METODO EDMISTER - POLACK

Mid BP °F Vol % Cut Gravity

Cut Cum MDP API GE Curva ASTM
100 5.5 5.5 2.75 75 0.7022 1200
175 4 9.5 7.5 66 0.7342
225 4.5 14 11.75 61 0.7532 1000

275 5 19 16.5 57 0.7692

f(x) = 8.923488077 x + 11
325 6 25 22 53 0.7859
R² =800
0.996975093914363

Temp. °F
600
375 6 31 28 49 0.8033
425 6 37 34 45 0.8215 400
475 6 43 40 42 0.8357
200
525 6 49 46 39 0.8504
575 6 55 52 36 0.8657 0
0 10 20 30 40 50 60
625 6 61 58 35 0.8709
%Vol
675 6 67 64 33 0.8815
725 6 73 70 30.05 0.8976
775 6 79 76 28 0.9091
825 5.5 84.5 81.75 25 0.9265
875 5.5 90 87.25 21.8 0.9459
925 3.5 93.5 91.75 18.5 0.9667
975 4 97.5 95.5 14.2 0.9952
1025 2.5 100 98.75 10 1.0247

ASTM a TBP (P = 14.7 psia)

Interpolando tabla anterior

curvas de ASTM a TBP
CURVA TBP
%vol ASTM °F ∆F ASTM ∆F TBP TBP °F
1000
10 180.56 147.83
30 366.67 186.11 211 358.83 800
50 533.33 166.67 182.5 541.33 600
Temp °F

70 700.00 166.67 178.8 720.13

400
90 875.00 175.00 187 907.13
200

0
0 10 20 30 40 50 60 70 80
%Vol
15°F=45°F

curvas
de ASTM a
EFV
%vol ASTM °F ∆F ASTM ∆F EFV EFV °F
10 180.56 235.33
30 366.67 186.11 142 377.33
50 533.33 166.67 123 500.33
70 700.00 166.67 118 618.33
90 875.00 175.00 117.5 735.83

pendiente 8.65740741
VOL ASTM TBP EFV
Cum
5.50 100 116.78 217.09
9.50 175 154.37 241.93
14.00 225 196.67 269.87
19.00 275 243.67 300.92
25.00 325 300.07 338.18
31.00 375 356.46 375.44
32.95 375.00 387.55
37.00 425 412.86 412.70
43.00 475 469.26 449.96
49.00 525 525.65 487.22
55.00 575 582.05 524.48
600
 61.00 625 638.45 561.74
67.00 675 694.84 599.00
73.00 725 751.24 636.26
79.00 775 807.64 673.52
84.50 825 859.34 707.68
90.00 875 911.03 741.83
93.50 925 943.93 763.57
97.50 975 981.53 788.41
100.00 1025 1005.03 803.93
METODO EDMISTER - POLACK

Curva ASTM CURVA API Curva SG Specific

1200 80 1.2
70
1000 1
f(x) = 8.923488077 x + 111.7762882 60
0.8
R² =800
0.996975093914363 50
Temp. °F

40

API
0.6

SG
600
30
400 0.4
20
10 0.2
200
0 0
0 0 10 20 30 40 50 60 70 80 90 100 0 10 20 30 40 50
0 10 20 30 40 50 60 70 80 90 100
%VOL %Vol
%Vol

TBP
1000
900
f(x) = 9.3995 x + 65.0780000000002
800 R² = 0.999072776863038
700
600
TBP °F

