s
try i
would have been required for the complete decomposition of ozone in the original mixture?

i s
Assume O2 is not interferring in the above reactions.
em
em Ch
Ch
Q.30 An aqueous solution containing 0.10g KIO3 (formula wt. = 214.0) was treated with an excess of KI
solution. The solution was acidified with HCl. The liberated I2 consumed 45.0 ml of thiosulphate solution
to decolourise the blue starch - iodine complex. Calculate the molarity of the sodium thiosulphate
solution.
ts r ts
Q.31
p er x
How many millilitre of 0.5 M H2SO4 are needed to dissolve 0.5 gm of copper II carbonate?
x pe
E
Q.32
yE try
Hydrogen peroxide solution (20 mL) reacts quantitatively with a solution of KMnO4 (20 mL) acidified

str i s
miwith dilute H2SO4. The same volume of the KMnO4 solution is just decolorized by 10mL of MnSO4 in

em
e h
neutral medium simultaneously forming a dark brown precipitate of hydrated MnO2. The brown precipitate

Ch C
is dissolved in 10mL of 0.2M sodium oxalate under boiling condition in the presence of dilute H2SO4.
Write the balanced equations involved in the reactions and calculate the molarity of H2O2.

Back Titration

r ts ts
pe r
Q.33 50gm of a sample of Ca(OH)2 is dissolved in 50ml of 0.5N HCl solution. The excess of HCl was titrated

E x x
with 0.3N – NaOH. The volume of NaOH used was 20cc. Calculate % purity of Ca(OH)2.
y pe
s tr ryE
Q.34
i t
One gm of impure sodium carbonate is dissolved in water and the solution is made up to 250ml. To 50ml

i s
em
of this made up solution, 50ml of 0.1N – HCl is added and the mix after shaking well required 10ml of
h em
C Ch
0.16N – NaOH solution for complete titration. Calculate the % purity of the sample.

Q.35 10 g CaCO3 were dissolved in 250 ml of 1 M HCl. What volume of 2 M KOH would be required to
neutralise excess HCl.

s
Q.36 A 3.00g sample containing Fe3O4, Fe2O3 and an inert impure substance, is treated with excess of KI

r t
pe
solution in presence of dilute H2SO4. The entire iron is converted into Fe2+ along with the liberation of

x ts
iodine. The resulting solution is diluted to 100 ml. A 20 ml of the diluted solution require 11.0 ml of 0.5 M
E r
try pe
Na2S2O3 solution to reduce the iodine present. A 50 ml of the diluted solution, after complete extraction

i s x
of the iodine requires 12.80 ml of 0.25 M KMnO4 solution in dilute H2SO4 medium for the oxidation of
E
hem i s try
Fe2+. Calculate the percentages of Fe2O3 and Fe3O4 in the original sample.

C em
C h
Page # 4
 R E D O X R E A C T I O N S

Hardness of water

r ts
s pe
Q.37 Calculate the weight of CaO required to remove hardness of 106 L of water containing 1.62 gram
Ca(HCO3)2 per litre.
e r t x
Q.38 Hardness of water is 180x
p r .y
E
r E ppm of MgSO . Express it in terms of ppm of CaCO
4
t
s hardness of water
yand 0.000111% CaCl is present in water. What ismtheimeasured 3

i t
sof washing soda required to purify 1000 L water. he
Q.39 0.00012 % MgSO
m
4 2

e
& millimoles
h C
Q.40CA sample of hard water contains 96 ppm of SO 24 

and 183 ppm of HCO , with Ca as the only
3
2+

cation. How many moles of CaO will be required to remove HCO 3 from 1000 kg of this water? If

ts r ts
1000 kg of this water is treated with the amount of CaO calculate above, what will be the conentration

er pe
(in ppm) of residual Ca2+ ions (Assume CaCO3 to be completely insoluble in water)? If the Ca2+ ions in

x p x
E
try
one litre of the treated water are completely exchanged with hydrogen ions, what will be its pH (one ppm

ryE
i st s
means one part of the substance in one million part of water, weight/ weights)?
i
em hem
Ch C

r ts ts
e r
E xp x pe
ry yE
i st i s tr
em m
Ch Ch
e

r ts
xpe ts
yE r
is tr x pe
em ryE
C h i s t
hem
C
Page # 5
 R E D O X R E A C T I O N S

