: SAMPLE-1_1.

SPX

[cps]
600
Fe

500

400
Sr

300 Rb

Rb Ca

Si S
200
Zn Al
Zn Fe
100 K
Mg K
Ca Ti
Na Sr Ti Cr Cr Zn Zn Rb Sr Rb Sr
0
0 5 10 15 20 [keV]
Marker 1 H Cursor 0.000 keV 0.000 cps

Sample-1_1.SPX

Live time : 100 s Processing Time : P2

XGT Dia. : 1.2 mm X-ray tube vol. : 30 kV
Current : 1.000 mA
X-ray Filter : Nonexistence Cell : Nonexistence

Quant. Corr. : Standard-less

Elem. Line Mass 2sigma Atomic Intensity Formula Mass Molecule

[%] [%] [%] [cps/mA] [%] [%]
11 Na K 2.131 0.727 2.018 2.05 Na2O 2.872 3.364
12 Mg K 0.818 0.081 0.732 6.47 MgO 1.356 2.442
13 Al K 8.647 0.119 6.978 373.78 Al2O3 16.339 11.634
14 Si K 19.423 0.208 15.054 1795.95 SiO2 41.550 50.201
16 S K 6.027 0.067 4.092 2207.47 SO3 15.050 13.647
19 K K 2.503 0.031 1.394 1064.85 K2O 3.015 2.324
20 Ca K 5.724 0.064 3.109 3089.66 CaO 8.008 10.368
22 Ti K 0.837 0.012 0.381 530.88 TiO2 1.397 1.269
24 Cr K 0.028 0.003 0.012 28.35 Cr2O3 0.041 0.020
26 Fe K 7.210 0.077 2.811 10597.39 Fe2O3 10.308 4.686
30 Zn K 0.017 0.002 0.006 35.99 ZnO 0.021 0.019
37 Rb K 0.013 0.002 0.003 41.06 Rb2O 0.014 0.006
38 Sr K 0.024 0.002 0.006 71.44 SrO 0.028 0.020
8 O 46.599 0.382 63.406
 : SAMPLE-1_2.SPX

[cps]
600
Fe

500

400 Sr

Rb
Ca
300
Rb
Si S
200
Zn Al
Zn Fe
100 KK
Mg Ca Ti
Na Sr Ti Cr Cr Zn Zn Rb Sr Rb Sr
0
0 5 10 15 20 [keV]
Marker 1 H Cursor 0.000 keV 0.000 cps

Sample-1_2.SPX

Live time : 100 s Processing Time : P2

XGT Dia. : 1.2 mm X-ray tube vol. : 30 kV
Current : 1.000 mA
X-ray Filter : Nonexistence Cell : Nonexistence

Quant. Corr. : Standard-less

Elem. Line Mass 2sigma Atomic Intensity Formula Mass Molecule

[%] [%] [%] [cps/mA] [%] [%]
11 Na K 0.000 0.822 0.000 0.00 Na2O 0.000 0.000
12 Mg K 0.972 0.088 0.874 7.72 MgO 1.611 2.917
13 Al K 8.670 0.126 7.029 374.19 Al2O3 16.382 11.726
14 Si K 18.767 0.220 14.613 1726.01 SiO2 40.145 48.759
16 S K 6.911 0.083 4.715 2525.76 SO3 17.258 15.733
19 K K 2.243 0.030 1.255 935.92 K2O 2.702 2.094
20 Ca K 6.814 0.081 3.719 3608.96 CaO 9.535 12.408
22 Ti K 0.905 0.014 0.413 547.69 TiO2 1.509 1.378
24 Cr K 0.032 0.003 0.013 30.51 Cr2O3 0.046 0.022
26 Fe K 7.510 0.087 2.941 10494.97 Fe2O3 10.738 4.907
30 Zn K 0.030 0.002 0.010 59.84 ZnO 0.038 0.034
37 Rb K 0.009 0.002 0.002 26.40 Rb2O 0.010 0.004
38 Sr K 0.022 0.002 0.005 62.44 SrO 0.026 0.018
8 O 47.116 0.422 64.410
 : SAMPLE-1_3.SPX

[cps]
600
Fe

500

400 Ca

Rb
300
Rb

200 Si S
Zn
Al Fe
Zn Sr K Ti
100
Mg K Ca
Na Sr Ti Cr Cr Zn Zn Rb Sr Rb Sr
0
0 5 10 15 20 [keV]
Marker 1 H Cursor 0.000 keV 0.000 cps

Sample-1_3.SPX

Live time : 100 s Processing Time : P2

XGT Dia. : 1.2 mm X-ray tube vol. : 30 kV
Current : 1.000 mA
X-ray Filter : Nonexistence Cell : Nonexistence

