ve AZAD JAMMU & KASHMIR PU Note: Select the Examination for Post: L Questiva Paper Subject: Chemistry Paper: MCQs Time: 100 Minutes correct answer and fil its circle completely on OMR BLIC SERVICE COMMISSION Date: 18-05-2017 Maximum Marks: 100 answer sheet 4. Plants look green due to absorption. a) Green light bY Blue light Centre of distributi en by: - / ay Mean b) Mode 3. Phase that is never gained in sublimation is: a) Sold by Liquid 4. In Universal indicators, red color shows a) strong acids \ bby strong alkalis, 5. Aqua Regia is : a} 1 part cone. HCI and 3 parts cone HNOs b) 3part conc. HCI and 1 parts cone. HNOs ¢) 2 part cone. HCI and 1 parts conc. HNOs 9) 3 part conc. HCI and 2parts conc. HNOs compound in solution? a) Calonmeter. b) Colourmeter. 7. Pattern on paper in chromatography is called : a) chroming b) chroma ©) Red light d) Yellow light c) Average d) Standard deviation o) Gas d) Vapors \ co) weak acids d) weak bases 2 of an instrument used to measure the absorbance of a coloured c) Coulometer. dy Colorimeter ¢) chromatograph @y chromatogram 8. lon exchange chromatography is based on the = af electrostatic attraction t) electrical mobility of ionic species c) adsorption chromatography 4) partition chromatography 9. Concentration change during the titration is given by: @ Conductometry b) Voltametry 40. Locating agent of amino acids is : a) Diazo reagent DF ninhycsin spray 41. NH.Ci(s) + NaOH — a) NazCOs + Hy+NOz by NazCO:(Hz0}s + HCI ©) Coloumetry i 4) Polarography ¢) Amphoteric oxides d) neutral oxides ©) NaCl + H,0 +NHs d) NaCl + HNO> 12. Which of the followings is different from the other three in length? a) Imeter 1} 10° nanometer c) 10° meter ) 10° meter | 13. Which of the following is not commonly used as solvent for infrared spectroscopy? a) Ethanot &) Chior: ¢) Carbon tetrachloride oY Carbon disuiphide“2° of basic radicals , HCI is preferred to FN @ 14, na qualitative inorganic analysis ae preparing the solution of different substances be a) Nitrates are not decomposed to sulphides b) Nitric acid contain nitrogen ¢) Hydrochloric acid is not an oxidizing agent d) Chlorides are easily converted to sulphides 45, The Rivalue is always in the range of : a) -1t00 ©) to2 by tot d) 1to 14 16. According to followings? a) Distance that the light has travelled through the sample ae b) Extinction coefficient of the sample. ) Solution concentration, Colour of the solution. 47. A shift to lower wavenumber for an absorptio! _ a) a shift to lower frequency. i b) a loss of intensity. 48. An absorption in an electronic spectrum is recorded at 17000 cm the Beer-Lambert Law, absorbance is independent of which of the nin a spectrum corresponds to: ) a shift to lower wavelength. d) a shift to higher energy. *, What does. | this correspond to in nm? a) 5900 nm ©) 590m b) 59m 4) 59.000 nm 19. Components which have small value of K have affinity for | a) mobile phase ©) no phase by’ stationary phase a) solution Lo 20. In gas chromatography, the basis for separation of the components of the volatile material is the difference in: a) partition coefficients c) molecular weight b) conductivity d) molarity 21. Which of the following techniques does not involve electromagnetic vibrations? a) Infrared spectroscopy b) NMR spectroscopy c) Mass spectroscopy 4) Alllof these involve electromagnetic radiations 22. What is the wavelength range of the ordinary infrared region? a) 0.8-2.5 ym c) 16-1000 ym , b) 2.5-16 ym a 400-800 pm 23. Which of the following species is detected in the mass spectroscopy? 