EXERCISE-2 (Objective Questions)

r ts
(I)
r t s
e is based upon _________.
Fill in the blanks with appropriate items :
x pe
1.
x p
The balancing of chemical equation
r y E
r E
yiron is 56. The equivalent mass of the metal in FeCl
i t
sis ___________ and that in
2.
s t
The atomic mass
i
of
e m 2

e m
FeCl is _________.
3

C h
3. h Eq. weight of Na HPO when it reacts with excess of HCl is ______________.
CThe 2 4

4. A metallic oxide contains 60% metal. The Eq. weight of the metal is __________.

ts r ts
r e
5. The number of gm of anhydrous Na2CO3 present in 250 ml of 0.25 N solution is___________.

________ ml of 0.1 M Hp
e x p
6.
x 2 4
y .
EH CO ___________ in presence of NaOH if producttisrNaHCO E
SO is required to neutralize 50 ml of 0.2 M NaOH solution.

r y s
7.
i st
Value of n-factor of 2 3
m i 3

e m h e
ChThe equivalent mass of KMnO in alkaline medium is molarCmass divided by five.
(II) True or False Statements :
1. 4

2. The equivalent mass of Na2S2O3 in its reaction with I2 is molar mass divided by two.

3.
r ts ts
In a reaction, H2MoO4 is changed to MoO2+. In this case, H2MoO4 acts as an oxidising agent.
e
p agent. It accepts 6 electrons to give KBr. er
4.
x
KBrO acts as a strong oxidising
Ehas normality of 0.05 N. x p
y
3

st r ryE
5.

m i
0.1 M sulphuric acid
i s t
6.
h e
The
e m
reaction, 2H O  2H O + O is not an example of a redox reaction.
C The disproportionation reaction, h
2 2 2 2

7.
2Mn + 2H O  MnO + Mn + 4H
3+
C +2 +
2 2
is an example of a redox reaction.

8.
ts
The oxidation number of hydrogen is always taken as + 1 in its all compounds.
r
9.
x pe of an element implies that the element has undergone reduction.ts
The increase in oxidation number

r y E e r
i st state of oxygen atom in potassium super oxide is . 1
x p
10. The oxidation

e m

2
r y E
C h i s t
h em
C
Page # 6
 R E D O X R E A C T I O N S

(III) OBJECTIVE TYPE :

r ts
Single correct
r ts x of ferrous
e that will be needed to react completely withyoneEmole pe
Q.1 The number of moles of KMnO
x p r
y E 4

i s t
str
oxalate in acid solution is
(A) 3/5
i (B) 2/5 (C) 4/5
e m (D) 1

h one mole of sulphite ions in acidic

Q.2 Thee
h is m
number C
of moles of KMnO that will be needed to react with
Csolution
4

(A) 2/5 (B) 3/5 (C) 4/5 (D) 1

Q.3 The normality of 0.3 M phosphorus acid (H3PO3) is

ts r ts
r pe
(A) 0.1 (B) 0.9 (C) 0.3 (D) 0.6

p e x
Q.4
x y E
An aqueous solution of 6.3 gm of oxalic acid dihydrate is made upto 250 ml. The volume of 0.1 N
E
r y
NaOH required to completely neutralize 10 ml of this solution is
s tr
i st
(A) 40 ml (B) 20 ml (C) 10 ml
m i (D) 4 ml

Ine m theeequivalent mass of K Cr O is

standarization of Na S O using K Cr O by iodometryh
Ch C
Q.5 the 2 2 3 2 2 7 2 2 7
M. Mass M. Mass M. Mass
(A) (B) (C) (D) Same as M. Mass.
2 6 3

Q.6
r ts
MnO4 is good oxidising agent in different medium changing to –
ts
e r
MnO4