500

CURVA TBP 400

300
200
100
0
0 10 20 30 40 50 60 70
%Volumen

10 20 30 40 50 60 70 80 90 100
%Vol
 CURVA EFV
800

700 f(x) = 6.21 x + 182.933

R² = 0.998422008515199
600

500

Temp °F
400

300

200

100

0
0 10 20 30 40 50
%Vol
 COMPARACIÓN ASTM, TPB Y EFV
1200

1000

800

ASTM
Temp °F

600 TPB
EFV
400

200

0
0.00 20.00 40.00 60.00 80.00 100.00 120.00

%Vol
200

0
0.00 20.00 40.00 60.00 80.00 100.00 120.00
%Vol
 Curva SG Specific Gravity
1.2

0.8

0.6
SG

0.4

0.2

0
0 10 20 30 40 50 60 70 80 90 100

%Vol

TBP

f(x) = 9.3995 x + 65.0780000000002

R² = 0.999072776863038

TBP
Linear (TBP)

10 20 30 40 50 60 70 80 90 100
%Volumen
 CURVA EFV

f(x) = 6.21 x + 182.933

R² = 0.998422008515199

10 20 30 40 50 60 70 80 90 100
%Vol
B Y EFV

ASTM
TPB
EFV

100.00 120.00
100.00 120.00
 Diseñe una torre de destilación para el petróleo crudo que se resume a continuación y en el gráfico adjunto.
Otros datos pertinentes son los siguientes: barómetro = 14.7 psia de agua de enfriamiento disponible a 85 °
F, vapor disponible a 50 psig y saturado
Especificaciones del producto
Gasoline ASTM EP=375 °F
Gasoline 95% - kerosene 5% gap=20 °F
Kerosine EP=600°F
Kerosene 95% - gas oil 5% overlap=-10°F
Gas oil by difference
Gas oil 95% - bottoms 5% overlap=-5°F
Reduced crude

ANEXO 5 ANEXO 5
ANEXO 4 Ecuación
ASTMi TBPi ASTMi ASTMi TBPi
CORTE
100% 100% 95% 5% 0% % Volumen
Gasolina 375 395 365 0 375 29.27
Kerosene 600 640 595 385 355 605 25.05
Gasoil 715 765 695 585 570 730 14.34
690 695 31.34
reducido
CORTE
TBP Vol. Acum Vol.corte
Gasolina 375 29.27 29.27
Kero 605 54.32 25.05
Gasoil 730 68.66 14.34
crudo reducido 100.00 31.34
100
TBP
Temperatura %Vol Temperatura (°F) &Vol. Acumulado
1000
Asumido ASTM 0 2.75 900
800
395 29.27
Temperatura (°F)

700
355 29.27 600
640 54.32 500
400
570 54.32 300
765 68.66 200
695 68.66 100
0
0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75
% Volumen Acumulado
gráfico adjunto.
isponible a 85 °

TBP (°F) &Vol. Acumulado

1000
900 f(x) = 0.000416667 x³ − 0.06875 x² + 12.7083333 x + 52.375
800

Curva TBP 700

Temperatura (°F)

600
X Y
500 T
29.27 375 B
400 P
300
54.32 605
200
100
68.66 730.040291 0
100 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100
% Volumen Acumulado

) &Vol. Acumulado

45 50 55 60 65 70 75 80 85 90 95 100
men Acumulado
 %Vol Vol TBP
0 0 52.375 Curva de rendimiento TBP
10 2.9226210441 88.937984
750
30 8.7678631322 158.777589
Gasolina

50 14.61310522 224.634803 700 f(x) = 1.59765887471988 x + 569.986592016363

R² = 0.999997752349467
70 20.458347308 286.988939 650
90 26.303589397 346.31931 600
100 29.226210441 375.000369 f(x) = 2.49074329604613 x + 357.96957512514
550
R² = 0.99980136625694
0 27.181661357 355.000363
500
10 29.909402525 381.619559
30 35.36488486 433.437503 450

Temperatura (°F)
Kerosene

50 40.820367194 483.686253 400

70 46.275849529 532.755489 350
f(x) = 3.21487001350802 x + 60.3882243833772
90 51.731331864 581.034895 300 R² = 0.998959943028077
100 54.459073032 605.000188
250
0 50.478854545 570.000354
200
10 52.29696909 586.011061
30 55.933198181 617.927035 150
Gasoil

