Professional Documents
Culture Documents
Table of Contents
Summary ......................................................................................................................................... A
Introduction ..................................................................................................................................... B
Lime ................................................................................................................................................ C
Gypsum ........................................................................................................................................... E
Conclusion ...................................................................................................................................... F
References ....................................................................................................................................... G
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Summary
This report contains essential data concerning both lime and gypsum materials that are commonly
utilized in the construction of buildings. Commencing from defining each term, uses,
classifications, and types etc. The cycle of both lime and gypsum are provided along with its
properties. Gypsum products are also identified stating its advantages and disadvantages in
construction. Of course, its occurrence, constituents and precautions are also mentioned. At last, a
lab concerning the standard reactivity test as a measure of lime’s quality has also been provided.
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Introduction
First and foremost, lime is a carbonate, oxide, or hydroxide of calcium while gypsum is a sulphate
of calcium. Lime has alkaline properties when gypsum is a neutral salt in water (neither alkaline
nor acid). Moreover, lime raises the pH of soils by neutralizing hydrogen ions and gypsum will
not neutralize acid soils or effectively raise pH. Some uses of lime in the construction industry
include road base, railroad ballast, concrete and cement when it's fired in a kiln with crushed shale.
Building gypsum is used as heating resistant, moisture preserving, sound absorbing and fire
proofing material. It is important to realize that building gypsum and its products are largely used
in projects such as finishing mortar, wall-surface putty, model making, anaglyphic products,
plasterboard partitions and ceilings etc. Thus, the main goal is to give the lecturer a summary on
the main information being learnt about lime and gypsum in the construction industry.
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CONTENT C
What is lime
Limestone is a rock that is formed chiefly by accumulation of
organic remains (such as shells or coral), consists mainly
of calcium carbonate, is extensively used in building, and yields
lime when burned.
Uses of building lime
Some uses of lime include road base, railroad ballast, concrete
and cement when it's fired in a kiln with crushed shale.
Composition of lime
Limestone is a rock that is formed chiefly by accumulation of organic remains (such as
shells or coral), consists mainly of calcium carbonate, is extensively used in building, and
yields lime when burned.
Classification of lime
Limestone is a sedimentary rock composed principally of calcium carbonate (calcite) or
the double carbonate of calcium and magnesium (dolomite). It is commonly composed
of tiny fossils, shell fragments and other fossilized debris. Limestone is a sedimentary
stone with 50% by weight calcite or calcium carbonate (CaCO3) content. Limestone is a
“clastic” sedimentary stone.
CONTENT C
Uses of Lime
• It can be used as a building material.
• It is used in the production of cement by heating powdered limestone with clay. Cement is
an ingredient in mortar and concrete. Mortar – used to join bricks together – is made by
mixing cement with sand and water. Concrete is made by mixing cement with sand, water,
and aggregate (crushed rock).
• It is a major ingredient in toothpaste.
• It can be used as a food additive to provide calcium ions for strong teeth and bones.
• It can be processed as a useful raw material in the chemical industry.
• It can be used to neutralize acidic soil to allow plants to grow more effectively. This is
mainly used for large-scale agriculture. Quicklime and slaked lime can also be used for this
purpose, as well as neutralizing acidity in water sources such as lakes.
Properties of Lime
▪ Limestone is a sedimentary rock such as greater than 50% calcium carbonate (calcite –
CaCO3).
▪ Color: It can be yellow, white, or gray.
▪ Chemical Composition: Calcite.
▪ Texture – Clastic or Non-Clastic.
▪ Grain size – Variable, can consist of clasts of all sizes.
▪ Hardness – Generally hard.
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CONTENT C
Composition of various forms of limestone
Limestone, sedimentary rock composed mainly of calcium carbonate (CaCO3), usually
in the form of calcite or aragonite. It may contain considerable amounts of magnesium
carbonate (dolomite) as well; minor constituents also commonly present include clay, iron
carbonate, feldspar, pyrite, and quartz.
Precautions of Limestone
Eye/face protection: Wear safety glasses with side shields (or goggles). Respiratory
protection: When handling or performing work with limestone that produces dust or
respirable crystalline silica more than applicable exposure limits, wear a NIOSH-approved
respirator that is properly fitted and is in good condition.
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CONTENT D
Synopsis
The method used to assess the reactivity of lime was evaluated to gauge it usefulness as a
quality control tool. The effect of particle sizes, different lime, and water masses for a fixed
s:l ratio and the same for various s:l ratios on the reactivity values obtained, were
investigated. An attempt to introduce the amount of grit produced during the slaking
reaction as an additional measure of lime’s quality and reactivity, proved to be
unsuccessful. It was also found that the relative amount of lime slaked during the different
tests was independent of the reactivity value of the lime. The investigation confirmed the
usefulness of the accepted test procedure as a reliable method to measure the reactivity of
lime, despite various reservations expressed from a theoretical point of view.