E
Mn2+
xp x pe
r y MnO24
y E
i st Mn O
MnO 2

i s tr
e m in oxidation number respectively are –
2 3

m
C h
Changes
(A) 1, 3, 4, 5 (B) 5, 4, 3, 2 (C) 5, 1, 3, 4 e
h (D) 2, 6, 4, 3

Q.7 Oxidation number of Cl in CaOCl (bleaching powder) is –

C
2
(A) Zero, since it contains Cl2 (B) –1, since it contains Cl–
(C) +1, since it contains ClO– (D) +1 and –1 since it contains ClO– and Cl–

r ts
Q.8
xpe
Which of the following is a redox-reaction-
ts
E
(A) 2Na[Ag(CN)2] + Zn  Na2[Zn(CN)4]+ 2Ag
y r
tr
(B) BaO2 + H2SO4  BaSO4 + H2O2
is x pe
e
(C) N2O5 + H2O  2HNO3
m
(D) AgNO3 + K  Ag + KNO3
r yE
h t
is is –
C In the coordination compound, K [Ni(CN) ], the oxidation stateeofmnickel
Q.9
–1 h
4 4
(A) +1 (B) +2 (C)
C (D) 0

Page # 7
 R E D O X R E A C T I O N S

Q.10 What would happen when a solution of potassium chromate is treated with an dilute nitric acid ?

r ts
s (D) and H O are formed x pe
(A) CrO24 is reduced to +3 state of Cr (B) CrO24 is oxidized to +7 state of Cr

e r t
x p
(C) Cr3+ and Cr2O72 are formed Cr2O72

y E 2

r and if the equivalent

y E i s t
s r E respectively then equivalent weight of Ahcanebemexpressed as
weights are E tand
Q.11 If m gram of a metal
A A displaces m gram of another metal B from its salt solution
B

m i A B

h e m
 A m m A Cm B
E B mA
 EB
C (A) E = E (B)
B E = (C) E = (D) E = B
m A
B E A
Bm A
A
A mB

Q.12 When BrO3 ion reacts with Br– in acid medium, Br2 is liberated. The equivalent weight of Br2 in this
ts r ts
er pe
reaction is
5M
x p 5M 3M 4M
E x
(A)
8
r y E (B)
3
(C)
5
(D)
6
tr y
Q.13
i s t i s
Calculate the mass of anhydrous oxalic acid, which can be oxidised to CO2(g) by 100 ml of an

e
MnOm 

h e
solution, 10 ml of which is capable of oxidising 50 ml of 1NmI to I . –

Ch(A) 45 gm
4 2
(B) 22.5 gm (C) 30 gmC (D) 12.25 gm

Q.14 1 gram at a sample of CaCO3 was strongly heated and the CO2 liberated was absorbed in 100 mL of
0.5 M NaOH. Assuming 90% purity for the sample. How much mL of 0.5 M HCl would be required to

r ts
react with the solution of the alkali to reach the phenolphthalein end point?
t s
(A) 73 mL
e
pNa C O and H C O required V litre of 0.1 M KMnO in acidic
(B) 41 mL (C) 82 mL (D) 87 mL
r
emedium
x p
EThe same amount of the mixture required V litre of 0.2 M NaOHEforxneutralization.
r y
Q.15 An equimolar mixture of
y
stV to V (V /V ) is :
2 2 4 2 2 4 1 4
for complete oxidation.
The ratioiof
i tr
sNone of these
2

e 2m
m
1 2 1 2

h
(A) :5 (B) 1 : 2 (C) 4 : 5
e
(D)
C 2gm of an impure mixture of MgCO was dissolved in 50 mlCofh0.8 M HCl. The excess of acid required
Q.16 3
20 ml of 0.2M NaOH for complete neutralization. The percentage of MgCO3 in the sample will be
(A) 7.56 % (B) 37.8 % (C) 75.6 % (D) None of these

r ts
xpe ts
yE r
is tr x pe
em ryE
C h i s t
hem
C
Page # 8
 R E D O X R E A C T I O N S

s
Match the column

r t
Q.17 To find molarity of 2 separate solutions of KMnO4 and O2 (O2  O–2), a student titrated 20 ml of

er ts x pe
KMnO4 (in neutral medium) and 10 ml of O2 separately using 3 reagents A, B & C, performing 3
p E
x try
1
E
different experiments for KMnO4 and O2 each. He found molarity of KMnO4 and O2 as
s
M and

try
20
1
s mi
i M respectively..
e
m Ch
10
e
A, B & C are FeCr2O4 , CuFeS2, FeS respectively and their reactions are :