50 59.569427272 649.798577 100

70 63.205656363 681.741078 50
90 66.841885454 713.869927
0
100 68.66 730.040291 0 10 20 30 40 50 60 70 80 90 100

% Volumen
 TBP - EFV Volumen F TBP EFV F
GASOLINA % TBP AT AT EFV
to TBP 0 52.375
10 88.937984 36.562984 7 158.634803
50% 224.634803 30 158.777589 69.8396048 25 183.634803
+ 569.986592016363 30%-10% 69.8396048 50 224.634803 65.8572143 26 209.634803
AT -15 70 286.988939 62.3541363 25 234.634803
90 346.31931 59.3303707 26.5 261.134803
+ 357.96957512514 100 375 28.6806899
TBP - EFV Volumen F TBP EFV F
KEROSENE % TBP AT AT EFV
0 355.431899
10 381.619559 26.18766 5 443.686253
50% 483.686253 30 433.437503 51.8179444 19 462.686253
+ 60.3882243833772
30%-10% 51.8179444 50 483.686253 50.2487494 20.5 483.186253
AT -0.5 70 532.755489 49.0692366 19.5 502.686253
90 581.034895 48.2794062 22 524.686253
100 605 23.9651045
TBP - EFV Volumen F TBP EFV F
GASOIL % TBP AT AT EFV
0 570
50% 649.798577 10 586.011061 16.0110613 3 641.798577
60 70 80 90 100 30%-10% 31.9159734 30 617.927035 31.9159734 1 642.798577
AT 5 50 649.798577 31.8715426 12 654.798577
70 681.741078 31.942501 12.5 667.298577
90 713.869927 32.1288486 15 682.298577
100 730 16.130073
 TBP-ASTM
F
Volumen TBP
Curva de rendimiento TBP-EFV 0 52.375
10 88.937984

Gasolina
750
30 158.777589
700
50 224.634803
650 70 286.988939
600 90 346.31931
550
100 375
605
500
Volumen TBP
450 TBP Gasolina
Temperatura (°F)

0 355.431899
TBP Kerosene
400

Kerosene
TBP Gasoil 10 381.619559
350 EFV Gasolina 30 433.437503
EFV Kerosene
300 EFV Gasoil 50 483.686253
250
70 532.755489
90 581.034895
200
100 605
150
F
100 Volumen TBP
50 0 570
0 Gasoil 10 586.011061
0 10 20 30 40 50 60 70 80 90 100 30 617.927035
% Volumen 50 649.798577
70 681.741078
90 713.869927
100 730
 TBP ASTM F
AT AT ASTM
109.134803 Curva de rendimiento TBP-EFV- ASTM
36.562984 19.5 128.634803
69.8396048 49 177.634803 800

65.8572143 51 228.634803 750

62.3541363 52 280.634803 700

59.3303707 54.5 335.134803 650
28.6806899 27 308.134803 600
TBP ASTM F 550 TBP Gasolina
AT AT ASTM TBP Kerosene
500

Temperatura (°F)
TBP Gasoil
450
26.18766 14 463.5 EFV Gasolina
400 EFV Kerosene
51.8179444 35 498.5 EFV Gasoil
350
50.2487494 40 538.5 ASTM Gasolina
300 ASTM Kerosene
49.0692366 41 579.5
ASTM Gasoil
48.2794062 42.5 622 250

23.9651045 22 600 200

TBP ASTM F 150
AT AT ASTM 100
50
16.0110613 8 617
0
31.9159734 24 641 0 10 20 30 40 50 60 70 80 90 100
31.8715426 27.5 668.5 % Volumen
31.942501 31 699.5
32.1288486 36 735.5
15.5 720
FV- ASTM

TBP Gasolina
TBP Kerosene
TBP Gasoil
EFV Gasolina
EFV Kerosene
EFV Gasoil
ASTM Gasolina
ASTM Kerosene
ASTM Gasoil

00