Introduction
Lime and limestone/dolomite are materials often used in many industries, among them the
water treatment as well as steel and ferro-alloy production industries. Lime is obtained by
calcining limestone and its quality must be controlled to satisfy customer expectations.
Two industry-accepted tests are normally conducted on unslaked lime to ensure its
compliance with specifications, namely the available lime content determination according
to SABS standard method 8241 and the reactivity test described in a German DIN
procedure contained in the European Norm 12485 of 19962. The first test mentioned above
measures the acid neutralization capacity of the unslaked lime, while the second one
describes the kinetics of how fast the material will react with water to produce a calculated
RDIN value or reactivity value.
This latter test supposedly gives an indication of how ‘reactive’ the unslaked lime is. The
classifications of lime’s reactivity are as follows: RDIN value > 30 – highly reactive lime
10 < RDIN value < 30 - reactive lime RDIN value < 10 - unreactive lime for steel-making
processes and effluent treatment applications, lime of at least a reactive grade is required.
This choice stems from the assumption that high reactivity lime possesses the necessary
chemical reactivity to react fast and to slake well in water. One of the main problems
encountered by customers buying lime revolves around its reactivity. Although logic
predicts that there is a relationship between available lime content and reactivity, its extent
cannot be calculated from basic principles. This is further aggravated by conditions during
the production process and the varying chemical nature and origin of the materials
themselves and South African commercial lime. However, an often-forgotten fact that can
in many cases explain poor reactivity results obtained in tests, is the test method itself. The
standard procedure calls for an amount of 150 g of unslaked lime with a particle size of
between 1 mm and 4.75 mm to be added to 600 grams of water at 20°C in a thermostatically
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isolated container and for the time to be measured that it took the water’s temperature to
rise to 60°C because of the exothermic slaking reaction between the water and the lime.
The required RDIN value is then calculated by dividing 2400 (40°C temperature rise x 60
sec/min) by the time in seconds in which the temperature rise occurred. This technical note
will examine the effect of different variables of the method, e.g., particle size, total water
and lime amounts and various solid: liquid ratios, on the reactivity values obtained.
Experimental procedure
Commercial unslaked lime was crushed and sieved in various size fractions, ranging from
< 75 µm to 4.75 mm. These various size fractions, or portions from it, were calcined at
950°C for an hour to ensure that only CaO was present in the material. The necessary mass
for each test was then weighed and added to the selected amount of water at 20°C. The
mixture was stirred with a mechanical stirrer at 300 rpm and the temperature rise monitored
with an ordinary thermometer and stopwatch. At least three repetitions of each test run
were conducted to obtain reasonably repeatable values. RDIN values were then calculated
in each case as prescribed by the European Norm2. In selected instances the per cent
available lime at the start of the test and after completion was also determined. The
procedure for this was reported earlier in detail in literature4.
An additional test introduced in this investigation to try and distinguish between reactivities
of different limes, is a determination of the amount of grit produced during the slaking
procedure. For this purpose, the limewater reaction mixture was transferred to a 0.5 mm
pore size sieve for screening after the reactivity test. The rationale behind this was that any
slaked lime would form very fine calcium hydroxide particles that would easily pass
through this sieve size, while the course, hydrated parts and impurities would be trapped
by this sieve size. The residue trapped on the sieve was dried in an oven for 3 hours at
100°C and then cooled. After cooling, the residue was gently brushed with a paintbrush
until all the fine powder was removed and only the coarser and hard solid particles were
left on the sieve. This final residue was weighed to calculate the per cent grit as a percentage
of the original mass of lime used in the test.
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proportionality between the amount of heat required and the mass of water whose
temperature must be increased. What is interesting though, is that the amount of grit
produced in each case is independent of the reactivity values measured. This confirms
previous indications that the amount of grit produced is a poor measure of the reactivity of
the lime. The tests using 150 g of lime and 300 ml of water resulted in inefficient slaking
of the lime and produced an explosive and violent reaction. The difficulty in measuring the
reactivity in such cases is reflected in the large standard deviation obtained. A temptation
often arising in laboratories, especially when insufficient material is available for
evaluation purposes, is to reduce the required quantities of reagents used in a prescribed
method by pro-rata amounts.
This could lead to unreliable results being obtained. For this purpose, modifications in the
amounts of lime and water used in the reactivity test were made while keeping the ratio
between them constant at 1:4. The results obtained in this exercise are shown graphically
in Figure 1. The data indicate that the reactivity values stay the same within experimental
error. There seems to be a tendency to higher reactivity values when lesser amounts than
those prescribed by the standard test method are used, although too little work has been
done to make conclusive deductions about this. However, the limited data is enough to
caution that using lesser amounts when limited material for testing is available can produce
misleading figures reflecting a higher reactivity of the lime than is truly the case.