Quant. Corr. : Standard-less

Elem. Line Mass 2sigma Atomic Intensity Formula Mass Molecule

[%] [%] [%] [cps/mA] [%] [%]
11 Na K 0.000 0.217 0.000 0.00 Na2O 0.000 0.000
12 Mg K 1.002 0.078 0.920 7.69 MgO 1.661 3.002
13 Al K 8.133 0.082 6.732 341.08 Al2O3 15.368 10.981
14 Si K 17.031 0.084 13.539 1556.90 SiO2 36.432 44.171
16 S K 6.156 0.034 4.288 2313.97 SO3 15.372 13.988
19 K K 1.894 0.015 1.082 817.63 K2O 2.282 1.765
20 Ca K 9.731 0.047 5.422 5271.36 CaO 13.616 17.688
22 Ti K 1.866 0.014 0.870 1066.42 TiO2 3.112 2.838
24 Cr K 0.035 0.004 0.015 30.70 Cr2O3 0.051 0.024
26 Fe K 8.417 0.038 3.366 10760.38 Fe2O3 12.034 5.490
30 Zn K 0.024 0.002 0.008 42.88 ZnO 0.030 0.027
37 Rb K 0.010 0.002 0.003 27.47 Rb2O 0.011 0.004
38 Sr K 0.028 0.002 0.007 70.86 SrO 0.033 0.023
8 O 45.675 0.162 63.749
 : SAMPLE-2_1.SPX

[cps]
600
Fe

500

400

Rb
300 Pb
Rb Mn
Ca
S
200 Si
Zn
Al Pb
Zn Fe
100
Mg Zr KK Ti Mn
Ca
Na Zr Ti Cr Cr Zn Zn Pb Pb Rb Rb Zr Zr
0
0 5 10 15 20 [keV]
Marker 1 H Cursor 40.870 keV 0.010 cps

Sample-2_1.SPX

Live time : 100 s Processing Time : P2

XGT Dia. : 1.2 mm X-ray tube vol. : 30 kV
Current : 1.000 mA
X-ray Filter : Nonexistence Cell : Nonexistence

Quant. Corr. : Standard-less

Elem. Line Mass 2sigma Atomic Intensity Formula Mass Molecule

[%] [%] [%] [cps/mA] [%] [%]
11 Na K 4.651 0.645 4.396 4.52 Na2O 6.270 7.250
12 Mg K 1.358 0.120 1.214 10.31 MgO 2.251 4.003
13 Al K 7.841 0.108 6.315 323.01 Al2O3 14.816 10.415
14 Si K 17.688 0.181 13.683 1605.19 SiO2 37.837 45.131
16 S K 6.579 0.069 4.459 2440.94 SO3 16.430 14.709
19 K K 1.820 0.022 1.012 778.41 K2O 2.193 1.668
20 Ca K 5.876 0.061 3.186 3239.25 CaO 8.222 10.508
22 Ti K 1.210 0.015 0.549 775.39 TiO2 2.019 1.811
24 Cr K 0.023 0.003 0.009 22.90 Cr2O3 0.033 0.016
25 Mn K 0.037 0.003 0.015 44.92 MnO2 0.059 0.048
26 Fe K 6.862 0.069 2.670 10111.43 Fe2O3 9.810 4.403
30 Zn K 0.021 0.002 0.007 44.41 ZnO 0.026 0.023
37 Rb K 0.008 0.002 0.002 24.33 Rb2O 0.008 0.003
40 Zr K 0.011 0.002 0.003 29.80 ZrO2 0.015 0.009
82 Pb L 0.010 0.005 0.001 10.31 PbO 0.010 0.003
8 O 46.005 0.348 62.480
 : SAMPLE-2_2.SPX

[cps]
600
Fe

500

400

Rb
Pb
300 Mn
Rb
S
Ca
200
Si
Zn
Al Pb Fe
Zn
100
Mg Zr KK Ti Mn
Ca
Na Zr Ti Cr Cr Zn Zn Pb Pb Rb Rb Zr Zr
0
0 5 10 15 20 [keV]
Marker 1 H Cursor 40.870 keV 0.000 cps

Sample-2_2.SPX

Live time : 100 s Processing Time : P2

XGT Dia. : 1.2 mm X-ray tube vol. : 30 kV
Current : 1.000 mA
X-ray Filter : Nonexistence Cell : Nonexistence