Ch(A)
(B)
FeCr2O4  K2CrO4 + Fe2O3
CuFeS2  Cu+ + Fe2+ + SO2
(C) FeS  Fe+3 + SO2

ts
Column-I represents solution of A, B, C used for titration
r ts
er
Column-II represents milli moles of A, B, C consumed with KMnO4 or with O2.
x p x pe
E
yE try
Column-I Column-II

FeCrtr s
i
3
(A)
i s O 2 4 (P)
m11
e m (Q) he
3

C h
(B) CuFeS 2
C 7
4
(C) FeS (R)
7
4

r ts (S)
11
ts
e r
E xp x pe
ry yE
i st i s tr
em m
Ch Ch
e

r ts
xpe ts
yE r
is tr x pe
em ryE
C h i s t
hem
C
Page # 9
 R E D O X R E A C T I O N S

r ts
r ts
e EXERCISE-1 x pe
x p r yE
3BaCl + y
r AlE
i s t
Q.1 (i)

i s t
2 (SO ) ¾® 2AlCl + 3BaSO .
2 4 3

em
3 4

m
(ii) e 2KCN + H SO ¾® K SO + 2HCN C h
Ch 2 4 2 4

(iii) 4BCl3 + P4 + 6H2 ¾® 4BP + 12HCl

ts r ts
r pe
Step-1

p e x
x E
stryE
i s try
mi em
e h
Ch C
Step-2 6H2 + P4 ¾® 4P–3 + 12H+
Step-3
r ts
4BCl3 + P4 + 6H2 ¾® 4BP + 12HCl
ts
e r
E xp x pe
(iv)
r y
(NH4)2 Cr2O7 ¾®N2 + Cr2O3 + 4H2O
yE
i st
Step-1
i s tr
em m
Ch Ch
e

r ts
x pe) + Cr O ¾® N + Cr O ts
E
2

r
Step-2 2(NH +

y (NH ) Cr O ¾® N + Cr O + 4H O e
4 2 7 2 2 3

is tr
Step-3
x p
em
4 2 2

ryE7 2 2 3 2

h
C (v) KMnO + HCl ¾® MnCl + H O + Cl + KCl emis
4
t
2 2 2

Step-1
Ch
Page # 10
 R E D O X R E A C T I O N S

r ts
er ts x pe
p E
E x
s try
i s try emi
em Ch
Ch Step-2 or
2MnO 4 + 10Cl– ¾® 2Mn+2 + 5Cl 2

2KMnO4 + 10Cl– + 6Cl– ¾® 2MnCl2 + 5Cl2 + 2KCl

Step-3 2KMnO4 + 16HCl ¾® 2MnCl2 + 5Cl2 + 2KCl + 8H2O
ts r ts
x p er x pe
E
E try
(vi) Ca(OCl)2 + KI + HCl ¾® I2 + CaCl2 + H2O + KCl
Step-1ry
i st i s
em hem
Ch C

r ts ts
pe) + 4I ¾® 2I + 2Cl
x(OCl per
E Ca(OCl ) + 4KI ¾® 2I + 2KCl x
Step-2 –2 – –

y
2 2

r
st of other elements. r yE
i t
2 2

emStep-3 Ca(OCl ) + 4KI + 4HCl ¾® 2I + 4KCl +mCaClis + 2H O

Balancing

Ch 2

C he 2 2 2

(vii) H3AsO4 + KI + HCl ¾® H3AsO3 + KCl + I2 + H2O

Step-1

r ts
xpe ts
yE r
is tr x pe
em ry E
C h i s t
Im
H AsO + 2KI + HCl ¾® H AsO +e
Step-2 3 4