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Conclusions
The reliability of the industry accepted method for measuring lime reactivity was
established within the prescribed parameters of the method. Possible sources of error when
not using the prescribed particle sizes and correct amounts of water and lime were
investigated and their influences established. This work shows conclusively that the
reactivity test yields result reliable enough to use it as a measure to investigate the slaking
process of lime. Further investigations in this regard will be reported in other
communications.
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CONTENT E
What are gypsum plasters
Gypsum plaster, white cementing material made by partial or complete dehydration
of the mineral gypsum, commonly with special retarders or hardeners added. Applied in
a plastic state (with water), it sets and hardens by chemical recombination of the gypsum
with water.
What is gypsum board
Gypsum board, commonly known as drywall is the premier building material for wall,
ceiling, and partition systems in residential, institutional, and commercial structures.
Designed to provide a monolithic surface when joints and fastener heads are covered with
a joint treatment system, gypsum products also provide sound control, economy,
versatility, quality, and convenience.
What is a gypsum tile?
It is made of light weight plaster board covered on the face with P.V.C & covered on the
back with aluminum foil. The tile panel system with its range of finishes provides an
alternative, versatile & decorative ceiling.
Occurrence of gypsum
Occurrence. Gypsum is a common mineral, with thick and extensive evaporite beds in
association with sedimentary rocks. Deposits are known to occur in strata from as far back
as the Archaean eon. Gypsum is deposited from lake and sea water, as well as in hot
springs, from volcanic vapors, and sulfate solutions in veins.
CONTENT E
Advantages of gypsum
• Source of calcium and sulphur for plant nutrition.
• Improves acid soils and treats aluminium toxicity.
• Improves soil structure.
• Improves water infiltration.
• Helps reduce runoff and erosion.
Disadvantages of gypsum
• Gypsum plaster cannot be used for outside walls since they retain dampness. Also,
gypsum plastering cannot be done in areas which are continuously damp such as
bathroom etc.
• Gypsum plaster is costlier than traditional cement motar plaster (cement and sand) for
same thickness of plaster.
Uses of gypsum
Building gypsum is used as heating resistant, moisture preserving, sound absorbing
and fire proofing material. Building gypsum and its products are largely used in projects
such as finishing mortar, wall-surface putty, model making, anaglyphic products,
plasterboard partitions and ceilings etc.
• Retarders like organic acids, soluble salts, basic phosphates, and proteins are used in
gypsum plaster to reduce its setting time.
• Hardeners also can be added to gypsum plaster for improving strength and non-
brittleness properties.
• Gypsum has a self-life of 3-4 months from the date of manufacture. But self-life can
be increased further for additional 6 months if stored properly with great care.
• Gypsum has a setting time of 25-30 minutes which may be reduced due to exposure to
humidity, moisture, and frozen backgrounds. Hence, it should be stored in a closed area
such that its hydrating property won’t let it to be expired soon even in humid conditions.
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CONTENT E
• It is light in weight.
• It is slightly soluble in water (hence it cannot be adopted for damp conditions and external
work).
• It is set by the natural process by crystallization; hence it can be applied with ease and
without wastage.
• It sets with little volume change and with negligible shrinkage on drying.
• Since it dries up quickly, the finishing coat can be applied soon after the undercoat has set,
usually the same day.
• A porous gypsum is an important sound-absorbing material while dense and hard plasters
are efficient reflectors of sound up to 90% energy incident at their surfaces.
• It is used as a heat-insulating material to protect wood or metal columns and beams from
high temperatures.
• The gypsum plasterboards which are cheap, light in weight, fire-proof, and easy to work
are used for the ceiling, for internal lining of walls, and partition walls.
• Gypsum blocks are very useful in the construction of non-load bearing partitions in dry
conditions because of good thermal insulation and small dead load and therefore facilitate
speedy construction. These blocks are also used for the protection of columns, beams, and
elevated shafts against fire.
• Slotted gypsum plaster tiles 13 mm thick measuring 300 mm × 300 mm size can be
prepared using calcined gypsum and sawdust mix in a proportion of 65:35 parts by weight.
These acoustic tiles are used in large offices and auditoriums to reduce the echo. The
effectiveness of tiles depends on their surface porosity and the extent to which pores are
interconnected.
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Conclusion
To conclude, both lime and gypsum topics were essential because it gave the student a better
understanding on their functionalities in buildings. At this point, the student has gained sufficient
knowledge that can now be applied for future purposes. Thus, the main goal was to give the lecturer
a summary on the main information being learnt about lime and gypsum in the construction
industry.
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References
European Norm En 12485. Chemicals used for the treatment of water intended for human
1996.
FRANK, G. Determining the reactivities of limes by means of the wet slaking curve. Zement-Kalk-
study of factors influencing lime slaking. Part I. Production and storage conditions. (In press)
Min. Eng.
study of factors influencing lime slaking. Part II. Chemical composition and water composition
POTGIETER, S.S., POTGIETER, J.H., and LEGODI, B. Proposed modifications to the method of