Quant. Corr. : Standard-less

Elem. Line Mass 2sigma Atomic Intensity Formula Mass Molecule

[%] [%] [%] [cps/mA] [%] [%]
11 Na K 0.000 0.177 0.000 0.00 Na2O 0.000 0.000
12 Mg K 0.830 0.090 0.745 6.31 MgO 1.376 2.506
13 Al K 7.917 0.083 6.406 328.47 Al2O3 14.960 10.775
14 Si K 19.096 0.087 14.840 1715.03 SiO2 40.849 49.920
16 S K 7.536 0.039 5.131 2659.12 SO3 18.819 17.261
19 K K 2.094 0.017 1.169 837.72 K2O 2.522 1.966
20 Ca K 5.673 0.031 3.090 2913.89 CaO 7.937 10.393
22 Ti K 1.196 0.011 0.545 720.81 TiO2 1.994 1.833
24 Cr K 0.025 0.003 0.011 24.05 Cr2O3 0.037 0.018
25 Mn K 0.039 0.003 0.015 43.59 MnO2 0.061 0.052
26 Fe K 7.959 0.035 3.111 10883.38 Fe2O3 11.380 5.233
30 Zn K 0.025 0.002 0.008 48.23 ZnO 0.032 0.028
37 Rb K 0.008 0.002 0.002 24.30 Rb2O 0.009 0.004
40 Zr K 0.013 0.002 0.003 31.81 ZrO2 0.018 0.010
82 Pb L 0.006 0.005 0.001 5.63 PbO 0.006 0.002
8 O 47.583 0.162 64.922
 : SAMPLE-2_3.SPX

[cps]
600
Fe

500

400

Rb
300
Pb Mn
Ca
Rb
S
200 Si
Zn
Al Pb Fe
Zn
100
Mg Zr KK Ca Ti Mn
Na Zr Ti Cr Cr Zn Zn Pb Pb Rb Rb Zr Zr
0
0 5 10 15 20 [keV]
Marker 1 H Cursor 40.870 keV 0.000 cps

Sample-2_3.SPX

Live time : 100 s Processing Time : P2

XGT Dia. : 1.2 mm X-ray tube vol. : 30 kV
Current : 1.000 mA
X-ray Filter : Nonexistence Cell : Nonexistence

Quant. Corr. : Standard-less

Elem. Line Mass 2sigma Atomic Intensity Formula Mass Molecule

[%] [%] [%] [cps/mA] [%] [%]
11 Na K 3.832 0.687 3.603 3.86 Na2O 5.165 5.855
12 Mg K 1.194 0.115 1.061 9.54 MgO 1.979 3.449
13 Al K 6.626 0.098 5.309 287.94 Al2O3 12.521 8.627
14 Si K 20.687 0.216 15.919 2012.29 SiO2 44.253 51.738
16 S K 5.999 0.066 4.045 2249.91 SO3 14.981 13.146
19 K K 1.431 0.019 0.791 628.36 K2O 1.724 1.285
20 Ca K 5.925 0.064 3.195 3389.36 CaO 8.290 10.385
22 Ti K 0.835 0.012 0.377 555.42 TiO2 1.392 1.224
24 Cr K 0.021 0.003 0.009 22.47 Cr2O3 0.031 0.014
25 Mn K 0.028 0.003 0.011 35.98 MnO2 0.045 0.036
26 Fe K 6.700 0.070 2.593 10389.67 Fe2O3 9.579 4.214
30 Zn K 0.013 0.002 0.004 30.03 ZnO 0.017 0.014
37 Rb K 0.007 0.001 0.002 23.68 Rb2O 0.008 0.003
40 Zr K 0.008 0.002 0.002 24.00 ZrO2 0.011 0.006
82 Pb L 0.004 0.004 0.000 4.42 PbO 0.004 0.001
8 O 46.690 0.377 63.078
 : SAMPLE-3_1.SPX

[cps]
600
Fe

500

400

Ca
300
Mn
Si
200 S
Zn Al
Zn Sr Fe
100 KK
Mg Ca Ti Mn
Na Sr Ti Cr Cr Zn Zn Sr Sr
0
0 5 10 15 20 [keV]
Marker 1 H Cursor 40.870 keV 0.000 cps

Sample-3_1.SPX

Live time : 100 s Processing Time : P2

XGT Dia. : 1.2 mm X-ray tube vol. : 30 kV
Current : 1.000 mA
X-ray Filter : Nonexistence Cell : Nonexistence