'a} Positively charged species ©) Neutral molecules b) Radicals d) More electronegative specie 24. The frequency of a transition is 5.4 x 10" Hz. What is the corresponding wavelength? a) 5.6*10%m c) 560. nm b) 5.6 10%m d) 180000 cm* 25. The frequency of a transition is 3.1 « 10°° Hz. What is the energy of this transition? a) 2.0% 107 kd oc) 21% 10* ks b) 2.0107) d) 24% 10 ne) oie of the following atomic orbitals contains one nodal plane? b) 3py t a Sa (RL Re terre pA DY. ra ae sun et © 8 ©3 27. The correct ordering of the electronegativities of the following atoms is: / a) N 5. ** a)" SO2 and CO c) BF3 and NF3 bY CO and NO, d)_COz and [Ns ~ 36. Which of the followings has the most polar bond? D2 HF b) HBr cea 22 d) HCl 37. Which molecute does not have Ty symmetry? ot . a) SiFs oF Py ©) CHy 4) XeF. 38. Which ligand is teast likely to adopt a bridging mode between two metal centres? a) cr bp [CNT c) PPhy d) [MeCO,- — 39. Which acid is thiosulfuric acid? c) H2S204 d) H2S202 a) diaquatetrafiuoroiron(it!) ion ©) dizquatetrattvorciron(t) ie bydiaquatetrafluoroferrate (Ill) ion 4) diaquatetraftuoroferrate(!) ion 41. Given the list of ligands and their corresponding names, choose the pait that disagree. UGAND NAME ay OH hydroxo Be b) ON cyanide ine. Nae c) ct chloro d) H,0 aqua4 {dod to Mg’ ion solution, then which of the followi\ 742. Whon EDTA solution i statemonts is not true? a) four coordinate sites of Mg” are occupied by water moleet by All six coordinate sites of My?” are occupied c) pH of the solution is decreased d) Colorless [Mg-EDTA},~ chelate is formed 43. Least paramagnetic property is shown by: a) Fe b) Mn c) Ni G Cu “44, tron exhibits 2+ and 3+ oxidation states. Which of t! about iton is incorrect? a) eivous oxide is more vasic 1 nature than the ferric oxide b) Ferrous compounds are relatively more ionic than the corresponding fe! compounds ©) Ferrous compounds are less volatile than the corresponding ferric compounds | d) Ferrous compounds are more easily hydrolyzed than the corresponding ferric » occupied by EDTA and remaining two sites ai he following statements. tic compounds 45. Inits ground state, an H' ion has: af Two spin-paired electrons. c) Two electrons in different orbitals b) Two electrons with parallel spins d) One electron 46. The VSEPR model is consistent with one of the following molecules cr ions being non-linear. Which is non-linear? a) CO b) (CIF.]" oF INS] 4) [by 47. Which ligand can coordinate in either a monodentate or chelating manner? a) en b) {Nol Gf phen d) THF 48, Wi od 1g ofS, content metal to finn octahedral ligand field, which orbitals are raised least in energy? a) dy and dye ©) daand dy diy, dye and dye ) dee, dye and do 49. In which one of the following species does the transition metal ion have d? electronic configuration? a) [Cr (NHs)6}"* c) [CoFe}* b) [Co (OHa)eI" + 8) [Fe (CN) 50. Which has maximum paramagnotic character? a) [Fe(CN)e]" ¢) [Cu(NHs)4P* b) [Cu(H;0).)"* d) [Mn (H20)o)* =<51. Which of the following (X) is the best leaving group? ® A ns or Ns a NH3 sax 4 Ng? ic | Dae eet (A) X = Iodide (B)X=Chlotide |S (C) X= Promide (09 X= Fluoride 52. TMS is used as internal standard in (A) FTIR (B) UV () Raman spectroscopy (0) H-NMR 83. Carbgnyl compounds have an odor similar to ‘Ay, Blue cheese (8) Almonds (AFruits (D) GrapesPen 54, An amphoteric compound is that which contains (A) Acidic functional group (B) Basic functional group (@ Acidic and basic functional groups (D) Neutral functional group 55. Pentane and 2-methyl butane have the same: (A) Boiling point (8 Melting point {C) Percentage composition (0) Structural formula 56. Geometric isomerism is usually found i (A) Alkanes (Bf Alkenes (C) Alkyne (0) Esters 57. Which of the following statements correctly pertal Avthey rotate the plane of polarized light by exactly the same am directions. B. They rotate the plane of polarized light by differing amounts and in opposite directions C. They rotate the plane of polarized ight by differing amounts and in the seme direction D. The have different melting points. 