LEARNING PACKAGE WEEK NUMBER 23 - February 8-13, 2021

Solutions are Everywhere

Name: Date Received:

Grade and Section: Date Submitted:
Subject:General Chemistry 2 Teacher’s Name:Mr.Patrick C. Andales Teacher’s Signature:

Standards: The learner…

Content: demonstrates an understanding of the properties of liquid and solids to the nature of forces between particles;
Performance : designs a simple investigation to determine the effect on boiling point when a solid is dissolved in water
Formation : does something when things observed to be disorder
Learning Outcomes/Objectives:
The learner…
1. explains the first law of thermodynamics; (MELC)
2. explains enthalpy of a reaction; (MELC)
3. calculates the change in enthalpy of a given reaction using Hess Law
4. makes a choice between an order or a disorder way of living 
PVMGOV: Produce self-disciplined, responsible, independent, cooperative and Christ-centered individuals.
21st Century Skills: Communication, Critical Thinking-and-Doing, Career and Learning Self-reliance
Introduction : This week you will be dealing with the changes of energy that accompany chemical transformations. The discussion
for this week are based on the principle of the first law of thermodynamics.Don’t forget to pray before and after doing your activity.
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Day 1-3
Core Content: Energy Changes in Chemical Reactions (Explore Activities)
1. How do you think people would survive if the chemical transformations do not occur with the absorption or release of energy?
2. What should people do to be able to support the activities that they need to do in order to survive?
3. How would they be able to get the energy that they need from the food they eat?
TS: All changes that matter undergoes, whether physical or chemical occur with loss or gain of energy. Let’s find out how these
changes being observed.
In-text Activities: (Firm-Up/Deepen Activities)
Thermodynamics is the study of the energy changes that accompany all processes , whether chemical or physical. The study of
energy changes that accompany chemical transformations in matter is referred to as thermochemistry.
The first law of thermodynamics, also known as the the law of conservation of energy, states that “energy cannot be created or
destroyed but can simply be converted to other forms of energy. It can also be written as ΔU = q+w where ΔU is the change in internal
energy of the system and is determined by the equation ΔU = Ufinal - Uinitial. The symbol q represents the heat absorbed or evolved by
the system. Its value is positive when heat is absorbed and negative when heat is evolved. The symbol w represents the work
performed by the system or on the system. Its value is negative when the system performs work on its surroundings and positive when
the surroundings perform work on the system.
HEAT OF FORMATION
Enthalpy is the total heat absorbed in a process at constant pressure if the only work done is pressure-volume work. It is the sum
of the internal energy of the system and the product of pressure and volume. Enthalpy can be describes by the equation H=U+PV.
Since pressure is constant, the change in enthalpy is given by ΔH = ΔU + PV
The heat of reaction or the heat change for a reaction is usually represented as change in enthalpy of a reaction ( ΔHreaction) since most
reactions take place under constant atmospheric pressure. The change in enthalpy of the reaction is the heat of reaction at constant
pressure. The standard heat of reaction, ΔH°reaction, can be evaluated from the heats of formation of the reactants and products in the
given chemical reaction. The heat of reaction measured at constant pressure (ΔH) and the heat of reaction measured at constant
volume (ΔU) are related to one another by the equation: ΔHreaction = ΔUreaction + Δ(pV) This can also be written as: ΔHreaction = ΔUreaction +
ΔngRT where ΔHreaction = ΔUf,reactants - ΔUf,products Δng = (number of moles of gaseous products) - (number of moles of gaseous
reactants)
In some instances, the reaction may becarried out indirectly, that is via several stepsbut with the resulting net reaction being
the desired chemical reaction. Since ΔH is a state function, the manner by whihc the reaction (change) is carried out is not important
and will therefore lead to the same value. According to Hess’ Law of heat summation, the enthalpy change of the overall process is
the sum of the enthalpy changes of the individual component steps. This can be illustrated by the following example:
Consider the following reactions:
Fe(s) + 1/2 O2(g) → FeO(s) ΔH° 25°C = 272.0 kJ Solution: Let us label the given equations (1) and (2)
2Fe(s) + 3/2 O2(g) → FeO3(s) ΔH° 25°C = 825.5 kJ Equation 1: Fe(s) + 1/2 O2(g) → FeO(s) ΔH° 25°C = 272.0 kJ
Determine ΔH° 25°C for the reaction 2FeO(s) + 1/2 O2(g) → Fe2O3(s) Equation 2: 2Fe(s) + 3/2 O2(g) → FeO3(s) ΔH° 25°C = 825.5 kJ

The final equation requires 2 moles of FeO which means we will multipy equation 1 and its enthalpy change by 2. However, FeO is
found in the first equation on the product side while we need it to be on the reactant side. This means we need to reverse the
reaction. To write the reaction in reverse form, we write the reactants on the product side and the products on the reactant side
then change the sign of the enthalpy change. We now get Equation 1: 2FeO (s) →2 Fe(s)+O2(g) ΔH° 25°C = [2x(-272.0 kJ)] = 544 kJ
Fe2O3(s) is already on the product side so we use equation 2 it is as given.
We can now combine Equation 1 with Equation 2:
Equation 1 : 2FeO(s) →2 Fe(s)+O2(g) ΔH° 25°C = 544 kJ
Equation 2 : 2Fe(s) + 3/2 O2(g) → FeO3(s) ΔH° 25°C = 825.5 kJ

This causes cancellation of Fe and 1 mole of O2, and we come up with

2Fe(s) + 1/2 O2(g) → Fe2O3(s) ΔH° 25°C = 544 kJ-825.5 kJ = -281.5 kJ
Closure: Use your energy wisely to become a productive student.
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Day 4
Use your paper in answering the quiz. Show your solution.

1. Calculate ΔH for the reaction 2C(s) + H2(g) →C2H2(g) using the following data:
1. H2(g) + 1/2 O2(g) →H2O(l) ΔH = -286 kJ
2. C(s) + O2(g) → CO2(g) ΔH = -394 kJ
3. C2H2(g) + 5/2 O2(g) → 2CO2(g) + H2O(l) ΔH = -1 300 kJ

2. Cite concrete example to expound the idea of first law of thermodynamics : “energy cannot be created or destroyed but can simply
be converted to other forms of energy”.

PVMGOV Integration)
When can you say that life is in disorder manner. What could you do to live with peace and order?

Summary: (Learning Outcomes/Objectives Check)

Indicate here the activity/ activities that made the competencies realized.

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Closure: Remember the 90-10 principle? May we not forget about it :)

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Day 5
Chinese New Year
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Resources/Materials: DLP 
Teaching Guide for SHS, CHED
          General Chemistry 2, Ilao, L., Lontoc, B., Paderna-Gayon,E.
         Basic Chemistry, Seese,W., Daub, W.
For questions or clarifications please reach me out with this number 09615378578 or through messenger @ Patrick Casquejo
Andales