Balancing of other elements. C h3 + KCl + H O

3 2 2

Page # 11
 R E D O X R E A C T I O N S

Step-3 H3AsO4 + 2KI + 2HCl ¾® H3 AsO3 + 2KCl + I2 + H2O

r ts
r ts
e NaCl + I + KCl + H O x pe
xp
(viii) NaClO + KI + HCl ¾®
3 2

r yE 2

Step-1
r yE i s t
i s t em
em C h
Ch
ts r ts
p er p e
Step-2
x
NaClO + 6KI ¾® NaCl + I + 6KCl + H O
3

E x2 2

r yE NaClO + 6KI + 6HCl ¾®NaCl + 3I + 6KCl + 3HtrOy

i st
Step-3 i s
e m
3

h e m 2 2

Q.2Ch
(i) 6Ag + AsH + 3H O ¾® 6Ag + 6H + H AsO C
+
3 2
+
3 3

(ii) 3H2S + 2K2CrO4 + 5H2SO4 ¾® Cr2(SO4)3 + 2K2SO4 + 8H2O + 3S

(iii)
r t s
2KMnO4 + 3H2SO4 + 5H2O2 ¾® K2SO4 + 2MnSO4 +8 H2O + 5O2

ts
(iv)
e
24H2S + 8Cr2O72– + 16H+ ¾® 8Cr2O3 + 3S8+ 32H2O
pn = 3, n = 1 , n = 3, er
Q.3
E x
(i) 2,6,2,3 (ii) 3,2,6/5 (iii)
x p
y E
f f f

Q.4 1
i s t r Q.5 61.25
try
Q.6
e
40 ml
m Q.7 60 ml i s
Q.8 h 12.5 l em
C 12.5 l
Q.10 KOH = 35%, Ca(OH) = 65%
Q.9
Q.11 V C
h
= 3 lit.
2

Q.12 200 mL Q.13 +3

Q.14 zero
r ts Q.15 V = 160 ml

pe
Q.16 0.588 N Q.17 4 lit.

E x r ts
2
tr y pe
is
Q.18 Q.19 3l
3
E x
hel m try
Q.20 12.5
C 16.66%
Q.21 6l
i s
Q.22 Q.23 3
hem
Q.24
Q.26
38 %
0.15 N
Q.25
Q.27
C
5
0.174g; 3.48%
Page # 12
 R E D O X R E A C T I O N S

Q.28 4.48 % Q.29

r s
6.57% O3(by weight), 1.2 × 1021 photons
t
Q.30 0.0623M
e r ts Q.31 8.097 ml
x pe
Q.32 0.1M
p Q.33 1.406%
E
Q.34 90.1%
r E x
yFe O = 34.8% Q.35 V = 25 mL
i s try
i s
Q.36 Fe O = 49.33%,t Q.37 560 Kg
em
m 2 ppm,h
2 3 3 4

h e
Q.38 150 ppm Q.39
C 20 m mole.
Q.40C1.5, 40 ppm, pH = 2.6989

s EXERCISE-2
r ts
(I)
p ert x pe
x E
yE try
1. Law of conservation of mass 2. 56/2, 56/3

i s tr i s
3.
emMolecular weight
4. 12
hem
Ch
2

5. 3.3125 g 6. 50
C
7. 1
(II)
r ts ts
1. False 2. pe
xFalse 3. True 4. True
p er 5.
False
6. False
r7. E True
y 8. False 9. False
E x10. True
is t t ry
em i s
(III)
h e m
Q.1C A Q.5 hB
Q.2 A Q.3 D Q.4 A
C Q.6 C Q.7 D
Q.8 A Q.9 D Q.10 D Q.11 A Q.12 C Q.13 B Q.14 C

r ts
Q.17e (A) Q, R (B) P, S (C) Q, R
Q.15 C Q.16 C
xp ts
r yE er
is t x p
em ryE
C h i s t
h em
C
Page # 13