58. One important aspect when choosing a solvent system for ins to a pair of enantiomers? fount and in opposite extraction to pick two (AY immiscible solvents (B) Miscible solvents (C) High density solvents (D) Low density solvents 59. What is the relationship between trans-2-butene and cis-2-butene (A) Unrelated compounds (8) Constitutional isomers Geometric Isomers (DyDiastereomer (C) Enantiomers ddition reaction with chlorin 60. Which of the following will undergo an a (A) CH3CH2CH2CHs. (8) (CH3CH;CH=CHCH3 (Cy CeHs (D) CHyCH2COOH 61. Which of the following is the enantiomer of the following substance? 4 4 oH Hy when | ote he oe 1 I mn (Al (By i (D) It does not have a non-superimposable enantiomer 62. A single atom or group of atoms which gives characteristic properties to a compound is called (A) Radical (B) Hydrocarbon (6 Functional group (0) Ton 63. 2-Propanol and 1-propanol show the isomerism (A) Metamerism (B) Geometric isomerism (C) Functional group isomerism —_(DyPesition isomerism 64, Functional group’s information of compound under investigation is obtained (A) Mass Spectrometry (eyFTIR (C)'H-NMR (D) UV 65. A plane of symmetry is a plane passing through an object such that the part on ‘one side of the plane is exact reflection of part on the other side. This plane of symmetry also called (A) Alternating Axis of symmetry (Ph Mirror plane (©) Centre of symmetry (D) Centre of axis, 66. Absorption of what type of electromagnetic radiation results in electronic transitions? (A) Microwaves (#) X-rays (C) Radio waves._-—_(D) Ultraviolet light6 ‘ pwise. What is the fir: a mild oxidation agent? (8) COz table intermediate pro 67. Ethanol can be oxidized ster st si Pr when ethanol is oxidized with (x) CHyCOOH (©) cHoHO (O)CHICHOH 68. Which of the following hydrocarbons does not have com rt (A) CrHie. (B) Coie (C) CsHio (D) CaHe 69. All nucleophiles are (A Lewis acids {B) Lewis bases (C) Bronsted bases (D) Bronsted acids 70. What is the correct name for this molecule? CL. CH, OLE . remo Br" if CH (A) (2R,3R)-2-bromo-3-chlorobutane (B) (28,3R)-2-bromo-3-chlorobutane (C) (2S,3S)-2-bromo-3-chlorobutane (D) (2R,38)-2-bromo-3-chlorobutane 74. Rank the following cations in order from most stable to least stable: Ce Oe Od On (A) 1>2>3>4 aot (C) 2>1>4>3 6 3>4>2>1 Which of the following is the best reagent to promote an Sug reaction? 2 OR + Cl | (A) tert-BuONa/ tert-BuO- (B) tert-BuOH/H20_ (C) EtONa/EtOH (0) EtOH/H20 73. Bromine water does not react with benzene at (A) High temperature (B) Room temperature (G) Low temperature () Constant temperature 74, That elimination in which both groups are lost form the same carbon atom to give carbine is called (A) a-Elimination (B) B-Elimination (C)_ y-Elimination (D¥6-Elimination 75. .Explain why the two stereoisomers of 1,4-dimethylcyclohexane are achiral 7 (A) Because they are identical (®4 Because they are enantiomers (C) Because they both have the same absolute configuration (D) Because they are no stereocenters present in either moleculedz- 76. Which of the following conditions is necessary for a reaction to be spontaneous? a) ASs.>0 ©) ASsur + ASsys > 0 WT AS,,.>0 d) DSsur + ASsys < 77. For a spontaneous change in a system at constant temperature and which of the following statements is true? a) AG<0 b) AG=0 oY AG > 0 d) There is no restriction on the value of AG 78. The amount of heat required to raise the tempera’ through one degree at constant volume, is called & specific heat at constant volume ©) Kilo Joule b) specific heat at constant pressure d) heat capacity 79. An adiabatic process is one in which: a) no heat enters or leaves the gas b) the temperature of the gas changes c) the change in internal energy is equal to the mechs d) all of the above i 80. The entropy in an irreversible cyclic process. | pressure, ture of the unit mass of gas yanical work done \ 1 af remains constant ©) Increases | b) decreases d) remains zero i 81. The measurement of a thermodynamic property known as temperature is based on af Zeroth law of thermodynamics ) First law of thermodynamics 