“aD JAMMU & KASHMIR, PUBLIC SERVICE COMMISION Ans: e8 Examination for the post: subject Specialist Chemistry (p-17) oate:3—-Y~18 Paper: MCQS Max Marks: 100 inne: 100 min Note: Setect the correct answer and fill completely its circle 0” OMR answer sheet 5 : vee question No. 2. What is the type of hybridization of Phosphorus i? PCl,molecule? . fabs? (bjsp'd? ¢(c)sp'd ee A Guestion No. 2. what's shape of lodine heptafluoride IF) molecule? 6 pentagonal bipyramidal (b) heptagonal pyramidal ( (c) octahedral (d) heptahedral Question No. 3. What are bond angles (degree) in $F, molecule? ia) 120° (b) 109° w) 90° (4) 60° ae Question No, 4. In CIF; molecule, two lone pair of electrons will prefer position in molecular structure? (a Both axial isin equatorial (c) One axial other equatorial (¢) Random Question No. 5. A proton consists of a quarks? {a} one up and one down (BYone up and two down {c) two up and one down (d) two up and two down Question No. 6. What is relationship between 16S, 17”"Cl, 3 Ar and yo "K? {a) tsotope (b) isoelectronic @ isobar, (a) tsotone “0” Plchot Ele hed A.Question No. 7. Which of following compound could not exist in a pyranose form? fee 5 n=j-oli =o Hap uot il i>-onl u i oll boon | im iui frou Eon oy HOH gy C.0N fg Clon ay Son Question No. 8. Which of following molecule is achiral? Beil 4a it 4 maid Secu, thy ly Be, ch iy tse aBr Ir HC > fon te ellen axe u ue ‘ (c) Hy i Question No. 9. Which intermediate specie is formed in the following amide hydrolysis’ ° o eu thea 4 HO e HCE = CHCON © (CH NHC ocr ou | IC “f Cle HG () Pee Question No, 10. Which positions on following steroid are readily deuterated when it is reacted with NaOD in 0,0 medium? 4b) 2, 4 and 20 only (a) 1, 2, 17 and 20 only (¢) 2, 4 and 17 only (d) 2 and 20 only Question No. 11. Which of following specie has highest bond order according to molecular orbital theory? (a) NO? (b) NO~ (c) NO (df No* Question No. 12. Which of following metal carbonyl is not stable according to the expended octet rule? (23V, asMn, 26Fe, 2»Co)? ? (4 {V(CO),I"(b) {MIn(CO)s}~Le) {Fe(CO)al?~(a) (Co(CO).I"Question No. 13. In petrol engine, knocking occurs due to _ of fuel. (a) low flash point (bf low calorific value , (0) Ignition delay (d) premature ignition _4 (by 2HF yA eng LO AML, iether It cn, ( \ HL LAATEL, dicthyt exter (ay in Ho Question No. 29 Which set of given reactants will produced following compound via Diels-Alder reaction mechanism? cit, f 1 hoch Cite oO fi och CH, J COCH C4 \ wr oH 0 CH,cH ye JG LCHCH, eke och ( i ( , CH.GH a “GILCH, OCH (c) Question No, 30, Which compound among following reacts with water to produce Hydrogen gas? (a) CHy (b) NH, (c) HS. (d) LiQuestion No. 31. How much “Zn in gm is produced in 25.6 hours by following nuclear reaction? “cu Zn + Be Half-life = 12.8 hrs (a) 12.8 (b) 25.6 (c) 50 (af 75 Question No. 32. Which is the most stable conformation of a molecule among followings? ie cu J 2 I (a) te) te cn L7 \ / (a hy adel Question No. 33. Which of following does not have a threefold rotational symmetry axi (a) BCI; (b) CIF (c) NH (af CHa Question No. 34. Which of following transmutation nuclear reaction involves absorption of one *;He”? and release of one +H’? (a)7.0 4H (b) 20 --?MsoTh (0 74Pa (SN «0 Question No. 35. For which set of AH(kJ) and AS(J/K) values below, a reaction will be spontaneous only at high temperature? (a) -50, -12 (b) +50, -12 (4 +50, +12 (d) 0, -12 Question No. 36. For a triprotic acid (H3A), at which pH range H,A is in excess while Kyi = 10°, Ky = 10° and K3= 10"? (a)1-2 (b)2-3 (G35 (a) 5-7Question No. 37, What Is relationship among following compounds? con co Cal ie C=, cn on {a) Diastereomers (8 Conformational isomers {c) Enantiomers (d) Identical Question No. 38. Who has lowest freezing point among following equimolal sok tions? (a) KBr (b) NaNO; (ef CH,COONa (d) AKINOs)s Question No. 39. Which of following compound has a ring or a double bond? (aFCeHi0 —(d)CeH CO (€) CeHysCl_—_(d) CoH CIO Question No. 40. What is the IUPAC name of following compound? (a) 3-butyl-2-(1-methylethyl)pentane(b) 2-isopropyl-3-butylpentane {ef 2-isopropyt-3-ethylheptane(d) 4-ethyl-2,3-dimethyloctane Question No. 41. Third ionization energy of iron is equivalent to which of following processes? (a) Fey + & Fe, (b) 3Fe ws 73Fe'w + 3€ (of Few Fete (d) Fea Fe") + 3e- Question No. 42. What is the molar weight of 2 695 who's 5.6 Liter weighs 2.0 g at 0°C temperature and 0.025 atmosphere pressure? (a) Se (b) 168 (F322 | (6) 48Question No. 43. Solubility product (K.p) of Sn(IO,)s Is (a) [Sn] (105) (b) [5n""}’ 10, (J {Sn} (1057) {d) (Sn 10,7 Question No. 44. For following equation, which one Is correct? Mite + M P= 23 (a) M’is readily reduced (b) Mis readily oxidized (c) Mis a poor reducing agent (df Mis a good oxdizing agent Question No. 45. A 0.01 w/v% solution of CaCl; is equivalent to? {a) LOppb (bY1.0 ppt (c)10 ppt (d) 100 ppm Question No. 46, What is molecular shape of BeH, molec (a)Trigonal (b) linear (of Bent (4). pyramidal Question No. 47. What is set of quantum numbers for a single electron in 34,, orbital? 