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4CH1 - 2C - Que - 20201121 TODAY.
4CH1 - 2C - Que - 20201121 TODAY.
Chemistry
Unit: 4CH1
Paper 2C
Instructions
• Use black ink or ball‑point pen.
• centre
Fill in the boxes at the top of this page with your name,
number and candidate number.
• Answer allthequestions.
Answer
• – there may bequestions in the spaces provided
more space than you need.
• Show all the steps in any calculations and state the units.
• mind about
Some questions must be answered with a cross in a box . If you change your
an answer, put a line through the box and then mark your new
answer with a cross .
Information
• The total mark for this paper is 70.
• The marks for each question are shown in brackets
– use this as a guide as to how much time to spend on each question.
Advice
• Read each question carefully before you start to answer it.
• Try toyour
Write answers neatly and in good English.
• Checkanswer every question.
• your answers if you have time at the end.
Turn over
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P62047A
©2020 Pearson Education Ltd.
1/1/1/1/1/1/1/
2
The Periodic Table of the Elements
1 2 3 4 5 6 7 0
1 4
H He
hydrogen helium
Key 1 2
23 24 27 28 31 32 35.5 40
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
11 12 13 14 15 16 17 18
39 40 45 48 51 52 55 56 59 59 63.5 65 70 73 75 79 80 84
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
85 88 89 91 93 96 [98] 101 103 106 108 112 115 119 122 128 127 131
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
133 137 139 178 181 184 186 190 192 195 197 201 204 207 209 [209] [210] [222]
Cs Ba La* Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium lanthanum hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
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55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
[223] [226] [227] [261] [262] [266] [264] [277] [268] [271] [272]
Fr Ra Ac* Rf Db Sg Bh Hs Mt Ds Rg Elements with atomic numbers 112–116 have been reported but not fully
francium radium actinium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium
authenticated
87 88 89 104 105 106 107 108 109 110 111
* The lanthanoids (atomic numbers 58–71) and the actinoids (atomic numbers 90–103) have been omitted.
The relative atomic masses of copper and chlorine have not been rounded to the nearest whole number.
BLANK PAGE
3
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Answer ALL questions.
(b) The student then uses this apparatus to obtain pure water from the salt solution.
water out
water in
flask
Z
salt solution
heat
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Y............................. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
(ii) State what remains in the flask when the separation is complete.
(1)
The student puts a small drop of each substance on the pencil line.
The diagram shows the student’s chromatogram at the end of the experiment.
solvent front
at end
pencil line
B R Y S T U V
solvent level
at start
(a) Which of the unknown substances contains only one food dye?
(1)
A substance S
B substance T
C substance U
D substance V
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Rf = ......................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
(ii) State how the chromatogram suggests that the yellow food dye Y is less soluble
in the solvent than the red food dye R.
(1)
(i) Identify the metal from the box that burns with a bright white flame.
(1)
(ii) In the Earth, metals are found either in ores or as uncombined elements.
Explain which metal from the box is most likely to be found as an
uncombined element.
(2)
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iron
lead
The method used to obtain a metal from its oxide depends on the reactivity of the metal.
Two possible methods are
Method 1 heating the metal oxide with carbon
Method 2 electrolysis
(b) Ethanol (C2H5OH) is an alcohol that can be obtained from glucose (C6H12O6).
(i) Name the process that converts glucose into ethanol.
(1)
(ii) Explain why this process is carried out in the absence of air and at a temperature
below 40 °C.
(4)
ethanoic acid C2H4O2
H H O
propanoic acid H C C C
H H O H
H H H O
C4H8O2 H C C C C
H H H O H
(d) The compounds in the table can react with alcohols to form esters.
When preparing esters, a small amount of concentrated sulfuric acid is also used.
(i) State the purpose of the acid.
(1)
(ii) Draw the displayed formula of the ester that forms when propanoic acid reacts
with ethanol.
(2)
property.......... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
................................ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................................................................................................................... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
H H
C C H
H C C
H H
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(ii) The equation for the reaction between butadiene and bromine can be shown
using displayed formulae.
H H
C C H H H H H
H C C + 2Br Br → H C C C C H
H H Br Br Br Br
Use this information to calculate the enthalpy change, ΔH, for the reaction.
Include a sign in your answer.
(4)
ΔH = ............... . . . . . . . . . . . . . . . . . kJ/mol
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(c) A scientist does an investigation to find out if butadiene would be a good fuel.
He burns a sample of butadiene gas and observes that carbon forms as black soot.
(i) Complete the equation to explain the scientist’s observation.
(1)
2C4H6 + 7O2 → .......... C + 4CO + 2CO2 + .......... H2 O
(ii) Explain how one of the products, other than carbon, may cause a problem.
(2)
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17
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6 A student is provided with a bottle containing a colourless solution X.
Solution X is thought to be dilute sulfuric acid of concentration 0.10 mol/dm3.
The student does some experiments on samples of solution X to try to show that it is
dilute sulfuric acid.
The student adds a few drops of litmus to a sample of solution X.
The litmus turns red.
(a) The student knows that the products of the electrolysis of dilute sulfuric acid are
hydrogen and oxygen.
She carries out the electrolysis using this apparatus.
oxygen
hydrogen
solution X
+ −
power supply
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(i) Suggest why the student does not use zinc electrodes in her experiment.
(1)
(ii) State what is observed at both the anode and the cathode during the electrolysis.
(1)
(iii) Which of these tests shows that the gas formed at the cathode is hydrogen?
(1)
A a glowing splint relights
B a burning splint gives a squeaky pop
C a burning splint goes out
D limewater turns cloudy
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21
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7 This question is about reactions involving gases.
(a) Potassium carbonate reacts with dilute hydrochloric acid to produce carbon dioxide gas.
The equation for the reaction is
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(i) Predict the effect on the yield of CO(g) at equilibrium when the temperature is
increased without changing the pressure.
Give a reason for your answer.
(2)
(ii) Predict the effect on the yield of CO(g) at equilibrium when the pressure is
increased without changing the temperature.
Give a reason for your answer.
(2)
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