82. ‘Work done in a free expansion process is a) Maximum Ff Positive b) Zero ) Minimum 83. Which of the followings requires a corpuscular interpretation of light? a) Refraction ©) Photoelectric effect b) Interference dy Bragg's diffraction law 84, The phenomenon of lowering of vapour pressure is defined as: a) Decrease in vapour pressure of a solvent on addition ofa volatile non electrolyte solute init. bf Decrease in vapour pressure of a solvent on addition of a non-volatile non electrolyte | ) Second law of thermodynamics 1 d) none of these | solute in it. ©) Decrease in vapour pressure of a solvent on addition of a volatile electrolyte solute in it. 4) Decrease in vapour pressure of a solvent on addition of a non-volatile solute in it 85. Incase of radiations, amount of energy is proportional to: frequency of radiation c) waves b) density of radiation ) light 86. A photoelectron has a kinetic energy of 3.588 x 10-19 J. What is its speed? a) 443.7 x 103 ms @ 1.220x109ms" b) 883.9 103ms" d) 20.79 x 103 ms" 87. What is the degeneracy of the energy level with n=6 ina hydrogen atom or =~ ion? a) 25 b) 16 ay 36 4) 9 88. In determining kinetic equation of gases, the velocity of all molecules is not ‘equal. So, we use: a) Square of velocity, ©) Under root of velocity by Mean square velocity d) Cube of velocityPee as f 8 * 89, Molar concentration of a solution is \ ‘@) Equal to the molatity of solution b) Less than the molality of solution ; ©) Move than the molality of solution ) Anvays equal to normality of solution 90. Ahomogenous mixture of a pair of benzene ai fa) Variable deviation from Raoult’s law b) Positive deviation from Raout’s law ©) Avery small deviation from Raoult’s law 4) Negative deviation from Raoutt’s law 91, Which of the following statements about t! {2) The order of the reaction can only be determined by b) A second order reaction is also bimolecular ©) The order of reaction must be positive integer ) The order of reaction increases with increasing temperature 92. Half-life period of second order reaction is: 'a) tnversely proportional to square of initial concentration of the reactants b) Independent of initial concentration of reactants ©) Proportional to initial concentration of the reactants ) Inversely proportional to initial concentration of reactants 93. According to the collisions theory of reaction rates: a) Allthe reactions which occur in gaseous phase are zero order reacti b) Every collision between reactants leads to a chemical reaction. ©) Rate of reaction is proportional to velocity of molecules 4d) Rate of reaction is proportional to number of effective collisions per second 94, The outermost electronic configuration of the most electronegative element is nd toluene represents he order of the reaction is true: the experiment ions ayaa’ i ) ns? np? b) ns?_np* * d)_ns?, np® 95. Whatis the root-mean-squared speed of methane, CHs, molecules in a sample of at 25°C. a) 6.24ms-' c) 21.5ms" b) 10.2ms¥ d) 681ms 96. The Miller indices are often used in the area of a) Polymer structure ©) Molecular spectrum ) Single crystal d) Surface chemistry 97. The mass of a unit coll of CsCl corresponds to. a) 1Cs* and 1Cl~ c) 8Cs* and 1Ci~ by 1Cs* and 6CI~ d) 4Cs* and 4ci~ 98. The photon of visible region would not show the Compton effect, because they: a) Have too small mass c) Have no momentum é b) Travel too slowly d) Have large wavelength 99, The osmotic pressure of a solution can be measured by: es 5 a) Pfeffer method ©) Barkeley and Hartley method b) Morse and Frazer method d) Allof the above 100. When the vapor pressure of th e solutions of two liquids expected from ideal solutions, they are said to have pe tcesiees cater a) Positive deviations for Ecalive Gaviations ft low concentrations and negative deviation for higher b) Positive deviation from ideal behavior ch Negative deviation from ideal behavior d) None