Quant. Corr. : Standard-less

Elem. Line Mass 2sigma Atomic Intensity Formula Mass Molecule

[%] [%] [%] [cps/mA] [%] [%]
11 Na K 0.000 0.736 0.000 0.00 Na2O 0.001 0.001
12 Mg K 0.888 0.079 0.803 7.00 MgO 1.472 2.640
13 Al K 9.175 0.122 7.475 394.00 Al2O3 17.336 12.294
14 Si K 18.680 0.198 14.618 1691.37 SiO2 39.961 48.087
16 S K 5.925 0.065 4.063 2147.45 SO3 14.796 13.364
17 Cl K 0.000 0.004 0.000 0.00 Cl 0.000 0.000
19 K K 2.139 0.027 1.203 896.62 K2O 2.577 1.978
20 Ca K 8.553 0.092 4.691 4509.05 CaO 11.968 15.431
22 Ti K 1.052 0.014 0.483 605.93 TiO2 1.755 1.588
24 Cr K 0.017 0.003 0.007 15.94 Cr2O3 0.025 0.012
25 Mn K 0.016 0.003 0.007 17.94 MnO2 0.026 0.022
26 Fe K 7.016 0.074 2.761 9384.46 Fe2O3 10.031 4.542
30 Zn K 0.021 0.002 0.007 41.32 ZnO 0.026 0.023
38 Sr K 0.023 0.002 0.006 63.18 SrO 0.027 0.019
8 O 46.494 0.379 63.877
 : SAMPLE-3_2.SPX

[cps]
600
Fe

500

400 Ca

300
Mn
Si
200 S
Zn Al
Zn Sr K Fe
100 K Ca
Mg Ti Mn
Na Sr Ti Cr Cr Zn Zn Sr Sr
0
0 5 10 15 20 [keV]
Marker 1 H Cursor 40.870 keV 0.000 cps

Sample-3_2.SPX

Live time : 100 s Processing Time : P2

XGT Dia. : 1.2 mm X-ray tube vol. : 30 kV
Current : 1.000 mA
X-ray Filter : Nonexistence Cell : Nonexistence

Quant. Corr. : Standard-less

Elem. Line Mass 2sigma Atomic Intensity Formula Mass Molecule

[%] [%] [%] [cps/mA] [%] [%]
11 Na K 1.422 0.760 1.360 1.38 Na2O 1.917 2.223
12 Mg K 0.770 0.070 0.696 6.27 MgO 1.276 2.276
13 Al K 9.135 0.124 7.445 406.85 Al2O3 17.260 12.167
14 Si K 18.018 0.200 14.105 1700.94 SiO2 38.543 46.103
16 S K 5.795 0.066 3.975 2220.40 SO3 14.472 12.993
19 K K 2.032 0.026 1.143 900.50 K2O 2.447 1.867
20 Ca K 9.321 0.104 5.114 5181.83 CaO 13.042 16.715
22 Ti K 0.883 0.013 0.405 526.70 TiO2 1.473 1.325
24 Cr K 0.023 0.003 0.010 22.01 Cr2O3 0.034 0.016
25 Mn K 0.013 0.003 0.005 14.45 MnO2 0.020 0.016
26 Fe K 6.624 0.073 2.608 9273.79 Fe2O3 9.470 4.262
30 Zn K 0.018 0.002 0.006 37.10 ZnO 0.022 0.020
38 Sr K 0.020 0.002 0.005 58.16 SrO 0.023 0.016
8 O 45.928 0.386 63.123
 : SAMPLE-3_3.SPX

[cps]
600

Fe
500

Ca
400

300

Mn
200 Si S
Zn Al
Zn Sr K Fe
100
Mg K Ca Mn
Ti
Na Sr Ti Cr Cr Zn Zn Sr Sr
0
0 5 10 15 20 [keV]
Marker 1 H Cursor 40.870 keV 0.000 cps

Sample-3_3.SPX

Live time : 100 s Processing Time : P2

XGT Dia. : 1.2 mm X-ray tube vol. : 30 kV
Current : 1.000 mA
X-ray Filter : Nonexistence Cell : Nonexistence

Quant. Corr. : Standard-less

Elem. Line Mass 2sigma Atomic Intensity Formula Mass Molecule

[%] [%] [%] [cps/mA] [%] [%]
11 Na K 1.565 0.811 1.506 1.47 Na2O 2.110 2.434
12 Mg K 0.767 0.078 0.697 6.00 MgO 1.271 2.255
13 Al K 8.905 0.128 7.300 381.67 Al2O3 16.827 11.803
14 Si K 17.169 0.204 13.518 1571.97 SiO2 36.728 43.711
16 S K 5.854 0.071 4.038 2203.67 SO3 14.617 13.057
19 K K 1.926 0.026 1.089 833.95 K2O 2.320 1.761
20 Ca K 10.874 0.128 6.001 5862.22 CaO 15.215 19.403
22 Ti K 0.893 0.014 0.412 497.76 TiO2 1.489 1.333
24 Cr K 0.017 0.003 0.007 14.93 Cr2O3 0.025 0.012
25 Mn K 0.012 0.003 0.005 12.54 MnO2 0.018 0.015
26 Fe K 6.525 0.077 2.584 8572.01 Fe2O3 9.329 4.178
30 Zn K 0.018 0.002 0.006 35.10 ZnO 0.022 0.020
38 Sr K 0.023 0.002 0.006 64.13 SrO 0.027 0.019
8 O 45.453 0.405 62.830