0) 1,3, -2, #1/2 : (67°3, 2,-2, 41/2 (6) 3,3, -2, 41/2 (6} 3, 2,-3, +4/2 Question No. 48.NO, +H,0 —> ? {a)HNO; — (KJHNO, ~—(c) HNO; +NO (d) NH, +H202 Question No. 49. At which state given below, a reaction is at equilibrium in a closed rigid vessel at constant temperature? (afBs=0 (b)QH=0 = {c)AU=0—(d) BA=0 Question No. 50. Which compound is produced by saponification of following ester by using isotopical oxygen labeled alkali and water? cH 9ctl, cu, Heo on He CO cl cCHy | I oo eae a oll cu CH, | | HO mC —H Ui ae ou CH, i | O ne ye oily Question No. $1. Which is strongest base among followings? oS EN © O, a NZ Question No. 52. Which carboxylic acid is more acidic among followings? fa) (a) HCO2H (b) ClCCO.H (c) CHsCO.H (ff Phco,H Question No. 53. Which is the strongest Bronsted acid among followings? fel — (by HOC! (c) HCI; (4) HCIOs Question No. 54. Which of following has highest vibrational frequency among various isotopic hydrogen molecules? {a) H2(#) HD (c) Dad) Ta Question No. 55. What value of ’n’ in Huckel’s rule applies to the compound depicted below? AN Se (ay3 (b)4 (c)5 9 10‘Question No. 56. Which of following ligand forms linkage isomers complex? (a) NH(SFPF,(c) NO,” (A) SO, Question No. 57. Which of the following electronic transitions is forbidden for a hydrogen like atoms? (2p > 1s (b)2p-> 35 (e)2p-> 4s (d) 2P~ 3. Question No. 58. Which of electronic transition below cause fluorescence? fa A (iB (c)C (dD Question No. 59. How much number of signals will be shown in °C NMR spectra of following compound? oO aAN WAC chy {a1 (b)2— (ef (d)7 Question No. 60. lodine molecule has strong intermolecular forces so exist in solid state. What are the types of these forces? {a) Keesom forces (b) Debye forces (c) London dispersion forces {aflon-dipole forces Question No. 61. Which compound forms the strongest intermolecular hydrogen bonds among followings? (Af HE (b)HCCl §— (c) PH, (d) HS. Cuestion No, 62. Which is strongest oxidizing agent specie among followings? {a) 0,* (b) O,c) 0,7 (d) 0,7 uQuestion No. 63. Which of the following reactions does not involve the formation of a Lewis acid-base adduct? (a) (CH))sN + BF;~> eal AI(OH); + OH: > AM(OH)y- (c) H,O + H'-> HO*(Gf PF, + Fp PFs Question No. 64. What is chemical name of following compound? Nu V (a) cis-diamminedichloroplatinum(It)(b) cis-diammoniaplatinumdichloride (cP cis-dichlorodiammineplatinum(IV)(d) Platinum cis-ammoniumchloride Question No. 65. What is correct for xenon element? (a) Ithas lower first ionization energy than Na (b) It does not form any chemical compounds Aare formns compounds with some highly electronegative elements {d) It exists as diatomic molecule Question No. 66. Which halide is highly reactive with sodium iodide in acetone? [7 ; ) Sen © Br Opes é — CH Br (a) (br () (d) None of Ree these Question No. 67. Which phenomenon is observed due to wavelike property of electrons? (a) Photoelectric effect (b) Diffraction pattern of electrons scattered from a crystalline solid (Deftection of an electron beam by electrical plates {d) lonization of atom 2ee ee te eS ee Question No. 68. Which is the name of orbital shown below? (2) dulb) dy (P diay2 (d) dhe Question No. 69. What is main advantage of a hollow-cathode lamp used in atomic absorption spectroscopy? {a) Ithas high intensity (b) temits a complete ultraviolet spectrum (c) It has a narrow line width {d}# eliminates the need for an ionization suppressor. Question No. 70. Which IR vibrational mode is most affected by intramolecular hydrogen bonding in the following molecule? -OW (oleae SNe Il ° (@ Methyl group C—H stretching (b)_ Aromatic ring C—H stretching (c) Aromatic ring C—H bending (df Hydroxyl group OH stretching Question No. 71. Communication is a Two way process b. One way process cc. Explanation of ideas 4. Exemplification Question No. 72. General Science is the branch of ure science ‘Natural science ©. Social science 4d. Sofi sciences 3